1. Number of moles of neutrons in 1.8 mL of 10.

Calculate the amount of 50% H2SO4 required

water is :- to decompose 25 g of calcium carbonate :-
(1) 4.8 × 1023 (2) 4.8 × 1022 (1) 98 g (2) 49 g
(3) 0.8 (4) 0.1 (3) 24.5 g (4) 196 g
2. The weight of 350 mL of a diatomic gas at 0°C
13. The maximum number of molecules are present
and 2 atm pressure is 1 g. The weight of one
in :-
atom is :-
(1) 15 L H2 gas at STP
16 32
(1) N (2) N (2) 5 L of N2 gas at STP
A A

(3) 16 NA (4) 32 NA (3) 0.5 g H2 gas

3. 10 mL of gaseous hydrocarbon on complete (4) 10 g of O2 gas
combustion gives 20 mL of CO2 and 30 mL of
H2O(g). The hydrocarbon is :-
(1) C4H10 (2) C2H6
(3) C4H8 (4) C8 H10
4. For the reaction A + 2B ® C, 5 moles of A and 8
moles of B will produce :-
(1) 5 moles of C
(2) 4 moles of C
(3) 8 moles of C
(4) 13 moles of C
5. If the atomic weight of carbon is set at 24 amu,
the value of the avogadro constant would be :-
(1) 6.022 × 1023 (2) 12.044 × 1023
(3) 3.011 × 1023 (4) none of these

7. A compound on analysis gave the following

results C = 54.54%, H = 9.09% and vapour
density of compound = 88. Determine the
molecular formula of the compound:-
(1) C8H16 O4 (2) C4H16O8
(3) C2 H4 O (4) CH 4O2

8. Two elements X and Y (atomic mass of X = 75

and Y = 16) combine to give a compound having
76% of X. The formula of compound is :-
(1) XY (2) X2 Y (3) X2Y2 (4) X2Y3
9. Mass of CO2 produced on heating 20 g of 40%
pure limestone :-
(1) 8 g (2) 8.8 g
(3) 3.52 g (4) none of these
52. FM radio broadcasts at 900 KHz. What 54. The wavelength of a neutron with a translatory
wavelength does this correspond to ? kinetic energy equal to KT at 300 K is :-
(1) 333 m (2) 3.03 × 10–3 m (1) 178 pm (2) 200 pm
(3) 330 cm (4) 3300 m (3) 17.8 pm (4) 20.0 pm
53. Energy of 1 mole of radio wave photons with a 55. Frequency of a matter wave is equal to :-
frequency of 909 KHz is :-
(1) 6.02 × 10–28J (2) 3.62 × 10–4J ( KE ) 2 ( KE ) ( KE )
(1) (2) (3) (4) l
2h h h
(3) 1.00 × 10–4J (4) 6.02 × 10–3 J
56. Ionisation energy of He+ is 19.6 × 10–18 J atom–1.
The energy of first stationary state (n =1) of
Li+2 is :-
(1) 4.41 × 10–16 J atom–1
(2) –4.41 × 10–17 J atom–1
(3) –2.20 × 10–15 J atom–1
(4) 8.82 × 10–17 J atom–1
57. Kinetic energy of an electron in the second
Bohr orbit of a hydrogen atom is (a0 is Bohr
radius):-
h2 h2
(1) (2)
4 pma 20 16p2 ma 02

h2 h2
(3) (4)
32p2 ma 02 64 p2 ma 02

58. The potential energy of an electron in the

second Bohr's orbit of the He+ ion is :-
(1) –54.4 eV (2) –27.2 eV
(3) –108.8 eV (4) –13.6 eV
59. If the radius of the first bohr orbit is X, the
de Broglie wavelength of the electron in the
third orbit is nearly.:-
(1) 2pX (2) 6pX (3) 9X (4) X/3
60. According to Bohr's theory, the angular
momentum of an electron in 5th orbit is :-

h h h h
(1) 25 (2) 1.0 (3) 10 (4) 2.5
p p p p

61. The number of d electrons retained in Fe +2

(atomic number Fe = 26) ion is :-
(1) 3 (2) 4 (3) 5 (4) 6
342. A real gas behaves as ideal behaviour when :-
(1) Z > 1 (2) Z < 1 352. At relatively high pressure, vander Waal's
equation reduces to
(3) Z = 1 (4) Z ¹ 1
a
343. A 1 mol gas occupies 2.4L volume at 27°C (1) PV=RT (2) PV=RT +
V
and 10 atm pressure then it show :-
a
(1) +ve deviation (2) –ve deviation (3) PV=RT +Pb (4) PV=RT–
V2
(3) Ideal behaviour (4) None of these 353. Which gas can most readly liquified
344. The value of vander waal's constant a and b (1) NH3 (2) Cl2
for two gases X and Y are 4.6, 0.04 (for X) (3) SO2 (4) CO2
and 5.1, 0.06 (for Y). Which can be liquified 354. Density of a gas is found to be 5.46 g/L at 27°C
easily an application of pressure :- and 2 atm pressure. what will be its density at
(1) X (2) Y STP
(3) Both 1 & 2 (4) None of these (1) 3 g/L (2) 2 g/L
346. The ratio of rate of diffusion for two gases is (3) 1.5 g/L (4) 1 g/L
1 : 2 if their molecular masses :-
(1) 16 : 1 (2) 1 : 16 (3) 1 : 4 (4) 4 : 1
347. Which of the following gases always show
positive deviation from ideal gas behaviour with
increase in pressure?
(1) NH3 (2) CO2 (3) H2 (4) CO
348. If the ratio of the rates of diffusion of two gases
A and B is 4:1 the ratio of their density is
(1) 1:16 (2) 1:4 (3) 1:2 (4) 1:8

349. Which of the following gas will have highest

value of van der Waal's constant 'a'?
(1) H2 (2) He (3) CO2 (4) NH3
123. Which solubility order is correct ? 131. Based on VSEPR theory, the number of 90
(1) BaSO4 > SrSO4 > CaSO4 > MgSO4 degree F–Br–F angles in BrF5 is
(2) ZnS > Na2S > CoS (1) 5 (2) 4
(3) BaCO3 > MgCO3 > Na2CO3 (3) 0 (4) 1
(4) KOH > NaOH > Mg(OH)2 132. Which of the following represent most
124. What is incorrect about reaction of NH3 and effective p-bond
BF 3 ? (1) 2pp-3pp (2) 3dp-3dp
(1) hyrbridisation of both N & B change (3) 2pp-3dp (4) 3dp-3pp
(2) It is an example of redox change 135. Which of the following compound has non-
(3) In the final adduct formed, back bonding zero dipole moment
appears between B & N (1) XeF4 (2) B2H6 (3) PF3Cl2 (4) PCl3F2
(4) All
136. Which of the following molecule is planar due
126. Correct order of dipole moment is (decreasing to back bonding
order)
(1) NCl3 (2) PF3 (3) BF3 (4) None
(1) CH3Cl, CH3Br, CH3F
(2) CH3F, CH3Cl, CH3Br 139. The coordinate bond is absent in
(3) CH3Cl, CH3F, CH3Br (1) NaNO3 (2) CaCO3
(4) CH3Br, CH3Cl, CH3F
(3) O3 (4) KNC
127. Correct order of stability of species
N2, N2+, N2 –
(1) N2 > N2+ = N2– (2) N2 > N2+ > N2–
(3) N2 > N2– > N2+ (4) N2+ > N2 > N2–

129. Which is not stable

(1) KHF2 (2) KI3
(3) CH3–CH(OH)2 (4) Cl 3 C–CH(OH)2