11_chemistry_sp_01

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Class 11 - Chemistry
Sample Paper - 01 (2024-25)
Maximum Marks: 70
Time Allowed: : 3 hours
General Instructions:
a. There are 33 questions in this question paper with internal choice.

b. SECTION A consists of 16 multiple-choice questions carrying 1 mark each.
c. SECTION B consists of 5 very short answer questions carrying 2 marks each.
d. SECTION C consists of 7 short answer questions carrying 3 marks each.
e. SECTION D consists of 2 case-based questions carrying 4 marks each.
f. SECTION E consists of 3 long answer questions carrying 5 marks each.
g. All questions are compulsory.
h. The use of log tables and calculators is not allowed
Section A
1. Consider the chemical reaction gven as,

--CO (g) + -- H 2(g) → -- C 8H18(l) + -- H 2O.
This equation can be balanced by inserting the following in blank spaces
a) 8,2,1,17
b) 8,17,1,8
c) 8,8,1,17
d) 8,2,8,17
2. In an alpha scattering experiment, few alpha particles rebounded because
a) The mass of the atom is concentrated in the centre

b) Positive charge of the atoms very little space
c) All the positive charge and mass of the atom is concentrated in small volume
d) Most of the space in the atom is occupied
3. Consider the reactions given below. On the basis of these reactions find out which of the algebraic relations given in
options (i) to (iv) is correct?
A. C (g) + 4 H (g) → CH 4(g); Δ rH = x kJ mol − 1

B. C (graphite,s) + 2H 2(g) → CH 4(g); Δ rH = y kJ mol − 1
a) x = y
b) x = 2y
c) x < y
d) x > y
4. Give the number of electrons in the species, O 2 and O 2+ .
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a) 16 and 8
b) 16 and 14
c) 16 and 15
d) 32 and 16
5. Which of the following always has a negative value?
a) Heat of reaction
b) Heat of solution
c) Heat of formation
d) Heat of combustion
6. What will be the Electronic configuration of the element having atomic number 24?
a) 1s2 2s2 2p6 3s2 3p6 3d4 4s1 4p1

b) 1s2 2s2 2p3 3s2 3p6 3d5 4s1 4p3
c) 1s2 2s2 2p6 3s2 3p6 3d5 4s1
d) 1s2 2s2 2p6 3s2 3p3 3d5 4s1 4p3
7. On the reaction
2Ag + 2H2SO4 ⟶ Ag2SO4 + 2H2O + SO2 sulphuric acid acts as an?
a) a reducing agent
b) an oxidizing agent
c) a catalyst
d) an acid as well as an oxidant
8. The reaction
Peroxide
CH 3CH = CH 2 + HBr → CH 3CH 2CH 2Br can be explained by
a) carbanion formation
b) free-radical mechanism
c) carbocation formation
d) electrophilic substitution
9. Which of the following organic materials damage DNA of our body?
a) Tabacco
b) Coal
c) All of these
d) Petroleum
10. In terms of period and group, where would you locate the element with Z = 114 in the modern periodic table?
a) 7th period and 14th group

b) 6th period 14th group
c) 6th period and 13th group
d) 7th period and 13th group

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11. For the reaction at 298 K, 2A + B → C, ΔH = 400 kJ mol-1 and ΔS = 0.2 kJ K-1mol-1. At what temperature will the
reaction become spontaneous considering ΔH and ΔS to be constant over the temperature range.
a) 3500 K
b) 2000 K
c) 1500 K
d) 2500 K
12. Soda lime is a mixture of
a) NaOH + Ca(OH)2
b) NaOH + MgO
c) NaOH + Mg(OH)2
d) NAOH + CaO
13. Assertion (A): Allyl and benzyl carbonium ions are stable than propyl corbonium ions.
Reason (R): Electron releasing groups stabilize cabonium ions.
a) Both A and R are true and R is the correct explanation of A.

b) Both A and R are true but R is not the correct explanation of A.
c) A is true but R is false.
d) A is false but R is true.
14. Assertion (A): Trans-2-butene on reaction with Br2 gives a meso-2,3-dibromobutane.

Reason (R): The reaction involves the syn-addition of bromine.

15. Assertion (A): Threshold frequency is a characteristic for a metal.

Reason (R): Threshold frequency is the maximum frequency required for the ejection of electrons from the metal
surface.

16. Assertion (A): Under similar conditions of temperature and pressure, gases combine in a simple ratio of their volume
but, not always.
Reason (R): Gases deviate from ideal behaviour.

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Section B
17. Calculate the solubility of A2X3 in pure water, assuming that neither kind of ion reacts with water. The solubility product
of A2X3, Ksp = 1.1 × 10–23.
18. Helium has an electronic configuration of 1s2 but it is placed in p-block in group 18. Explain.
19. How many moles of methane are required to produce 22g CO2 (g) after combustion?
20. Explain why the system are not aromatic.
OR
What happens when benzene is oxidized at 770K in presence of V2O5? Give chemical equation.
21. In an atom, an electron is moving with a speed of 600 ms-1 with an accuracy of 0.005 %. Find the certainty with which
the position of the electron can be located. (h = 6.6 × 10-34 kg m2s-1, mass of electron me = 9.1 × 10-31 kg).
Section C
22. Draw the resonating structure of
i. ozone molecule
ii. nitrate ion
23. Answer:
1. Consider the same expansion, but this time against a constant external pressure of 1 atm.
2. At what temperature entropy of a substance is zero?
3. Predict the change in internal energy for an isolated system at constant volume.
24. i. Why standard entropy of an elementary substance is not zero whereas standard enthalpy of formation is taken as
zero?
ii. Under what conditions will the reaction occur, if
a. both ΔH and ΔS are positive
b. both ΔH and ΔS are negative
25. Write the anode reaction, the cathode reaction and the net cell reaction in the following cells. Which electrode would be
positive terminal in each cell?
i. Zn(s) | Zn2+ || Br2 | Br- | Pt(s)
ii. Cr(s) | Cr3+ || I2 | I- | Pt(s)
iii. Pt(s) | H2(g) | H+ (aq) || Cu2+ | Cu(s)

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26. Emission transitions in the Paschen series end at orbit n = 3 and start from orbit n and can be represeted as v = 3.29 ×
1015 (Hz) [1/32 - 1/n2] Calculate the value of n if the transition is observed at 1285 nm. Find the region of the spectrum.
27. Among the elements B, AI, C and Si
i. Which has the highest first ionization enthalpy?

ii. Which has the most negative electron gain enthalpy?
iii. Which has the largest atomic radius?
iv. Which has the most metallic character?
28. Calculate the molecular mass of the following.
i. H2O
ii. CO2
iii. CH4
Section D
29. Read the following text carefully and answer the questions that follow:
Once an organic compound is extracted from a natural source or synthesised in the laboratory, it is essential to purify it.
Various methods used for the purification of organic compounds are based on the nature of the compound and the
impurity present in it. Finally, the purity of a compound is ascertained by determining its melting or boiling point. This is
one of the most commonly used techniques for the purification of solid organic compounds. In crystallisation Impurities,
which impart colour to the solution are removed by adsorbing over activated charcoal. In distillation Liquids having
different boiling points vaporise at different temperatures. The vapours are cooled and the liquids so formed are collected
separately. Steam Distillation is applied to separate substances which are steam volatile and are immiscible with water.
Distillation under reduced pressure: This method is used to purify liquids having very high boiling points.
i. Which method can be used to separate two compounds with different solubilities in a solvent?
ii. Distillation method is used to separate which type of substance?
iii. Which technique is used to separate aniline from aniline water mixture?
OR
Why chloroform and aniline are easily separated by the technique of distillation?
30. Read the following text carefully and answer the questions that follow:
The molecular orbital theory is based on the principle of a linear combination of atomic orbitals. According to this
approach when atomic orbitals of the atoms come closer, they undergo constructive interference as well as destructive
interference giving molecular orbitals, i.e., two atomic orbitals overlap to form two molecular orbitals, one of which lies
at a lower energy level (bonding molecular orbital). Each molecular orbital can hold one or two electrons in accordance
with Pauli's exclusion principle and Hund's rule of maximum multiplicity. For molecules up to N2, the order of filling of
orbitals is:
( ) ( ) ( ) ( ) ( ) ( )
∗ ∗
σ(1s) σ (1s), σ(2s) σ (2s), π 2p x = π 2p y , σ 2p z , π 2p x = π 2p y , σ 2p z

∗ ∗ ∗
and for molecules after N2, the order of filling is:
( ) ( ) ( ) ( ) ( ) ( )
∗ ∗
σ(1s) σ (1s), σ(2s) σ (2s), σ 2p z , π 2p x = π 2p y , π 2p x = π 2p y , σ 2p z

∗ ∗ ∗
1
Bond order = [bonding electrons - antibonding electrons]
2
Bond order gives the following information:

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I. If bond order is greater than zero, the molecule/ion exists otherwise not.
II. Higher the bond order, higher is the bond dissociation energy.
III. Higher the bond order, greater is the bond stability.
IV. Higher the bond order, shorter is the bond length.
i. Arrange the following negative stabilities of CN, CN+ and CN- in increasing order of bond. (1)
ii. The molecular orbital theory is preferred over valence bond theory. Why? (1)
iii. Ethyne is acidic in nature in comparison to ethene and ethane. Why is it so? (2)
OR
Bonding molecular orbital is lowered by a greater amount of energy than the amount by which antibonding molecular
orbital is raised. Is this statement correct? (2)
Section E
31. Attempt any five of the following:
1. Classify the hydrocarbons according to the carbon-carbon bond.
2. Explain why alkynes are less reactive than alkenes towards addition of Br2.
3. What is electrophile in sulphonation?
4. Why are Alkenes called olefins?
5. n-propylmagnesium bromide on hydrolysis gives propane. Is there any other Grignard reagent which also gives
propane? If so, give its name, structure and equation for the reaction.
6. Write IUPAC name: CH 3CH − C CH 3 ( )2

7. Which of the two trans-but-2-ene or trans-pent-2-ene is non-polar?
32. The value of Kp for the reaction,

CO2(g) + C(s) ⇌ 2CO (g)
is 3.0 at 1000 K. If initially, P CO = 0.48 bar and PCO = 0 bar and pure graphite is present, calculate the equilibrium
2
partial pressures of CO and CO2.
OR
One of the reactions that take place in producing steel from iron ore is the reduction of iron (II) oxide by carbon
monoxide to give iron metal and CO2.
FeO(s) + CO(g) ⇌ Fe(s) + CO2(g); Kp = 0.265 atm at 1050 K
What is the equilibrium partial pressures of CO and CO2 at 1050 K if the initial pressures are: Pco = 1.4 atm and P CO =
2
0.80 atm?
33. Answer:
1. i. What is the basic principle of chromatography?
ii. What is the general molecular formula of saturated monohydric alcohols?
2. OR

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i. What is the basic principle involved in the estimation of nitrogen by Dumas method.
ii. Explain hyperconjugation effect. How does hyperconjugation effect explain the stability of alkenes?To
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Class 11 - Chemistry
Sample Paper - 01 (2024-25)
Solution
Section A
1. (b) 8,17,1,8
Explanation:
The balanced equation for the given equation is,

8CO(g) + 17H2(g) ⟶ C8H18(l) + 8H2O
2. (b) Positive charge of the atoms very little space

Explanation:
Positive charge of the atoms very little space
3. (d) x > y
Explanation:
Here, x > y. Because in equation (B) all the reactants are in their most stable states of aggregation hence have zero
standard molar enthalpies of formation.
4. (c) 16 and 15
Explanation:
atomic number O has atomic number = 8 so number of electrons in O 2 = 16

while in O 2+ there is one unit positive charge so no. of electron =15.
5. (d) Heat of combustion

Explanation:
Combustion is an exothermic process. Hence heat of combustion has a negative value.
6. (c) 1s2 2s2 2p6 3s2 3p6 3d5 4s1

Explanation:
The atomic number 24 is of Cr. Due to half-filled orbital stability, it does not follow the Aufbau rule so its electronic
configuration is 1s2 2s2 2p6 3s2 3p6 3d5 4s1.
7. (d) an acid as well as an oxidant

Explanation:
sulfuric acid (H2SO4) is a strong acid, signifying that it fully dissociates into H3O+ and HSO4- in an aqueous
environment (the bisulfate ion is amphiprotic, but usually behaved as a weak bronsted acid given it's feeble alkalinity).
Now, consider some oxidizing agents: F2, O2, Cl2, etc. All of these species are driven by high electronegativities/electron
affinities, a result of quantum mechanical effects that contribute to the properties of these agents. However, the
H+ (H3O+) ion is essentially a naked proton, resulting in an extremely dense positive charge; this will force it's reduction

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by more electropositive species by either physical gaining of electrons or the sharing of a lone pair.
Furthermore, the bisulfate/sulfate ion is capable of forming entropically preferable compounds due to the presence of
oxygen, another powerful oxidizing agent.
8. (b) free-radical mechanism

Explanation:
In the presence of peroxide and light, the addition of HBr to unsymmetrical alkenes occurs contrary to Markovnikov's
rule. The chemistry follows a free-radical mechanism. Organic reactions, which proceed by homolytic fission are called
free radical or homopolar or nonpolar reactions.
9. (c) All of these

Explanation:
Tabacco, coal and petroleum damages DNA of our body and causes cancer.
10. (a) 7th period and 14th group

Explanation:
Elements with atomic numbers Z = (87 - 114) are placed in the 7th period.
Thus, the element with Z= 114 (Flerovium) is placed in the 7th period and 14th group of the modern periodic table.
11. (b) 2000 K

Explanation:
Gibbs free energy, ΔG = ΔH - TΔS

ΔH
At equilibrium ΔG = 0; then T= = 2000K
ΔS
Therefore, above 2000K, the reaction will be spontaneous.
12. (d) NAOH + CaO

Explanation:
Soda lime = NaOH + CaO
13. (b) Both A and R are true but R is not the correct explanation of A.
Explanation:
The stability of carbonium ions is influenced by both resonance and inductive effects, allyl and benzyl carbonium ions
can be stabilized by resonance but proply carbonium ion (CH3CH2CH2+) has no resonating forms.
14. (c) A is true but R is false.

Explanation:
With trans-2-butene, the product of Br2 addition is optically inactive due to the formation of symmetric meso
compounds.

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15. (c) A is true but R is false.
Explanation:
The threshold frequency is the minimum frequency required for the emission of electrons from the metal surface.
16. (d) A is false but R is true.

Explanation:
Gases do deviate from ideal behaviour but under the same conditions of pressure, temperature, etc., they combine in a
simple ratio of volume fairly accurately.
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Section B
17. A 2X 3 → 2A 3 + + 3X 2 −
K sp = A 3 + [ ] [X ]
2 2− 3 = 1.1 × 10 − 23
If S = solubility of A2X3, then
[A ] = 2S; [X ] = 3S
3+ 2
therefore, Ksp = (2S)2(3S)3 = 108S5
= 1.1 × 10–23
thus, S5 = 1 × 10–25
S = 1.0 × 10–5 mol/L
18. The electronic configuration of helium (He) is 1s2. It should be kept in s-block as the last electron enters in 's' orbital.
Due to the presence of completely filled valence shell (1s2 ) and similarities in properties with noble gases, it is placed in
p-block i.e. group 18.
19. According to the chemical equation,

CH4 (g) + 2O2(g) → CO2(g) + 2H2O (g)
44g CO2 (g) is obtained from 16 g CH4 (g).
[ ∴ 1 mol CO2(g) is obtained from 1 mol of CH4(g)]
Number of moles of CO2 (g)
1molCO 2 ( g )
= 22 g CO2 (g) ×
44gCO 2 ( g )
= 0.5 mol CO2(g)
Hence, 0.5 mol CO2 (g) would be obtained from 0.5 mol CH4 (g) or 0.5 mol of CH4 (g) would be required to produce 22
g CO2 (g).
20. For the given compound, the number of π-electrons is 8.

By Huckel’s rule,
⇒ 4n + 2 = 8
⇒ 4n = 6
⇒ n = 3/2

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For a compound to be aromatic, the value of n must be an integer (n = 0, 1, 2…).
This is not true for the given compound as it is a fraction. Hence, it is not aromatic in nature.
OR
Benzene, when undergoes a process of a complete oxidation reaction by V2O5, gives Maleic Anhydride.
21. Given, Mass of electron me = 9.1 × 10-31 kg and h = 6.6 × 10-34 kg m2s-1
0.005
Uncertainty in speed, Δv = 600 × = 0.03ms − 1
100
6.6 × 10 − 34
Using Heisenberg’s uncertainty principle, Δx = = 1.92 × 10 − 3m.
4 × 3.14 × 9.1 × 10 − 31 × 0.03
.
Section C
22. i. The resonating structures of O3 are shown below:
−
ii. Nitrate ion, NO 3
23. Answer:
1. We have q = -w = pex (8) = 8 litre-atm
2. The Third Law of Thermodynamics states, “The entropy of a perfect crystal is zero when the temperature of the
crystal is equal to absolute zero (0 K).
3. For an isolated system at constant volume, there is no transfer of energy in the form of heat or work.
So, ΔU = q + W
⇒ ΔU = 0 + 0
⇒ ΔU = 0

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24. i. A substance has perfectly ordered arrangement of its constituent particles only at absolute zero. When the element
from itself. This means no heat change.
Thus ΔfH = 0
ii.
a. If both ΔH and ΔS are positive ΔG can be -ve only in magnitude. Thus the temperature should be high.
b. If both ΔH and ΔS are negative ΔG can be negative only TΔS < ΔH is magnitude. Thus the value of T should be
low.
25. i. At anode: Zn → Zn2+ + 2e- ...(i)
At cathode: Br2 + 2e- → 2Br- ....(ii)
on adding (i) and (ii)
Zn + Br2 → Zn2+ + 2 Br-
ii. At anode: [Cr → Cr3 + 3e- ] × 2 ...(iii)

At cathode: [I2 + 2e- → 2I-] × 3 ...(iv)
on adding (iii) and (iv)
2Cr + 3I2 → 6I- + 2Cr3+
iii. At anode: H2(g) → 2H+ (aq) + 2e- ...(v)
At cathode: Cu2+ (aq) + 2e- → Cu(s) ...(vi)

on adding (v) and (vi)
H2(g) + Cu2+ (aq) → Cu(s) + 2H+ (aq)
Cathode will be positive terminal in each cell.
26. v = (3.29 × 1015 Hz)

( )
3
1
2 −
1
n2
λ = 1285 nm = 1285 × 10-9 m = 1.285 × 10-6 m
c ( 3 × 10 ms )
8 −1
v= = = 2.3346 × 1014s-1
λ
( 1.285 × 10 − 6m )
2.3346 × 1014 = 3.29 × 1015
2.3346 1 1 1
[ ]1
1
32
−
1
n2
= − or 0.71 = −
32.9 32 n2 9 n2
1 1
= - 0.071 = 0.111 - 0.071 = 0.04
n2 9
1
n2 = = 25 or n = 5
0.04
Paschen series lies in infrared region of the spectrum.
27. i. C has the highest first ionization enthalpy.

ii. C has the most negative electron gain enthalpy.
iii. AI has the largest atomic radius.
iv. AI has the most metallic character.
28. i. Molecular mass of H2O = 2 × H + 1 × O = 2 × 1.0079u + 1 × 16.00u = 18.0158 u
ii. Molecular mass of CO2 =1 × C + 2 × O = 1 × 12.01 u + 2 × 16.22 u = 44.01 u

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iii. Molecular mass of CH4 = 1 × C+ 4 × H = 1 × 12.01 u + 4 × 1.0079 u = 16.0416 u
Section D
29. i. Fractional crystallizationis used to separate two compounds with different solubilities in a solvent.
ii. volatile liquids from nonvolatile impurities.
the liquids having sufficient difference in their boiling points.
iii. Aniline is separated from aniline water mixture by steam distillation as one of the substances in the mixture is water
and the other, a water insoluble substance.
OR
Chloroform and aniline are easily separated by the technique of distillation because chloroform and aniline have
sufficient difference in their boiling points.
30. i. The increasing order of negative stabilities of CN, CN+ and CN- is CN+ > CN > CN-.
ii. The molecular orbital theory is preferred over valence bond theory because molecular orbital theory explains the
magnetic nature of the molecule.
iii. In ethyne, hydrogen atoms are connected to sp hybridized carbon atoms, but in ethene, they are attached to sp2
hybridized carbon atoms and in ethane, they are attached to sp3 hybridized carbons.
OR
The given statement is not correct because the bonding molecular orbital is lowered by a lesser amount of energy
than the amount by which antibonding molecular orbital is raised.
Section E
31. Attempt any five of the following:
1. Hydrocarbons are categorized into three categories according to the carbon-carbon bond that exists between them:
a. Saturated hydrocarbon (In which carbon-carbon single bond are present)

b. Unsaturated hydrocarbon (In which carbon-carbon double and triple bonds are present)
c. Aromatic hydrocarbon (In which alternate single and double bond and (4n+2)π electrons are present)
2. The triple bonds of alkynes, because of its high electron density, are easily attacked by electrophiles, but less reactive
than alkenes due to the compact C-C electron cloud. The three-membered ring bromonium ion formed from the
alkyne (A) has a full double bond causing it to be more stained and less stable than the one from the alkene (B),
Also, the carbon’s of (A) that are part of the bromonium ion has more s-character than (B), further making (A) less
stable than (B).
3. SO3
4. Alkenes are commonly known as olefins because the lower members form oily products on treatment with chlorine
or bromine.
5. Iso-propylmagnesium bromide, (CH3)2CHMgBr,

(CH3)2CHMgBr + H2O ⟶ CH3CH2CH3 + Mg(OH)Br
6. 2-methylbutane

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7. In trans-but-2-ene, the dipole moments of the two C—CH3 bonds are equal and opposite and therefore, they cancel
out each other.
Hence, trans-2-butene is non-polar.
32. For the reaction,

let ‘x’ be the decrease in pressure of CO2, then
CO2(g) + C(s) ⇌ 2CO(g)
Initial
pressure: 0.48 bar 0
At equilibrium: (0.48 – x)bar 2x bar
2
p CO
Kp = p CO
2
Kp = (2x)2/(0.48 – x) = 3
4x2 = 3(0.48 – x)
4x2 = 1.44 – x
4x2 + 3x – 1.44 = 0
a = 4, b = 3, c = –1.44
( −b± √b2 − 4ac )
x=
2a
−3± √ 3 2 − 4 ( 4 ) ( − 1.44 )
x=
2(4)
= (–3 ± 5.66)/8
= (–3 + 5.66)/8 (as value of x cannot be negative hence we neglect that value)
x = 2.66/8 = 0.33
The equilibrium partial pressures are,
P CO = 2x = 2 × 0.33 = 0.66 bar
2
P CO = 0.48 – x = 0.48 – 0.33 = 0.15 bar

2
OR
pco 2 ( 0.8 atm )

Qp = pco
= ( 1.4 atm )
= 0.571
Since Qp > kp (0.265), this means that the reaction will move in the backward direction to attain the equilibrium.
Therefore, the partial pressure of CO2 will decrease while that of CO will increase so that the equilibrium may be
attained again. Let p atm be the decrease in the partial pressure of CO2. Therefore, the partial pressure of CO will
increase by the same magnitude i.e. p atm.
P CO = (0.8 - p) atm; P CO(g) = (1.4 + p) atm
2
p co
2 ( 0.8 − p ) atm ( 0.8 − p )
At equilibrium K p = = =
p co ( 1.4 + p ) atm ( 1.4 + p )
( 0.8 − p )
or 0.265 = ( 1.4 + p )

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0.371 + 0.265 p = 0.8 - p or 1.265 p = 0.8 - 0.371 = 0.429
p = 0.429 / 1.265 = 0.339 atm
The equilibrium partial pressure of CO is (P CO)eq = (1.4 + 0.339) = 1.739 atm
The equilibrium partial pressure of CO2 is (P CO )eq = (0.8 - 0.339) = 0.461 atm
2
33. Answer:
1. i. Chromatography is based on the principle of different adsorption.
ii. Monohydric alcohols are the compounds derived from an alkane by replacing one H by - OH group.
Example:
replacing H with OH
CH 4 → CH 3 − OH
Methane Methanol
Therefore, the general molecular formula of saturated monohydric alcohols is CnH2n+1OH.
2. OR
i. This method is based upon the fact that nitrogenous compound is heated with copper oxide in an atmosphere
of carbondioxide yield free nitrogen.
y z
C xH yN z + CuO ⟶ xCO 2 + H 2O + N 2 + (Cu)
2 2
ii. Hyperconjugation: The relative stability of various classes of carbonium ions may be explained by the
number of no-bond resonance structures that can be written for them. Such structures are arrived by shifting
the bonding electrons from an adjacent C - H bond to the electron - deficient carbon. In this way, the
positive charge originally on carbon is dispersed to the hydrogen. This manner of electron release by
assuming no-bond character in the adjacent C - H bond is called Hyper conjugation or No-bond Resonance.
The greater the hyperconjugation, the greater will be the stability of the compound. The increasing order of
stability can be shown as:
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a. There are 33 questions in this question paper with internal choice.

1. Consider the chemical reaction gven as,

2. In an alpha scattering experiment, few alpha particles rebounded because

a) The mass of the atom is concentrated in the centre

A. C (g) + 4 H (g) → CH 4(g); Δ rH = x kJ mol − 1

4. Give the number of electrons in the species, O 2 and O 2+ .

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5. Which of the following always has a negative value?

a) 1s2 2s2 2p6 3s2 3p6 3d4 4s1 4p1

9. Which of the following organic materials damage DNA of our body?

a) 7th period and 14th group

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12. Soda lime is a mixture of

a) Both A and R are true and R is the correct explanation of A.

14. Assertion (A): Trans-2-butene on reaction with Br2 gives a meso-2,3-dibromobutane.

a) Both A and R are true and R is the correct explanation of A.

15. Assertion (A): Threshold frequency is a characteristic for a metal.

a) Both A and R are true and R is the correct explanation of A.

a) Both A and R are true and R is the correct explanation of A.

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of A2X3, Ksp = 1.1 × 10–23.

20. Explain why the system are not aromatic.

22. Draw the resonating structure of

2. At what temperature entropy of a substance is zero?

i. Zn(s) | Zn2+ || Br2 | Br- | Pt(s)

ii. Cr(s) | Cr3+ || I2 | I- | Pt(s)

iii. Pt(s) | H2(g) | H+ (aq) || Cu2+ | Cu(s)

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27. Among the elements B, AI, C and Si

i. Which has the highest first ionization enthalpy?

28. Calculate the molecular mass of the following.

σ(1s) σ (1s), σ(2s) σ (2s), π 2p x = π 2p y , σ 2p z , π 2p x = π 2p y , σ 2p z

and for molecules after N2, the order of filling is:

σ(1s) σ (1s), σ(2s) σ (2s), σ 2p z , π 2p x = π 2p y , π 2p x = π 2p y , σ 2p z

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1. Classify the hydrocarbons according to the carbon-carbon bond.

3. What is electrophile in sulphonation?

4. Why are Alkenes called olefins?

6. Write IUPAC name: CH 3CH − C CH 3 ( )2

32. The value of Kp for the reaction,

partial pressures of CO and CO2.

1. i. What is the basic principle of chromatography?

ii. What is the general molecular formula of saturated monohydric alcohols?

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The balanced equation for the given equation is,

2. (b) Positive charge of the atoms very little space

Positive charge of the atoms very little space

atomic number O has atomic number = 8 so number of electrons in O 2 = 16

5. (d) Heat of combustion

Combustion is an exothermic process. Hence heat of combustion has a negative value.

6. (c) 1s2 2s2 2p6 3s2 3p6 3d5 4s1

7. (d) an acid as well as an oxidant

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8. (b) free-radical mechanism

9. (c) All of these

10. (a) 7th period and 14th group

11. (b) 2000 K

Gibbs free energy, ΔG = ΔH - TΔS