PART – A 7.

An electrochemical cell can behave like an

electrolytic cell when _______

TIME : 1HOUR Maximum Marks:50

1.A sample of drinking water contains 15 ppm

(by mass) of a carcinogen (120 g mol-1) what is 8. What is the ascending order of strength of
Molality of Carcinogen________ mol kg-1 the following metals as reducing agents based
on standard electric potential?
(A) 2.50 × 10-4 (B) 2.50 × 10-3
Ag+ / Ag = 0.80 V, Mg+2 / Mg = -2.37 V
(C) 1.25 × 10-4 (D) 1.25 × 10-3
Hg+2 / Hg = 0.79 V, Cr+3 / Cr = -0.74 V
2. When the attraction between A-B is greater
than that between A-A and B-B _______ (A) Hg < Ag < Mg < Cr

(A) positive deviation of Raoult's law (B) Hg <Cr < Hg < Ag

(B) Negative deviation of Raoult's law (c) Cr < Mg < Ag < Hg

(C) There is no deviation of Raoult's law. (d) Ag < Hg < Cr < Mg

(D) Nothing can be said. 9. copper vessel can be safely filled with_____

3. Which of the following pairs are congruent Solution among the following.
pairs?
(A) ZnSO4 (B) AgNO3
(A) 0.15 M NaCI and 0.1 M Na2SO4
(C) AuCl3 (D) All of the above
(B) 0.2 M urea and 0.1 M sugar
10. Standard reduction of Cu+2/ Cu and Cu+2/
(C) 0.1 M BaCl2 and 0.2 M Urea Cu+, The values of potential are 0.337 and
0.153 V respectively, So what is the cell
(D) 0.4 M MgSO4 and 0.1 M NH4Cl potential for Cu+/ Cu half cell?
4. Find the mole fraction of urea in an
(A) 0.184 V (B) 0.827 V
aqueous solution of 1 mol urea (NH2CONH2)
(C) 0.521 V (D) 0.490 V
(A) 0.01878 (B) 0.01768
11. Which of the following statements is not
(C) 0.01800 (D) 0.01698 correct for electrolyte solutions?
5. What is the molality of 3.0 g of ethanoic
(A) The conductivity of a solution depends on
acid in 50 g of benzene? the size of the ions have.
(A) 1.0 (B) 0.6 (C) 0.1 (D) 0.06
(B) Conductivity depends on the viscosity of
6. 0.01 m KX [Fe(CN)6] Molal concentration of the solution have.
a solution, decrease at 0.0744 K. solution’s
(C) Base conductance of ions is not on
molal Constant 1.86 K kg mol-1 If the whole of
solvation of the solution.
the solute dissociation occurs, what will be
the correct atomic formula of the solute? (D) Corductivity of a solution increases with
increasing temperature.

12. Required to obtain 1 mole of aluminum

from Al2O3 Amount of charge is ________
(A) 1 F (B) 6 F (C) 3 F (D) 2 F (C) (a + b) = (1 + m)

13. Find the strongest reducing agent based (D) Either (a + b) and (1 + m) are equal or not.
on the following information:
18. A stepwise process A with k1 gives b, b
with k2 gives c, c with k3 gives d if K3 < K2 < K1
for Which process the rate-determining step?

(A) A → B (B) B → C

(C) C → D (D) A → D
14. The graph for the process R P is given 19. If the 3d orbital is incompletely filled with
below. What will be the enthalpy change of electrons, they are called elements of which
the process? transition series?

(A) First (B) Second (C) Tertiary (D) IV

20. Which of the following element is d-

division but is not transition element?

(A) Cu (B) Ti (C) Ag (D) Cd

21. Low value of Eθ = (M+2/M) for element V is

due to which of the given electron
(A) -50 kJ (B) 50 kJ (C) 120 kJ (D) 170 kJ configuration?

15. For a given first-order process A → B (A) Whole d10 (B) Semi-complete d5

The half-life of the process is 0.3010 min. 2.0 (C) d3 (D) Semi complete t2g level
min will be the ratio of the reactant 22. Which of the given lanthanides Is
concentration to the (initial) concentration of antimagnetic?
the reactant __________ at time.
(A) Eu+2 (63) (B) Yb+2 (70)
(A) 200 (B) 300 (C) 100 (D) 400
(C) Ce+2 (58) (D) Sm+2 (62)
16. The velocity law of the resulting process
aA + bB— is velocity = K[A]m [B]n. If the 23. Mohr's salt contains which two different
concentration of A is doubled and the salts?
concentration of B is halfed, keeping the (A) FeSO4 and (NH4)2 SO4
temperature constant, how much will the
velocity increase? (B) Fe2(SO4)3 and (NH4)2 SO4

(A) 2m+n (B) 2n-m (C) 2m-n (D) 2mn (C) FeSO4 and K2SO4

17. If the velocity law for the process aA + (D) Fe2(SO4)3 and Al2(SO4)3
bB→
24. Tetra ammine aquachlorido of cobalt (III)
chloride Molecular formula is_________
Is = K[A]p [B]q then which option is
correct?

(A) (a + 1) < (b + 1)

(B) (a + b) > (1 + m)
25. If A and B are different monodentate
ligands Which of the following shows a
complex geometric isomorphism?

(A) [MA2B] and Quaternary

(B) [MA2B2] and square

(A) (iii)
(C) [MA2B2] and tetrahedral
(B) (ii)
(D) [MA3B] and square
(C) (i)
26. [Ni(CO)4] for which option is incorrect?
(D) All the given compounds have the same
(A) Equilateral shape melting point.
(B) Antimagnetic 31. Displacement of halogen from which of
(C) Zero oxidation state of Ni the following halide compounds is most
difficult?
(D) orbital free complex
(A) C6H5 – Cl (B) CH3 - CH2 - Cl
27. What does CFT not explain?
(C) CH2 = CH - CI (D) CH2 = CH - CH2 - Cl
(A) Magnetic property of complexes
32. State the constitutional formula of L-
(B) Covalent specificity of the bond between glyceride.
the ligand and the mediating metal

(C) Color of complexes

(D) Formation and formation of complex

compounds

28. Which of the following is a (2º) alkyl halide

compound?

(A) 2-Chlorobutane (B) Benzyl chloride

33. Tertiary halides are largely insensitive to
(C) Iso-propyl chloride (D) Both A and C the SN2 process. Its main reason________
29. Why are the boiling points of alkyl and aryl (A) Effect of steric hindrance of three alkyl
halides higher than hydrocarbons of the same groups
molecular weight?
(B) High volatility of 3° C+ produced
(A) Since C - C is closed polar
(C) Dominant + I effects of three alkyl groups
(B) Since C - X is closed nonpolar
(D) Due to being insoluble in water
(C) Since C - X is closed polar

(D) Since H - is closed in C-X

30. Which of the following compounds has the

highest melting point? 34. What is the IUPAC
name of the compound?

(A) 2-Ethyl-1-hydroxycyclotoluene
(B) 2-ethyl-5-methyl cyclohexanol iodoform test, but not the Fehling test What
will be the compounds A, P and Q?
(C) 3-methyl-6-ethyl cyclohexanol

(D) 1-ethyl-4-methyl cyclohexanol

35. What is the oxidation of 2° alcohol with

chromic acid?

(A) Aldehyde (B) Ketone

(C) Carboxylic acid (D) Esters

36. How many moles of H2 gas will be

obtained by treating 23 g of sodium with a
sufficient amount of methanol?

(A) 1 mole (B) 1/2 Mol (C)1/4 mol (D)3/2 Mol

37. Phenol has acidic strength greater than

Be_______ 41. Which of the following is the structure of

ethanol semi carbazone?
(A) HCI (B) С2H5ОН
(A) CH3 - CH = N - CONH – NH2
(C) СН3COОН (D) H2SO4
(B) CH3 - CH = N – NHCONH2
38.
(C) CH3 - CH = N - OH

(D) CH3 - CH = N – NH2

Select 42. Naturally occurring fatty acids have a

the correct option For Q. carbon number are _________

(A) 2, 4, 6-Tribromobenzene (A) C1 to C5 (B) C5 to C10

(B) Bromobenzene (C) C12 to C18 (D) More carbon to C18

(C) 1, 3, 5-tribromobenzene 43. Which of the following is the weakest

acid?
(D) 2, 4-dibromobenzene
(A) CI CH2 – COOH (B) Cl2 - CH - COOH
39. What type of isomers are propanal and
propan-2-one? (C) CH3 – COOH (D) Cl3 - C - COOH

(A) place coefficients 44.Which type of amine can C3H9Nrepresent?

(B) Light coefficients (A) Primary (B) Secondary

(C) Geometrical coefficients (C) Tertiary (D) All of the given

(D) Active mass coefficients 45. In the 1º - amine obtained in the Hoffman
bromamide process How much decrease in
40. Reactive alkyne A having the atomic molar mass than amide?
formula C5H10 A mixture of P and Q than
reductive ozonolysis gets Among these are P (A) 12 g / mol (B) 28 g / mol
iodoform and Fehling test, while Q gives the (C) 16 g / mol (D) 24 g / mol
46.Which of the following compounds does 49. Which of the following pairs of proteins
not react with Hins berg reagent? are globular proteins?

(A) Triethyl amine (B) Tertiary butyl amine P-keratin, Q- insulin, R- myosin, S- albumin

(C) N -methyl aniline (A) R, S (B) Q, R (C) P, R (D) Q, S

(D) 1-methyl cyclohexyl amine 50. Which of the following is a type and
example of endocrine correct?
47. which sugar is not reducing sugar?
(A) Amino acid derivatives - epinephrine and
(A) Glucose (B) Sucrose
Norepinephrine
(C) Maltose (D) Lactose
(B) Polypeptide → insulin and endorphin
48. How are gluconic acid and saccharic acid
(C) Steroids - estrogens and androgens
different?
(D) All of above
(A) Gluconic acid has six carbon atoms, while
saccharic acid has seven carbon atoms.

(B) Gluconic acid contains one -CH2OH group,

while saccharic acid contains two -CH2OH
groups.

(C) Gluconic acid contains one -COOH group,

while saccharic acid contains two -COOH
groups.

(D) Gluconic acid contains one -CHO group,

while saccharic acid contains two -CHO
groups.
 SECTION : B

Time : 2 hour Maximum marks : 50

SECTION : A

* Write short answers to any 8 questions from questions 1 to 12 given below. (Each question
carries 2 marks.) [16]

1. Write about standard-hydrogen pole.

2. The following process takes place in air and is first order.

A(g) → B(g) + C(g)

Total pressure = pt and partial pressure A = pi atm at t time. Derive the integral velocity constant
equation for this process.

3. Mn+2 compounds are more stable than Fe+2 with respect to being oxidized to the +3 state. Why?

4. If the atomic number of an element is 26, calculate the magnetic field of the trivalent ion in its
aqueous solution.

5. (i) K3[Cr(C204)3] : write the IUPAC name.

(ii) Write the formula of tetraammine aquachlorido cobalt (III) chloride.

6. Explain that solution of [Ni(H20)6]+2 is green but solution of [Ni(CN)4]-2 is colourless.

7. State the observation of photo-reactivity by Louis Pashwar.

8. Write the equation for the formation of 1-iodobutane from but-1-ene.

9. Give the results of the following process.

10. Give the conversion of phenol to salicylic acid.

11. Write the reactions of acetone with (i) NaHSO3 (ii) HCN.

12. Give information about maltose.

SECTION : B

* Write detailed answers to any 6 questions from questions 13 to 21 below. (Each question carries
3 marks.) [18]

13. What is solubility? Explain the solubility of a solid solute in a liquid solvent.

14. A cell in which the following process takes place.

2Fe+3(aq) + 2I-(aq)  2Fe+2(aq) + I2 (S)

At 298 K tempreture E-cell = 0.236 V. Calculate the standard Gibbs-energy and equilibrium constants
of the cell process.

15. Explain the reaction theory of chemical processes.

16. Write about atomization enthalpy of transition series elements.

17. Which of the following pairs of alkyl halides would you expect to undergo a faster reaction via the
SN2 reaction? Explain your answer.

18. Explain formation of ether compound by dehydration of alcohol compound and its action with
suitable example.

19. Write about Tollens test.

20. Explain the reaction of amine with arylsulfonyl chloride.

21. Give the transformation: (in three steps) from nitrobenzene to chlorobenzene

SECTION : C

* Answer any 4 of the following questions 22 to 27 in detail as required. (Each question carries 4
marks.) [16]

22. Na2CO3 and NaHCO3 how many ml of 0.1 M HCI would be required to completely process 1 g of a
mixture containing equimolar amounts of both substances?

23. What is primary battery called? Write about one known primary battery.

24. The relationship between atomic mass( NE /NT ) and temperature with a Boltzmann-Maxwell
diagram.

25. Explain color in heavenly compounds.

26. Write the Kolbe and Rimer Teeman processes of phenol.

27. The molecular formula of an organic compound is C9H10O. Forms a 2, 4-DNP derivative, a Tollan's
reduction reaction and a Cannizzaro process. By vigorous oxidation it gives 1, 2-benzine dicarboxylic
acid. So identify this compound and write the equation of its entire processes.