Date

Expt.No. Page No. 27

chemiceal Reccient 2 Mn SO, t
LAim To Pes fosa the CASscy of hydogen Aesz0 cîde
Poteussium Potcs Suleneie
Clid
SulPhotepotessium
SI, +gHe0 Sulehacte Sohtion &to find nt Vohme stoegta of
Hae given somPle.
(Todine) Cuocter)
obseVelion Po3 KMnOy Refet Pnce DA, RS, elitus M. viAd M.Veghela,
Gutette o. N sodiun Hiusulphete DR, Hetel R. Breja Poti y areiccl s @n
Comicet
Plcis - 2S ml cpfocimetely . 02 MKMmoy, 2 g KI+ phetmacentlcel Ancuysis Mahecm
Tondic eto stasch Puste
Colvus change 3 Yellow to bue to 4Regul enents
colousless
+obseUatiom talale foh kmui A-Cseasscate i- Baraete, Coniccl Alesk , Pipette
Brreltte fnmel, Voumetic Aesk
Tecding Cmu) m) Avege slg- chemicculs HydsOgen Poide solM,20 vlu.
Fnal 34.40 reoding H,sou , O,02 MKAmo4
Tnitiel 35.20 35.00
O.00 O.00
DiMehence 34.90
3S.20 35.00
A)stcodcthdizcHon of PgePetaed O.02 MKMnO4 i
1 ml O.D NNOs0
0.00316 2 of Km
Tt Rs Possible to cscy H, (O, by many melhods
houeyeh, the 449ctfan uith kMnoy so utiong
hes been an easy &oficicl method.
Xsn 3,03Xxo.003l6 This detemminction depenas up on ocidlion
edction Hthtion.
H,0, 4enercaly acts cs Cm cocidiziny agent
X= 0.1|o6 gmofKno, becense {t ibesates O geadiy.Pat ehen it fs
cted aoitta acidiied KmnO Cstmge cridizing
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 Date
sohution contcins 0.||06 Expt.No.
Page No. 25
(000 md of KMno solutton coneins (7)
eLgent , t ccts cs c edueing
cgenta
25 S0KMnOu cidizeg
Molasity coeigkt in am x f seduced qets, shiah caseg deele 'decataizatn
MolecuteS welglbx v (I+) of ke4nOy sohdton. At he end Poiat iecess
= 4.42 4l xl
dsoP of KMnoy coill give Rink col
- [0.02% M 2Mn0 +GH* +sH, 2 Mnte +KHa0 tS0,
Hah concentction of aaid fs 1esead to paevent
chemi ccl Recclion oksH, U2 the fasmetion Of Mno, eohich may case
decomPosiHon of H,O,.
2 Mno +6H*45H, 0, 2Mn 4s Heo tSO,
thydbesen) (onsnetate) (Oxizen)
Cs
volume stength i
(Pemengumate) Peocid e
The Vohume stsengta of the sohtion Ps the mnbe
LOE nl of 0cygem at STP thet com be obtoned by
Cornplete thermul decomposiom of 1 ml of sohion
Bursette ?0.02 MKMmoy
Gonical
Plusk - 1 me o Hz02t 20 m IM Has0
Tndiccatan BMne self- indicata hydngen Pesocide :
Cdous cherge- Asele to An oficicl sopmele of dlhte
colousless to Pínk. Soliom Comtcuns6 7 H,0 C20 vol.).
*oloseVation teulole fo H,o, Pzocede
Bysette
Seuding Len) A) Pseperction ofa Stcmdsdization ofo.02 MKCm,
Auscige Pes,YMCmqanate sahtion
Fincl 31.90 3200 Tedimg 0 25 m0 oP Potcssium add 2 q of PoteSSiuA
Tnitial 0,00 32.0 Inc qleas s Stoppesed Alesk
32:3 lodine wiHa co.N
Difeence 31,40 32.00 32.SD acid TTAzcate the libezcated meetach Gchtioa.
Haiosulpaete ueimg 3
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 Dale
Expt.No.
Page No. 29

gm ofHo, uddedtorocds ttae end af the

Jml o.02 M KMno0. 00|40|
gm oF Ha0, iadiccto.sa
e Pe hation ,cs cm
32.13 md O.02MKMmO, (x) fo szm the blamk deleamimcatiom.
X m= 0,00ltol x 32.13x O 024 AAssay oF hydo gen er0oide
0. 02 piPette
sohaiaat
ut1 md of SamPle Cod cdd 20 m
M H, SO clod Hthate eoita o,o2 M HMnlee
7 ml of Sample solutfon contcains 0. 04596 gn of
He
S0, 400md ol ample solution contcim (l)

Voume shaength

Y= 324. 2 X0,0459
1

&Aesult
5 The
+,61.Geszcentage%olu
of H,0,. Dag
Cimd volme stoength toas foumd to be
24.48 m

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 Date
Expt.No.
Page No. 30

To
fertus detese
Fet2 Fets 4e fAim the PeS,Centoge Pusty C% wlw) of
(Fesous ion) (Fesic ton) Sulehcrte
Ce'ie ce'
Ccetic ton) (cepus ton) Refezes0e. Raua HrbalAanio oL shoh A, Pscaucica
in inasgarmlc and Cnaky4tcel chenistsg
Aisc and Raoel pSzcalkorghaun seet edHon.
(Fevoin sulehate) fage Ao, - t66-I69.
LxRequiseonent
bach n cf O.lM cesuc cmrnenNm mitrate o,02?%0l 1 HA-Crlcss cwcusek Bussettemecsusing cyltodesbeaket
of FesoyHz0, Pipete ,Conical Acsk.
Deicon Of a Facto i B- chemicls -Galibn bicasboncte, sulphusic octd
fessons Sulphate comple, OlMce ic coano
1 mole of cessi Canmonim nitote mam nitzete feshoin.
1mnole Fes
Ecuch nl o.lM CehiC Pincple - The Pinciele invoved in the deteaoinetiaalàn.
nmoni°m nithote o.02KOlFeso3oF of fesat0nLS SulPhate s cehsic hedosc
qcidic nedia.
nget, in
robseuttoni Fe-91018 5ulehate,c gaedhicing
is 4zated
oNHNO
coth ceic ammanium mitcte ashene
Buszete 0.\ Cessic CeCaso),suH,o sing fesron as am îdicatas
Coniccl - 2.S crmrenium mi,oste coloucharnges foeonmSued to Pale blue. çesic.
FesOy NaHCo, lond
Flusk t mitatecin cidizing agent is used
Licaor i Fesuoin Sulphusuc acid t 0.4 I Clmmoni
aeconse -in netsal conditorn
ny n acidic mmedia bagic 5olHs Paecipitate cut Cos.sid
colous - Red to Ces-sic hudsode os yello) im_ Colcus, hense
Chenge Pale blue i0nsoh1tion is iatense intencd sedoxe
Can be mceased hy addion oFessoim sulehoto fa
ndicotoh ike £esumim Sarlehte pf t
combinction
coxoplesc osamed by
aed Colos, SulPhote. Afteg,
-phenonhaollone coih fos.uuS
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 Date

Expt. No. Page No. 31

obsetalion tablei enilalent point the nect dsuoP o! cestnic Camoniun

loidcte Ocidze fesszoin sulehce to coe Ponding
Buette
eudin
TL
()
Aveage
Teading Cn) oth-phenanthkoline -Rsuon C) melec, ohich is
Fincl 14.90 Pale blae in colo,..
14.70
Iniiol
DifereTmce
0.00
14.70
0.00

l4.90
o. 00
(S.10
|4.9OGn) AP0ce chuSe

rimution of fes,s, 0n1 sulebacte &

Dissoue 2.r fesseak Stelaedte- · sodium loBce9loancte
Each ml a)M cessic cmonium nithote ia mihise af Iso ml alotes, cnd lo ml suleusic acid
0.02ro| 90f SulPhete
14.90 ml o.lM Cesic oamnium nitate Feso, when eHesvengcense cecLses add. O.y g fessue
(R) of Fego, cccUsately coeighed shake qeataly to dissoe cnd
- 44.9Ox0.| XO.02%0l coRth OM ceic cmnum mit.orte usimg
4ts.cute
0.4142 3of Feso, nil colo changes fom med to Pole blue
Eachml of QlM cesic cnnonilm its.ccte is
’Poscentese
O.4 9
Pusity
Sample contims =0.4142 g of
loo 9 samPle Fego
= |00x 0.4142Comtairy () Conclusion
O.4
= (03 %, contains mot legs han 9% ?o dnd
o of Feso Fesous Salehete
Cas Pes IP 200t.
Resut - These fose,Hhe qiven test soanple Cozmplieg do not
Complieg in the test usity nccoSdin9 4o TP 200.
The 9iven Sumple contain
l0g % ol of Feso,.

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 Date
Expt.No.
Page No. 32
t chesiced 6encton
Aio Q.IM_sive
Agel t NanNO,
AgNo, + Nael sodium
Sodium) /silve
(silve oitoste
Chloside. chloside A Re lezen0e i Rvl HUr Reuldanic
nitscte S.L shaa D.A
2A900g + ha ChO
foBessim 3? vez
chsomate. chsomete) Htet edilion PeaeU, - 9K- 200.
miHote
42Ht 2HCSO,C,O tH, 0 Reie ment

(chsemete)
Rom
Arpzets setteQoniccl Poskme0nning
cylinde, beohespîPelte.
chenicalg Sodam caloside sive, mitsodte
Poteseium chson0cte swND).
Each ni of o.[M sive nitscte is euival ent t0

to ctmosphesic
sves mtscte cohen ecposed geducllon 0 1etalic.
I mole of AgNo 1mole of Nucl iis qete duken duemitscteto
solhtiorn shauld be
sives. Hence sive,stexmdusdization o Agnoa ic
Gcmdcue dized, oith Ps ima1y stendeod
Eachm o.lM Ag0, 90.005K Pes.fosanmed to its diteuction a PreciPitete of
Aact.
3 of Nacl COmPOumd acl which fosm been 4itoded tae
hee
hencl Hhechlaside mitsate eacts oh Potuseiunm
enesct d9oP of silves OOImge med coloszed silwes,
chomocte cod giveg adicoting the emd Point.
Chsconte comelesc CndPaint detecton k
The netaod imvovinq
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tobseVedlon' Expt.No. Date

Page No. 33
Bustete PePoted AgNo, solufo choomcte CoCte,
Conical
flask - lCalled Potcecim
Mohi's chomotp
foeciPitcdiocLsm cm indlcoctosr
Of
AsclRs ComPlete)
îs
Rcction rectpi4otion 4tsodiom 44Sart
melhod sIhe
Tndicata3- Po tcagsim chomate celled 9gen
Hmetsic dsoiom.
Colose colouteless t0 0cnge Mohsi's tciom chnld be Pes ogned in
clenge Ted alkale condiion fPH Gat 9)o o natal as
follocoing
HeSe chate mection tekes plece. aidtc condiion
tt obse ion acte CL cn aoid
Vedion teable - mty chhomate ion
cOncontsuot ?om
Cmd COM SeRE
eccllon minctee ood end geduces tn Ahe
Busete mot be Bopes Tn hiahly
Polat detecion may
seading
Trnal
Lem) Aveoae stves,
hdoocide gede
clkeltne onditton
poecipiteted
TntHal
U3.40
0.00 350 seodin? Pocedate
0.00 0.00
Difeence. 43.40
44.00
43x0
43.73
PsefcetRon nt o.M 'Silves mitzarte -
Dissove .44 oe ailves nitote in S1cienf
0etes în coniccl flosk, to poodoe oo mla
stemdedizadion of silves nitote aahtfon:
Weiah D24of Naal cnd dssove it tn 2nd

Saldion Qni calor chamges to 0Seamge Sed

Eaeh m o o.lM Sies, nitsote ?s emuivclent
to

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 Dat:

Page No34

-As caltlrlien
ICCO n
Each
9 cfNacl
63.33 m! ()M A'C, C.,2
Mclutiy cf Agcey - 0. 2 xC.,|
43.13 xO,005R4

M AgNo

Resut
nolesity cf given A9NG, scheton is o.0t .

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 Date
Expt.No.

Aacion?
ntz (2nc)+2Ht
Page No.
+ CH,x)- To
Paepcae Ond stamdosdize
einc
d'sodin ComPlec Hydbwgen
ion
edetote Soion accosding 'O.0sA disodum
to TP 200t
EoTA
Qeleence Raucd H.g Boldonic SL
In inotgantc aod shh DA. Pucicle
Each mm of O.osM ti'sodim ede tate
o.003279ozine Cnd RoOPal cnatukcot chemist, Niad
Bokosthon Cst ediion e NO-213-2|s.
1 mole of disodium edetate gects coith mole of zine
(o00 ml of 1M disodiym edeteate APRAhcrts i- Buszete coniced Closk,
|000 n Of o.os M
s.34 3 o zino
d'sodim edetete 9 3.26& 3 of zinc meisubing cylndes beakesVolumeticAlask
Eaoh mi f o,0s Mdisodium
edetade g.00327 3 of zinc chemicls i zinc qaumules, dfsolium edetote dihte hydzo
chlosic dcid 2 M Sodam
obse Vaion - bufes, pH I0, moadunt hleuck hydsocide.
TL mictuhe
1cmmonia
Busette - Poefosed
disodium edelate sotiom
Conical 25+ ml of solufion
flusk (o.s 3 of zinc +2n of The Psncple nvolved Rom Hhe
meb9omine
of Oete coate+ gufcient cocte to mke diuteHel semdaszdizctfon f
disodimm edetate i's complesco metsic ittet ion . Disodimg
t
Tndiccts 3- ammomta laufe pH 10. 2s0nlIso eleBate îs not a pimaty gkndatd beccee ?t Contalnea
Colou MOSdant baak IL toce camomt of moishise cmd i4 is aNuilculale ag dlihydote
change Violet to g9ee oSodim edetate Ps slemdedized aoiHh Puse zinc
4zormules. zinc 9szomles ate dissolved in hydzochlosic
acid emd titscted coith disodium edetode in alholine
medic using nadent bleck TI as indiCatos Besie
ation zinc os1ms metad imdiato CommPle ImRodig
Ged colou9,to he sohton, Dusing tsodBon,meBad
osms somplesc mith EDTA Cnd Altde indicatos 3efe
ibaated, AL Hae exnd Pont all the indicotor set Greel
ich imnPesds gszeen colos otae goludiom. Aomcaía
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 Date

Expt.No, Page No.

obse Valion teble r

bufles pH I0 s added im Hhe tsodion
Aveoge lalkoline medto
Pusete
secding (nt) () (ml) ecading DFb fncsecsing the sleabilityol metal elefate comlec by
netrclizotfon of Psotoms lbected dnsimg comPlec
220
Fncl 2%, 00
28.|0 Conatfon reacions.
0.00
0.00
6 The colos, change of m0sudamt blcak T indicoto is visible
Tnilial 0.00 2&./0
2.20 Poa alkaline medic (eH4H) as Hhe indicod as, palynekiz es
oifeence 28.00
oned bubOm Po0dauct in stomaly eucidic me dia.
&B0cedhe
Eaah m of o.05 Mdisodium edetate =0.0022? of nc o PrePuzat'on of 0.0M disolium edetate soution:
Dissolve &G19 of disodiym edetcate in Suficient cOcte
oF X M disodrum edefote =0.0& 3 of zinc to Podce
X= O. 0& xO.OS F slemdesdizcion of Q.0r disodium edetote soluion:
230 X0,00324 Weiah acescrtel albout o.cg of q90.mulated zinc dissove
by gete csming in l2 md of dihute hydzo chlosic aid
x= 0.0435 M| lCad o,lml of b0Tmine GOCrte. Boil to oemove eccese
bonime,cool cmd add suftciend ates to Ps.cduce
Aesutt 2s0.m pirette 2rml of the Szesling solution nto u
250 ml Comical flcusk cnd nely nenttsolize aoith 2M
’ The
nolcsity of Sodamm hyclsoncide Soltion Dihte to about so nl aoHa
be o.o43S M Prefed EoTA souion fs found to GDatesodd uficient Canonic buffes, pH lO to dissove
tae zecipitote amd cdd s ml in bcces. Addso m4
o moszdcrat black I mictue amd tsete coithtunsHhe
disodium edetcte solhiom mlil Hhe sohutlom
zeen. Ech md of O.0SM disodium eletate ?s e9uivculent

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Expt.No.
Page No.

Aing o deteanine % usity Cy cal00) of calcium 4luconcte

Cat + CH,x hylsoen
disaiu
cccosrding to TP 200t.
Calsium jon
ion EDTA
XRefesence i Hr Rovcd isL Bcldootc Dinc A. shoih Poractcles
in in0Aenic dnd cmals<icol chemisty isAV K
Euch ml of C,0S Mdisodiurm edette O. 0224 g of Calcim RooPad okoglhon,Ci &t edlon,hge no. i-216 -21%e
Slu concte
Deivatton of Factos 3
eacts cotth I n0le of calcvn
1 mo le of disodim edetate slucosate APPcutus & Buzete conicol losk, Beoke P0rete
lo00 m of 1M disoum edette 4ug of calcium gluconate chemicls - Celcim ghicomete , 0.0S Mdisodim) edetote,
tooo m of o,05 M disodium eBette 9 22,4 q of Calciyn guConate Cmmonic, magnesitm Suehote, matdunt black IL
Each mg of O.05M disodiUm edetode o, o22u Y of cal ciunm
3hconete iniele
The Pinciple involved in the eslipa tom of colcum
qluconcte is sbeitukon compleCometic ktxutton. Suls
Bubuette - Stundoêud'eed tution ttfoms mse Cus9ied Qt fo Hhose metol îons
Hact donot geact 0 geoc yn satiseuctoily coita metal
Conicul O.53 of colctum shconote tsoml Lkadicotos,, WIHa epect to colciun ghuconote,Calciun fona
Ckusk Sml of magmegium
SulPhate
of Sn
3ohuton eoct em sotisfactosily cotth mahdeunt blouk I hadicoos cod
Tndicate Rosm elolively gmoae -sBeale complesc coitth ED TA, Tn eslina
Mosidcrt black.L HRen of calcium qluconcte smagnes titn ioms Qge cadded m
Co(cu
Chonge ;- ged eome to blue Small amourat oich fosag stelale mcgnesium fadicoda Cocn
ler ismoe seable thon calcium fndicot097 ComPleocbnt legs
stable 62a_ncgnesiun edekde complesc Hence dusaing ttaaL
Hon o calcizon ions, Ep TA Aat eccts eotacalcium and
mcgmegium ions. Bt calcium edetote comPleg is ooe slele
Hacin masnesin edeBcte complec cmd hence aalctum
Calcium of magmesiumiong foang
tons
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 Iypt No.

ANezce 9ued maestren ndicaBos, cornteles ahlck Jeacs olll exei

Buglle n) neoulhy lof EDIA nl he Cnd tolot to ltbes,ale fuee fudtcealor (l,lue in
l4,00
(4,003.00 lcola). Vahkne ol discdiun vdekale hrnce uacd is codccled lbs
l4.00 4he slsht cnnount of megesluo tona lo giue el Cntnt
0.00 0.00
0.00 0ebcd fo0 calcinm ons defebmiealfo.Aomunla sehiliun
(3.00
Difeene |4.00 /t. 00 Rs added othe bad forn pacess fos, teaNidns clkol e edka
0 fos. nseosing 4he clelility of vnold cdetate rootle
AcaleulaBion; by mcudsaltealion clons ILe oled thusng contlet.
’Blqmk= ml
osrnationL oeacions.
’ Cach md of o. os M diso diunn edeBte a0. 022(,2 9 oF CzBt,c ) The colosz charnge of TA0hdont black IL (ndicet o9, is visiLle
in allkulne neAia CPH 1) as he adicalus polsoelees
(y-) ml of M Motee Of disodium edefete y zq to ed böxown Poduc! pn ctsvngl acidic zncta.

APcceu9e Llimyylin of calciurn gluconale ?

O,0s weish acuratelg x4 of calciuen gh (onate md dissolve 1n
(s0-14) x0.058 x0, 02242
O,os
49cle oifh o.os M disoditen delate uaig so09uaal Llack IL
0,356| sof Calcium alhucemate
0.5 9n Ganple con toim'= c | discdiusn cdeBcde sohulion 09 snCnlioncd n revicug fsrac lked,
to0 gn SarnPle (öntan = (9)
- |00x 0.358| 4sucLct he voluzoe cf he maresi°n sulfhate chdfon odded
O.S Cos Poltsn blank tGatfom by CantH?rg Calchrca ghuanate).

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 Date

Expt. No. Page No. 39

Comcusion:

As Pes TP 2001 Calcan_ gh1camate conteins mot less

Hacanq Aamd mot m0ne tHhan lo2., of CoLleium
auconate calalated aoith neo,enceta dszie à Gule
lslemce Theelosp the qiven test sunn le compItes
donot Conelie fn Hae test o, Puszty cccosdng

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