KENDRIYA VIDYALAYA SANGATHAN: HYDERABAD REGION

MODEL QUESTION PAPER -2 2024-25

ANSWER KEY
CLASS : XII SUBJECT : CHEMISTRY (THEORY)

Q.No. Answers/Value points Marks

SECTION-A
1 d 1
2 a 1
3 b 1
4 c 1
5 c 1
6 a 1
7 d 1
8 b 1
9 d 1
10 a 1
11 d 1
12 c 1
13 a 1
14 c 1
15 c 1
16 b 1
SECTION-B
17 a) At anode - Ag dissolves ½
At cathode - Ag deposits ½
b) At anode - O2 gas is released ½
At cathode - H2 gas is released ½
18 a) Rate increases by 9 times 1
b) Rate increases by 8 times 1
19 sp3d2 , Octahedral geometry 1
Paramagnetic as 4 unpaired electrons are present 1
20 a) As AgCN is covalent compound, NPS takes place fromN atom with
lone pair of electrons. 1
b) Because the intermediate benzyl carbocation formed is stabilised by 1
resonance.
21 a) 4- Methylaniline < 3- Methylaniline < Aniline 1
b) Hoffmann Bromamide reaction , Ethanamine ½+½
OR
a) p- nitroaniline < Aniline < p- toluidine 1
b) CH3CH2N(CH3)2 1
SECTION – C
22 Cell reaction Mg(s) + Cu2+(aq) → Mg2+(aq) + Cu(s) ½
Correct Nernst equation ½
Correct substitution and calculation 1
Correct answer E0cell = 2.68 V 1
23 a) Correct integrated equations 1
Correct derivation 1
b) One difference OR 1
a) Reaction B as it has lower activation energy 1
b) Correct definition and example ½+½
c) Correct graph and slope = -Ea/2.303RT ½+½
24 a) Compound A - tert-Butyl bromide correct structure 1
Compound B - 2-Bromobutane correct structure 1
b) Compound B and reason 1
25 a) Correct equation 1
b) Correct equation 1
c) Correct equation 1
26 a) i) n- Hexane 1
ii) Gluconic acid 1
b) Glycogen 1
27 a) Diazotisation followed by reacton with warm water. 1
b) As aniline is basic and reacts with acid to form -R effect anilinium ion. 1
c) For both diazotisation followe by reaction with phenol- aniline gives 1
orange dye.
28 a) The -CONH- bond formed by condensation reaction between amino
acids in proteins is called as peptide linkage. 1
b) Because rate of metabolism increases and blood sugar decreases. 1
c) Testosterone and estradiol ½+½
SECTION –D
29 a) Correct statement 1
b) It is the conductance of all the ions produced from one mole of the
electrolyte. ½
Scm2mol-1 ½
c) 0.01 M CH3COOH 1
Molar conductivity increases with dilution. 1
OR
Correct formula and substitution 1
Λm0 CH3COOH = 390.5 Scm2mol-1 1

30 i) c 1
ii) [Fe(H2O)6]2+ < [Fe(CN)4(H2O)2]2- < [Fe(CN)6]4- 1
iii) t2g3eg2 and t2g5eg0 respectively 1+ 1
OR
Neat correct diagram 2
31 a) i) Correct statement 1
ii) Correct statement 1
b) ∆Tf = 0.34 K ½
correct formula ½
Substitution and calculation 1
MB = 182.35 g mol-1 1
OR
a) When pressure applied is greater than osmotic pressure 1
Use - Desalination of sea water 1
b) Correct formula ½
Substitution and calculation 1.5
Ps = 23.63 mm of Hg 1
32 A - CH3CH2COCH3 1
B - CH3CHOHCH2CH3 1
C - CH3CH=CHCH3 1
D - Butene ozonide 1
E - CH3CHO 1
OR
a) Due to lesser +I effect and lesser steric hinderance in CH3CHO 1
b) Mild oxidation with PCC followed by aldol condensation 1
c) Correct equation 1
d) Any one test 1
e) Oxidation by alk. KMnO4 1
33 a) As Mn2+ has more stable d5 electronic configuration 1
b) 5f orbitals are more poor shieders than 4f orbitals. 1
c) Co2+ 1
d) As the energy difference between 4s and 3d orbitals is less. 1
e) On increasing pH it changes to chromate solution. 1
f) Correct equation 1
g) Correct equation 1
Any 5 Any Five