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Ut 1 Xii (Chem)

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10 views2 pages

Ut 1 Xii (Chem)

Uploaded by

shauryabhardwaj192s
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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ATOMIC ENERGY CENTERAL SCHOOL, NARORA

FIRST UNIT TEST 2024-2025


CLASS: XII SUBJECT: CHEMISTRY MAX. MARKS: 35 TIME: 90 Min.

Note:
1. Section A: Q.No.1. contains 4 MCQ type of questions carrying 1 mark each & Q. No. 2
contains 4 very short answer type of questions carrying 1 mark each.
2. Section B: Q. No. 3 to Q. No. 9 contains 7 short answer type of questions carrying 2 marks
each.
3. Section C: Q. No. 10 and Q. No.11 contains 2 short answer type of questions carrying 3
marks each.
4. Section D: Q. No. 12 and Q. No. 13 contains 2 long answer type of questions carrying 4
marks each
SECTION A

Q. 1. Choose the appropriate answer from the given alternatives 4 marks


(i) The best method for preparation of alkyl fluoride is
(a) Finkelstein reaction (b) Swartz reaction
(c) free radical fluorination (d) Sandmeyer’s reaction
(ii) Ethers react with cold and conc. H2SO4 to form
(a) Oxonium salts (b) alkene (c) alkoxide (d) alcohol
(iii) Which of the following 0.1M aqueous solutions will exert higher osmotic pressure?
(a) NaCl (b) BaCl2 (c) MgSO4 (d) Al2(SO4)3
HBr alc.KOH
iv) CH3-CH=CH2 --------------- A ------------------ B
Peroxide
In the above reaction , the product B is

(a) N-propyl alcohol (b) isopropyl alcohol (c) propene (d) propane
Q.2. Answer in one or two sentences. 1 x 4 = 4 marks
(i) Write IUPAC name of t-butyl alcohol
(ii) What is racemic mixture?
(iii) Give the characterstic test for phenols.
(iv) Arrange the following compounds in order of their increasing boiling points:
n-butyl alcohol, tert-butyl alcohol, isobutyl alcohol
SECTION : B
Answer any five of the following. 2 x 5 = 10 marks
Q.3. Convert: a) Bromoethane to ethoxyethane
b) ethyl bromide to ethyl isocyanide
Q.4.Define: a) osmosis b) isotonic solution
Q.5.How will you prepare
a) picric acid from phenol
b) ethanol from methanal
Q.6. Explain optical isomerism in 2-chlorobutane
Q.7. Calculate molar mass of a solute if a solution is prepared by dissolving 0.822g of it in
300 ml of water has an osmotic pressure 0.961atm at 298K.
Q.8. State: a) Henry’s law b) Raoult’s law
Q.9. Explain : a) Wurtz-fittig reaction
b) Kolbe’s reaction
SECTION: C
Answer any one of the following: 3 x 1 = 3 mark
Q.10. Write the structural formula of Pentan-1,4 -diol
Write the reaction showing major and minor products formed by Saytzeff’s rule, on
heating butan-2-ol with conc. Sulphuric acid.
Q.11. Write the structural formula of 3-Methoxyhexane
Give the equations of reactions for the preparation of phenol from cumene.
SECTION: D
Answer any one of the following: 4 x 1 = 4 mark
Q.12. a) Derive the relation between elevation of boiling point and molar mass of solute.
b) The normal boiling point of ethyl acetate is 77.06 °C. A solution of 50 g of non-
volatile solution 150 g of ethyl acetate boils at 84.27 °C. Evaluate the molar mass of
solute if Kb=2.77 °CKg/mol
Q.13. a) Using Raoult’s law, how will you show that ∆P= P10 x2.
b) A solution is prepared by dissolving 394 g of a non-volatile solute in 622 g of
water. The vapour pressure of solution is found to be 30.74mm Hg at 30°C. If vapour
pressure of water at 30°C is 31.8mm Hg, what is the molar mass of solute?

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