CHEMISTRY FULL SYLLABUS PAPER 1 By VIREN PANCHAL
PART -A (A) 10 % w/V Urea (ag)
(B) 10 % w/V Glucose (aq)
(C) 10 % w/V (aq)
1 State the correct order of Van’t (D) The endpoints will be the same for all
hoffcoefficientThe three solutions A, B, C options.
shown below. 4. State the order of solubility of gases in
Solotion : A Solution : B Solution : liquid solvents at constant temperature
C with the help of the graph given below.
0.1 Mole 0.1 Mole 0.1
Mole
CH3COOH + CH3COOH + (A) A< B < C (B) A > B > C
CH3COOH
(C) A = B = C (D) B > A > C
1 lit Water 2 lit Water 3 lit
5. State the molarity of an aqueous
Water
solution of 10 ppm chloroform.
(A) IA = iB = iC (B) iA>iB>iC
(A) 0.0836(B) 8.36 10-5
(C) IA<iB<iC (D) iA = iB>iC
(C) 8.36 10-3 (D) 8.336 10-4
6. Which of the following options is
2 Choose the incorrect statements for
inconsistent with osmosis?
solid soluteand Liquid solvents.
(A) concentrations lower than 0.9% w/V
(i) Solubility increases with
saline solution placing blood cells in
increaseintemperature.
solution causes blood cells to swell.
(ii) Solubility increases with increase in
(B) The phenomenon of osmosis is
pressure.
reverses by appling pressure greater than
(iii) Solvents like KCL are insoluble in the osmotic pressure toward a solution of
benzene. higher concentration.
(Iv) Heat is always generated during this (C) solute particles coming into contact
type of solution with solution of different concentrations
through a semipermeable membrance
(A) ii,iv (b) I,iii (c) i, iv
move from a solution of lower to a higher
(d) ii, iii
concentration
3 Which of the following solutions will
(D) Water from the soil is the result of
have maximum Boling point?
partial osmosis into the roots of the tree.
7. Pt |H | H+ ||Cu+2 |Cu
(S) 2(g,1qut) (aq,1M) (aq,1M) (A) Aggregate PbSO4in a lead collector
(E0 =0.34 V) which option is incorrect for Cu? cell is deposited on the electrode
cell
(A) E0 +2 = 0.34 v (B) Mercury cell uses HgOand carbon
Cu |Cu
(B) Cu+2 Easier reduction as compared to H+ pulp as anode.
(C) H Gas can oxidize Cu
2 (c) process Ni(OH)3 at the cathode in a Ni-
(D) Cu metal does not dissolve in HCL
cd cell
8. Arrange the order of the reducers (D) A concentrated aqueous NaOH
based on the given information. solution is used in an H2 fuel cell.
E0Cu+2 | Cu = 0.34 V 13.The half – life of this process is related
to the initial concentration [R]0of the
E0 Cr2o7-2 | Cr+3 = 1.33 V
process if pradiano velocity is K = 2.5 X
E0 Mg+2 | Mg =-2.36 V
10-2mol-2L2s-1?
E0 Mno-
4 | Mn
+2 = 1.51 V
(A) [R0]2 (B) [R0]-2
(C) [R0]-3 (D) Independent of
[R0]
14. For complex processes ,the velocity of
the process can be expressed by which
formula according to the collision theory?
(A) Velocity = ZAB . e -Ea/RT
9. State the value of n for G = -nFEfor E
(B) Velocity = ZAB .e a / RT
C
5H12 + 8O2 5CO2 + 6H2O (C) Velocity = PZAB . e -Ea/RT
(A) 8 (B) 4 (C)16 (D)32 (D) Velocity = k . e -Ea / RT
10. Which metal will deposite more mass 15. KClO3 +6FeSO4 + 3H2SO4KCl +
at the cathodwhen the same amount of 3Fe2(SO4)3 + 3H2O reaction which option
electricity is passed through following suitable?
molten solutions?
(A) Process = Molecularity
(A) NaCl (B) KCl(C)MgCL2 (D) ALCL3
(B) This process is not a phased process
11. The impedance of a solution of 0.01mol m-3kcl is 100Ωand
if the cell frequency is 129 m-1, state the molar conductivity. (c) The process sequence is 10.
(A) 1.29 S cm2 mol-1 (B) 129 X 104 S cm2 (D) Unit of rate constant of process is
mol-1 mol-1L1s-1
(c)129 S cm2 mol-1 (D) 0.129 S cm2 mol-1 16.Raising the temperature of a process
by 10 °Calmost doubles the rate of the
process, so how much does the rate
increase from 298 K to 328 K?
(A) 2(B) 22(C)23(D) 10 (B) Statement and reason are true,
reason is not the explanationof the
17.Select the correct statements for
statement.
ionization enthalpy of transition
elements. (C) The statement is true, the reason is
false.
(i) iH increases sharply from left to right.
(D) The statement is false, the reason is
(ii) i H of Mnt is lower than that of Cr+.
true.
(iii) Tertiary ionization enthalpy of Cu, Ni,
22. Which metal is not useful in steel and
Zn is relatively higher than others.
stainless steel alloy production?
(iv) lonization enthalpy gives some
(A) Cr (B) W(C) Neither(D) Mn
guidance on the relative stability of
oxidation states of elements. 23.State the incorrect statement for
K2Cr2O7.
(A) ito iv (B) ii, iii, iv(C) i, iii, iv (D) i, iv
(A) K2Cr2O7 is more soluble than
18. Which of the following is a Wilkinson
Na2Cr2O7.
stimulant?
(B) Cr-O - Cr bond angle in Cr2O7-2- is 126°.
(A) [(Ph3P)3, RhCl] (B) [(Ph3P)2,RhCl]
(C) K2Cr2O7 is a strong oxidizing agent.
(C) [(Ph3P)3, Rh]Cl (D) [(Ph3P)3,
RhCl2] (D) K2Cr2O7 occurs as orange crystals.
19. Which of the following complexes will 24. State the correct electron
be most stable? configuration of Gd+2 forGd (gadolinium)
(Z = 64).
(A) K4[Fe(CN)6](B) K3[Fe(CN)6]
(A) 4f7 6s1 (B) 4f8 (C) 4f7 5d1 (D) 4f66s2?
(C) [Fe(en)3]+3(D) [Fe(Ptn)2]+3
25.If [Fe(CI)6]n- is 5.92 B.M. in
20. The number of geometric constants of
parentheses,
the convolution MABXL is p.And if the
number of geometrical coefficients of state n.
MA3B3is q, state (p + q). (A, B, X, L =
(A) 2(B) 5(C) 4(D) 3
monodentate ligand)
26. For K3[Cr(C2O4)3] which option is true?
(A) 4(B) 5(C) 3(D) 2
(i) Has a complex chelate structure.
21. Statement: of gaseous ammonia on
the surface of platinumDecomposition is (ii) Complex is of heteroleptic type.
a zero order process at lowpressure.
(iii) Total number of ions in it is 4.
Reason: Zero order processes relatively
uncommon (iv) Primary and secondary valence of
Cris 3, 6 respectively.
(A)Statement and Reason True, reason is
the explanation of thestatement. (A) i, ii, iv (B) i, iii, iv (C) iii, iv (D) ii, iii, iv
27.Equation: R -- X+ KCN → R -- CN +
KXyields cyanide.
Reason: KCN is an ionic compound which 32. let X and Y
gives CN-- ion in solution in which carbon respectively.
atom becomes e- donor.
(A) Benzoic acid, phenol (B) Benzoic acid,
(A) the statement, the reason is true, the benzene
reason is the explanation of the
statement. (C) Phenol, benzoic acid (D) Benzene,
Benzene
(B) The statement, the reason is true, the
reason" of reason of the statement. 33. Which of the following compounds
will have the weakest conjugatebase?
(C) The statement is true, the reason is
false. (A) CF3COOH(B) СС|3COOH
(D) The statement is false, the reason is (C)NO2CH2COOH (D) FCH2COOH
true. 34. Which of the following processes
28. Which of the following combinations does not show a correct result?
gives the fastest SN1
(A) C6H5Cl(B) C6H5CH2Cl
(C) C6H5CH(Cl)C6H5(D)C6H5CH(Cl)CH3
29. State the number of σ and π bonds
respectively in Pthalimidecompound.
(A) 17, 6 (B) 17, 5 (C) 20, 5 (D) 20, 6
react with I2
30. How many of the following compounds
+ NaOHWill give? Pentane-2-on,
methanol, but-3-ene-2-on,benzaldehyde,
acetophenone
(A) 3(B) 2(C) 5 (D) 4
31. State the incorrect statement for
polyhelo compound.
(A) CH2Cl2 produces severe irritation on
So which compounds can be used as B?
direct skin contact.
(A)Phosphinic acid, CH3CHO
(B) CHCl3 is oxidized by air in the
presence of light to form fosgin (COCl2). (B) Phosphinic acid, C2H5OH
(C) DDT has 29 σ and 6 π electrons. (С) Н3PO3, C2H5OH
(D) CCl2 F2 is called Freon-12. (D) Н3PO3, CH3CHO
36. State the total number of aromatic Column-1Column-Il
isomers having the atomicformula C7H8O.
(P) Lucas test(X) Aldehyde
(A) 3(B) 4(C) 6(D) 5
(Q) carbyl amine(Y) Alcohol
37.Which functional group in methyl
(R) Tollens test(Z) alkyne
salicylate compound present?
(S) Unsaturation test(W) Primary amine
(A) -OH, -COOH (В) -ОН, -СOO
(A) P → X, Q → Z, R → Y, S → W
(C) -COO, -CHO (D) -COO, -COOH
(B) P → Y, Q → W, R → X, S → Z
38. If the boiling points of the organic
compounds carboxylic acid, aldehyde, (C) P → X, Q → W, R → Y, S → Z
alcohol, haloalkane having almost same
(D) P → Z, Q → W, R → X, S → Z
molecular weight are X, Y, Z, W
respectively, state their ascending order. 42. State R and R' in Williamson synthesis
(R-X+R' -ONa) for formation of tertiary
(A) X, Y, Z, W (B) X, Z, Y, W
butyl ethyl ether.
(C) W, Y, Z, X (D) W, Z, Y, X
(A) R = (CH3)3C- R' = CH3CH2-
(B) R = (CH3)2CH- R' = (CH3)2CH-
(C) R =CH3CH2- R' = (CH3)3C-
(D) R =CH3CH2- R' = (CH3)2CH-
43.Which alkyl group is attached around
the double bond of the major product
alkyne from the reaction of 2-
chloropentane with alcoholic KOH?
(A) Methyl, propyl(B) Ethyl, Methyl
(C) Methyl, Isopropyl (D) Methyl, Butyl
40. State the chromium complex of the
Etard
(A) Ethanamine(B) Propane-1-amine
(C) Propane-2-amine(D) Methanamine
41.Match Column-I (Test Name) with 45.In which of the following pairs is the
Column-II (Assay of Combination) given first compound more activethan the
belowcorrectly.
second compound for the indicated (D) The base cytosine present in it is of
process? pyrimidine type
(A) 1° alcohol, 2 alcohol, 50.State true for thyroxine produced in
dehydrationProcess thyroid gland.
(A) an iodinated derivative of tyrosine.
(B) Its increase leads to hypothyroidism.
(С) СН3CHO, СН3COСН3 , dendritic
additionprocess (C) Its elevation can be avoided by using
iodized salt.
(D) C6H5Cl, P– NO2C6H4Cl, arboreal
displacement process (D) Its increase leads to depression,
Obesit
46.State the total number of chiral
carbons in the linear structureof glucose.
(A) 4(B) 3(C) 5(D) 6
47. Which is the correct pair for the
following amino acidand its nature?
(A) Glycine-neutral, glutamic acid-acidic,
arginine-neutral
(B) Alanine-neutral, aspartic acid-acidic,
arginine-basic
(C) glycine-neutral, aspartic acid-
acidic,lysine-neutral
(D) Glycine-neutral, valine-neutral,
isoleucine-basic
48.Name and available source of vitamin
B2 respectively.
(A) Thiamine, milk(B) Pyridoxine, gram
(C) Riboflavin, egg white(D) Ascorbic
acid,amla
49. State the incorrect statement for
nucleic acid.
(A) It is a long chain of nucleotides.
(B) It is formed by the attachment of a
nucleoside to a Base.
(C) It is responsible for heredity.
PART – B
SECTION -A
Write short answers to any 8 questions from questions 1 to 12 given below,
Eachquestion carries 2 marks. [16]
1.Decomposition of N2O5 into NO2 and O2 takes place as per the provein below.
the initial concentration of N2O5Is 0.5 M. At the end of the process, if decreases
0.1 M, how much will Dricentration of NO2 have?
2. Write down the process at the anode and cathodefor a mercury cell and
approximately howmuch voltage does it produce Describe.
3. Process equation at anode-cathode for electrolysis of aqueous solution of
AgNO3 with Pt electrodes Describe.
4. Name the hexagonal ligand and draw its structure.
5. Show the transformation of but-1-ene to n-butyl iodide in two steps.
6. reactions that occur when the ph of an aqueous solution of chromate (Cro4-2)
and dichromate (Cr2o7-2) ions changes.
7. Amino acid compounds have higher melting points and water solubility than
their corresponding carboxylic acid compoundsexplain.
8. Explain Stephan reduction process with one example.
9. Explain the inversion of sucrose by giving an equation.
10. Name and structure of sugars of DNAand RNA in nucleic acid structure.
11. Calculation of molecular mass is easy by osmotic pressure method explain.
12. Give the manufacturing process of aspirin. State its use.
SECTION -B
From questions 13 to 21 given below, answer any 6 questions in detail. (Each
question carries 3 marks.) [18]
13. The vapor pressures of pure liquids A and B at 350 K are 450 and 700 mm
Hg respectively. If the total vapor pressure 600mm Hg Find the density of the
liquid mixture. And find the concentration of A and B in the vapor phase.
14. Derive the formula of Arrhenius equation for two different temperatures.
15. Explain intermolecular compounds of transition metals.
16. Explain with examples the methods of inversion, assumption and
resummation.
17. Give the Gabriel phthalimide synthesis equation and explain.
18. Explain the coupling processes of banzin diazonium chloride.
19. State the main result of heating each of the following ether compounds
with 1 mole of HI
20. Write three points of difference between amylose and amylopectin, the
main components present in starch.
21. Explain in terms of CFT the color exhibited by [Ti(H2O)6]+3 negative ion. If
the H2O ligand is removed, why is the colourless becomes explain.
SECTION -C
From questions 22 to 27 below, answer any 4 questions in detail as required.
(Each question carries 4 marks.) [16]
22. Explain the method for obtaining alcohols from alkenes by acid catalyzed
hydrogenation with mechanism.
23. The conductivity of 0.00241 M acetic acid is 7.896 x 10-5 Scm-1 Calculate its
molar conductivity. If acetic acidValue of ^0m is 390.5 Scm2mol-1respectively for
then calculate its dissociation constant.
24. The time required for 10% completion of a first order process at 298 K is
the same as the time required for 25% completion of the same process at 308
K. If the value of A is 4 x 1010 s-1 calculate k and Ea at 318 K temperature.
25. Explain magnetic properties and hybridization by valence bonding in
[Co(NH3)6]+3.
26.Explain the decarboxylation process for carboxylic acids with equation and
explain Kolbe's electrolysis.
27.How many ml of 0.1 M HCI solution will be required to completely process 1
g of a mixture containing equimolar amounts of both substancesNa2co3and
NaHCO3?
