Chapter 5 - Lecture Notes
Chapter 5 - Lecture Notes
Pressure path
in reservoir
Critical
point
Dewpoint line Volatile oil
2
Five Basic
Pressure, psia
Pressure
Black Oil % Liquid
% Liquid
Reservoir
Fluids
33
Separator Separator
Temperature, °F Temperature
Pressure path
in reservoir Pressure path Pressure path
1 in reservoir in reservoir
Retrograde gas 1 1
2
Pressure
Pressure
Wet gas
Pressure
Critical Dry gas
point
% Liquid
Critical % Liquid
% Liquid
point
3 2 2
Separator Separator
Separator
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Pressure-Temperature Diagrams
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Phase Diagrams
Single Gas
Initial Phase
Reservoir Region
Single Liquid State
Phase Critical
Cricondenbar Point
Region
Pressure, psia
Two-Phase
Region
Cricondentherm
% Liquid
Separator
Temperature, °F
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Black Oil
Pressure path
in reservoir
Critical
Point Dewpoint line
Pressure, psia
Black Oil
% Liquid
Separator
Temperature, °F
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Volatile-Oil
2
Volatile oil
% Liquid
Pressure
Separator
Temperature, °F
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Retrograde Gas
Pressure path
in reservoir
1
Retrograde gas
2
Pressure
Critical point
% Liquid
Separator
Temperature
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Wet Gas
Pressure path
in reservoir
1
Wet gas
Pressure
Critical % Liquid
point
2
Separator
Temperature
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Dry Gas
Pressure path
in reservoir
1
Pressure
Dry gas
% Liquid
2
Separator
Temperature
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Field Identification
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Primary Production Trends
GOR
GOR
GOR
GOR
No
liquid
API
API
API
API
No
liquid
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Exercise 1
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Properties of Natural Gas
Equation-of-State (EOS)
Apparent Molecular Weight of Gas Mixture
Density of Gas Mixture
Gas Specific Gravity
Z-factor (Gas Compressibility or Gas Deviation Factor)
Isothermal Compressibility
Gas Formation Volume Factor
Gas Viscosity
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Gas Equation of State (EOS)
T Temperature Rankine
Universal Gas 10.73
R
constant psia.ft3/lb-mole. R
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Molecular Weight of a Gas Mixture
Mg ?
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Density of Gas Mixture
mg nM g p pM g
g = = (lb/ft ) 3
Vg nZRT ZRT
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Gas Specific Gravity
g Mg Mg
g = =
air sc M air 28.97
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Gas Deviation Factor (Z-factor)
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Standing-Katz Chart
p T
p pr ; Tpr
p pc Tpc
Step 3: Use Standings-Katz chart to determine Z
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Dranchuk & Abou-Kassem Correlation
R2
F ( r ) R1 r R 3 r2 R 4 r5 R 5 r2 (1 A11 r2 ) exp( A11 r2 ) 1 0
r
r 0.27 p pr / ( Z T pr )
R1 A1 A2 / T pr A3 / T pr3 A4 / T pr4 A5 / T pr5
R 2 0.27 p pr / T pr
R 3 A6 A7 / T pr A8 / T pr2
R 4 A9 ( A7 / T pr A8 / T pr2 )
R 5 A10 / T pr3
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Wichert-Aziz Correction Method
T pc T pc , o R
120 y H 2S yC O2
0 .9
y H 2S yCO2
1 .6
1 5 y H 2 S 0 .5 y H 2 S 4 .0 ,
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Exercise 3
Given the following real gas composition,
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Sutton Correction Method
Step1: Calculate the parameters J and K:
2
1 Tc 2
0 .5
Tc
J yi yi , o R /p sia
3 i p
c i 3 i p
c i
T ci
K yi , o R /p sia
i p ci
J 0 .6 0 8 1 F J 1 .1 3 2 5 F J2 1 4 .0 0 4 F J y C 7
6 4 .4 3 4 F J y C2 7
Tc
K 0 .3 1 2 9 y C 7 4 .8 1 5 6 y C2 7 2 7 .3 7 5 1 y C3 7
p
c C7
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Sutton Correction Method (cont.)
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Correlations for Pseudo-Critical Properties
of Real Gas Mixture (Standing, 1977)
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Correlations for Pseudo-Critical Properties
of Real Gas Mixture with Impurities
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Isothermal Compressiblity of Real Gas
Mixture
By definition, the compressibility of the gas is
1 dV 1 1 dz
cg or cg
V d p T p z d p T
1 1 dz
c pr c g p pc
p pr z d p p r T pr
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Gas Isothermal Compressiblity Correlation
by Matter, Brar & Aziz (1975)
dz
1 0 .2 7 d r T pr
cg 2
p pr z T pr r dz
1
z d r T
pr
dz
4 r
8 r
8 r
4 2 2 4 2
T 2T 5T 2T 1 A A exp A
d r Tpr
1 2 r 3 r 8 r
A2 A3 A5
T1 A1 3 ; T2 A4 A1 0.3150624 A5 -0.61232032
Tpr Tpr Tpr
A2 -1.04671 A6 -0.10488813
A5 A6 A7 0.27 p pr A3 -0.578327 A7 0.68157001
T3 ; T4 3 ; T5
Tpr Tpr Tpr A4 0.5353077 A8 0.68446549
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Gas Formation Volume Factor
Gas FVF represents changes in volume with respect to pressure and
temperature at two different conditions one of which is normally the
surface condition
V p ,T p sc z T
Bg
V sc T sc p
In field units:
zT
B g 0 .0 2 8 2 7 (ft 3 /sc f)
p
zT
B g 0 .0 0 5 0 3 5 (b b l/scf)
p
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Gas Viscosity
Viscosity of fluid represents how easy the fluid can flow in a
conduit.
Unit: cp (centipoise)
1 poise = 100 cp = 0.1 Pa.s
g f ( p , T , yi )
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Empirical Correlation for Gas Viscosity by
Carr, Kobayashi and Burrows (1954)
Step 1: Calculate pseudo-critical properties and the corrections to
these properties for the presence of nonhydrocarbon gases (CO2,
H2S, N2)
1 1 N CO H S
uc 2 2 2
Step 4: Calculate the gas viscosity from m1 and the viscosity ratio
(mg/m1)
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Atmospheric Gas Viscosity Correlation
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Gas Viscosity Ratio Correlation
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Standing’s Correlation for Atmospheric Gas
Viscosity
1 1 .7 0 9 1 0 5 2 .0 6 2 1 0 6 g T 4 6 0
uc
8 .1 1 8 1 0 3 6 .1 5 1 0 3 lo g g
C O 2 y C O 2 9 .0 8 1 0 lo g g 6 .2 4 1 0
3 3
N 2 y N 2 8 .4 8 1 0 3 lo g ( g ) 9 .5 9 1 0 3
H 2 S y H 2 S 8 .4 9 1 0 3 lo g ( g ) 3 .7 3 1 0 3
1 1 CO N H S
uc 2 2 2
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Dempsey’s Correlation for Gas Viscosity Ratio
a0 = −2.46211820
a1 = 2.970547414
a2 = −2.86264054 (10−1)
a3 = 8.05420522 (10−3)
g a4 = 2.80860949
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Empirical Correlation for Gas Viscosity by
Lee, Gonzalez & Eakin (1966)
Lee et al. expressed gas viscosity as a function of temperature,
density and molecular weight of the gas mixture
g f (T, g , M g )
g Y
g 104 K exp X
62.4
K
9.4 0.02 M T g
1.5
209 19M g T
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Exercise 4
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Properties of Crude Oil
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Crude Oil Density
mo
o (lb/ft ) 3
Vo
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Estimate of Oil Density at (p,T) –
General Formula
350.17 o 0.0764 g Rs
o (lb/ft ) 3
5.615Bo
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Estimate of Oil Density at (p,T) – For Ideal
Solutions with Composition Data
API Method (Daubert and Danner, 1997)
n
C x MW i i
p ,T sc sc sc i 1
C p ,T n
xi MWi
i 1 i , sc
𝜌,
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Estimate of Oil Density at (p,T) – For Ideal
Solutions with Composition Data
C j A A T A T
1
j
2
j j
pr 3
j j 2
pr A T 4
j
pr
j 3
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Estimate of Oil Density at (p,T) – For Ideal
Solutions with Composition Data
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Exercise 5
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Crude Oil Gravity
o
o ; wsc 62.4 lbm/ft 3 350.17 lbm/ bbl
w sc
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Gas Solubility Rs
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Gas Solubility Rs
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Oil Formation Volume Factor Bo
Vo p ,T
Bo , bbl/STB
Vosc
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Oil Formation Volume Factor Bo
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Correlations for Oil Systems
Oil Compressibility
Oil viscosity
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Bubble Point Pressure
1
Rsb C2
pb
C3 API
C1 g exp
T 460
T Temperature of interest oF
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Exercise 6
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Solution Gas Oil Ratio Rs
C3 API
Rs C1 g p exp C2
T 460
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Empirical Constants for Pb and Rs
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Oil FVT Bo – Saturated
API API
Bo 1 A1 Rs A2 T 60 A3 Rs T 60
g g
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Oil FVT Bo – Undersaturated
Bo Bob exp co pb p
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Oil Compressibility co
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Oil Viscosity - Undersaturated
m
p
o ob
pb
m 2.6 p1.187 exp 11.513 8.98 10 5 p
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Oil Viscosity - Saturated
o A od B
A 10.715 Rs 100
0.515
B 5.44 Rs 150
0.338
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Oil Viscosity
od 10 x 1.0
x T 1.163
exp 6.9824 0.04658 API
T Temperature of interest oF
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Exercise 7
For the oil given in Exercise 6, estimate the values of (a) oil
compressibility co, (b) solution gas oil ratio Rs, (c) oil
formation volume factor Bo, and (d) oil viscosity o for the
range of pressure from 100 to 5000 psia. Plot the results as
functions of pressure
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