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Chep202 MS

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21 views5 pages

Chep202 MS

Uploaded by

leviackermanop1991
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© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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CHEP202 MS

KENDRIYA VIDYALAYA SANGATHAN ERNAKULAM REGION


PRE BOARD EXAMINATION – 2022-23
CLASS XII
SUBJECT – CHEMISTRY (043)
MARKING SCHEME

Section A (1m each)


1. B
2. C
3. C
4. D
5. D
6. C
7. D
8. C
9. C
10. A
11. D
12. B
13. D
14. C
15. III
16. IV
17. II
18. II
Section B

19. : reacts faster by SN1 mechanism ……………………………………………1m


it is a tertiary halide and it produces a stable tertiary carbocation….1m
20. t99% = 2.303 log (100/0.1) ------(1) ………1/2m
k
t1/2 = 0.693 ------(2) ………1/2m
k
t99%/ t1/2 = 6.909/0.693 = 10 ………..1m
21. A Each name rn:. Explanation and eqn ………………1m
or
B. Each name rn: Explanation and eqn ………………1m
22. According to Arrhenius eqn,
log k = log A - Ea ……………1/2m
2.303 RT
log k = 14.34 – 1.25 × 104K/T
comparing both the equations:
Ea = 1.25 x 104 …………….1/2m
2.303 R
Ea = 2.303 x 8.314 x 1.25 x 104
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= 239.34 kJ/mol ……………1m

23

24

25. 1m each for the correct equations


Section C
26. Since MgS04 is an ionic compound, so undergoes complete ionisation in the following way:
MgS04(aq) → Mg2+(aq) + SO42-(aq)
i= no. of particles after dissociation = 2/1 = 2 ……. 1m
no. of particles before dissociation
∆ Tb = i Kb m = i Kb W2 x 1000 = 2 x 0.52 x 4 x 1000 = 0.346K …….1m
M2 x W2 120 x 100
Boiling point of water = 373.15 K
Tb= Tb° + ΔTb = 373.15 K + 0.346 = 373.496 K ………..1m

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27. (i) structures of cis and trans isomers (½ m each)
(ii) Electronic configuration for d4 ion if Δ0 < P is t2g3eg1 (high spin complex is formed)…….1m
(iii) [Ni(H2O)6]2+ is an outer orbital complex due to weak field ligand H2O and the presence of unpaired
electrons undergoes d—d transition (by absorbing red light and shows green colour) while [Ni(CN)4]2- is an
inner orbital complex and has no unpaired electrons hence colourless………….1m
28. (a) Chlorobenzene has lower dipole moment than cyclohexyl chloride due to lower magnitude of -ve charge
on the Cl atom and shorter C – Cl distance. Due to greater S-character, a sp2-hybrid carbon is more
electronegative than a sp3-hybrid carbon. Therefore, the sp2-hybrid carbon of C – Cl bond in chlorobenzene has
less tendency to release electrons to Cl than a sp3 hybrid carbon of cyclohexyl chloride. 1m
(b) Alkyl halides and polar molecules are held together by dipole-dipole interaction. The molecules of H2O are
held together by H- bonds. Since the new forces of attraction between water and alkyl halide molecules are
weaker than the forces of attraction already existing between alkyl halide-alkyl halide molecules and water-
water molecules, therefore alkyl halides are immiscible (not soluble) with water. 1m
(c) n-Butyl bromide has higher boiling point than 30-Butyl bromide because it has larger surface area hence
have more Van der Waals’ forces. 1m
29. a. CH3—NH2 has higher boiling point than (CH3)3N. (1/2m)
Reason: CH3—NH2 shows strong intermolecular H bonding whereas (CH3)3N has weak dipole dipole forces.
1/2m
b. A = CH3-CH2-CN, Propanenitrile ….½ m each
B = CH3-CH2- CH2- NH2, Propanamine …..½ each

30. mechanism with three steps: 1m for each step


31. 1. Lactose. 1m
2. Globular protein. 1m
3. Phosphodiester linkage 1m
4. Vitamin K. 1m

32. i) (b) 0.174 1m


ii) (a) I 1m
iii) (a) ideal solution 1m
iv) (c) 0.734 1m

33. a. m = 1.5g, I = 1.5A, Molar mass = 108 g/mol, 1F = 96500C/mol


m = zIt …………………………1/2 m
1.5 = 108 x 1.5 t ………………………….1m
1 x 96500
t = 893s …………………………1/2 m

b. Fe Fe2+ + 2e
+
2H + 2e H2
Fe + 2H+ Fe2+ + H2
n = 2 …………1/2m
E0cell = 0.00 – (-0.44) = 0.44V ……………………1/2m
Ecell = E0cell – 0.0591 log[Fe2+] …………………..1/2m
2 [H+]2
= 0.44 - 0.0591 log[10-3]
2 [10-2]2
= 0.4105V ----------------------1/2m

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c. Primary cell. It has more efficiency and its voltage remains constant over a longer period of time.1m

34. (a) In transition elements, there are large number of unpaired electrons in their atoms, thus they have a
stronger inter atomic interaction and thereby stronger bonding between the atoms. Due to this they have high
enthalpies of atomization. ……..1m
(b) Due to variable valency and the availability of d-orbitals, they can easily form intermediate products which
are converted to products. The sizes of transition metal atoms and ions are also favourable for transition
complex formation with the reactants. They can adsorb reactants on their surface and catalyze reactions...1m
(c) Divalent ion with atomic number 26 is Fe2+
Electronic conf of Fe2+ - [Ar] 3d6
No. of unpaired e (n) = 4
µ = √𝑛(𝑛 + 2) = √24 =4.9 BM …………1m

1m each
35 A. a. The only o-substituted aromatic aldehyde having molecular formula which show the given reactions is
C9H10O is o-ethyl benzaldehyde or 2-Ethyl benzaldehyde………………….1m
Eqn for reaction with Tollen’s reagent ……………..1/2m
Eqn for reaction with 2,4-DNP …………………1/2m
Eqn for Cannizaro reaction of the identified compound …………….1m
b. 1mark each
OR
B. : a. A - Butyl butanoate CH3CH2CH2COOC4H9 ….1/2 m
B - Butanoic acid C3H7COOH ….1/2 m
C - But-l-ene CH3CH2CH= CH2 ….1/2 m

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b. i) Iodoform test- Propanone gives yellow ppt with NaOH and I2 whereas propanal does not react. (1m)
ii) NaHCO3 test / Neutral FeCl3 test- mention the characteristic change observed. (1m)

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