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JEE-MAIN-2024 (1st February-Second Shift)-MPC-2

PART – A (MATHEMATICS)
SECTION - A
(One Options Correct Type)
This section contains 20 multiple choice questions. Each question has four choices (1), (2), (3) and
(4), out of which ONLY ONE option is correct.

x2  25
*1. If the domain of the function (x) = 
 log10 x 2  2x  15  is  ,    ,   , then
 4  x2 
2 + 3 is equal to:
(1) 140 (2) 175
(3) 125 (4) 150

Ans. (4)
Sol. x2 – 25  0  (x – 5)(x + 5)  0  x  (–, –5]  [5, )
4 – x2  0  x  –2, 2
x2 + 2x – 15 > 0  (x + 5)(x – 3) > 0  x  (–, –5)  (3, )
Taking intersection, we get (–, –5)  [5, )
  = –5,  = 5  2 + 2 = 25 + 125 = 150

1
*2. If z is a complex number such that |z|  1, then the minimum value of z   3  4i  is:
2
5
(1) 2 (2)
2
3
(3) (4) 3
2

Ans. (3)
Sol. We know that |z1 + z2|  ||z1| – |z2||
3  3 5 3
 z    2iˆ   z   2iˆ  1  
2  2 2 2

3. Consider a ABC where A(1, 3, 2), B(– 2, 8, 0) and C(3, 6, 7). If the angle bisector

of
BAC meets

the line BC at D, then the length of the projection of the vector AD on the
vector AC is:
37
(1) (2) 19
2 38
39 38
(3) (4)
2 38 2

Ans. (1)

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JEE-MAIN-2024 (1st February-Second Shift)-MPC-3

 B(1, 3, 2)
Sol. AB  3iˆ  5ˆj  2kˆ  38

AC  2iˆ  3ˆj  5kˆ  38
BD AB 1
   BD = DC
DC AC 1
1 7  1 3
 D  , 7,   AD   ˆi  4ˆj  kˆ
2 2 2 2

    1 ˆi  4 ˆj  3 kˆ    2i  3 j  5k  = 37
ˆ ˆ ˆ B(–2, 8, 0) D C
 AD  AC  
 2 2  38 2 38

4. Consider the relations R1 and R2 defined as aR1b  a2 + b2 = 1 for all a, b  R and


(a, b)R2(c, d)  a + d = b + c for all (a, b), (c, d)  N  N. Then
(1) R1 and R2 both are equivalence relations
(2) only R1 is an equivalence relation
(3) only R2 is an equivalence relation
(4) neither R1 nor R2 is an equivalence relation

Ans. (3)
1
Sol. a2 + a2 = 1  a    (a, a)  R1  a  R  R1 is not reflexive
2
 R1 is not equivalence relation
a + b = b + a  (a, b), (a, b)  R2  R2 is reflexive
If (a, b) R2 (c, d)  a + d = b + c
 If a + d = b + c  c + b = d +a  (c, d) R2 (a, b)  R2 is symmetric
For transitive if we need to see it (a, b) R2 (c, d) and (c, d) R2 (e, f)  (a, b) R2 (e, f)
If (a, b) R2 (c, d)  a + d = b + c ….. (1)
If (c, d) R2 (e, f)  c + f = d + e ….. (2)
Adding equation (1) + (2), we get a + f = b + e  (a, b) R2 (e, f)
 R2 is transitive  R2 is equivalence relation

5. Let the system of equations x + 2y + 3z = 5, 2x + 3y + z = 9, 4x + 3y + z =  have


infinite number of solutions. Then  + 2 is equal to:
(1) 22 (2) 17
(3) 15 (4) 28

Ans. (2)
1 2 3
Sol. D = 0  2 3 1  0   = –13
4 3 
5 2 3
Dx = 0  9 3 1  0   = 15
 3 13
  + 2 = 17

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JEE-MAIN-2024 (1st February-Second Shift)-MPC-4


3
4
6. If  cos x dx  a  b 3 , where a and b are rational numbers, then 9a + 8b is equal to:
0
(1) 2 (2) 1
3
(3) 3 (4)
2
Ans. (1)

3 2
 1  cos 2x  1 2
Sol.   2  dx  4  1  cos 2x  2cos2x dx
0

1 3 cos 4x 3x sin 4x sin2x 3
=    2cos 2x dx   
4 2 2 8 32 4 0
 7 1 7
=  3  a  ,b 
8 64 8 64
9 7
 9a + 8b =   2
8 8

*7. Let  and  be the roots of the equation px2 + qx – r = 0, where p  0. If p, q and r be the
1 1 3 2
consecutive terms of a non constant G.P. and   , then the value of ( – ) is:
  4
(1) 8 (2) 9
20 80
(3) (4)
3 9

Ans. (4)
Sol. Let common ratio of G.P. be R
 ,  are roots of px2 + pRx – pR2 = 0
  +  = –R ;  = –R2
1 1 3  3 1 3 4
       R
  4  4 R 4 3
15 80
( – )2 = ( + )2 – 4 = R2 + 4R2 = 5P2 = 5  
9 9

2
8. Let Ajay will not appear in JEE exam with probability p = , while both Ajay and Vijay
7
1
will appear in the exam with probability q = . Then the probability, that Ajay will appear
5
in the exam and Vijay will not appear is:
9 3
(1) (2)
35 35
24 18
(3) (4)
35 35

Ans. (4)
Sol. Let A denote the event of AJAY appearing in JEE exam and B denote the event of
VIJAY appearing in JEE exam

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JEE-MAIN-2024 (1st February-Second Shift)-MPC-5

2 1
Given P  A    PA  B 
7 5
We need to find P  A  B 
5 1 18
P  A  B  P  A   P  A  B    
7 5 35

x2 y2
*9. Let P be a point on the ellipse   1 . Let the line passing through P and parallel to
9 4
y-axis meet the circle x2 + y2 = 9 at point Q such that P and Q are on the same side of
the x-axis. Then, the eccentricity of the locus of the point R and PQ such that
PR : RQ = 4 : 3 as P moves on the ellipse, is:
13 139
(1) (2)
21 23
13 11
(3) (4)
7 19

Ans. (3)
Sol. P(3 cos , 2 sin )
Line passing through P and parallel to y-axis is x = 3 cos 
 Q(3 cos , 3 sin )
Let R be (h, k)
12cos   9 cos  12sin   6 sin 
 h  k
7 7
7x 2 7y 2
 Locus 2  2  1
21 18
17 17 13
 182 = 212 (1 – e2)  e2  2
 e 
21 21 7

10 10
2
*10. Consider 10 observations x1, x2, …, x10 such that   xi     2 and
i1
  x  
i1
i  40 ,

where ,  are positive integers. Let the mean and the variance of the observations be
6 84 
and respectively. Then is equal to:
5 25 
(1) 2 (2) 1
5 3
(3) (4)
2 2

Ans. (1)
10
 xi 2  10
i 1
Sol. x   0.2  
10 10
 0.2 +  = 1.2   = 1

2 
 xi2   x 2 
84 40  102  2  2  10  36
 
10 25 10 25
2
 5 – 12 + 4 = 0   = 2

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JEE-MAIN-2024 (1st February-Second Shift)-MPC-6

11. let (x) = |2x2 + 5|x| – 3|, x  R. If m and n denote the number of points where is not
continuous and not differentiable respectively, then m + n is equal to:
(1) 5 (2) 3
(3) 2 (4) 0

Ans. (2)
Sol. Let g(x) = 2x2 + 5x – 3 = (2x – 1)(x + 3)  Graph of y = f(x) = |g(|x|)| is
Graph of y = g(x) is

It is continuous everywhere
m=0
1 1
It is non differentiable at x   , x  and x = 0
2 2
n=3

*12. The number of solutions of the equation 4sin2x – 4cos3x + 9 – 4cosx = 0; x  [– 2, 2]
is:
(1) 0 (2) 3
(3) 1 (4) 2

Ans. (1)
Sol. Let cos x = t  4t3 + 4t2 + 4t – 13 = 0 where t  [–1, 1]
Let f(t) = 4t3 + 4t2 + 4t – 13
f(t) = 12t2 + 8t + 4 > 0  t  R
 f(t) is always increasing
f(–1) = –4 + 4 – 4 – 13 = –17
f(1) = 4 + 4 + 4 – 13 = –1
 For t  [–1, 1] f(t) is never 0

*13. Let the locus of the midpoints of the chords of the circle x2 + (y – 1)2 = 1 drawn from the
origin intersect the line x + y = 1 at P and Q. Then, the length of PQ is:
1
(1) (2) 1
2
1
(3) (4) 2
2

Ans. (3)

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JEE-MAIN-2024 (1st February-Second Shift)-MPC-7

Sol. Let the midpoint of chord be (h, k)


 Equation of chord is T = S1
 hx + ky – (y + k) = h2 + k2 – 2k
 It passes through (0, 0)  –k = h2 + k2 – 2k
 Locus is x2 + y2 – y = 0
For P and Q (1 – y)2 + y2 – y = 0
1
 2y2 – 3y + 1 = 0  y = 1,
2
1
 x = 0, x 
2
 1 1 1
 P(0, 1) and Q   ,   PQ 
2 2 2

14. Let  be a non-zero real number. Suppose  : R  R is a differentiable function such


that f(0) = 2 and lim f(x)  1 . If (x) = (x) + 3, for all x  R, then (– loge2) is equal
x 
to _______.
(1) 7 (2) 9
(3) 3 (4) 5

Ans. (2)
dy dy 1
Sol.  y  3   y  3   dx  ln 2  3 = x + c
dx 
 ln |y + 3| = (x + c),
at x = 0, y = 2
1
 ln|2 + 3| = c  c  ln 2  3

1 1
 ln y  3  x  ln 2  3
 
y  3
 ln|y + 3| = x + ln|2 + 3|   e x
2  3
 y + 3 = (2 + 3)ex as x  –, y = 1   + 3 = 0   = –3
 –3y + 3 = –3e–3x  –y + 1 = –e–3x  y = 1 + e–3x
3 log
At x   loge2 ; y  1  e e2  9

x  3 y  4 z 1
15. Let P and Q be the points on the line   which are at a distance of 6
8 2 2
units from the point R(1, 2, 3). If the centroid of the triangle PQR is (, , ), then
2 + 2 + 2 is:
(1) 18 (2) 24
(3) 26 (4) 36

Ans. (1)
Sol. Any point on the line is (8 – 3, 2 + 4, 2 – 1)
It distance from R (1, 2, 3) is 6 units
 8  4 2   2  2 2   2  4 2  6
 722 – 72 + 36 = 36   = 0, 1

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JEE-MAIN-2024 (1st February-Second Shift)-MPC-8

 P(–3, 4, –1) and Q(5, 6, 1)


Centroid (1, 4, 1)  2 + 2 + 2 = 1 + 16 + 1 = 18

1
1
16. The value of 
0

2x 3  3x 2  x  1 3 dx is equal to:

(1) – 1 (2) 2
(3) 0 (4) 1

Ans. (3)
1 1
Sol. Let I    2x 3  3x 2  x  13 dx
0
b b
Using the property  f  x dx   f  a  b  x dx
a a
1 1 1 1
3 2
 I   2 1  x   3 1  x   1  x   1 3 dx =   2x3  3x 2  x  1 3 dx  I
a a

I=0

x 1 y 1 z  2
17. If the mirror image of the point P(3, 4, 9) in the line   is (, , ), then
3 2 1
14 ( +  + ) is:
(1) 102 (2) 138
(3) 132 (4) 108

Ans. (4)
x 1 y 1 z  2 P(3, 4, 0)
Sol. Any point on the line   is
3 2 1
Q(3 + 1, 2 – 1,  + 2)
D.R of PQ (3 – 2, 2 – 5,  – 7) Q
PQ is perpendicular to line 3(3 – 2) + 2(2 – 5) +  – 7 = 0
23
 14 – 23 = 0    P
14
 83 32 51   62 4 12 
 Q , ,   Image P  , ,    14( +  + ) = 108
 14 14 14   7 7 7 

*18. Let Sn denote the sum of the first n terms of an arithmetic progression. If S10 = 390 and
the ratio of the tenth and the fifth terms is 15 : 7, then S15 – S5 is equal to:
(1) 800 (2) 890
(3) 790 (4) 690

Ans. (3)
Sol. S[2a + 9d] = 390  2a + 9d = 78
a  9d 15
  8a – 3d = 0  a = 3  d = 8
a  4d 7
15 5
 S15  S5  6  112  6  32  790
2 2

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JEE-MAIN-2024 (1st February-Second Shift)-MPC-9

*19. Let m and n be the coefficients of seventh and thirteenth terms respectively in the
18 1
 1 
1 1  . Then  n  3 is:
expansion of  x 3  2  m
3   
 2x 3 
1 1
(1) (2)
9 4
4 9
(3) (4)
9 4

Ans. (4)
6 12 12 6
18  1  1  1  1
Sol. n C12     ; m  18C6    
3 2 3 2
1
n 36  n 3 9
  6    
m 2 m 4

 x  1,x is even,  x 3  x  
20. Let (x) =  x  N. If for some a  N, (((a))) = 21, then lim     ,
 2x, x is odd, x a  a
  a  
where [t] denotes the greatest integer less than or equal to t, is equal to:
(1) 169 (2) 121
(3) 225 (4) 144

Ans. (4)
 x  1 ; x is even
Sol. f x  
 2x ; x is odd
If a is even f(f(a)) = f(a – 1) = 2(a – 1)
 f(f(f(a))) = 2(a – 1) – 1  2a – 3
 2a – 3 = 21  a = 12
If a is odd f(f(a)) = f(2a) = 2a – 1
f(f(f(a))) = 2(2a – 1) thus not possible
3
x x
 lim     = 144
x 12 a a

SECTION - B
(Numerical Answer Type)
This section contains 10 Numerical based questions. The answer to each question is rounded off to the
nearest integer value.

*21. Three points O(0, 0), P(a, a2), Q(– b, b2), a > 0, b > 0, are on the parabola y = x2. Let S1
be the area of the region bounded by the line PQ and the parabola, and S2 be the area
S1 m
of the triangle OPQ. If the minimum value of is , gcd(m, n) = 1, then m + n is equal
S2 n
to ________.

Ans. 7

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JEE-MAIN-2024 (1st February-Second Shift)-MPC-10

a2  b2
Sol. Equation of PQ = y  a2 = (x  a) 2
ab (–b, b )Q
 (a  b) x  y + ab = 0 P(a, a2)
a

   a  b x  ab  x  dx
2
 S1 =
b
O(0, 0)
  a  b 2  a2  b2  ab  
= a  b   ab  
 2 3 
1
S2 = ab  a  b 
2
 a  b 2  a2  b2  ab 
 ab   a  b 2 1  a b
S1 2 3 
       2
S2 ab / 2 3ab 3b a 
S1 4  a b 
 minimum value of is    2   m + n = 7
S2 3  b a 

22. The sum of squares of all possible values of k, for which area of the region bounded by
the parabolas 2y2 = kx and ky2 = 2(y – x) is maximum, is equal to _______.

Ans. 8
2
k  1 2  1
Sol. y2  x and  y    x  
2  k k  2k 
For point of intersection
 2  2k
ky 2  2  y  y 2   y  0 and y  2
 k  k 4
2k
k2  4
  2y  ky2 2y2
2k 2 2
 Area bounded   dy 
  2

  2 k
3 k  4 
2  16 
0 3  k2  2  8 
 k 
16
For maximum area we have to minimize k 2  2  8
k
16
k2  2
k  4  k 2  16  8
2 k2
It holds for k =  2

23. If y =
 
x  1 x2  x  1  
(3cos2x – 5)cos3x, then 96y   is equal to ______.
x x x x 15 6

Ans. 105
x2 x  x  x2  x cos5 x cos3 x
Sol. y  
x xx x 5 3
 x  1  x x  x  x  cos5 x cos3 x
y  
x x x x 5 3
dy
 1  cos 4 x sin x  cos2 x sin x
dx

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 dy 9 3 35
 at x = ,  1  
6 dx 32 8 32
 
 96y'   = 105
6

dx 1  x  y 2
24. If  , x(1) = 1, then 5x(2) is equal to_________.
dy y

Ans. 5
dx x 1
Sol.   y
dy y y
1
  y dy 1
Integrating factor = e 
y
x  1 
    2  1 dy  x  1  y 2  cy
y y 
at y = 1, x = 1  c = 3  x = 1  y2 + 3y
at y = 2, x = 1  4 + 6 = 1
 5x(2) = 5

x 12
25. Let : (0, )  R and F(x) = 
2
tf(t)dt . If F(x ) = x
4
+ x5, then  f r 
r 1
2
is equal
0
to ________.

Ans. 219
x2
Sol. F(x2) =  t f  t  dt
0
Differentiating both sides w.r.t. x
F'(x2)  2x = x2 f(x2)  2x
5
 f(x2) = 2 + x
2
12 12
5 5 12  13
  f r 2    2  2 r  24  2  2
 219
r 1 r 1

2
*26. Let ABC be an isosceles triangle in which A is at (– 1, 0), A = , AB = AC and B is on
3
the positive x-axis. If BC = 4 3 and the line BC intersects the line y = x + 3 at (, ),
4
then is _______ .
2

Ans. 36

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Sol. Let AB = AC = x C
Using sine rule
/6
AB BC

sin30 sin120
2/3
4 3 /6
 2x = x=4 A(–1, 0) B
3/2
 B(3, 0)
Equation of BC
1 
y0= x  3   x  3y  3  0
3
Put y = x + 3  x  x  3 3  3  0
3 1  3  6
 x ,y
3 1 3 1
2
4 1296  3  1
   36
2 
4
3  1  9 1  3 
2

27. Let A = 2 – 2 MMT, where M is a real matrix of order 2  1 such that the relation MTM = 1
holds. if  is a real number such that the relation AX = X holds for some non-zero real
matrix X of order 2  1, then the sum of squares of all possible values of  is equal to
__________.

Ans. 2
Sol. Let A = I2  2MMT
M is real matrix 2  1 order
a 
Let M =   a, b  R
b 
a   a2 ab 
 MMT    ab   
b   ab b2 
M M = [a + b2] = [1]  a2 + b2 = 1
T 2

1  2a2 2ab 
Now, I2  2MMT =  A
 2ab 1  2a2 
Now, (A  I) X = 0
1    2a2 2ab   x1 
     0
 2ab 1    2b2   x2 
Since, X is non zero real matrix
1    2a2 2ab 
 0
 2ab 1    2b2 
 (1  )2  2(1  ) (b2 + a2) = 0,  (1  ) [1    2] = 0
=1
      
28. Let a  ˆi  ˆj  kˆ , b  ˆi  8ˆj  2kˆ and c  4iˆ  c 2 ˆj  c 3kˆ be three vectors such that b  a  c  a .

If the angle between the vector c and the vector 3iˆ  4ˆj  kˆ is , then the greatest integer
less than or equal to tan2 is _______ .

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Ans. 38
      
Sol. b  a  c  a  c  b   a  0
     
 c  b is parallel to a  c  b  a
 4iˆ  c ˆj  c kˆ     1 ˆi     8  ˆj     2  kˆ
2 3

  = 5  c2 = –3, c3 = 7

 c  4iˆ  3ˆj  7kˆ
1875 1875
cos   74 26  tan    tan2    38.26
7 49

*29. If three successive terms of a G.P. with common ratio r(r > 1) are the lengths of the sides
of a triangle and [r] denotes the greatest integer less than or equal to r, then 3[r] + [– r] is
equal to _____

Ans. 1
Sol. Let the length of the sides of a triangle are a, ar, ar2
 1 5 
 a + ar > ar2  r2 – r – 1 < 0  r   1, 
 2 
 [r] = 1 and [–r] = –2  3[r] + [–r] = 3 + (–2) = 1

*30. The lines L1, L2, ……, L20 are distinct. For n = 1, 2, 3, …., 10 all the lines L 2n – 1 are
parallel to each other and all the lines L2n pass through a given point P. The maximum
number of points of intersection of pairs of lines from the set {L1, L2, ……., L20} is equal
to ______ .

Ans. 101
Sol. Maximum number of point of intersection will occur if the point of concurrency of L2n
does not lie on the lines L2n – 1 and none of these of the lines from L2n is parallel to L2n – 1
Then number of point of intersection will be
(No. of ways of choosing 1 line from L2n)  (No. of ways of choosing 1 line from L2n – 1) +
1 point of concurrency of L2n
= 10 C1  10 C1  1  101

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PART – B (PHYSICS)
SECTION - A
(One Options Correct Type)
This section contains 20 multiple choice questions. Each question has four choices (1), (2), (3) and
(4), out of which ONLY ONE option is correct.

31. From the statements given below:


(A) The angular momentum of an electron in nth orbit is an integral multiple of  .
(B) Nuclear forces do not obey inverse square law.
(C) Nuclear forces are spin dependant.
(D) Nuclear forces are central and charge independent.
(E) Stability of nucleus is inversely proportional to the value of packing fraction.
Choose the correct answer from the options given below:
(1) (B), (C), (D), (E) only (2) (A), (C), (D), (E) only
(3) (A), (B), (C), (E) only (4) (A), (B), (C), (D) only

Ans. (3)

Sol. Theoretical
 
*32. A body of mass 4 kg experience two forces F1  5i  8j  7k and F2  3i  4j  3k . The
acceleration acting on the body is:
(1) 2i  j  k (2) 4i  2j  2k
(3) 2i  j  k (4) 2i  3j  3k

Ans. (1)
  
Sol. Fnet  F1  F2  8iˆ  4 ˆj  4kˆ

 Fnet
a  2iˆ  ˆj  kˆ
m

33. Monochromatic light of frequency 6  1014 Hz is produced by a laser. The power emitted is
2  10 3 W . How many photons per second on an average are emitted by the source?
(1) 5×1015 (2) 7×1016
(3) 6×1015 (4) 9×1018

Ans. (1)

P
Sol. n(per second) =  5  1015
hr

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34. C1 and C2 are two hollow concentric cubes enclosing charges 2Q and
3Q respectively as shown in figure. The ratio of electric flux passing
through C1 and C2 is:
3Q
(1) 3 : 2 (2) 5 : 2 2Q
(3) 2 : 5 (4) 2 : 3

Ans. (3)

Qc1 2Q 2
Sol.  
Qc2 2Q  3Q 5

35. A galvanometer (G) of 2 resistance is connected in the given 4 6 F


circuit. The ratio of charge stored in C1 and C 2 is:
G C2
2 C1
(1) 1 (2)
3 4 F 6
3 1
(3) (4)
2 2
6V

Ans. (4)

Q1 C1V1 4(3) 1
Sol.    .
Q2 C2 V2 6(4) 2

36. Match List-I with List-II.


List-I List-II
(Number) (Significant figure)
(A) 1001 (I) 3
(B) 010.1 (II) 4
(C) 100.100 (III) 5
(D) 0.0010010 (IV) 6
Choose the correct answer from the options given below:
(1) (A)-(II), (B)-(I), (C)-(IV), (D)-(III) (2) (A)-(IV), (B)-(III), (C)-(I), (D)-(II)
(3) (A)-(I), (B)-(II), (C)-(III), (D)-(IV) (4) (A)-(III), (B)-(IV), (C)-(II), (D)-(I)

Ans. (1)

Sol. Theoretical

*37. A big drop is formed by coalescing 1000 small droplets of water. The surface energy will
become:
1 1
(1) th (2) th
100 10
(3) 100 times (4) 10 times

Ans. (2)

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E2 4 (10R)2  T 1
Sol.  2

E1 1000(4 )R  T 10

*38. A cricket player catches a ball of mass 120g moving with 25 m/s speed. If the catching
process is completed in 0.1 s then the magnitude of force exerted by the ball on the
hand of player will be (in SI unit):
(1) 30 (2) 24
(3) 12 (4) 25

Ans. (1)

P
Sol. F=  30N
t

39. In a metre-bridge when a resistance in the left gap is 2Ω and unknown resistance in the
right gap, the balance length is found to be 40 cm. On shunting the unknown resistance
with 2Ω , the balance length changes by:
(1) 62.5 cm (2) 22.5 cm
(3) 20 cm (4) 65 cm

Ans. (2)

2 X
Sol. 
40 60
X=3
2 6/5
 ,  = 62.5 cm,  = 22.5 cm.
 100  

*40. A diatomic gas    1.4  does 200 J of work when it is expanded isobarically. The heat
given to the gas in the process is:
(1) 800 J (2) 600 J
(3) 700 J (4) 850 J

Ans. (3)

Q nCP T CP 7
Sol.   
w nRT R 2
Q = 700 J

*41. Train A is moving along two parallel rail tracks towards north with speed 72 km/h and
train B is moving towards south with speed 108 km/h. Velocity of train B with respect to
A and velocity of ground with respect to B are (in ms–1):
(1) –50 and –30 (2) –50 and 30
(3) –30 and 50 (4) 50 and –30

Ans. (2)
  
Sol. v BA  VB  VA
VBA = 30 – 20 (taking north direction as positive)

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= 50 m/s.
 
VGB   VBG = 30 m/s

*42. A light planet is revolving around a massive star in a circular orbit of radius R with a
period of revolution T. If the force of attraction between planet and star is proportional to
3
R then choose the correct option:
2

7
(1) T 2  R 2
(2) T 2  R 3
5 3
(3) T 2  R 2
(4) T 2  R 2

Ans. (3)

mv 2 GMm
Sol.  3/2
R R
GM
V=
R1/ 2
2 R 2 R5 /4
T =
V GM

43. A microwave of wavelength 2.0 cm falls normally on a slit of width 4.0 cm. The angular
spread of the central maxima of the diffraction pattern obtained on a screen 1.5 m away
from the slit, will be:
(1) 60 o (2) 45 o
(3) 15 o (4) 30o
Ans. (1)
Sol. a sin  = 
 = 300
Angular speed = 2 = 600

*44. If the root mean square velocity of hydrogen molecule at a given temperature and
pressure is 2 km/s, the root mean square velocity of oxygen at the same condition in
km/s is:
(1) 1.0 (2) 1.5
(3) 2.0 (4) 0.5

Ans. (4)

3RT
Sol. Vrms =
M0
 Vrms  H2
Vrms)o2 =  0.5 km / s
4

45. If frequency of electromagnetic wave is 60 MHz and it travels in air along z direction then
the corresponding electric and magnetic field vectors will be mutually perpendicular to
each other and the wavelength of the wave (in m) is :
(1) 2.5 (2) 5
(3) 10 (4) 2
Ans. (2)

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Sol. C=
 = 5m

46. To measure the temperature coefficient of resistivity  of a B


0.8m 
semiconductor, an electrical arrangement show in the figure A C
is prepared. The arm BC is made up of the semiconductor. G
The experiment is being conducted at 25o C and resistance 1m  3m 
of the semiconductor arm is 3mΩ . Arm BC is cooled at a D

constant rate of 2o C/s . If the galvanometer G shows no


deflection after 10 s, then  is: V=5mV
(1) -1×10 -2 o C-1 (2) -2×10 -2 o C-1
(3) -2.5×10 -2 o C -1 (4) -1.5×10 -2 o C -1

Ans. (1)

R1 R3
Sol. 
R 2 R4
R = RT
0.8 x

1 3
x = 2.4 m
x = -0.6 m
x
 T
x
 = 1  10-2 0C-1

47. Conductivity of a photodiode starts changing only if the wavelength of incident light is
 X
less than 660 nm. The band gap of photodiode is found to be   eV . The value of X is:
8
-34 -19
(Given, h = 6.6×10 Js, e = 1.6×10 C ) .
(1) 11 (2) 13
(3) 15 (4) 21

Ans. (3)

hc Xe
Sol. 
 8
X = 15

48. A transformer has an efficiency of 80% and work at 10 V and 4 kW. If the secondary
voltage is 240 V, then the current in the secondary coil is:
(1) 1.33 A (2) 13.33 A
(3) 1.59 A (4) 15.1 A
Ans. (2)
Sol. P  0.8 =VSIS .
IS = 13.33 A

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49. In an ammeter, 5% of the main current passes through the galvanometer. If resistance of
the galvanometer is G, the resistance of ammeter will be:
(1) 199 G (2) 200 G
G G
(3) (4)
200 199

Ans. (none)

G 95
Sol. 
X 9
X = G/19
GX G
R= 
G  X 20

*50. A disc of radius R and mass M is rolling horizontally


without slipping with speed  , it then moves up an
inclined smooth surface as shown in figure. The  h
maximum height that the disc can go up the incline is:
3 2 2
(1) (2)
4 g g
2 2 1 2
(3) (4)
3 g 2 g

Ans. (4)

1
Sol. mv 2  mgh (Rotational K.E. remains constant)
2
v2
H=
2g

SECTION - B
(Numerical Answer Type)
This section contains 10 Numerical based questions. The answer to each question is rounded off to the
nearest integer value.

*51. A mass m is suspended from a spring of negligible mass and the system oscillates with
a frequency f1 . The frequency of oscillation if a mass 9 m is suspended from the same
f1
spring is f2 . The value of is_________.
f2

Ans. 3

1 k
Sol. f
2 m

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f1 9m
 3
f2 m

52. In an electrical circuit drawn below the amount of charge stored 10 V


R1
4
in the capacitor is _______ C. + –

C R2

10  F 5

R3 6

Ans. 60

Sol. At steady state


10
I  1A
46
V = 6V
Q = 60 C

*53. A particle initially at rest starts moving from reference point x = 0 along x – axis, with
velocity  that varies as   4 x m / s . The acceleration of the particle is __________
ms-2

Ans. 8

Vdv
Sol. a=
dx
 1 
= (4 x )  4  
 2 x
= 8 m/s2

54. Suppose a uniformly charged wall provides a uniform electric field of 2×10 4 N/C
normally. A charged particle of mass 2 g being suspended through a silk thread of length
20 cm and remain stayed at a distance of 10 cm from the wall. Then the charge on the
1
particle will be C where x  ______ . use g  10 m / s 2  .
x
Ans. 3
qE
Sol. tan  =
mg
1 mg 1 2  103  10 1
Q=  4
= C
3 E 3 2  10 3

55. A moving coil galvanometer has 100 turns and each turn has an area of 2.0 cm2. The
magnetic field produced by the magnet is 0.01 T and the deflection in the coil is 0.05
radian when a current of 10 mA is passed through it. The torsional constant of the
suspension wire is x  10 5 N  m / rad . The value of x is ________
Ans. 4

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Sol. G = nIAB
N  10-5  0.05 = 100  10-2  2 10-4  0.01
N=4

*56. One end of a metal wire is fixed to a ceiling and a load of 2 kg hangs from the other end.
A similar wire is attached to the bottom of the load and another load of 1 kg hangs from
this lower wire. Then the ratio of longitudinal strain of upper wire to that of the lower wire
will be _______
[Area of cross section of wire = 0.005 cm2, Y  2  1011 Nm 2 and g  10 m / s 2 ].
Ans. 3
T
Sol. =
A
 1 T1
 3
 2 T2

o
57. In Young’s double slit experiment, monochromatic light of wavelength 5000 Α is used.
The slits are 1.0 mm apart and screen is placed at (1)0 m away from slits. The distance
from the centre of the screen where intensity becomes half of the maximum intensity for
the first time is _________ 106 m.
Ans. 125
 dy
Sol. I = Imax cos2
D
Y = 125  10-6 m

58. A coil of 200 turns and area 0.20 m2 is rotated at half a revolution per second and is
placed in uniform magnetic field of 0.01 T perpendicular to axis of rotation of the coil.
2
The maximum voltage generated in the coil is volt. The value of β is __________.
β
Ans. 5
Sol. max = nBA
= 0.4 
=5
*59. A uniform rod AB of mass 2 kg and length 30 cm at rest on a smooth horizontal surface.
An impulse of force 0.2 Ns is applied to end B. The time taken by the rod to turn through

at right angles will be s, where x = ___________.
x
Ans. 4
J m  2
Sol.  
2 12
 

2 x
x=4

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60. A particular hydrogen-like ion emits the radiation of frequency 3  1015 Hz when it makes
transition from n = 2 to n = 1. The frequency of radiation emitted in transition from n = 3
x
to n = 1 is  1015 Hz , when x = ________.
9

Ans. 32

 1 1
Sol. h = 13.6 z2  2
 2
 n1 n2 
x 1
 1015 1 2
9  3 .
3  1015 1
1 2
2
x = 32

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PART – C (CHEMISTRY)
SECTION - A
(One Options Correct Type)
This section contains 20 multiple choice questions. Each question has four choices (1), (2), (3) and
(4), out of which ONLY ONE option is correct.

*61. In the given reactions identify A and B


CH3 C2H5
Pd/C
H2 + A C=C
H H
Na/LiquidNH3
CH3  C  C  CH3  H2  "B "
(1) A : n – Pentane B : Cis – 2 – butene
(2) A : 2 – Pentyne B : Cis – 2 – butene
(3) A : n – Pentane B : trans – 2 – butene
(4) A : 2 – Pentyne B : trans – 2 – butene

Ans. (4)
Sol. A  CH3  C  C  CH2  CH3
H3C H

B C C
H CH3
A will produce cis alkene and Na/Liquid NH3 gives trans alkene.

*62. Solubility of calcium phosphate (molecular mass, M) in water is W g per 100 mL at 25°C.
Its solubility product at 25°C will be approximately.
3 5
W W
(1) 107   (2) 103  
M M
5 5
W W
(3) 107   (4) 105  
M M

Ans. (3)
w
Sol. S  10 / L
M


Ca3  PO4 2  s  
 3Ca  2PO4
 3S 2S
5 5
3 2 3 2 5 W  W
4    3S   2S   104   S   104 
Ksp  Ca   PO    10   107  
M  M

*63. Given below are two statements:


Statement (I): SiO2 and GeO2 are acidic while SnO and PbO are amphoteric in nature.
Statement (II): Allotropic forms of carbon are due to preprety of catenation and p  d
bond formation.

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In the light of the above statements, choose the most appropriate answer from the
options given below:
(1) Statement I is false but Statement II is true
(2) Both Statement I and Statement II are false
(3) Both Statement I and Statement II are true
(4) Statement I is true but Statement II is false

Ans. (4)

*64. The set of meta directing functional groups from the following sets is:
(1) CN,  NH2 ,  NHR,  OCH3 (2) CN,  CHO,  NHCOCH3 , COOR
(3) NO2 , NH2 , COOH, COOR (4) NO2 , CHO, SO3H, COR

Ans. (4)

65. [Co(NH3 )6 ]3  and[CoF3 ]3  are respectively known as:


(1) Inner orbital complex, spin paired complex
(2) Spin paired complex, spin free complex
(3) Spin free complex, spin paired complex
(4) Outer orbital complex, inner orbital complex
Ans. (2)
Sol. NH3 is strong ligand while F– is weak ligand.

66. The transition metal having highest 3rd ionisation enthalpy is:
(1) Mn (2) Fe
(3) Cr (4) V

Ans. (1)

Sol. Mn  25    Ar  ,4s 2 , 3d5


Mn   Ar  4s0 ,3d5 ,d5 is stable due to half filled subshell.

67. Match List-I with List-II


List-I Compound List-II Use
(A) Carbon tetrachloride (I) Paint remover
(B) Methylene chloride (II)Refrigerators and air
conditioners
(C) DDT (III) Fire extinguisher
(D) Freons (IV) Non Biodegradable insecticide
Choose the correct answer from the options given below:
(1) (A) – (II), (B) – (III), (C) – (I), (D) – (IV) (2) (A) – (III), (B) – (I), (C) – (IV), (D) – (II)
(3) (A) – (I), (B) – (II), (C) – (III), (D) – (IV) (4) (A) – (IV), (B) – (III), (C) – (II), (D) – (I)

Ans. (2)

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68. Match List-I with List-II


List-I Reactants List-II Product
(A) Phenol, Zn /  (I) Salicylaldehyde
(B) Phenol, CHCl3 ,NaOH,HCl (II) Salicylic acid
(C) Phenol, CO2, NaOH, HCl (III) Benzene
(D) Phenol, Conc. HNO3 (IV) Picric acid
Choose the correct answer from the options given below:
(1) (A) – (IV), (B) – (I), (C) – (II), (D) – (III) (2) (A) – (III), (B) – (I), (C) – (II), (D) – (IV)
(3) (A) – (IV), (B) – (II), (C) – (I), (D) – (III) (4) (A) – (III), (B) – (IV), (C) – (I), (D) – (II)

Ans. (2)

69. Given below are two statements:


Statement (I): Dimethyl glyoxime forms a six-membered covalent chelate when treated
with NiCl2 solution in presence of NH4OH.
Statement (II): Prussian blue precipitate contains iron both in (+2) and (+3) oxidation
states.
In the light of the above statements, choose the most appropriate answer from the
options given below:
(1) Statement I is false but Statement II is true
(2) Both Statement I and Statement II are true
(3) Statement I is true but Statement II is false
(4) Both Statement I and Statement II are false

Ans. (1)

70. alc. KOH Br2 KCN


C2H5Br A B C +
CCl4 Excess H3 O
Excess

D
Acid D formed in above reaction is:
(1) Malonic acid (2) Oxalic acid
(3) Succinic acid (4) Gluconic acid
Ans. (3)
Br Br H2C CN H2C COOH
| |
Sol. A  CH2  CH2 , B  C H2  C H2 , C= , D=
H2C CN H2C COOH

71. Lassaigne’s test is used for detection of:


(1) Phosphorous and halogens only
(2) Nitrogen, sulphur and phosphorus only
(3) Nitrogen, sulphur, phosphorus and halogens
(4) Nitrogen and sulphur only

Ans. (3)

72. The strongest reducing agent among the following is:


(1) SbH3 (2) NH3
(3) BiH3 (4) PH3
Ans. (3)

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73. Given below are two statements: one is labelled as Assertion (A) and the other is
labelled as Reason (R)
Assertion (A): In aqueous solutions Cr 2  is reducing while Mn3  is oxidising in nature.
Reason (R): Extra stability to half filled electronic configuration is observed than
incompletely filled electronic configfurations.
In the light of the above statements, choose the most appropriate answer from the
options given below.
(1) (A) is true but (R) is false
(2) Both (A) and (R) are true and (R) is the correct explanation of (A)
(3) Both (A) and (R) are true but (R) is not the correct explanation of (A)
(4) (A) is false but (R) is true

Ans. (2)

*74. The functional group that shows negative resonance effect is:
(1) –OH (2) –OR
(3) –COOH (4) –NH2

Ans. (3)

*75. The number of radial node/s for 3p orbital is:


(1) 3 (2) 2
(3) 1 (4) 4

Ans. (3)

Sol. Radial node  n    1   3  1  1  1

*76. Which among the following has highest boiling point?


(1) CH3 CH2 CH2 CH2  OH (2) CH3 CH2 CH2 CH3
(3) CH3 CH2CH2 CHO (4) H5 C2  O  C2H5

Ans. (1)

Sol. Due to H-bonding

*77. Given below are two statements:


Statement (I): A  bonding MO has lower electron density above and below the inter-
nuclear axis.
Statement (II): The  * antibonding MO has a node between the nuclei.
In the light of the above statements, choose the most appropriate answer from the
options given below:
(1) Both Statement I and Statement II are true
(2) Both Statement I and Statement II are false
(3) Statement I is true but Statement II is false
(4) Statement I is false but Statement II is true

Ans. (4)

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78. Given below are two statements:


Statement (I): Both metals and non-metals exist in p and d-block elements.
Statement (II): Non-metals have higher ionisation enthalpy and higher electronegativity
than the metals.
In the light of the above statements, choose the most appropriate answer from the
options given below.
(1) Both statement I and statement II are false
(2) Both statement I and statement II are true
(3) Statement I is false but statement II is true
(4) Statement I is true but statement II is false

Ans. (3)

79. Which of the following compounds show colour due to d-d transition?
(1) K 2 Cr2 O7 (2) CuSO4 .5H2 O
(3) KMnO 4 (4) K 2CrO 4

Ans. (2)

*80. Select the compound from the following that will show intramolecular hydrogen bonding.
NO2

(1) (2) H2O


OH
(3) C2H5 OH (4) NH3

Ans. (1)
SECTION - B
(Numerical Answer Type)
This section contains 10 Numerical based questions. The answer to each question is rounded off to the
nearest integer value.

81. The number of tripeptides formed by three different amino acids using each amino acid
once is ___.

Ans. 6

82. Mass of ethylene glycol (antifreeze) to be added to 18.6 kg of water to protect the
freezing point at –24°C is _________ kg (Molar mass in g mol–1 for ethylene glycol 62, Kf
of water = 1.86 K kg mol–1)

Ans. 15
K f  w  1000 1.86  w  1000
Sol. T  ,24  , w  14.88kg
MW 62  18.6  1000

*83. Total number of isomeric compounds (including stereoisomers) formed by


monochlorination of 2-methylbutane is ___________ .

Ans. 6

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Sol. I CH3  C H  CH2  CH2  Cl 1


|
CH3
Cl
|
II CH3  C H  C H  CH3 1  1
| *
CH3
Cl
|
III CH3  C  CH2  CH3 1
|
CH3
Cl
| *
IV  C H2  C H  CH2  CH3 1  1
|
CH3

84. The following data were obtained during the first order thermal decomposition of a gas A
at constant volume:
A(g)  2B(g)  C(g)
S. No. Time/s Total pressure/(atm)
(1) 0 0.1
(2) 115 0.28
The rate constant of the reaction is __________ × 10–2 s–1 (nearest integer)

Ans. 2

A  2B  C
Sol.
0.1 0 0 t 0
 0.1  Px  2Px Px t  115 sec
According to question
0.28  0.1  Px  2Px  Px

Px 
 0.28  0.1  0.09
2
2.303 0.1
K log  2  102
115  0.1  0.09 

*85. For a certain reaction at 300K, K = 10, then G for the same reaction is ________
–1 –1
101 kJmol1 . (Given R = 8.314 JK mol )

Ans. 57
2.303  8.314  300  log10
Sol. G0  2.303RTlogK    5.74  57.4  101kJ / mol
1000

86. The amount of electricity in Coulomb required for the oxidation of 1 mol of H2O to O2 is
____ 105 C .

Ans. 2

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1
Sol. H2O  O2  2H  2e 
2
2  96500  193000C  1.93  105
1.93  2

*87. Following Kjeldahl’s method, 1g of organic compound released ammonia, that


neutralised 10 mL of 2M H2 SO4 . The percentage of nitrogen in the compound is
_______ %.

Ans. 56
1.4  10  2  2
Sol. %N   56
1

88. Consider the following redox reaction:




MnO 4  H  H2 C2O 4  2
 Mn  H2 O  CO2
The standard reduction potentials are given as below (Ered):
EoMnO /Mn2  1.51 V
4

o
E CO2 /H2 C 2O 4
 0.49 V
If the equilibrium constant of the above reaction is given as K eq  10x , then the value of
x = _______ (nearest integer)

Ans. 338
Sol. E0cell  E0c  E0A  0.49  1.51
0.0591
0  E0cell  logK
n
0.0591
E0cell  log K eq
10
0.0591
2  log K eq
10
K eq  10338
x = 338

89. Number of compounds which give reaction with Hinsberg’s reagent is __________ .
O O NH2
 
N Cl
2
NH

N NH2
NH N
I NH2

NH2 O
||
N N H2N  C  NH2
|
H
Ans. 5

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*90. 10 mL of gaseous hydrocarbon on combustion gives 40 mL of CO2(g) and 50 mL of


water vapour. Total number of carbon and hydrogen atoms in the hydrocarbon
is __________.
Ans. 14
Sol.  y y
CxHy   x   O2  xCO2  H2O
 4 2
10 10x
10x  40
x=4
10y
 50
2
y  10
C 4H10
x  y  4  10  14

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