Solution
Solution
4001CJA101021240048 JA
PART-1 : PHYSICS
SECTION-I (i)
1) Water coming out of the mouth of a tap and falling vertically in streamline flow forms a tapering
column, i.e., the area of cross-section of the liquid column goes on decreasing as it moves down, the
As the water moves down, its speed increases and hence its pressure decreases. It is then
(A)
compressed by the atmosphere
Falling water tries to reach a terminal velocity and hence reduces the area of cross-section to
(B)
balance upward and downward forces
The mass of water flowing past any cross-section must remain constant. Also, water is almost
(C)
incompressible. Hence, the rate of volume flow must remain constant.
(D) The surface tension causes the exposed surface area of the liquid to decrease continuously
2) A gas is filled in different spherical balloons in vacuum, each with n moles of an ideal gas at
temperature T. Radius of a balloon is r. The stress in the walls of the balloon is
(A) Independent of r
(B) Inversely proportional to r2
(C) Inversely proportional to r
(D) Proportional to r2
3) An alloy of two metals is formed by taking their equal masses and it was found to float on mercury
(density 13.6 g cm–3) with 52.7% above the mercury surface. When an alloy is formed by taking equal
volumes of these two metals it was found to float on mercury with 51.5 % of its volume below the
surface of mercury. The densities of the two metals in g cm–3 are closest to
(A) 6 and 8
(B) 5 and 9
(C) 4.5 and 9.5
(D) 4 and 10
4) At the disposal of a physicist, there are two thermal reservoirs - very hot with temperatures 227
°C and just hot with temperatures 77 °C. Physicist is told to run a refrigerator by extracting 2000 J
from just hot body. What is the minimum mechanical work he'll have to do? The heat capacities of
the hot and very hot body can be considered very large.
(A) 6000/7 J
(B) 600 J
(C) 2000 J
(D) 14000/3 J
SECTION-I (ii)
(A) If atmospheric pressure increases slightly, height of mercury in tube would decrease.
If a little amount of mercury was added to tube, the surface area of mercury in flask would
(B)
slightly increase.
If there was no mercury in the tube, the pressure of the air in the empty space would be 76 cm
(C)
of mercury column
If mercury in the tube were to be removed completely, the surface area of the mercury in the
(D)
flask would decrease.
2) Adjacent figure shows a block A, held by a spring balance D and submerged into a liquid in a
beaker. The beaker is kept on a weighing balance E. Mass of the beaker plus the liquid is 2.5 kg.
Balance D reads 2.5 kg and E reads 7.5 kg. Volume of the block is 0.003 m3. Consider the following
statements. Select the correct statement(s). Take : g = 10 m/s2
3) A piece of ice floats in water in a calorimeter. We lower the constant heater into the calorimeter
having a power of 10 cal/sec and start measuring water temperature every minute. During the first
three minutes the temperature increased by 2 degrees, and by the end of the fourth minute by
another 5 degrees. Neglect the heat losses and the heat capacity of the calorimeter. Swater = 1
cal/gm°C, Lice = 80 cal/gm.
SECTION-II (i)
Housewives face a typical problem when cleaning the house. Sometimes when they are wiping the
floor with water, the water from the bucket spills over. This water can form a puddle on the ground
and can be quite a menace to clean. It can be assumed that the water has spread out on the ground
like a pancake whose parameters are shown here. If the volume of the drop is small, it will form a
small drop whose cross section is a sphere. But that is not the worry of the housewife. The worry is a
large puddle as shown here. Assume that 6 liters of water of density 1000 kg/m3 are spilled on the
ground with contact angle θE. The surface tension is 0.49 N/m., g = 10m/s2, atmospheric pressure is
105 Pa.
1) Calculate the wet surface area (in m2) when contact angle is .
2) Calculate the gauge pressure (in N/m2) at the base of the puddle when the contact angle is 180°.
4) What is the pressure difference (in Pa) between the upper and lower bases?
SECTION-II (ii)
1) A steel ball is dropped from a height of 1 m on to a hard non-conducting surface. Every time it
bounces it reaches 80 % of its previous height. All the losses in the energy are accounted only for
increasing the temperature of the ball. Nearly how much is the total rise in temperature (in
multiples of 0.001 °C) of the ball just after the third bounce? (g = 10 m/s2, specific heat capacity of
material of the ball = 488 J/(kg K))
2) Half of the liquid flows out of a vertically placed thin tube filled with a viscous liquid in time of 8
sec. After how much time (in sec) will the rest of the liquid flow out? Neglect surface tension and
assume that the liquid is so viscous that it is in steady state.
3) In a cylindrical glass with a volume V = 200 cc and a cross-section S = 18 cm2, standing on a table
at room temperature Tk = 20°C, put a piece of ice weighing m = 100 g, having a temperature T0 =
0°C, and covered the glass with a tightly fitting lid. Estimate the force (in N) required to remove the
lid from the glass immediately after the ice melts. Consider that heat enters the glass only from
below, there is no friction pa = 105 Pa, ice density ρice = 900 kg/m3, water density ρw = 1000 kg/m3.
(Round off to nearest integer if required.)
4) A portion of oxygen is heated at a constant pressure until the volume of the gas increases 2 times,
and then cooled at the resulting volume. until the gas has given up all the heat received during
expansion. If initial temperature was 200 K, what was final temperature (in K) ?
5) The filament of a 50 W, 200 Volt light bulb is made of tungsten. The density of tungsten is 20
gm/cc, its resistivity is 10–8 Ωm (assumed to be constant), Its emissivity is 0.5, Stefan’s constant is 6
× 10–8 W/m2K4. Assess the mass of filament if its temperature is 2000 K. It is radiating in free space.
If mass is a × 10–bkg. Find b. (1 < a < 10) Take : π2 = 10
6) A Cyclic heat engine consists of two adiabatic and two isochores. Find the efficiency of the cycle
in percentage rounded off to nearest integer, if we know the temperature T1 = 400 K and T2 = 100 K
at start and end for one of the adiabats. Operating system is a monoatomic ideal gas.
PART-2 : CHEMISTRY
SECTION-I (i)
(A) Ne + He + SO2
(B) NH3 + HCl + HBr
(C) O2 + N2 + CO2
(D) N2 + H2 + O2
3) When 100 ml 0.2 M KOH is mixed with 100 ml 0.2 M HCl, temperature of solution increases by
t1°C while when 300 ml 0.2 M KOH is mixed with 300 ml 0.1 M HCl then increase in temperature is
t2°C then which is correct.
(Assuming density as well as specific heat of final solutions are same).
(A) t1 = t2
(B) t1 = 2 t2
(C) t2 = 2 t1
(D) t1 = 1.5 t2
(A) At constant P and T, |ΔG| represents maximum non PV work that can be done by the system.
(B) If ΔG° = 0, then equilibrium constant for the reaction = 1.
(C) If ΔG° = 0, then the reaction is in equilibrium at any condition.
(D) For the reaction : H2O (s, 2 atm, 273 K) → H2O (ℓ, 2 atm, 273 K), ΔG < 0.
SECTION-I (ii)
3) Consider O2 gas at 300 K and SO2 gas at 600 K. Assume both gases behave ideally. Select the
correct graph(s).
(A)
(B)
(C)
(D)
SECTION-II (i)
3) The pressure at which graphite and diamond will be at equilibrium at 300 K in bar is P. Find value
of .
SECTION-II (ii)
4) Sodium azide (NaN3) is used in automobile bags. If car accident happens, these NaN3(s) present in
the bag decomposes by following reaction to inflate air bags.
5) On a humid day at 40°C, humidity of atomspheric air is 90%. If partial pressure of water vapour in
air is 45 torr. Calculate vapour pressure of water at 40°C (in torr).
6) The temperature (in kelvin) at which Urms speed of helium (He) becomes equal to Ump speed of CH4
at 327°C.
PART-3 : MATHEMATICS
SECTION-I (i)
1) Let f(x) be a real valued cubic polynomial with real coefficients such that both f(0) and f(–1) are
odd integers. Also the leading coefficient is unity. Which of the following is/are true
(A)
(B)
(C)
(D)
3) If , then S equals
(A)
(B)
(C)
(D)
4) Let x,y,z are the real variables satisfying the equation x + y + z = 6 and xy + yz + zx = 7. The
range of possible values of x is
(A)
(B)
(C)
(D)
SECTION-I (ii)
1) Let f(x) = ax2 – (a2 + b)x + ab and a2 < b. Which of the following options is/are true
(A)
If , then f(–2) > 0
(B)
If , then f(0) < 0
(C)
If , then f(0) > 0
(D)
If , then f(2) > 0
A1 = and for each n > 2 and n ∈ N, . Which of the following is/are true
(A)
(B)
(C) A3 = A1A2
(D)
3) The roots of the equation, x3 – 3ax2 + bx + 18c = 0, form a non-constant A.P. and the roots of the
equation
x3 + bx2 + x – c3 = 0, form a non-constant G.P. If c ∈ R and a,b ∈ N then which of the following is/are
true
(A) a = 2
(B) b = 9
(C) b = 2
(D)
c=
SECTION-II (i)
1) The value of (A + B + C) is
3) Value of |2a + b| is
SECTION-II (ii)
1) x,y,z are the first three terms of an increasing G.P., whose first term is 'x' and common ratio are
both positive integers. Given that x,y,z also satisfy the relation, 1 + log2(xy + z) = log2(xz + y).
Minimum possible value of (x + y + z) equals
2) Given that x2 – 3x + 1 = 0, then the value of the expression (x9 + x7 + x–9 + x–7) is divisible by a
prime number 'k' which is less than 10. Value of k is
3) Let a,b,c,d > 0 be real numbers such that a + b + c + d = 6. If the minimum value of
is λ then equal
5) Let P denotes number of digits before decimal in and Q denotes number of zeroes after
6) Number of ordered pair (p,q) where p,q ∈ N if the equation (x2 – px + q) (x2 – qx + p) = 0 has all
roots as natural numbers
ANSWER KEYS
PART-1 : PHYSICS
SECTION-I (i)
Q. 1 2 3 4
A. C B B A
SECTION-I (ii)
Q. 5 6 7
A. A,B,C,D A,B,C,D B,C,D
SECTION-II (i)
Q. 8 9 10 11
A. 85.71 140.00 6.00 2400.00
SECTION-II (ii)
Q. 12 13 14 15 16 17
A. 10 8 20 120 5 75
PART-2 : CHEMISTRY
SECTION-I (i)
Q. 18 19 20 21
A. B B B C
SECTION-I (ii)
Q. 22 23 24
A. B,C,D A,B,C C,D
SECTION-II (i)
Q. 25 26 27 28
A. 4.40 250.00 9000.50 2400.00
SECTION-II (ii)
Q. 29 30 31 32 33 34
A. 36 180 5 65 50 100
PART-3 : MATHEMATICS
SECTION-I (i)
Q. 35 36 37 38
A. B C B A
SECTION-I (ii)
Q. 39 40 41
A. A,B,C B,C A,B,D
SECTION-II (i)
Q. 42 43 44 45
A. 4.00 3.00 0.50 0.25
SECTION-II (ii)
Q. 46 47 48 49 50 51
A. 65 3 8 8 1 3
SOLUTIONS
PART-1 : PHYSICS
2)
pπr2 = σ × 2πrt
PV = nRT
4) Refrigerator
5)
100 cm × 100 = (76 + h) × (100 – 100 y)
0.1 (10 + 24) = 0.1 h + 100 y
h = 34 – 1000 y
100 = (110 – 1000y) (1 – y)
10 = 11 + 100 y2 – 11y – 100 y
100y2 – 111 y + 1 = 0
6) 5g = B = ρL = Vg
7) 10 × 3 × 60 = m'i × 80 + m × 2 × 1
1× 10 × 60 = m × 5 × 1
m = 100 gm
1800 – 240 = m'i × 80
mi = 19.5 gm
9)
Ah = 6 litre
p = p0 + hρg
11)
From frame of cylinder
πR2v = π(R2 – r2)v'
From ground
vwater = vwc + vc
U + K = constant.
mg – Δpπr2 = ma
= 2400 Pa
12)
ΔE = 0.488 h mg = mSΔθ
13)
v is ind. of length
⇒ T same.
14)
ΔpA = F
F = 20 N
T3 = 120 K
16)
≈ 1.6 × 10–5 kg
17)
4T4 = T3
Qgiven =
Qextracted =
PART-2 : CHEMISTRY
18)
19)
20)
24)
If two gases have same ratio then their velocity distribution will be same
26)
At high P, Z = 1 +
∵Z=1+
or, =1+
or, PV = nbP + nRT
∵ RT = 20 ⇒ T = = 250 K.
28)
C(graphite) → C(diamond)
dG = VdP – SdT
At constant T, dG = VdP
or, d(ΔG) = ΔVdP
or,
or, –ΔG° = ΔV(P – 1)
or, –3000 = (P – 1)
29)
30)
N2O4 ⇌ 2NO2
Initial moles 1 0
At eqm mole 1–α 2α
ΔG° = –RT ln KP
= –2 × 300 ln
= –2 × 300 × 0.3 = –180 cal.
|ΔG°| = 180.
31)
32)
∴ NaN3 = × 65 g = 3.61 g.
33)
R.H. =
or, 0.9 =
34)
THe = 100 K
PART-3 : MATHEMATICS
⇒
⇒ b – c = odd ...(i)
If all the roots (say α,β,γ) of f(x) are integers
⇒ αβγ = –d (odd integer) ⇒ α,β,γ all should be odd
now
–b = α + β + γ ⇒ –b should be odd too
αβ + βγ + γα = c ⇒ c should be odd too
⇒ b – c = even ...(ii)
From (i) & (ii) we have a contradiction.
36)
Now
Thus
37)
∴
38) x + y + z = 6 ....(1)
xy + yz + zx = 7 ....(2)
Putting the value of z from (1) in (2) we get
xy + y(6 – x – y) + x(6 – x – y) = 7 ⇒ y2 + y(x – 6) + x2 – 6x + 7 = 0
since y is real, so (x – 6)2 – 4(x2 – 6x + 7) > 0 ⇒ –3x2 + 12x + 8 > 0
∴ other root is .
Also a2 < b ⇒ b > 0
Case-I Case-II
a>0 a<0
∴ Option A ⇒ ⇒ case- I
Option B ⇒ ⇒ case- II
Option C ⇒ ⇒ case- I
Option D ⇒ ⇒ case- II
⇒ Roots
∴ p3 = c3 ⇒ p = c is a root
c3 + bc2 + c – c3 = 0 ⇒ c(bc + 1) = 0
But c ≠ 0 ⇒ bc = –1 ....(ii)
∴ By quadratic formula,
∴ For b ∈ I ⇒ a = 1,2,3,6,9,18 only
But only at a = 2; b = 9 ∈ I
∴ Possible (a,b) = (2,9)
42) (A)
xyz = 1
A=1
(B) log3(6log2|x| – 3) – log3(4log2|x| – 5) = 1
⇒ 6log2|x| – 3 = 12log2|x| – 15
⇒ 6log2|x| = 12
log2|x| = 2
|x| = 4, x = ±4
B=2
(C) log3(log23.log34log45log56log67log78)
log3(log28) = log3(3)
C=1
A+B+C=4
43) (A)
xyz = 1
A=1
(B) log3(6log2|x| – 3) – log3(4log2|x| – 5) = 1
⇒ 6log2|x| – 3 = 12log2|x| – 15
⇒ 6log2|x| = 12
log2|x| = 2
|x| = 4, x = ±4
B=2
(C) log3(log23.log34log45log56log67log78)
log3(log28) = log3(3)
C=1
|log1/22A – 2log2B + log2C|
= |log1/22 – 2 log2 2 + log21|
= |–1 – 2 + 0| = |3| = 3
45)
Case-II :
As x ∈ I ⇒ r – 2 = 1 or 3
⇒ r = 3 or 5
If r = 3 ⇒ x = 5 ⇒ Nos are 5,15,45
r = 5 ⇒ x = 3 ⇒ Nos are 3,15,75
47) x2 + 1 = 3x ...(i)
....(ii)
16 8 2 8 4 4 2 8
x + 1 = (x + 1) – 2x = ((x +1) – 2x ) – 2x
= (((x2 + 1)2 – 2x2)2 – 2x4)2 – 2x8
= ((7x2)2 – 2x4)2 – 2x8
∴ (ii) becomes
48)
49) ....(1)
ℓn2 ℓny
(x + 1) = 5 ....(2)
by (1) ℓn5(ℓn5 + ℓn(x + 1)) = ℓn2(ℓn2 + ℓny)
Let
A = ℓn(x + 1)
B = ℓny
b(b + A) = a(a + B) ...(3)
By (2) aA = Bb ...(4)
⇒ A = –b ⇒ ℓn(x + 1) = –ℓn5
50) Let
log10N = 100(log103 – log102) = 100(0.1761)
= 17.61 ⇒ P = 18
Let
log10N1 = 100(log102 – log103) = –18 + 0.39
Numerical value = 18; number of zeroes are 17 = Q
51) α + β = p & αβ = q
γ + δ = q and γδ = p
⇒ α + β – αβ + γ + δ – γδ = 0
∴ (α – 1) (β – 1) + (γ – 1) (δ – 1) – 2 = 0
(α – 1) (β – 1) + (γ – 1) (δ – 1) = 2
Case-1 let (α – 1) (β – 1) = 0 and (γ – 1) (δ – 1) = 2
(γ, δ) = (3,2) and (2,3) (p,q) = (6,5)
Case-2 (α – 1) (β – 1) = 1 (γ – 1) (δ – 1) = 1
(α,β) = (2,2) ⇒ (p,q) = (4,4)
Case-3 (α – 1) (β – 1) = 2 and (γ – 1) (δ – 1) = 0
(α,β) = (2,3) ⇒ (p,q) = (5,6)
Hence number of ordered pair = 3