It is desired to market oxygen in small cylinders having volumes of 0.

5 CU t and
each containing 1.0 lb of oxygen. If the cylinders may be subjected to a
muSt be
maxmum femperature of 120°F, calculate the pressure of which fhey
designed, assuming the applicability of:fhe ideal-gas law.
bmol O, 2 32 6/U003125 bmol
32F = 273-15 K
120 F = 322: 0 38 K

Py,=n,RT,
I at 359 IXRx 2131S
P x 0-5 O-o3125x Rx 3 22-038

P= 26453 alm.
388-75 hoi
 AT

35J
Z. Calculate the number of cubic feet of hydrogen sulfide,
measured o O
Temperature of 50°C and pressure of 29.5 in Hg, which may be produced
Ib of iron sulfide (FeS). from 7
T= 50C
P = 295 Hg

bml FeS = 88 = 0-079545 bmol

T=323-15 k
P= 295 x2S4 )3600% 9:81= 99968-608 Pu
lo0

Pv,=m,RT,
l01325 X 3 S 9 I RX 273-I5
99968 608 V 0079S45R 3231S

(0 V= 34 242 cube feet

3. An Qutomobile tire is infloted to a ggge pressure of 35 psi at a temperature of
0F. Calculate the maximum temperature to which the tire may be heated
Without the gage pressure exceeding 50 psi. (Assume that the volume of the fire
does not change.)

Gag Pheune 35 ae
lemp = 255 372 K
Po T
y9.7 255 372
647 T

T: 332-446 k
= 54.29°c
= |38 133F
. Calculate the densities in pound per cubic foot at standard conditions and the
specific gravities of the following gases:
(a) ethane, (b) sulfur dioxide, (c) hydrogen sulfide. (d) chlorine.
3
STP
I bml occutus a vole of 354 t at =0 1471 3

Ehane Mars 30o Lb/b mol 359 fE

2.9 b =0-08o779 b
359
b
f=
64 e6 =017827
Sþute Grony
o -083S60344
0-o80779
34 es b 220688
354A3
5. The gas acetylene is produced according to the following reaction by treating
calcium carbide with water:

Caça+ 2H:0 = Cata + Ca(OH)2

Calculate the number of hours of service that çan be derived from 1.0 lb of
carbide in an acetylene lamp burning 2 cu ft of gas per hour at a temperature
of 750F and apressure of 743 mmn Hg.
1b o caleum canbide Caly
Caly t HH0
bimol of CaC, = 0o15625 bmol
bmo of CH, = 00156 25 lbmo
60 x 359 IRX 27315
743 * V O-o/5625 x R 247-0388
3
V= 6:239 fe
Hows Run = 6239 312 hon
2
6. Anatural gas has the following composition by volume: CH 94. 1%
This gas is piped form the wellata
temperature of 80-F and absolute pressure of
50psi. It may be assumed that the ldeal-gos law Is CaHe 3.0
applicable.
Calculate:
(a) Partial pressure of the nitrogen.
N2 2.9
(b) Pure-component volume of nltrogen per 100 cu ft of gas.
(c) Densityof mixture in poundsper cubic foot ont existing conditions
a Pastal bLne of N, = 2:9 50 =1:45 be
C Bsbmol of misde gao
b. |4-7 * 359 1XR% 213-15 Mss (lL)
IR 299-8I6 Mot.Ma
50 N 15 056
044|
cH4 0 03 30
3
0-0 24 28 o 812
Volme o N= 29, 5-8498 = 33596 R b
lo0 Tola: l6 768

Fo ttal voums o 15-8498 f, vdwie of335

3 U5-84g8
I6768 eb 443 OI44739
3-3596 lo0
11S-8448
3
 7. A gas mixture contains 0.274 lb-mole of HCI, 0.337 Ib-mole of nitrogen ondn
Ib-mole of oxygen. Calculate:
(a) The volume occupied by this mixture and
(b) Its density in pounds per cubic foot at a pressure of 40 psi anda temperature
of 30°C.

To tal Mola o214 +0-337 +0-0 89 Mol Mar (s/0me) Mas (U5)
HCL 0274 36S Io-o01
= 07 bmol
N O337
0089
28
32
q436
2-848

Tolal 0: 100 22285

T=303-15 k
| R X 273-15 Tol Man 22-25 B
|4-7 X 354
07R 303-15
= 22. 285 6 =02742
3 lo 2: 44S8 f'
V= lo2"4458 ft
8. A chimney gas has the following composition by volume: CO 9.5%
Using the ideal-gas law, calculate:
CO 0.2
(a) Its composition by weight. 9.6
lb-mol
(b) Volume occupied by 1.0 lb of the gas at 800F ánd N2 80.7
29.5 in. Hg pressure.
(c) Density of thegas in pounds per
cubic foof at the conditions of part b.
(d)Specific gravity of the mixture.
Baisi lo0 bmol C. R= 29 904 b
Uud M MasdUlm Mam(4) Men(7)
45 L4 418 |347 399-8
5-6 01872
Co 0 2 28
307-2 0-273
96 32
N 8o "7 23 2259 6 75 56
d
24404

Mol. Man = 29.9o4 b / d

Avng M At
Numbu of Umol
lo13 25 x 359 IXR 27315 29:904
I R 299-816
29
3
ka V3 8 03117
9. By electrolyzing amixed brine a mixture of gases is
having the following composition by weight: Ch 67% obtained at the cathode
Using the ideal-gas law, calculated: Br2 28

(a)Composition of the gas by volume. O2 5

of Hg pressore
sy of the mixture in grams per iter at 250C and 740 mm
(C) Specific gavily of the mixture.
V= 32-05
Basu I00 Mot Maso Mole Vol 7.
74-017 lo0
67 0.4436 = 312
1373
28 I6o o115 32-05S W
015625 12 25
5 32
M. Mas = 78-44
|-274 8S
Ag I-274 8S mol

740 |· 274 8S xo 08 21 X 2981S Sfete Grvavly 78 44 -=

7844 2705
760 29
10. A mixture of ammonia and air at a pressure of 730 mm Hg and temperature of
30°C of 100 cU ft per
contains 5.1% NH3 by volume, The gas is passed at a rate
gose
, o g han absorption tower in which only ommonigis removed. Ihe
conTaln
ne tower at pressure of 725 m Ha, g temperature of 20°C, and
O.05% NH3 by volume. Using the ideal-gas law, colcUlote:
(a)Rate of flow of gas leaving the tower in cubic feet per minute.
(b) (weight of ammonia obsorbed in the tower per minute.
Miztue of NHa a Au Talal Malea nt 99-952 n o 22 878

730 mm HA 30315 k
760 x 359 J*R 273-15 D:9495x247759x(0 v o 22 878
512. NH, 730 loo mR 303-15 V= 928
)= 0n2%392 ml
n 0 2l)o7 8
L302 15Ki
243k Volume V Moles of Ai =o22218
S-1% NHa Moles of Nt, =0 o1229 =0 o1217S hmd
99-457 Au

760 X359 XR 273-1S

725t y mR% 242|S
T.A producer gos hasthe following composition by volurne:
CO 23%

CO2 4,4

O2 2.6

N2 70.0

100%

(a) Calculate the cubic feet of gas, at 700F and 750mm Hg pressure, per pound
of carbon present.
(b)Calculole the volume of air, at the conditions of part a, required of the
combustion of 100 cu ft of the gas at the same conditions if it is desired that
the total oxygen present before combustion shall be 20% in excess of that
theoreticolly required.
(c) Calculate the percentage composition by volume of the gases leaving the
burner of port b, assuming complete combUstion.
(d) Calculate the volume of the gases leoving the combustion in parts band c
-at a temperature of 6000F and a pressure of 750 mm Hg per 100 cu ft of ggs
 >hoduca Gis Bass loo lbmot Mas of labow = 12 64)+-/12,
44
143¬
Co 23 644
- 276 + 5a-8 = 3 288 I
1936 s

2-6 39190-38
328-&
3

Pv, = mRT 3

76o 359 I R 213-15 R273-IS

|o0 x R29426 mR 294-26

29140- 138 t M=0:2551 Umol of ga

 Co, = o-0|| 2 24 bmo
Usmel
= 0 0o 6632
bmol

O069844 19 3187
I62 /
0, Reyiuud O o0.5 367
T20O024q33S = o035202 lLnl 79 o6
|oo
O 36 80|
Mols of 0 lo be added o o35202 -0 0066 32
= 0 o28s7mo

Moles of he Tolid Lbwmo deavmg = 0 B618o|

21 A =0o 2357 IR 21315

Joo J60x 35q
A 0 I3604 bml

Lbd Vod V= 283664 t

025SI

t do) S3 33