JEE Main Mock Test - 3
JEE Main Mock Test - 3
Question 1:
(1+a) (1+a+a ) 2
(1+a+a +a )
2 3
1 + 2!
+ 3!
+ 4!
+ . . . . . . . . . is equal to:
(e -e )
a
a. ( a - 1 )
(e a+e
)
b. (a-1)
(e -e )
a
c. ( a + 1 )
d. None of these
Question 2:
f(x) =
{ tan − 1x,
1
2
( | x | − 1),
|x| ≤ 1
|x| > 1
a. R − 0
b. R − 1
c. R − − 1
d. R − { − 1, 1}
Question 3:
a. 2x + 3y + 22 = 0
b. 3x + 4y + 22 = 0
c. 5x + 6y + 22 = 0
d. 7x + 8y + 22 = 0
Question 4:
→ → →
a, b, c are three vectors such that
→ → → → →
a + b + c = 0, | a | = 1, | b | = 2, | c | = 3, then a. b + b ⋅ c + c. a is equal to:
→ → → → → → →
a. 0
b. − 7
c. 7
d. 1
Question 5:
( )
The solution of the differential equation ydx + x + x 2y dy = 0 is:
1
a. − xy = C
1
b. − xy + logy = C
1
c. xy + logy = C
d. logy = Cx
Question 6:
The angle between the lines (2x = 3y = − z) and (6x = − y = − 4z) is:
a. 90 ∘
b. 0 ∘
c. 30 ∘
d. 45 ∘
Question 7:
a, b, c and u, v, w are the vertices of two triangles such that c = (1 − r)a + rb and
ω = (1 − r)v + ru where r is a complex number, then the two triangles:
b. Are similar
c. Are congruent
d. None of these
Question 8:
1
a. 2 x(x − 1)
1
b. 2 1 +( √1 + 4log2x )
1
c. 2 1 −( √1 + 4log2x )
d. Not defined
Question 9:
a. 50
b. 550
c. 10
d. 500
Question 10:
| |
n 1 5
If U n = n 2 2N + 1 2N + 1 N
then, evaluate ∑ n = 1U n
n3 3N 2 3N
a. 1
b. 0
c. 2
d. None of these
Question 11:
dy
The solution of the differential equation e dx = (x + 1), y(0) = 3
a. y = xlog | x + 1 | + x + log | x + 1 | + 3
b. y = xlog | x − 1 | − x − log | x + 1 | + 3
c. y = xlog | x + 1 | − x + log | x + 1 | + 3
d. None of these
Question 12:
Three athletes A, B and C participate in a race. Both A and B have the same
probability of winning the race and each is twice as likely to win as C. The probability
that B or C wins the race is:
2
a. 3
3
b. 5
3
c. 4
13
d. 25
Question 13:
{
− 1, x < 0
f(x) = 0, x = 0 then the value of f(g(x)) is:
1, x > 0
{
2 + x, 0 ≤ x ≤ 1
a. 2 − x, 1 < x ≤ 2
4 − x, 2 < x ≤ 3
{
2 − x, 0 < x < 1
b. 2 + x, 1 < x ≤ 2
4 + x, 2 < x ≤ 3
{
2 − x, 0 ≤ x ≤ 1
c. 2 + x, 1 ≤ x ≤ 2
4 + x, 2 < x ≤ 3
d. None of these
Question 14:
d. None of these
Question 15:
The most general value of θ which satisfies both the equations tanθ = − 1 and
1
cosθ = will be:
√2
7π
a. nπ + 4
7π
b. nπ + ( − 1) n 4
7π
c. 2nπ + 4
d. None of these
Question 16:
a. 6 + 8i
b. 2 + 8i
c. 4 + 8i
d. 6 + 4i
Question 17:
Between 1 and 31, m arithmetic means are inserted so that the ratio of 7 th and
(m − 1) th means is 5 : 9 then, the value of m is:
a. 16
b. 18
c. 12
d. 14
Question 18:
( xsin a − asin x )
Evaluate lim x → a (x−a)
a. sina − cosa
b. sina + cosa
c. sina − acosa
d. None of these
Question 19:
{
2x + 3, − 3 ≤ x < − 2
The function f(x) x + 1, − 2 ≤ x < 0
x + 2, 0≤x≤1
a. Continuous at x = 0
b. Continuous at x = 3
c. Continuous in interval = [ − 3, 1]
d. None of these
Question 20:
A dictionary is printed consisting of 7 letter words that can be made with the letters
of the word CRICKET. If the words are printed in the alphabetical order as in an
ordinary dictionary, then the number of words before the word CRICKET is:
a. 530
b. 480
c. 531
d. 481
Mathematics Section - B
Question 1:
Question 2:
A closed right circular cylinder has volume 2156 cubic units. The radius of its base
so that its total surface area may be minimum is:
Question 3:
dy
Let y(x) be the solution of the initial value problem dx + 2xy = x and y(0) = 0. Find
the value of lim x → 1y(x).
Question 4:
∑ kk == n1 tan − 1
2k
2 + k2 + k4 ()
6
= tan − 1 7 , then the value of 'n' is equal to:
Question 5:
In order to get at least once ahead with probability ≥ 0.9, the minimum number of
times a coin needs to be tossed is:
Question 6:
3 + 4i
If x + iy = 2 − i where i = √− 1, then what is the value of y ?
Question 7:
if ∫ sin − 1
( √
2x + 2
4x 2 + 8x + 13 )
dx = (x + 1)tan − 1 ( )
2x + 2
3 ( )
+ λln 4x 2 + 8x + 13 + C then
Question 8:
In the expansion of
( √x +
1
3x 2 ) 10
the value of constant term (independent of x ) is:
Question 9:
xtan x
Evaluate lim 1 − cos x .
x→0
Question 10:
= 2k(2 ≤ x < 4)
= − kx + 6k(4 ≤ x < 6)
[ ]
Find the value of E x 2 .
Physics Section - A
Question 1:
A book with many printing errors contains four different formulae for the
displacement of a particle undergoing a certain periodic motion x. Which one is the
wrong formula on dimensional grounds (A = amplitude, ω = angular velocity, T =
time period of motion)?
a. x = A√2 sin
( [ ] [ ])
2πt
T
+ cos
2πt
T
A
b. x = T sin A
[]t
c. x = Asin
( )
2πt
T
d. x = − Asin(ωt)
Question 2:
An annular ring with inner and outer radii R 1 and R 2 is rolling without slipping with a
uniform angular speed. The ratio of the forces experienced by the two particles
F1
situated on the inner and outer parts of the ring F is:
2
a. 1
R1
b. R
2
R2
c. R
1
()R1 2
d. R2
Question 3:
If g e and g m are the accelerations due to gravity on the surface of the earth and the
moon respectively and if Millikan's oil drop experiment could be performed on the
electronic charge on the moon
two surfaces, one will find the ratio electronic charge on the earth to be;
a. 1
b. 0
c. g e / g m
d. g m / g e
Question 4:
The figure below shows four plates each of area A and separated from one another
by a distance d.
∈A 0
a. d
2ϵ 0A
b. d
3ϵ 0A
c. d
4 ∈A 0
d. d
Question 5:
The truth table given below is for (A and B are the inputs, Y is the output). What type
of GATE it will form?
A B Y
0 0 1
0 1 1
1 0 1
1 1 0
a. NOR
b. AND
c. XOR
d. NAND
Question 6:
1
A planet of radius R = 10 × ( radius of Earth) has the same mass density as Earth.
R
Scientists dig a well of depth 5 on it and lower a wire of the same length and of
linear mass density 10 − 3kg m − 1 into it. If the wire is not touching anywhere, the
force applied at the top of the wire by a person holding it in place is: (take the radius
b. 108 N
c. 120 N
d. 150 N
Question 7:
a. − 5 J
b. − 10 J
c. − 15 J
d. − 20 J
Question 8:
A long infinite current-carrying wire is bent in the shape as shown in the figure. The
magnetic induction at point o is:
μ 0I
a. πR
μ 0I
b.
2√2πR
μ 0I
c.
2√2πR
μ 0I
d. 2πR
Question 9:
a. Both
b. Neither
c. Photon only
d. Electron only
Question 10:
a. Q
Q
b. 2
Q
c.
√3
Q
d.
√2
Question 11:
a. 6025 N-m
b. 12.50 N-m
c. 18.75 N-m
d. 25.00 N-m
Question 12:
Two gases A and B have equal pressure P, temperature T, and volume V. The two
gases are mixed together and the resulting mixture has the same temperature T and
volume V as before. The ratio of pressure exerted by the mixture to either of the two
gases is:
a. 1 : 1
b. 2 : 1
c. 3 : 1
d. 1 : 2
Question 13:
In a resonance tube, using a tuning fork of frequency 325 Hz, two successive
resonance lengths are observed at 25.4 cm and 77.4 cm respectively. The velocity of
sound in air is:
a. 320 m / s
b. 328 m / s
c. 330 m / s
d. 338 m / s
Question 14:
8
An ideal gas at 27K is compressed adiabatically to 27 of its original volume. The rise
a. 225K
b. 375K
c. 400K
d. 450K
Question 15:
9
a. 1 beat / s and intensity ratio of maxima to minima = 4
25
b. 1 beat / s and intensity ratio of maxima to minima = 1
9
c. 2 beat / s and intensity ratio of maxima to minima = 4
3
d. 4 beat / s and intensity ratio of maxima to minima = 2
Question 16:
a. 3 × 10 17
b. 3 × 10 18
c. 6 × 10 19
d. 3 × 10 20
Question 17:
The elastic limit of brass is 379MPa. What should be the minimum diameter of a
brass rod if it is to support a 400 N load without exceeding its elastic limit?
a. 1 mm
b. 1.15 mm
c. 0.90 mm
d. 1.36 mm
Question 18:
mg
a. YAcos θ
mg
b. YAsin θ
mg
c. YA cosθ
mg
d. YA sinθ
Question 19:
Two beams of red and violet colors are made to pass separately through a prism
(angle of the prism is 60 ∘ ). In the position of minimum deviation, the angle of
refraction will be:
Question 20:
The binding energy per nucleon of deuteron 1H 2 and helium atom 2He 4 is 1.1MeV
and 7MeV respectively. If two deuteron atoms react to form a single helium atom,
the released energy, is:
a. 13.9MeV
b. 26.9MeV
c. 23.6MeV
d. 19.2MeV
Physics Section - B
Question 1:
A proton is fired from very far away towards a nucleus with charge Q = 120e where
e is the electronic charge. It makes the closest approach of 10fm to the nucleus. The
de-Broglie's wavelength (in units of fm ) of the proton at its start is:
5 h
[m p = 3 × 10 − 27kg, e
= 4.2 × 10 − 15J. s / c
1 m
4π ∈ = 9 × 10 9 F , 1fm = 10 − 15m]
0
Question 2:
A parallel plate capacitor of 300μF is charged to 200 V. If the distance between its
plates is halved, the change in stored energy (in J) will be_______.
Question 3:
The relationship between the position coordinate (x) and time (t) for a moving car
along the x -axis is given by x = 2 + 5t + 6t 3. Its initial velocity (in m / s ) is:
Question 4:
Question 6:
Question 7:
If we increase the kinetic energy of a body by 300%, the percent increase in its
momentum is:
Question 8:
Question 9:
Question 10:
A body moves with a speed of 10 m/s in the curved path of 25 m radius of curvature.
If the tangential acceleration is 3 m/s 2, then total acceleration for the body will be:
Chemistry Section - A
Question 1:
He and Ar are monoatomic gases and their atomic weights are 4 and 40
respectively. Under similar conditions, He will diffuse through semi-permeable
membrane:
d. 10 times as fast as Ar
Question 2:
a. 4-phenylcyclopentene
b. 2-phenylcyclopentene
c. 1-phenylcyclopentene
d. 3-phenylcyclopentene
Question 3:
a. [Ru(NH3)4Cl2]+
b. [Co(NH3)5Cl]2+
c. [Ir(PR3)2H(CO)]2+
d. [Co(en)2Cl2]+
Question 4:
2−
a. Cr 3 + and Cr 2O 7 are formed
2−
b. Cr 2O 7 and H 2O are formed
2−
c. Cr 2O 4 is related to +3 state of Cr
Question 5:
Question 6:
a.
b.
c.
d.
Question 7:
a. A
b. 3A
c. 4A
d. 2A
Question 8:
Which type of 'defect' has the presence of cations in the interstitial sites?
a. Frenkel defect
b. Metal deficciency defect
c. Schottky defect
d. Vacancy defect
Question 9:
Which of the following alkyl/aryl halide reacts fastest with alc. AgNO 3 at room
temperature?
a. Bromobenzene
b. Carbon tetrachloride
c. Benzyl bromide
d. n-hexyl chloride
Question 10:
The pKa of a weak acid (HA) is 4.5. The pOH of an aqueous buffered solution of HA
in which 50% of the acid ionised is:
a. 4.5
b. 2.5
c. 9.5
d. 7.0
Question 11:
a.
b.
c.
d.
Question 12:
IP 1 and IP 2 of Mg are 178 and 384 kcal. The enthalpy required for the reaction
Mg → Mg 2 + + 2e −
a. − 562Kcal mol − 1
b. + 562Kcal mol − 1
c. 170Kcal mol − 1
d. + 170Kcal mol − 1
Question 13:
a. 3.33%
b. 7.14%
c. 12.50%
d. 4.54%
Question 14:
The equivalent mass of metal is 9 and vapour density of its chloride is 59.25. The
atomic mass of metal is:
a. 23.9
b. 27.3
c. 36.3
d. 48.3
Question 15:
Which one of the following gives, on ozonolysis, both aldehydes and ketones?
a. Me2C=CHMe
b. Me2C=CMe2
c. MeCH2-C(Me)=CMe2
d. MeCH(Me)-CH=CHMe
Question 16:
a. 2
b. 0
c. 3
d. 1
Question 17:
a. phenol
b. o-cresol
c. p-nitrophenol
d. p-chlorophenol
Question 18:
( K 1K 3 2 )
b. K2
3
( K 3K 2 )
c. K = K1
d. K 1K 2K 3
Question 19:
a. 25
b. 33
c. 50
d. 75
Question 20:
a. z = x + y
b. x = y − z
c. x = y + z
d. y = 2z − x
Chemistry Section - B
Question 1:
Question 2:
Question 3:
An element with atomic mass Z consists of two isotopes of mass number Z − 1 and
Z + 2. The percentage abundance of the heavier isotope is (up to one place of the
decimal):
Question 4:
[
log −
d[A]
dt ] [ ]
= log
d[B]
dt
+ 0.3
Question 5:
Question 6:
Question 7:
Calculate the amount of ice that will separate out on cooling a solution containing
50 g of ethylene glycol in 200 g of water to − 9.3 ∘ C. Molal depression constant for
water is 1.86 K kg / mol (up to two decimal places):
Question 8:
Find the heat change in the reaction NH 3(g) + HCl(g) → NH 4Cl(s) from the
following data (up to one place of decimal):
Question 9:
Question 10:
State whether the given statement is True or False. CuO can't be reduced by carbon
but it can be reduced by H 2.
∘
Given: ΔG f for
CuO = − 129.7 kJ mol − 1, CO = − 137.2 kJ mol − 1 H 2O = − 237.2 kJ mol 1
Explanations
Question 1 :
1+a 1 + a + a2 1 + a + a2 + a3
1 + 2! + 3!
+ 4!
+…
We have to find the sum of given series.
1 + a + a2 + a3 + … + an − 1
th
The n term of given series is given by a n = n!
1 − an 1 1 an 1
a n = ( 1 − a ) × n ! = ( 1 − a ) n ! − ( 1 − a ) × n ! [Using the sum of n terms of GP ]
Substituting n = 1, 2, 3, …, we get
a1 = [ 1
(1−a)
× 1!
1
] [ −
1
⋅
(1−a) 1!
a
]
a2 = [ 1
(1−a)
× 2!
1
] [ −
1
(1−a)
a2
× 2!
]
Adding all above terms, we get
= (1−a)
1
[ 1
1!
1
+ 2 ! + …. ∞ − ( 1 − a ) ] 1
[ a
1!
a2
+ 2 ! + …∞
]
ea − e
[ ( )] =
1
= ( 1 − a ) (e − 1) − ea −1 a−1
[Using series of exponential function]
Question 2 :
{
1
2
( − x − 1), x< −1
−1
f(x) = tan x, − 1 ⩽ x ⩽ 1… (i)
1
2
(x − 1), x>1
Question 3 :
[x+5] [y+4] r1 r2 r3
[ cos θ ]
= [ sin θ ] = AB = AC = AD
⇒y+4=[ −2
3
](x + 5)
2x + 3y + 22 = 0
Question 4 :
→ → → → → →
| a + b + c | = 0 and | a | = 1, | b | = 2, | c | = 3.....(i)
→ → →
We have to find the value of a. b + b ⋅ c + c. a
→ → →
→ → →
Now, from (i) we have a + b + c = 0
⇒ |a + b + c| = 0
→ → →
⇒ 2(a ⋅ b + b ⋅ c + c ⋅ a) = − 14
→ → → → → →
⇒ a. b + b ⋅ c + c. a = − 7
→ → → → → →
Question 5 :
(
ydx + x + x 2y dy = 0 )
ydx + xdy + x 2ydy = 0
Question 6 :
Equation of lines, (2x = 3y = − z) and (6x = − y = − 4z)
[The given equations are not in the standard form]
We have to find the angle between the given lines.
Writing equations of line in symmetrical form, we have
So, 2x = 3y = − z ⇒ x
1 =
y
1
z
= − 1 .........(i) and 6x = − y = − 4z ⇒ x
1
y
= −1 =
z
1 ........(ii)
2 3 6 −4
→ → → 1 1
Let b 1 and b 2 be two vectors parallel to (i) and (ii) respectively. Then, b 1 = 2 î + 3 ĵ − k̂
→ 1 1
b 2 = 2 î − ĵ − 4 k̂
→ →
Let θ be the angle between the given lines i.e. angle between the vectors b 1 and b 2 Then, using the formula of
angle between two vectors,
→ →
b1 ⋅ b2
We get cosθ =
| b1 | b2 ∣
→ →
( 1
2
1
î + 3 ĵ − k̂ )( ⋅
1
6
1
î + ĵ − 4 k̂ )
=
√( ) ( ) √( ) ( )
1 2 1 2 1 2 −1 2
2
+ 3
+ ( − 1 )2 6
+ ( − 1 )2 + 4
1 1 1
12
−3+4
= 1 1 1 1
√ 4
+ 9 +1
1
√ 36
1
+ 1 + 16
12 − 12
= =0
√ √
1 1 1 1
+ +1
4 9 36
+ 1 + 16
cosθ = 0 = cos90 ∘
⇒ θ = 90 0
Question 7 :
| |
a u 1
= b v 1
c w 1
| |
a u 1
= b v 1
c − (1 − r)a − rb w − (1 − r)u − rv 1 − (1 − r) − r
| |
a u 1
= b v 1
c w 1
= 0 Therefore, two triangles are similar.
Question 8 :
√
1 − 1 + 4log 2 y
But x ≥ 1, so x =
2
⩽ 1 is not possible.
1
Therefore, we take x = 2 (1 +
√4log2y)
⇒ x − f (y) = (1 + √4log y)
−1
1
2 2
Question 9 :
Question 10 :
| |
N
∑ n = 1n 1 5
N
N
∑ n = 1U n = ∑ n = 1n 2 2N + 1 2N + 1
N
∑ n = 1n 3 3N 2 3N
| |
(N+1)N
2
1 5
1
= 6
(N + 1)N(2N + 1) 2N + 1 2N + 1
1
4
(N + 1) 2N 2 3N 2 3N
[By sum of natural numbers, sum of squares of natural numbers and sum of cubes of natural numbers]
(N+1)N
Now, taking 12
common from C 1, we get
| |
5 1 5
N(N+1)
= 2(2N + 1) 2N + 1 2N + 1
12
3N 3N 2 3N
Applying C 1 → C 1 − C 2, we get
| |
5 1 5
N(N+1)
= 2(2N + 1) 2N + 1 2N + 1 =0
12
2
3N 3N 3N
Question 11 :
dy
Consider, the differential equation e dx = (x + 1), y(0) = 3
⇒ y = xlog | x + 1 | − ∫ [1 − ]dx 1
x+1
⇒ y = xlog | x + 1 | − x + log | x + 1 | + c
Now, at y(0) = 3, We get, c = 3, From (i), solution of differential equation is
⇒ y = xlog | x + 1 | − x + log | x + 1 | + 3
Question 12 :
⇒x+x+ x
2
=1 ⇒x= 2
5
⇒ P(A) = 5
2 2 1
, P(B) = 5 , P(C) = 5 [Using (i) ]
Since, events of winning the race by A, B and C are mutually exclusive ⇒ P(B ∩ C) = 0
Therefore, the probability of winning the race by B or C.
⇒ P(B ∪ C) = P(C) = 2
5
1 3
+ 5 = 5 [Using addition theorem of probability]
Question 13 :
{
− 1, x < 0
f(x) = 0, x = 0 .......(ii)
1, x > 0
We have to find the value of f(g(x)).
Now, g(x) = 1 + x − [x] or g(x) = 1 + {x}
Since 0 < {x} < 1 ⇒
g(x), is greater than 1 for all x ∈ R.
So, f(g(x)) = 1 [Using (ii)]
Question 14 :
Question 15 :
1
Two equations, tanθ = − 1 and cosθ =
√2
We have to find the most general value of which satisfies the above equations.
1
Consider, tanθ = − 1 and cosθ =
√2
We know that tangent function is negative in 4 th quadrant and cosine function is positive in 4 th quadrant.
7π
General solution of (i) and (ii) is given by 2nπ + 4
Question 16 :
| |z − 12
x − 8i
5
= 3,
| | z−4
x−8
=1
⇒ 3 | z − 12 | = 5 | z − 8i |
3 | (x − 12) + iy | = 5 ∣ x + (y − 8)i |
9(x − 12) 2 + 9y 2 = 25x 2 + 25(y − 8) 2 ....(i)
and
| | z−4
x−8
=1
⇒ |z − 4| = |z − 8|
| x − 4 + iy | = | x − 8 + iy |
(x − 4) 2 + y 2 = (x − 8) 2 + y 2
2
x=6 ⇒
Putting x = 6 in (i), we get y − 25y + 136 = 0
y = 17, 8
So, z = 6 + 17i or z = 6 + 8i
Question 17 :
m arithmetic means are inserted between 1 and 31 such that the ratio of 7 th and 9 th terms of (m − 1) th mean is
5: 9 .
We have to find the value of m.
Let x 1, x 2, x m be the arithmetic means inserted between 1 and 31 . They from an arithmetic progression so, the
(m + 2) th term is 31.
31 = T m + 2 = a + (m + 1)d
⇒d= 30
m+1
( as a = 1).........(i)
x7 5
We are given that, X = 9
m−1
∴
T8 a + 7d 5
Tm
= a+ (m−1)d = 9
[Using general term of AP = t r = a + (r − 1)d and substituting r = 8, m]
⇒ 9a + 63d = 5a + (5m − 5)d
⇒ 9a + 63 ( ) = 5a + 5(m − 1) (
30
m+1
30
m+1 ) [ using (i) ]
⇒ 2m + 2 = 75m − 1020
∴ m = = 14 1022
73
Question 18 :
( xsin a − asin x )
The expression, lim x → a (x−a)
We have to evaluate the given expression.
( xsin a − asin x )
Consider, lim x → a (x−a)
xsin a − asin a + asin a − asin x
= lim x → a x−a
( x − a ) sin a − a ( sin x − sin a )
= lim x → a x−a
( x − a ) sin a
{ ( ) ( )}
a 2cos
x+a
2
⋅ sin
x+a
2
= lim x → a (x−a)
− x−a
[Using transformation formulae- 2 ]
2acos
( ) ( )
x−a
2
⋅ sin
x−a
2
lim x → a
( xsin a − asin x
x−a ) = lim x → a
( sin a − acos x
1−0 )
= sina − a ⋅ cosa
Question 19 :
{
2x + 3, − 3 ≤ x < − 2
The function f(x) x + 1, − 2 ≤ x < 0
x + 2, 0 ≤ x ≤ 1
We have to check the points of continuity of the given function f (x).
At x = − 2,
LHS : lim x → 2 − f(x) = lim x → 2(2x + 3) = 2( − 2) + 3 = − 1
RHS : lim x → 2 + f(x) = lim x → − 2(x + 1) = − 2 + 1 = − 1
f( − 2) = − 2 + 1 = − 1
since, lim x → 2 − f(x) = lim x → − 2 + f(x) = f( − 2)
Therefore, f(x) is continuous at x = − 2
At x = 0
LHS : lim x → 0 − f(x) = lim x → 0(x + 1) = 0 + 1 = 1
RHS : lim x → 0 + f(x) = lim x → 0(x + 2) = 0 + 1 = 1
since, lim x → 0 − f(x) ≠ lim x → 0 + f(x
Therefore, f(x) is discontinuous at x = 0.
At x = 3, f(x) is not defined and hence not continuous at x = 3.
Therefore, f(x) is not continuous in the interval [ − 3, 1]
Question 20 :
A dictionary is printed consisting of 7 letter words that can be made with the letters of the word CRICKET.
We have to find the number of words before the word CRICKET if the words are printed in the alphabetical order
as in an ordinary dictionary.
Letters in alphabetical order in ordinary dictionary: C, E, I, K, R, T
There are two C's in word CRICKET.
∴ Number of words starting with CC = 5! [As remaining 5 letters arrange themselves in 5! ways]
Number of words starting with CE = 5!, Number of words starting with CI = 5!, Number of words starting with CK
= 5!, Number of words starting with CRC = 4!, Number of words starting with CRE = 4!, Number of words starting
with CRICE = 2!
Next word is CRICKET
∴ Total no of words which comes before the word CRICKET = 4(5!) + 2(4!) + 2!
= 4(120) + 2(24) +2 = 480 + 48 +2 = 530
Answers Mathematics Section - B
Explanations
Question 1 :
∴t= √
− 4 + 16 − 4
2
⇒ t = − 2 ± √3 or x + y√2 = − 2 ± √3
∴ Equation of lines are x + y√2 + 2 + √3 = 0 and x + y√2 + 2 − √3 = 0
since, two lines are parallel,
| 2√3 |
∴ distance between these lines = √1 + 2
=2
Question 2 :
Let the height, radius of the base and surface area of the cylinder be h, r and S, respectively. Then, Volume
= πr 2h
⇒ 2156 = πr h ⇒ 2156 = 2
22
7
r 2h ⇒h= 2156 × 7
22r 2
⇒h= 686
r2
…(1)
⇒S= 4312
r
+
44r 2
7
[ From eq (1)]
⇒ = dS
dr
4312
− r2
+ 7
88r
dS
For maximum or minimum values of S, we must have dr = 0
⇒ 4312
− r2
88r
+ 7 =0 ⇒ 4312
r2
88r
= 7 ⇒r 3 =
4312 × 7
88
⇒r 3 = 343 ⇒ r = 7cm
d 2s 8624 88
Now, = + 7
dr 2 r3
⇒ d 2s
dr 2
8624
= 343 + 7
88
⇒ d 2s
dr 2
176
= 7 >0
So, the surface area is minimum when r = 7cm
Question 3 :
dy
dx
= x − 2xy = x(1 − 2y)
dy
( 1 − 2y )
= xdx
Integrating on both sides:
dy
∫ 1 − 2y = ∫ xdx
ln ( 1 − 2y ) x2
−2
= 2 +c
Now given y(0) = 0
ln ( 1 − 2 × 0 ) ( 0 )2
Thus, −2
= 2
+c
c=0
ln ( 1 − 2y ) x2
Now, = 2
−2
ln(1 − 2y) = − x 2
2
1 − 2y = e − x
2
2y = 1 − e − x
2
1−e −x
y= 2
( )
2
1−e −x 1−e −1 e−1
lim x → 1y(x) = lim x → 1 2
= 2
= 2e = 0.316
Question 4 :
Now, tan − 1
( 2k
2 + k2 + k4 ) = tan − 1
( 2k
1 + k2 + 1 + k4 )
= tan − 1
( 2k
2 + k2 + k4 ) = tan − 1
( 1+
2k
( k + 1 + 2k − k )
4 2 2 )
= tan − 1
( 1+ (k +1 ) −k2
2k
2 2 )
( (k +1+k ) − (k +1−k )
)
2 2
= tan − 1
1 + (k + 1 + k ) ( k + 1 − k )
2 2
k=n
So, ∑ k = 1 tan
−1
2 + k2 + k4 ( 2k
)
(
= ∑ kk == n1 tan − 1 k 2 + 1 + k − tan − 1 k 2 + 1 − k ) ( )
Putting the values of k, we get,
tan − 1(3) − tan − 1(1) + tan − 1(7) − tan − 1(3) + tan − 1 n 2 + n + 1 − tan − 1 n 2 − n + 1 ( ) ( )
= tan − 1 7
() 6
⇒ tan (n −1 2
)
+ n + 1 − tan − 1(1) = tan − 1 7
()
6
⇒ tan (n −1 2
)
+ n + 1 = tan − 1(1) + tan − 1 7
()
6
( )
6
⇒ tan (n
1+ 7
−1 2
)
+ n + 1 = tan − 1 6
1− 7 ×1
⇒ n + n + 1 = 13 ⇒ n + n − 12 = 0 ⇒ (n − 3)(n + 4) = 0 ⇒ n = 3 or n = − 4
2 2
As, n cannot be negative, so n = 3.
Question 5 :
=1−
() 1
2
n
≥ 0.9 [Given]
⇒( ) 1
2
n
≤ 0.1 ⇒2 n
≥ 10 ⇒n>3
So, least value of n = 4.
Question 6 :
3 + 4i
x + iy = 2 − i
⇒ x + iy = 3 + 4i
2−i
× 2+i
2+i
⇒ x + iy = 6 + 11i + 4i 2
4 − i2
= − 1 ⇒ x + iy = ⇒ x + iy =
6 + 11i − 4 2 + 11i 2 11
2
As we know, i 4+1 5
= 5 +i 5
2 11
Comparing real and imaginary parts, we get x = 5 = 0.4 and y = 5 = 2.2
Question 7 :
sin − 1
( 2x + 2
√4x 2 + 8x + 13 ) ( = sin − 1
2x + 2
√ ( 2x + 2 )2 + ( 3 )2 )
tan − 1
( ) 2x + 2
3
∫ tan − 1
( ) 2(x+1)
3
dx
Put t = 1 + x ⇒ dt = dx
∫ tan − 1 3
()2t
Integrating by parts
⇒ tan −1
2t
3 ( d
∫ dt − ∫ dt tan − 1 3 × ∫ dt
2t
)
⇒ ttan −1
2t
3
−∫
( )
1+
1
4t 2
9
2
× 3 t dt
⇒ ttan −1
2t
3
− 8∫
6
9 + 4t 2( )
dt
8tdt
⇒ ttan − −1
2t
3
3
4 (
ln 9 + 4t 2 + c )
⇒ (1 + x)tan −1
2x + 2
3
−4
3
ln (4x 2
+ 4x + 13 + c )
⇒λ= =3 −3
4
Question 8 :
10 − 5r
10 − r
2 ×
( )
1
3x 2
r
= 10C r × 3 − r × x 2
Question 9 :
tan x sin x
As we know, cos2x = 1 − 2sin 2x, lim x
= 1, lim x
=1
x→0 x→0
xtan x xtan x
Given, lim 1 − cos x = lim x
x→0 x → 0 2sin 2
2
1 tan x x.x
= 2 lim x
× x
()
x→0 sin 2 2 x 2
×
()x 2 2
2
1 tan x 4
= 2 lim x
× x
x→0 sin 2 2
()x
2
2
1
= 2 ×1×4=2
Question 10 :
∞
Given, ∫ ∞f(x)dx = 1
2 4 6
∫ 0kxdx + ∫ 22kdx + ∫ 4( − kx + 6k)dx = 1
[ ] [ ]
2 6
⇒ kx 2
2
+ [2kx] 42 +
− kx 2
2
+ 6kx =1
0 4
⇒ 2k + 4k − 10k + 12k = 1
⇒k= 1
8
[ ]
E x 2 = ∫ 60x 2f(x)dx
2 4 6
= ∫ 0x 2kxdx + ∫ 2x 22kdx + ∫ 4x 2( − kx + 6k)dx
[ ] [ ] [ ]
2 4 6
kx 4 2kx 3 − kx 4 6kx 3
= 4
+ 3
+ 4
+ 3
0 2 4
k
= 4 (16 − 0) + 3 (64 − 8) +
112
2k
( −k
4 )
(1296 − 256) + 2k(216 − 64)
= 4k + 3 k + ( − 260k) + 304k
112
= 3 k + 48k = ( 112
3
×8
1
) ( + 48 × 8
1
) = 4.67 + 6 = 10.67
Question 1 :
The dimensions of time (t), angular velocity (ω) and amplitude (A) are [t] = [T], [ω] = [T ], [A] = [L]
−1
x = A√2 sin ( [ ] [ ])
2πt
T
+ cos
2πt
T
is zero.
⇒[ A
t
] [
= L − 1T ]
Thus, option 'B' is wrong on dimensional grounds.
C. The dimension of the argument in equation:
x = Asin ( ) [ ]
2πt
T
is
2πt
T
=
|T|
T
= dimensionless quantity
D. The dimension of the argument in equation: x = Asin(ωt) is [ωt] = [T ][T] = dimensionless quantity
−1
Thus, option 'D' is not wrong on dimensional ground. All the equations, except x = T sin A
A
()t
i.e. option 'B' have
dimensionless argument.
Question 2 :
The annular ring is rolling with constant angular velocity ω. All the particles on the ring will have the same
constant angular velocity ω. Since the two particles are moving in a circular orbit, the net force experienced by
them is the centripetal force. The diagram given below represents the direction of forces acting on the two
particles:
The centripetal force experienced by the particle on the inner circumference of radius R 1
F 1 = mR 1ω 2 where m is the mass of each particle and ω the angular velocity of the ring.
Similarly, for the particle at the outer circumference of radius R 2,
F 2 = mR 2ω 2
F1 mR 1ω R1
Then, the ratio of the two forces is
F2
= mR ω = R
2 2
Question 3 :
The electric charge is a universal constant and thus, it has the same value on the Earth and on the Moon. It does
not depend upon the value of acceleration due to gravity.
electronic charge on moon
Therefore, the ratio: electronic charge on earth = 1
Question 4 :
The above arrangement is equivalent to two parallel plate capacitors connected in parallel with the same
separation d and area A.
ϵ 0A ϵ 0A
Now, the capacitance of each capacitor is C 1 = , C2 =
d d
The equivalent capacitance of C 1 and C 2 is C = C 1 + C 2
⇒C=
ϵ 0A ϵ 0A 2ϵ 0A
d
+ d = d
Question 5 :
Truth table with A and B as inputs and Y as output. We have to find which gate corresponds to the given truth
table.
A. NOR gate can be made by using an OR gate followed by NOT gate, i.e. Y = A + B. Given truth table does not
satisfy this logic.
B. AND gate is a logic gate with the output as a product of the input, i.e. Y = A. B. The given truth table does not
satisfy this logic.
C. XOR gate is a function of two logical variables A and B which gives the value 1 if one of the variables is zero
and other is 1. If both the variables are 0 or both are 1, then the function is zero, i.e., Y = AB + AB. The given
truth table does not satisfy this logic.
D. NAND gate is inverse of AND gate and is given by the expression
Y = A. B
Truth table for NAND gate is
A B A.B A.B
0 0 0 1
1 0 0 1
0 1 0 1
1 1 1 0
Question 6 :
1
Radius of the planet R = 10 × ( radius of Earth)
R
Depth of the well = Linear mass density of the wire, μ = 10 − 3 kg m − 1
5
We have to find the force applies at the top of the wire by a person holding it in.
GM
Acceleration due to gravity on the planet will be given by g =
R2
⇒g= G
R2 (
× ρ × 3 πR 3
4
) ⇒g= 4
3
πGρR
4
(i) Acceleration due to gravity of earth g e = 3 πGpR e
g R
Dividing equation (i) by (ii), we get g = R
e e
⇒ ge
g Re
= 10 × R [ as R = 10
e
Re
] ⇒ g = 1m / s 2 [ as g e = 10m / s 2]
Now, we will consider a mass element dm of width dx at depth x below the planet.
Mass of this element will be dm = μdx
( )
R
F x
∫ 0df = ∫ 05 μg 1 − R dx
R
⇒ F = μg [ ]
x − 2R
0
x2 5
⇒ F = μg { ( ) (( ) )}
R
5
− 0 − 2R
1 R
5
2
−0
⇒ F = μg [ ( )] [ ]
R
5
− 2R 25
1 R2 R
= μg 5 − 50
R
F = 10 −3
× 1R
[ ]⇒
10 − 1
50
F = 10 −3
[ ]⇒
R 50
9 9
F = 50 × 10 −3
×
6 × 10 6
10
N ⇒ F = 108N
Question 7 :
( ) (
From the figure, we get W AB = PΔV = 10N / m 2 ⋅ 2m 3 − 1m 3 = 10J )
B → C is an isochoric process, thus W BC = 0 as dV = 0
Therefore, total work done by the gas is given as W total = W AB + W BC + W CA
⇒ 5J = 10J + 0 + W ⇒ W CA CA = − 5J
Question 8 :
Magnetic field induced by a finite current carrying conductor at a distance R is given by,
μ 0I
(
B = 4πR cosθ 1 − cosθ 2 ......(i))
Where, θ 1 and θ 2 are the angles made by the endpoints of the wire to the external point.
And using right hand thumb rule, we get direction of magnetic field,
π
st ∘
For the 1 semi-infinite part, θ 1 = 0 and θ 2 = 90 = 2
⊗
μ 0I
Substitute the above values in equation (i), we get B 1 = 4πR
[ 1
√2
+
1
√2 ]⊗
⇒B ⊗
μ 0I
2 = 2 2πR
√
π
For the second semi-infinite part, θ 1 = 2 and θ 2 = 0
⊗
μ 0I
Therefore, magnetic field will be, B 3 = − 4πR
Total magnetic field at point o is, B = B 1 + B 2 + B 3
⇒B=
μ 0I
2√2πR
Question 9 :
Total energy of a particle when it travels with a speed nearly equal to the speed of the light, the relativistic
energy is given by
2
E 2 = p 2c 2 + m 0c 4......(i)
where, p: momentum of the particle, m 0 : rest mass of the particle, c : speed of light
Question 10 :
⇒2 = q2
2C
Q2
2C
[ using equation (i) and (ii) ]
⇒q= √ Q
2
Question 11 :
Spring constant, k = 5 × 10 3 N / m
1
2
The work required to stretch the spring by the displacement x is W = 2 kx
( ) ( )
1 2
When the spring is stretched by 5 cm, work done is W 1 = 2 × 5 × 10 3N / m × 5 × 10 − 2m
⇒W 1 = 6.25J
When the spring is again stretched further by 5 cm, the net displacement of the spring from its equilibrium
position is
x ′ = 5 cm, + 5 cm = 10 cm
( ) ( )
1 2
Thus, the work required to stretch it further by an additional 5 cm is W 2 = 2 × 5 × 10 3N / m × 10 × 10 − 2m
⇒W 2 = 25J
So, the extra work required to stretch the spring by an additional
5 cm is ΔW = W 2 − W 1 ⇒
ΔW = 25J − 6.25J ⇒
ΔW = 18.75J or 18.75N − m
Question 12 :
Let P 1 and P 2 be the partial pressures of gases A and B, respectively. Under equal conditions of temperature
and volume, P 1 = P 2
Let P be the total pressure exerted by the mixture of two gases A and B. Using Dalton's law of partial pressures,
P = P1 + P2
⇒ P = 2P ⇒ 1 P1
P
= 1
2
⇒ P: P 1 = 2: 1
Question 13 :
λ
For resonance, length of the tube is L = (2n + 1) 4
λ
Let first resonance occur at n, thus Length, L 1 = (2n + 1) 4 = 25.4 (given)
Successive resonance will occur at n + 1
λ
Length L 2 = 2[(n + 1) + 1] 4 = 77.4 (given)
Question 14 :
()
γ−1
⇒T
V1
2 = T1 V
2
( )
5
⇒T 2 = 300 ×
27
8
3 −1
( )
2
⇒T 2 = 300 ×
27
8
3
⇒T 9
2 = 300 × 4 = 675K
⇒T 2 = 675 − 273 = 402K
Rise in temperature = 402K − 27K = 375K
Question 15 :
y 1 = 6cos(100πt)......(i)
y 2 = 4cos(102πt)......(ii)
Standard wave equation is given by y = A 0cos(ωt).......(iii)
From equation (i) and (iii), we get angular frequency ω 1 = 100π = 2πf 1 f 1 = 50 Hz ⇒
Amplitude, A 01 = 6 unit From equation (ii) and (iii), we get ω 2 = 102π = 2πf 2 ⇒
f 2 = 51 Hz
Amplitude, A 02 = 4 unit
Beat frequency = difference in frequencies of the two given waves = f 2 − f 1 = 51 Hz − 50 Hz = 1 Hz, i.e 1 beat
per sec
Resultant amplitude A of superposition of two waves of amplitudes A 01 and A 02 is
2 2
A=
√ A 01 + A 02 + 2A 01A 02cosϕ
For maximum resultant amplitude, phase ϕ = 0 ∘⇒A max =√36 + 16 + 48 = √100 = 10 units
For minimum resultant amplitude, phase ϕ = π ⇒ A min = √36 + 16 − 48 = √4 = 2 units
[ since cosπ = − 1]
Also, Intensity α A max
2
( )
So, I
I max
min
=
( )
A max
A min
2
=
( )
10
2
2
⇒
I max 25
I min
= 1
Question 16 :
Question 17 :
F
Stress = A
Stress = 400 × 4 / πd 2
= 379 × 10 6 N / m 2
( 400 × 4 )
d2 =
( 379 × 10 T ) 6
d = 1.15 mm
Question 18 :
The free-body diagram of the system is shown below:
If L is the original length of the string, then the increase in length is given by ΔL =
( )( )
T
A
L
Y
⇒ =(ΔL
L
mg
cos θ ) 1
× YA [ using equation (i) ]
⇒ stain = mg
YAcos θ
Question 19 :
Two beams of red and violet colors are made to pass separately through a prism (angle of the prism is 60°). We
have to find the angle of refraction at the position of minimum deviation. In the position of minimum deviation,
light passes symmetrically through the prism irrespective of the light wavelength used.
⇒r= 60 ∘
2
⇒ r = 30 ∘
for both the colour.
Question 20 :
( )
Binding energy per nucleon of a deuteron 1H 2 = 1.1MeV
We have to find released energy if helium is formed from the fusion of two deuterons. Rest mass energy of
⇒E R =2 [ (m n ) ] ( )
+ m p c 2 − 1.1 × 2 − 2m p + 2m n c 2 + 7 × 4
⇒E R = − 4 × 1.1 + 7 × 4
⇒E R = − 4.4 + 28
⇒E R = 23.6
Explanations
Question 1 :
⇒ ⇒v
1 kQ 1Q 2 2k ( 120e ) e
m v2 =
2 p r0
2 = r 0m p
5
Where, m p : mass of the proton = × 10 − 27 kg
3
v: velocity of the proton, k: Coulomb's constant = 9 × 10 9Nm 2C − 2, e: charge on an electron = 1.6 × 10 − 19C, r o:
distance of closest approach = 10fm
h h
The de-Broglie's wavelength of the proton at its start is calculated as follows: λ = p = m v
p
Question 2 :
Capacitance, C = 300μF = 3 × 10 − 4 F
Potential, V = 200 V
AG 0
Now, the capacitance of a parallel plate capacitor is given by, C = d
......(i) where d is the separation between
the plates.
Also, the charge on a capacitor is q = CV = 3 × 10 − 4F × 200 V = 6 × 10 − 2C
When the distance between the plates is halved, then from equation (i), the new capacitance is, C ∗ = 2C
= 2 × 3 × 10 − 4F = 6 × 10 − 4F
Using law of conservation of charge, total charge on the capacitor is conserved. Thus, the potential difference
q
′
between the plates becomes, V =
Cz
6 × 10 − 2C
= = 100 V
6 × 10 − 4 F
Question 3 :
Question 4 :
Charge, (Q) = 200nC, Separation between the plates, (d) = 5mm, Area of the plate, (A) = 10 sq.cm, Relative
Question 5 :
( )
= 3.0 × 10 4 × A Newton ...(i)
Mass per unit length is given by μ = ( Area ) × ( density )
( ) (
= A ⋅ m 2 × 7.5 × 10 3 kg / m 3 )
= A × 7.5 × 10 3 kg / m 3......(ii)
√
T
Using equation (i) and (ii), speed of the transverse wave is v =
μ
3.0 × 10 4 × A
=
√ A × 7.5 × 10 3
= 2ms − 1
Question 6 :
Question 7 :
300
ΔKE = 300%, Let, KE 1 = KE, KE 2 = KE + 100 KE, KE 2 = 4KE
The relation between the kinetic energy and momentum is given by, P = √2 × KE × m
Initial momentum, P 1 = √2 × KE × m .....(i)
Final momentum, P 2 =
√2 × KE2 × m = √2 × 4KE × m = 2√2 × KE × m .....(ii)
Question 8 :
→ →
When a magnetic dipole of moment M is held at an angle θ with the direction of a uniform magnetic field B, then
it experiences a torque.
The magnitude of the torque acting on the dipole is: T = MBsinθ ......(i)
Where M is magnetic moment and B is magnetic field
Given: Number of turns (N) = 10, I = 10A, B = 5T and radius (r) = 7cm = 7 × 10 − 2m
θ = 30 ∘
The magnitude of the torque acting on the circular coil is: τ = MBsinθ
Here, M = I × N × Area of coil
( ) ⇒ M = 154 × 10
22 2
M = 10 × 10 × 7 × 7 × 10 − 2 − 2Am 2
Putting the value of M in equation (i), we get, T = 154 × 10 − 2 × 5 × sin30 ∘ ⇒ T = 385 × 10 − 2Nm
Question 9 :
Now, Z = √ R + (X − 0 )
2
L
2
⇒ Z = √10 + (800 × 10 2 −3 × 300 ) ⇒ Z = 240.2Ω
2
⇒I
V0
From Ohm's law, V 0 = I 0R 0 = R
For an LCR circuit, the net resistance is the impedance Z.
∴I
V0 200
0 = Z = 240.2 = 0.832 A
Question 10 :
Centripetal Acceleration a c : ( )
∴a c = r
v2
⇒a c =
( 10 ) 2
25
100
= 25 m/s 2
2 2
Thus, net acceleration a =
√a t + ac = √4 2 + 3 2 = 5 m/s2
Explanations
Question 1 :
√ √
40 10
Substituting the values in equation (i), we get r = 4
= 1
= 3.16
Ar
Under similar conditions, He will diffuse through a semi-permeable membrane 3.16 times as fast as Ar.
Question 2 :
Question 3 :
Question 4 :
When potassium chromate (K 2CrO 4) is treated with an excess of dilute nitric acid, potassium dichromate and
water are formed.
The following chemical reaction takes place:
2K 2CrO 4 + 2H + → K 2Cr 2O7 + H 2O + 2K +
Yellow Colour
2− 2−
or, 2CrO 4 + 2H + → Cr 2O 7 + H 2O
Chromate ion Dichromate ion
Let oxidation state of Cr in K 2CrO 4 be y.
Thus, 2 × 1 + y + 4 × ( − 2) = 0 (As, oxidation states of K and 0 are +1 and -2 respectively. )
y=6
Let oxidation state of chromium in K 2Cr 2O 7 be X.
Thus, 2 × 1 + 2X + ( − 2) × 7 = 0 (As, oxidation states of K and 0 are +1 and -2 respectively. )
x = 6 As there is no change in the oxidation state for Cr, no redox reaction occurs.
Question 5 :
Whenever an alkyl halide reacts with alcoholic potash (or alcoholic sodium hydroxide), beta-elimination of the
halide occurs, leading to the formation of an alkene.
Question 6 :
We have to find the polymer obtained. Primary aliphatic amines on reaction with sodium nitrite (NaNO2) in
acidic medium (H3O+) yields alcohols which on polymerisation yield the product. The reactions involved are:
Question 7 :
Question 8 :
Frenkel defect: It is a stoichiometric defect. Frenkel defect arises when an ion leaves its normal site and
occupies an interstitial site. A cation is much smaller than an anion, thus, this defect is caused by the
displacement of cations from original sites to interstitial sites.
Question 9 :
As we know, in aryl halides there is a partial double bond character between C - CI bond due to the resonance
effect of Cl which has lone pair of electrons.
Thus, it cannot be cleaved. CCl 4 and n -hexyl chloride have covalent bonds, thus, cannot be broken. Now, benzyl
bromide (which is a 1 ∘ halide), the C − Br bond breaks easily as the carbocation formed is resonance stabilised
and thus, it reacts with alc. AgNO 3 at room temperature and brown precipitates of AgBr are formed.
Question 10 :
[HA] = A − [ ]
[A ]
−
For the acidic buffer, pH value can be given using Henderson's equation as: pH = pK a + log
[ HA ]
[ [A ]
]
−
Question 11 :
This gives a more stable carbocation, with the positive charge on the carbon adjacent to the phenyl group. The
phenyl group can stabilise the carbocation through resonance effect, i.e. through delocalisation of the positive
charge around the benzene ring.
3. In the final step, a proton is released and a double bond is formed.
Now, trans-alkene is more stable than that of cis-alkene because in cis-alkene, stearic hindrance is present.
Therefore, the main product of the given reaction is:
Question 12 :
Question 13 :
(
The following molar ionic conductivities : λ ∘ NH4 + ) = 72ohm − 1cm 2,
(
λ ∘ OH − ) = 198ohm − 1cm 2
∘
(
where, λ + NH 4
+
) = Molar ionic conductivity of ammonium ions λ (OH ) = Molar ionic conductivity of
∘ −
hydroxide ions
λ ∘ = 72 + 198 = 270ohm − 1cm 2
Now, the degree of dissociation(α), at any concentration is given
Substituting the values of λ C and λ o
9
α = 270 = 0.03333
Percentage dissociation = a × 100 = 0.03333 × 100 = 3.33%
Question 14 :
Question 15 :
Those alkenes in which double-bonded carbons have one or more hydrogen can give aldehydes. If all the
hydrogens of the doubly bonded carbons are substituted, then only ketones are obtained. We will consider the
ozonolysis reaction of all the compounds.
(A). On ozonolysis, Me2C = CHMe gives both aldehyde and ketone, as one doubly bonded carbon has one
hydrogen. The reaction can be represented as:
Question 16 :
( ) = 2 × 10 − 3mol dm − 3 s − 1 for which concentration of A, [A] = 0.05mol dm − 3
Rate r 1
Question 17 :
The acidity of the given phenols can be found out from their structures. The structures of the given phenols are
as follows:
1. The presence of an electron-withdrawing group (like NO2 and Cl) having a negative inductive effect and
negative resonance effect attached to the phenyl ring stabilises the negative charge on the oxygen of the
phenoxide ion which is the conjugate base of the corresponding phenols thereby making the phenols more
acidic.
2. The presence of an electron-donating group (like CH3) having +I and +R effects in the phenol ring,
destabilises the phenol ring (by intensifying the negative charge on the oxygen of the phenoxide ion) and
thereby decreasing the acidic character of the phenol.
3. Also, the NO2 group is more electron-withdrawing than the -Cl group.
Therefore, the order of acidity is: p-nitrophenol > p-chlorophenol > phenol > o-cresol.
Question 18 :
[ NH3 ] 2
K1 = .......(i)
[ N 2H 2 ] 3
| NO | 2
K2 = .........(ii)
| H2 | | O2 |
| H 2O | 2
K3 = .......(iii)
| H2 | | O2 | 1 / 2
We have to find out the equilibrium constant for the reaction:
5
2NH3 + 2 O2 ⇌ 2NO + 3H20
| H 2O | 3
[ NO ] 2
Let equilibrium constant for this reaction be K. K = ......(iv)
[ NH3 ] 2 [ O2 ] 5 / 2
∣H O ]
2
3
| NO | 2
3
Cubing equation (iii) and multiplying with equation (ii), we get K 3K 2 = ⋅
| H2 | 3 | O2 | 3 / 2 [ N2 ∣ [ O2 ]
| H 2O | 3
| NO | 2
= .......(v)
| N2 | | H2 | 3 | O2 | 5 / 2
[ ]3
[ NO ] 2 H 2O
3
K 3K 2 [ N2 ] [ H2 ] 3 [ O2 ] 5 / 2
Dividing equation (v) by equation (i), we get K =
1 [ NH3 ] 2
[ N2 ] [ H2 ] 3
∣ NO ] [ H O ]
2
2
3
= .......(vi)
| NH | | O |
3
2
2
5/2
K 33K 2
Comparing equation (iv) and (vi), we get K = K1
Question 19 :
No. of p -orbitals
We know that, Percentage of p-character = Total no. of orbitals × 100
3
Thus, percentage of p-character = 4 × 100 = 75%
Therefore, percentage of p-character in the orbitals forming P − P bonds in P 4 is 75%.
Question 20 :
i. C (graphite) + O 2(g) → CO 2(g); ΔrH ∘ = x kJmol − 1
1
ii. C( graphite ); 2 O 2(g) → CO 2(g) → CO(g); ΔrH ∘ = x − yΔrHo = y kJmol − 1
Subtracting equation (ii) from equation (i), we get
1
2
O 2(g) → CO 2(g) → CO(g); ΔrH ∘ = x − y
1
CO(g) + 2 O 2(g) → CO 2(g); ΔrH ∘ = x − y
This is equation (iii), enthalpy of reaction for equation (ii), is given as z kJmol − 1
∴z=x−y⇒x=y+z
0.05 × 10 − 14
Explanations
Question 1 :
x=
( 50
100 )
× 200 mm and t 1 = 53 minutes
Question 2 :
Question 3 :
Question 4 :
[
log −
d[A]
dt ] [ ]
= log
d[B]
dt
+ 0.3
For reaction, aA → bB
(Change concentration of reactant)
Rate of reaction is given as: = Time taken
1 d[A] 1 d[B]
Thus, rate of reaction is given as: − a dt
= b dt .........(i)
d[A] a d[B]
Rearranging, we get − dt
= b dt
a
( −
d[A]
dt ) a d[B]
= log b + log dt
log b = 0.3
a
or, b = 10 0.3 = 1.995 ≈ 2.00
Question 5 :
Δp 1
()
h
p
h
Δp ≥ 4π
p
≥ 4π
Δp 1
p
≥ 4x ( constant )…. (iii)
Thus, its velocity will be completely uncertain. Momentum, p is given by: p = mv
where, m = mass, v = Velocity
Thus, Δp = mΔv
mΔv 1
Substituting the value of p and Δp in equation (iii), we get mv = 4x
Δv 1
v
= 4π
Δv 1 1
Substituting the value of Π = 3.14 in above equation, we get v = 4 × 3.14 = 12.56
Δv 1
v
× 100 = 12.56 × 100
= 7.9617 ≈ 7.96
Question 6 :
Ca(OH) 2 ⇌ Ca 2+
+ 2OH −
Given, pH = 9 So, pOH = 14 − 9 = 5
[OH ] = 10 M
− −5
10 − 5
So, [Ca ] = 2+
2
=
( )
10 − 5
2 (10 )
−5 2 = 0.5 × 10 − 15 = 0.05 × 10 − 14
Question 7 :
Molal depression constant = Depression in Kelvin per mole of solute present in kg of solvent.
molecular mass of Ethylene Glycol = C 2H 6O 2 = 62 gm / mole
Number of moles 50 1000
kg of water
= 62 × 200 = 4 moles / kg
Actual depression in freezing point temperature: 1.86 ∘ K × 4 = 7.44 ∘ K
Specific heat of Ice = 2 J / gm − ∘ K
The heat released from 200gm of water (ice) due to the lowering of temperature = 7.44 × 2 × 200 = 2976 J
Latent heat of fusion of ice = 334 kJ / kg = 334 J / gm
Amount of ice that will melt away due to availability of 2, 976 J:
2976
= 334 = 8.91gm
Question 8 :
Question 9 :
The solubility S of Ca(OH) 2 is 1.50 kg m − 3 or 1.50 gL − 1. Convert the unit of solubility in moles per litre.
1.50 gL − 1
= 0.020 mol L − 1.
74.1 g mol − 1
The hydroxide ion concentration is twice its solubility.
[OH −
= 2S = 2 × 0.020M = 0.040M.
Question 10 :
CuO + C → Cu + CO
∘ ∘
ΔG ∘ = ΔG f (CO) − ΔG f (CuO)
= − 137.2 + 129.7 = − 7.5 kJ
CuO + H 2 → Cu + H 2O
∘
( )
ΔG ∘ = ΔG f H 2O − ΔG f (CuO)
∘