JAC BOARD 2024 BY : AMIT SIR

CLASS 12TH CHEMISTRY TEST 03 TIME : 3 HOUR

CHAPTER : SOLUTIONS AND ELECTROCHEMISTRY

A. Multiple choice questions : ( 1 X 26 = 26 )

1. The value of colligative properties of a solution increases when
solute molecules undergo-
(a) association (b) dissociation
(c) both (d) none of these
2. The Normality of 0.2M aqueous solution of a dibasic acid is-
(a) 0.4N (b) 0.1N
(c) 0.8N (d) None of these
3. Colligative properties of the solutions depend on
(i) Nature of the solution
(ii) Nature of the solvent
(iii) Number of solute particles
(IV) Number of moles of the solvent
4. Relative lowering in vapour pressure of solution is equal to :
(i) Molarity of solution
(ii) Molality of solution
(iii) Mole fraction of solute
(iv) Mole fraction of solvent
5. A molal solution is one that contains one mole of a solute in
(i) 1000g of solvent
(ii) 1 litre of solution
(iii) 1 litre of solvent
(iv) 22.4 litre of the solution
6. The molarity of the solution containing 5g of NaOH in 500 ml of
aqueous solution is :
(a) 1M
(b) 2.5M
(c) 0.25M
 (d) 0.025M
7. Which of the following is not a good conductor ?
(a) Cu metal
(b) NaCl (aq)
(c) NaCl (molten)
(d) NaCl (s)
8. The S.I. unit of molar conductivity is
(a) S cm2 mol-1
(b) S2 cm-1
(c) S-1 cm2 mol-2
(d) S cm-2 mol-2
9. For a galvanic cell , which one of the following statements is not
correct
(a) Anode is negatively charged
(b) Cathode is positively charged
(c) Reduction takes place at anode
(d) Reduction takes place at cathode
10. If 96500 C electricity is passed through CuSO4 solution , it will
liberate
(a) 63.5 g of Cu
(b) 31.76 g of Cu
(c) 127 g of Cu
(d) 95.25 g of Cu
11. E.M.F. of a cell with Ni and Cu electrode will be
Given E°(Ni2+/Ni) = -0.25 V
E°(Cu2+/Cu) = +0.34 V
(a) 0.59 V
(b) 0.09 V
(c) -0.59 V
(d) -0.09 V
12. The unit of cell constant is
 (a) Ohm-1cm-1
(b) cm
(c) Ohm-1cm
(d) cm-1
13. The charge required for the reduction of 1 mole of Al3+ to Al is
(a) 96500 C
(b) 193000 C
(c) 289500 C
(d) 386000 C
14. Which of the following is not a characteristic of ideal
solution?
(1) Vmix = 0 (2) Smix = +ve
(3) Hmix = 0 (4) Gmix = +ve
15. Solution of methanol and ethanol will form
(1) ideal solution
(2) non-ideal solution with positive deviation
(3) non-ideal solution with negative deviation
(4) none
16. Which of the following is not a characteristic of non-ideal
solution with positive deviation?
(1) Vmix > 0 (2) Hmix > 0
(3) Smix < 0 (4) Gmix < 0
17. Which of the following is a characteristic of non-ideal solution
with negative deviation?
(1) Vmix < 0 (2) Hmix > 0
(3) Smix < 0 (4) Gmix > 0
18. A solution of strong acid and water is an
(1) ideal solution
(2) non-ideal solution with positive deviation
(3) non-ideal solution with negative deviation
(4) none of the above
19. A mixture of water and benzene is a/an
(1) ideal solution
(2) non-ideal solution with positive deviation
(3) non-ideal solution with negative deviation
(4) none of these
20. At vapour pressure
(1) (rate)evaporation = (rate)condensation
(2) (rate)evaporation > (rate)condensation
(3) (rate)evaporation < (rate)condensation
(4) None of the above
21. The factor which affect vapour pressure is
(1) forces between liquid molecules
(2) temperature
(3) volatile solute
(4) all of these
22. The normality of a solution of sodium hydroxide 100 ml of
which contains 4 grams of NaOH is
(1) 0.1 (2) 40 (3) 1.0 (4) 0.4
23. For H2SO4, the relation between normality and molarity is
(1) Normality = ½  Molarity 2
(2) Normality = 2 × Molarity
(3) Normality = 3 × Molarity
(4) Normality = Molarity
24. What amount of solute is dissolved in 0.5 L of solution to
make it 20% (w/v)?
(1) 120g (2) 150g (3) 100g (4) 200g
25. Find mass by mass % of a solution of 20 ml volume having
solute of mass 4g. (density of solution = 1.4 g/ml)
(1) 7.14% (2) 8.2%
(3) 9.64% (4) 14.28%
 26. Which is not temperature dependent ?
(a) Molarity
(b) Molality
(c) Normality
(d) Volume percentage
B. Short answer type questions : ( 8 x 3 = 24)
1. Distinguish between molarity , Normality and molality.
2. 45g of ethylene glycol (C2H6O2) is mixed with 600g of water. Calculate-
(a) the freezing point depression and (b) the freezing point of the
solution.
3. Define the following terms :
(i) ppm (ii) (w/v) % (iii) Mole fraction
4. Define isotonic , Hypotonic and Hypertonic solution.
5. Calculate the molarity of a solution containing 5 g of NaOH in 450 mL
solution.
6. The value of Ʌ°m of NH4Cl , NaOH and NaCl at infinite dilution
are 129.8 , 248.1 and 126.4 Scm2mol-1 respectively. Find out the
value of Ʌ°m in NH4OH.
7. What is the value of electrode potential of Mg2+/Mg electrode
when it is dipped in a solution in which concentration of Mg2+ is
0.01M ? E°Mg2+/Mg = -2.36 V.
8. What is salt bridge ? Mention its functions.
C. Long answer type questions : (5 X 10 = 50 )
1. Define relative lowering of vapour pressure containing non volatile solute .
And also calculate the molar mass of solute ?
2. Vapour pressure of water at 293K is 17.535 mm Hg. Calculate the vapour
pressure of water at 293K when 25g of glucose is dissolved in 450g of
water.
3. Boiling point of water at 750 mm Hg is 96.63 C. How much sucrose
(C12H22O11) is to be added to 500g of water such that it boils at 100 C ?
Molal elevation constant for water is 0.52 Kkg/mol.
4. Calculate (a) molality (b) molarity and (c) mole fraction of KI if the density
of 20% (mass/mass) aqueous KI is 1.202 g mL-1 .
 5. Vapour pressure of chloroform (CHCl3 ) and dichloromethane (CH2Cl2 ) at
298 K are 200 mm Hg and 415 mm Hg respectively. (i) Calculate the vapour
pressure of the solution prepared by mixing 25.5 g of CHCl3 and 40 g of
CH2Cl2 at 298 K and, (ii) mole fractions of each component in vapour
phase.
6. The vapour pressure of pure liquids A and B are 450 and 700 mm Hg
respectively, at 350 K . Find out the composition of the liquid mixture if
total vapour pressure is 600 mm Hg. Also find the composition of the
vapour phase.
7. The boiling point of benzene is 353.23 K. When 1.80 g of a non-volatile
solute was dissolved in 90 g of benzene, the boiling point is raised to
354.11 K. Calculate the molar mass of the solute. Kb for benzene is 2.53 K
kg mol–1
8. Vapour pressure of pure water at 298 K is 23.8 mm Hg. 50 g of urea
(NH2CONH2 ) is dissolved in 850 g of water. Calculate the vapour pressure
of water for this solution and its relative lowering.
9. An antifreeze solution is prepared from 222.6 g of ethylene glycol ,
C2H4(OH)2 and 200 g of water. Calculate the molality of the
solution. If the density of the solution is 1.072 g/ml, then what
shall be the molarity of the solution ?
10. Three electrolytic cells A, B and C containing solutions of zinc
sulphate. Silver nitrate and copper sulphate respectively are
connected in series. A steady current of 1.5 ampere was passed
through them, until 1.45g of silver was deposited at the cathode
of the cell B. How long did the current flow ? What masses of
copper and zinc were deposited in the concerned cells ? [ Atomic
masses of Ag = 108, Cu = 63.5 , Zn = 65.5 ]

By : Amit Sir ( Department of chemistry ) M : 9507056168

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By : Amit Sir ( Department of chemistry ) M : 9507056168