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Revision Assignment Class 12, For Term 1 Syllabus Chapterwise

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15 views2 pages

Revision Assignment Class 12, For Term 1 Syllabus Chapterwise

Uploaded by

nityamaggarwal566566
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Q.

Calculate the emf of the cell in which the following reaction takes place:
Ni(s)+2Ag+ (0.002 M) -> Ni2+ (0.160 M)+2Ag(s) Given that E(-)(cell) = 1.05 V .
Q.Why does the conductivity of a solution decrease with dilution?
Q.The molar conductivity of 0.025 mol L-1 methanoic acid is 46.1 S cm2 mol-1.
Calculate its degree of dissociation and dissociation constant Given λ°(H+)=349.6 S
cm2 mol-1 andλ°(HCOO-) = 54.6 S cm2 mol-1
Q.Write the chemistry of recharging the lead storage battery, highlighting all the
materials that are involved during recharging.
Q.How much charge is required for the following reductions:
(i) 1 mol of Al3+ to Al?
(ii) 1 mol of Cu2+ to Cu ?
(iii) 1 mol of Mn04- to Mn2+?
Q.A first order reaction has a rate constant 1.15 x 10-3 s-1. How long will 5 g of this
reactant take to reduce to 3 g?
Q.The rate of the chemical reaction doubles for and increase of 10 K in absolute
temperature from 298 K. Calculate Ea.
Q.2.7. Henry’s law constant for CO2 in water is 1.67 x 108 Pa at 298 K. Calculate the
quantity of CO2 in 500 mL of soda water when packed under 2.5 atm CO2 pressure at
298 K.
Q.Why do gases always tend to be less soluble in liquids as the temperature is raised?
Q. According to Raoult’s law, what is meant by positive and negative deviaitions
and how is the sign of ∆solH related to positive and negative deviations from Raoult’s
law?
Q.Which is a stronger reducing agent Cr2+ or Fe2+ and why?
Q.Explain giving reasons:
(i)Transition metals and many of their compounds show paramagnetic behaviour.
(ii)The enthalpies of atomisation of the transition metals are high.
(iii)The transition metals generally form coloured compounds.
(iv)Transition metals and their many compounds act as good catalyst
Q.Describe the preparation of potassium permanganate. How does the acidified
permanganate solution react with (i) iron (II) ions (ii) S02 and (iii) oxalic acid? Write the
ionic, equations for the reactions.
Q.How would you account for the following:
(i) Of the d4 species, Cr2+ is strongly reducing while manganese (III) is strongly
oxidizing.
(ii) Cobalt (II) is stable in aqueous solution but in the presence of complexing reagents
it is easily oxidised.
(iii) The d1 configuration is very unstable in ions.
Q.Draw the structures of major monohalo products in each of the following reactions:

Q.Arrange each set of compounds in order of increasing boiling points :


(i) Bromomethane, bromoform, chloromethane, dibromomethane
(ii) 1- Chloropropane, isopropylchloride, 1- chlorobutane.
Q.Which alkyl halide from the following pairs would you expect to react more rapidly
by an SN2 mechanism? Explain your answer.

Q. Predict all the alkenes that would be formed by dehydrohalogenation of the


following halides with sodium ethoxide in ethanol and identify the major alkene:
(I) 1-Bromo-l-methylcyclohexane
(ii) 2-Chloro-2-methylbutane.
(iii) 2,2,3-Trimethyl-3-bromopentane.
R. How will you bring about the following conversions?
(I) Ethanol to but-l-yne.
(ii) Ethane to bromoethene
(iii) Propene to 1-nitropropane
(iv) Toluene to benzyl alcohol
(v) Propene to propyne
(vi) Ethanol to ethyl fluoride
(vii) Bromomethane to propanone
(viii) But-l-ene to but-2-ene
(ix) 1-Chlorobutane to n-octane
(x) Benzene to biphenyl
Q.Explain why the dipole moment of chlorobenzene is lower than that of cyclohexyl
chloride?
Q. Primary alkyl halide C4H9Br (a) reacted with alcoholic KOH to give compound (b)
Compound (b) is reacted, with HBr to give (c) which is an isomer of (a). When (a) is
reacted with sodium metal it give compound (d), C8H18 which is different from the
compound formed when n-butyl bromide is reacted with sodium. Give the structural
formula of (a) and write the equations for all the reactions.
Q.The standard electrode potential for Daniel cell is 1.1 V. Write the overall reaction and
Calculate the standard Gibbs energy for the cell reaction. (F = 96,500 C mol-1)
Q.Give chemical test to distinguish between the following pair of compounds :
Chloroform and Carbon tetrachloride
Q.For a chemical reaction R → P, the variation in the concentration (R) vs time (t) plot
is given as-
(i) Predict the order of the reaction.
(ii) What is the slope of the curve?

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