SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

Synergen OS Page 1(10)

Substance key: 000000487615 Revision Date: 06.10.2015
Version : 1 - 6 / EU Date of printing : 17.09.2018

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Trade name
Synergen OS
Material number: 260360
Chemical nature: Copolymer in rapeseed oil methyl ester

1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses of the substance or mixture
Industry sector : Crop Protection
Type of use : Auxiliary for formulating plant protection products

1.3. Details of the supplier of the safety data sheet

Identification of the company
Clariant Produkte (Deutschland) GmbH

65926 Frankfurt am Main

Telephone no. : +49 69 305 18000
Information about the substance/mixture
BU Industrial & Consumer Specialties
Product Stewardship
e-mail: [email protected]

1.4. Emergency telephone number

00800-5121 5121 (24 h)

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)
Not a hazardous substance or mixture.
2.2 Label elements
Labelling (REGULATION (EC) No 1272/2008)
Not a hazardous substance or mixture.

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of
0.1% or higher.
No additional hazards are known except those derived from the labelling.
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

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Substance key: 000000487615 Revision Date: 06.10.2015
Version : 1 - 6 / EU Date of printing : 17.09.2018

SECTION 3: Composition/information on ingredients

3.2 Mixtures
Hazardous components
Remarks : No hazardous ingredients

SECTION 4: First aid measures

4.1 Description of first aid measures

General advice : Remove/Take off immediately all contaminated clothing.
Show this safety data sheet to the doctor in attendance.

In case of skin contact : In case of contact, immediately flush skin with soap and plenty
of water.

In case of eye contact : In the case of contact with eyes, rinse immediately with plenty
of water and seek medical advice.

If swallowed : Call in a physician immediately and show him the Safety Data
Sheet.

4.2 Most important symptoms and effects, both acute and delayed
Symptoms : The possible symptoms known are those derived from the
labelling (see section 2).

Risks : The possible risks known are those derived from the labelling
(see section 2).

4.3 Indication of any immediate medical attention and special treatment needed
Treatment : Treat symptomatically.

SECTION 5: Firefighting measures

5.1 Extinguishing media

Suitable extinguishing media : Water spray jet
Alcohol-resistant foam
Dry powder
Carbon dioxide (CO2)

Unsuitable extinguishing : High volume water jet

media

5.2 Special hazards arising from the substance or mixture

Specific hazards during : In case of fire hazardous decomposition products may be
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

Synergen OS Page 3(10)

Substance key: 000000487615 Revision Date: 06.10.2015
Version : 1 - 6 / EU Date of printing : 17.09.2018

firefighting produced such as:

Carbon monoxide
Carbon dioxide (CO2)
Acrolein
Combustion gases of organic materials must in principle be
graded as inhalation poisons.

5.3 Advice for firefighters

Special protective equipment : Self-contained breathing apparatus
for firefighters

Further information : Wear suitable protective equipment.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions : Wear suitable protective equipment.
Ensure adequate ventilation.

6.2 Environmental precautions

Environmental precautions : The product should not be allowed to enter drains, water
courses or the soil.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up : Soak up with inert absorbent material (e.g. sand, silica gel,
acid binder, universal binder, sawdust).
Can be landfilled or incinerated, when in compliance with local
regulations.

6.4 Reference to other sections

Information regarding Safe handling, see chapter 7., For personal protection see section 8., For
disposal considerations see section 13.

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Advice on safe handling : No special measures necessary if stored and handled as
prescribed.

Advice on protection against : Observe the general rules of industrial fire protection
fire and explosion

Hygiene measures : Observe the usual precautions for handling chemicals. When
using do not eat or drink. Keep away from food and drink.
Wash hands before breaks and at the end of workday.
Remove/Take off immediately all contaminated clothing.
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

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Substance key: 000000487615 Revision Date: 06.10.2015
Version : 1 - 6 / EU Date of printing : 17.09.2018

7.2 Conditions for safe storage, including any incompatibilities

Further information on : - sensitive to frost - In case of the product becoming opaque,
storage conditions thickening or being frozen due to the effects of cold, allow to
thaw slowly at room temperature. Stir briefly before use. Keep
containers tightly closed in a cool, well-ventilated place.

7.3 Specific end use(s)

Specific use(s) : No further recommendations.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

8.2 Exposure controls
Personal protective equipment
Eye protection : Safety glasses

Hand protection
Remarks : These types of protective gloves are offered by various
manufacturers. Please note the manufacturers´ detailed
statements, especially about the minimum thickness and the
minimum breakthrough time. Consider also the particular
working conditions under which the gloves are being used.

Break through time : 30 min

Glove thickness : 0,4 mm
Remarks : For short-term exposure (splash protection): Nitrile rubber
gloves.

Break through time : 480 min

Glove thickness : 0,7 mm
Remarks : Long-term exposure Impervious butyl rubber gloves

Skin and body protection : working clothes

Protective measures : Observe the usual precautions for handling chemicals.

Avoid contact with skin and eyes.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Appearance : viscous liquid
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according to Regulation (EC) No. 1907/2006

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Substance key: 000000487615 Revision Date: 06.10.2015
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Particle size : Not applicable

Colour : brown

Odour : characteristic

Odour Threshold : not determined

pH : 3-8
Concentration: 50 g/lEthanol/Water 1:1

Solidification point : 1 °C
Method: ISO 3016

Boiling point : > 150 °C

Data relate to solvent
Flash point : 179 °C
Method: DIN EN 22719 / ISO 2719 (closed cup)

Evaporation rate : not determined

Upper explosion limit : Not applicable

Lower explosion limit : Not applicable

Combustion number : Not applicable

Vapour pressure :
not determined

Relative vapour density : not determined

Density : 1,015 g/cm3 (20 °C)

Method: DIN EN ISO 12185

0,985 g/cm3 (60 °C)

Method: DIN EN ISO 12185

Bulk density : Not applicable

Solubility(ies)
Water solubility : self-emulsifiable

Solubility in other solvents : not determined

Solvent: fat

Partition coefficient: n- : Not applicable

octanol/water

Auto-ignition temperature : not determined

SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

Synergen OS Page 6(10)

Substance key: 000000487615 Revision Date: 06.10.2015
Version : 1 - 6 / EU Date of printing : 17.09.2018

Decomposition temperature : 354 °C

Heating rate : 3 K/min
Method: DSC

Viscosity
Viscosity, dynamic : 8.550 mPa.s (20 °C)
Method: DIN 53019

Viscosity, kinematic : not determined

Explosive properties : Not explosive

Method: Expert judgement

Oxidizing properties : The substance or mixture is not classified as oxidizing.

Method: Expert judgement

9.2 Other information

no data available

SECTION 10: Stability and reactivity

10.1 Reactivity
See section 10.3. "Possibility of hazardous reactions"
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
Hazardous reactions : No dangerous reaction known under conditions of normal use.

10.4 Conditions to avoid

Conditions to avoid : None known.

10.5 Incompatible materials

Materials to avoid : Strong oxidizing agents

10.6 Hazardous decomposition products

When handled and stored appropriately, no dangerous decomposition products are known

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity
Product:
Acute oral toxicity : Remarks: no data available
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

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Substance key: 000000487615 Revision Date: 06.10.2015
Version : 1 - 6 / EU Date of printing : 17.09.2018

Acute inhalation toxicity : Remarks: no data available

Acute dermal toxicity : Remarks: no data available

Skin corrosion/irritation
Product:
Remarks: no data available

Serious eye damage/eye irritation

Product:
Remarks: no data available

Respiratory or skin sensitisation

Product:
Remarks: no data available

Germ cell mutagenicity

Product:
Germ cell mutagenicity- : No information available.
Assessment

Carcinogenicity
Product:
Carcinogenicity - : No information available.
Assessment

Reproductive toxicity
Product:
Reproductive toxicity - : No information available.
Assessment

No information available.

STOT - single exposure

Product:
Remarks: no data available

STOT - repeated exposure

Product:
Remarks: no data available
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

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Substance key: 000000487615 Revision Date: 06.10.2015
Version : 1 - 6 / EU Date of printing : 17.09.2018

Repeated dose toxicity

Product:
Remarks: This information is not available.

SECTION 12: Ecological information

12.1 Toxicity
Product:
Toxicity to fish : Remarks: no data available

Toxicity to daphnia and other : Remarks: no data available

aquatic invertebrates

Toxicity to algae : Remarks: no data available

Toxicity to bacteria :
Remarks: no data available

12.2 Persistence and degradability

Product:
Biodegradability : Remarks: no data available

12.3 Bioaccumulative potential

Product:
Bioaccumulation : Remarks: no data available

12.4 Mobility in soil

Product:
Distribution among : Remarks: no data available
environmental compartments

12.5 Results of PBT and vPvB assessment

Product:
Assessment : This substance/mixture contains no components considered
to be either persistent, bioaccumulative and toxic (PBT), or
very persistent and very bioaccumulative (vPvB) at levels of
0.1% or higher..

12.6 Other adverse effects

Product:
Environmental fate and : no data available
pathways

Additional ecological : Remarks: The product should not be allowed to enter drains,
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

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Substance key: 000000487615 Revision Date: 06.10.2015
Version : 1 - 6 / EU Date of printing : 17.09.2018

information water courses or the soil.

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Product : In accordance with local authority regulations, take to special
waste incineration plant

Contaminated packaging : Regulations concerning reuse or disposal of used packaging

materials must be observed.

SECTION 14: Transport information

Section 14.1. to 14.5.

ADR not restricted
ADN not restricted
RID not restricted
IATA not restricted
IMDG not restricted

14.6. Special precautions for user

See sections 6 to 8 of this Safety Data Sheet.

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code (International
Bulk Chemicals Code)
No transport as bulk according IBC - Code.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
Volatile organic compounds : Directive 1999/13/EC on the limitation of emissions of volatile
organic compounds
Remarks: According to the composition the product contains
no VOC component as defined by Directive 1999/13/EC.

Other regulations : Observe national specific workplace risk prevention and

health regulations.

15.2 Chemical Safety Assessment

No Chemical Safety Assessment (CSA) is yet available for the substance, or for the component
substances, contained in this product.
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

Synergen OS Page 10(10)

Substance key: 000000487615 Revision Date: 06.10.2015
Version : 1 - 6 / EU Date of printing : 17.09.2018

SECTION 16: Other information

Further information
Other information : Observe national and local legal requirements

This information corresponds to the present state of our knowledge and is intended as a general
description of our products and their possible applications. Clariant makes no warranties, express
or implied, as to the information's accuracy, adequacy, sufficiency or freedom from defect and
assumes no liability in connection with any use of this information. Any user of this product is
responsible for determining the suitability of Clariant's products for its particular application.
Nothing included in this information waives any of Clariant's General Terms and Conditions of
Sale, which control unless it agrees otherwise in writing. Any existing intellectual/industrial
property rights must be observed. Due to possible changes in our products and applicable
national and international regulations and laws, the status of our products could change. Material
Safety Data Sheets providing safety precautions, that should be observed when handling or
storing Clariant products, are available upon request and are provided in compliance with
applicable law. You should obtain and review the applicable Material Safety Data Sheet
information before handling any of these products. For additional information, please contact
Clariant.
REG_EU / EU