Chemistry: The Central Science, 13e, Global Edition (Brown et al.

)
Chapter 5 Thermochemistry

5.1 Multiple Choice Questions

1) Objects can possess energy as ________.

(a) endothermic energy

(b) potential energy
(c) kinetic energy

A) a only
B) b only
C) c only
D) a and c
E) b and c
Answer: E
Diff: 1 Var: 1 Page Ref: Sec. 5.1
LO: 5.2
GO: G2

2) The internal energy of a system is always increased by ________.

A) adding heat to the system
B) having the system do work on the surroundings
C) withdrawing heat from the system
D) adding heat to the system and having the system do work on the surroundings
E) a volume compression
Answer: A
Diff: 2 Var: 1 Page Ref: Sec. 5.2
LO: 5.2
GO: G2

3) The internal energy of a system ________.

A) is the sum of the kinetic energy of all of its components
B) is the sum of the rotational, vibrational, and translational energies of all of its
components
C) refers only to the energies of the nuclei of the atoms of the component molecules
D) is the sum of the potential and kinetic energies of the components
E) none of the above
Answer: D
Diff: 1 Var: 1 Page Ref: Sec. 5.2
LO: 5.2
GO: G2

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4) Which one of the following conditions would always result in an increase in the internal
energy of a system?
A) The system loses heat and does work on the surroundings.
B) The system gains heat and does work on the surroundings.
C) The system loses heat and has work done on it by the surroundings.
D) The system gains heat and has work done on it by the surroundings.
E) None of the above is correct.
Answer: D
Diff: 2 Var: 1 Page Ref: Sec. 5.2
LO: 5.2
GO: G2

5) When a system ________, ΔE is always negative.

A) absorbs heat and does work
B) gives off heat and does work
C) absorbs heat and has work done on it
D) gives off heat and has work done on it
E) None of the above is always negative.
Answer: B
Diff: 2 Var: 1 Page Ref: Sec. 5.2
LO: 5.2
GO: G2

6) Which one of the following is an endothermic process?

A) ice melting
B) water freezing
C) boiling soup
D) Hydrochloric acid and barium hydroxide are mixed at 25 °C: the temperature increases.
E) Both A and C
Answer: E
Diff: 2 Var: 1 Page Ref: Sec. 5.2
LO: 5.2
GO: G2

7) Which one of the following is an exothermic process?

A) ice melting
B) water evaporating
C) boiling soup
D) condensation of water vapor
E) Ammonium thiocyanate and barium hydroxide are mixed at 25 °C: the temperature
drops.
Answer: D
Diff: 2 Var: 1 Page Ref: Sec. 5.2
LO: 5.2
GO: G2

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8) Of the following, which one is a state function?
A) H
B) q
C) w
D) heat
E) none of the above
Answer: A
Diff: 2 Var: 1 Page Ref: Sec. 5.2
LO: 5.2
GO: G2

9) Which of the following is a statement of the first law of thermodynamics?

A) Ek = m

B) A negative ΔH corresponds to an exothermic process.

C) ΔE = Efinal - Einitial
D) Energy lost by the system must be gained by the surroundings.
E) 1 cal = 4.184 J (exactly)
Answer: D
Diff: 3 Var: 1 Page Ref: Sec. 5.2
LO: 5.2
GO: G2

10) The internal energy can be increased by ________.

(a) transferring heat from the surroundings to the system

(b) transferring heat from the system to the surroundings
(c) doing work on the system

A) a only
B) b only
C) c only
D) a and c
E) b and c
Answer: D
Diff: 2 Var: 1 Page Ref: Sec. 5.2
LO: 5.2
GO: G2

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11) A ________ ΔH corresponds to an ________ process.
A) negative, endothermic
B) negative, exothermic
C) positive, exothermic
D) zero, exothermic
E) zero, endothermic
Answer: B
Diff: 1 Var: 1 Page Ref: Sec. 5.3
LO: 5.2, 5.3
GO: G2

12) A ________ ΔH corresponds to an ________ process.

A) negative, endothermic
B) positive, exothermic
C) positive, endothermic
D) zero, exothermic
E) zero, endothermic
Answer: C
Diff: 1 Var: 1 Page Ref: Sec. 5.3
LO: 5.2, 5.3
GO: G2

13) ΔH for an endothermic process is ________ while ΔH for an exothermic process is

________.
A) zero, positive
B) zero, negative
C) positive, zero
D) negative, positive
E) positive, negative
Answer: E
Diff: 1 Var: 1 Page Ref: Sec. 5.3
LO: 5.2, 5.3
GO: G2

14) For a given process at constant pressure, w is positive. This means that the process
involves ________.
A) work being done by the system on the surroundings
B) work being done by the surroundings on the system
C) no work being done
D) an equal amount of work done on the system and by the system
E) work being done against a vacuum
Answer: A
Diff: 1 Var: 1 Page Ref: Sec. 5.3
LO: 5.2, 5.3
GO: G2

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15) Which one of the following statements is true?
A) Enthalpy is an intensive property.
B) The enthalpy change for a reaction is independent of the state of the reactants and
products.
C) Enthalpy is a state function.
D) H is the value of q measured under conditions of constant volume.
E) The enthalpy change of a reaction is the reciprocal of the ΔH of the reverse reaction.
Answer: C
Diff: 2 Var: 1 Page Ref: Sec. 5.4
LO: 5.4
GO: G4

16) Which of the following statements is false?

A) Internal energy is a state function.
B) Enthalpy is an intensive property.
C) The enthalpy change for a reaction is equal in magnitude, but opposite in sign, to the
enthalpy change for the reverse reaction.
D) The enthalpy change for a reaction depends on the state of the reactants and products.
E) The enthalpy of a reaction is equal to the heat of the reaction.
Answer: B
Diff: 3 Var: 1 Page Ref: Sec. 5.4
LO: 5.4
GO: G4

17) A chemical reaction that absorbs heat from the surroundings is said to be ________ and
has a ________ ΔH at constant pressure.
A) endothermic, positive
B) endothermic, negative
C) exothermic, negative
D) exothermic, positive
E) exothermic, neutral
Answer: A
Diff: 2 Var: 1 Page Ref: Sec. 5.4
LO: 5.2, 5.3
GO: G4

18) A chemical reaction that releases heat to the surroundings is said to be ________ and
has a ________ ΔH at constant pressure.
A) endothermic, positive
B) endothermic, negative
C) exothermic, negative
D) exothermic, positive
E) exothermic, neutral
Answer: C
Diff: 2 Var: 1 Page Ref: Sec. 5.4
LO: 5.2, 5.3
GO: G4

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19) The reaction

4Al (s) + 3O2 (g) → 2Al2O3 (s) ΔH° = -3351 kJ

is ________, and therefore heat is ________ by the reaction.
A) endothermic, released
B) endothermic, absorbed
C) exothermic, released
D) exothermic, absorbed
E) thermoneutral, neither released nor absorbed
Answer: C
Diff: 1 Var: 1 Page Ref: Sec. 5.4
LO: 5.2, 5.3
GO: G4

20) Under what condition(s) is the enthalpy change of a process equal to the amount of
heat transferred into or out of the system?

(a) temperature is constant

(b) pressure is constant
(c) volume is constant

A) a only
B) b only
C) c only
D) a and b
E) b and c
Answer: B
Diff: 3 Var: 1 Page Ref: Sec. 5.4
LO: 5.2, 5.3
GO: G2

21) The units of heat capacity are ________.

A) K/J or °C/J
B) J/K or J/°C
C) J/g-K or J/g-°C
D) J/mol
E) g-K/J or g-°C/J
Answer: B
Diff: 2 Var: 1 Page Ref: Sec. 5.5
LO: 5.5
GO: G4

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22) The units of specific heat are ________.
A) K/J or °C/J
B) J/K or J/°C
C) J/g-K or J/g-°C
D) J/mol
E) g-K/J or g-°C/J
Answer: C
Diff: 2 Var: 1 Page Ref: Sec. 5.5
LO: 5.5
GO: G4

23) The British thermal unit (Btu) is commonly used in engineering applications. A Btu is
defined as the amount of heat required to raise the temperature of 1 lb of water by 1 °F.
There are ________ Btu in one Joule. 1 lb = 453.59 g; °C = (5/9)(°F - 32°); specific heat of
H2O (l) = 4.184 J/g-K.
A) 1056 Btu
B) 1.896 × 10-3 Btu
C) 9.278 × 10-4 Btu
D) 5.120 × 10-3 Btu
E) Additional information is needed to complete the calculation.
Answer: C
Diff: 3 Var: 1 Page Ref: Sec. 5.5
LO: 5.5
GO: G4

24) Which of the following is a statement of Hess's law?

A) If a reaction is carried out in a series of steps, the ΔH for the reaction will equal the sum
of the enthalpy changes for the individual steps.
B) If a reaction is carried out in a series of steps, the ΔH for the reaction will equal the
product of the enthalpy changes for the individual steps.
C) The ΔH for a process in the forward direction is equal in magnitude and opposite in sign
to the ΔH for the process in the reverse direction.
D) The ΔH for a process in the forward direction is equal to the ΔH for the process in the
reverse direction.
E) The ΔH of a reaction depends on the physical states of the reactants and products.
Answer: A
Diff: 2 Var: 1 Page Ref: Sec. 5.6
LO: 5.6
GO: G2

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25) For which one of the following reactions is ΔH°rxn equal to the heat of formation of the
product?
A) N2 (g) + 3H2 (g) → 2NH3 (g)
B) (1/2)N2 (g) + O2 (g) → NO2 (g)
C) 6C (s) + 6H (g) → C6H6 (l)
D) P (g) + 4H (g) + Br (g) → PH4Br (l)
E) 12C (g) + 11H2 (g) + 11O (g) → C6H22O11 (g)
Answer: B
Diff: 3 Var: 1 Page Ref: Sec. 5.7
LO: 5.7
GO: G2

26) Of the following, ΔH°f is not zero for ________.

A) O2 (g)
B) C (graphite)
C) N2 (g)
D) F2 (s)
E) Cl2 (g)
Answer: D
Diff: 2 Var: 1 Page Ref: Sec. 5.7
LO: 5.7
GO: G2

27) Of the following, ΔH°f is not zero for ________.

A) Sc (g)
B) Si (s)
C) P4 (s, white)
D) Br2 (l)
E) Ca (s)
Answer: A
Diff: 3 Var: 1 Page Ref: Sec. 5.7
LO: 5.7
GO: G2

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28) Consider the following two reactions:

A → 2B ΔH°rxn = 456.7 kJ/mol

A → C ΔH°rxn = -22.1 kJ/mol

Determine the enthalpy change for the process:

2B → C
A) -478.8 kJ/mol
B) -434.6 kJ/mol
C) 434.6 kJ/mol
D) 478.8 kJ/mol
E) More information is needed to solve the problem.
Answer: A
Diff: 2 Var: 1 Page Ref: Sec. 5.7
LO: 5.7
GO: G4

29) In the reaction below, ΔH°f is zero for ________.

Ni (s) + 2CO (g) + 2PF3 (g) → Ni(CO)2(PF3)2 (l)

A) Ni (s)
B) CO (g)
C) F3 (g)
D) Ni(CO)2(PF3)2 (l)
E) both CO (g) and PF3 (g)
Answer: A
Diff: 1 Var: 1 Page Ref: Sec. 5.7
LO: 5.7
GO: G4

30) For the species in the reaction below, ΔH°f is zero for ________.
2Co (s) + H2 (g) + 8PF3 (g) → 2HCo(PF3)4 (l)

A) Co (s)
B) H2 (g)
C) PF3 (g)
D) HCo(PF3)4 (l)
E) both Co(s) and H2 (g)
Answer: E
Diff: 1 Var: 1 Page Ref: Sec. 5.7
LO: 5.7
GO: G4

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31) For which one of the following equations is ΔH°rxn equal to ΔH°f for the product?
A) Xe (g) + 2F2 (g) → XeF4 (g)
B) CH4 (g) + 2Cl2 (g) → CH2Cl2 (l) + 2HCl (g)
C) N2 (g) + O3 (g) → N2O3 (g)
D) 2CO (g) + O2 (g) → 2CO2 (g)
E) C (diamond) + O2 (g) → CO2 (g)
Answer: A
Diff: 3 Var: 1 Page Ref: Sec. 5.7
LO: 5.7
GO: G4

32) For which one of the following reactions is the value of ΔH°rxn equal to ΔH°f for the
product?
A) 2Ca (s) + O2 (g) → 2CaO (s)
B) C2H2 (g) + H2 (g) → C2H4 (g)
C) 2C (graphite) + O2 (g) → 2CO (g)
D) 3Mg (s) + N2 (g) → Mg3N2 (s)
E) C (diamond) + O2 (g) → CO2 (g)
Answer: D
Diff: 3 Var: 1 Page Ref: Sec. 5.7
LO: 5.7
GO: G4

33) For which one of the following reactions is the value of ΔH°rxn equal to ΔH°f for the
product?
A) 2C (s, graphite) + 2H2 (g) → C2H4 (g)
B) N2 (g) + O2 (g) → 2NO (g)
C) 2H2 (g) + O2 (g) → 2H2O (l)
D) 2H2 (g) + O2 (g) → 2H2O (g)
E) H2O (l) + 1/2 O2 (g) → H2O2 (l)
Answer: A
Diff: 2 Var: 1 Page Ref: Sec. 5.7
LO: 5.7
GO: G4

34) For which one of the following reactions is the value of ΔH°rxn equal to ΔH°f for the
product?
A) H2O (l) + 1/2 O2 (g) → H2O2 (l)
B) N2 (g) + O2 (g) → 2NO (g)
C) 2H2 (g) + O2 (g) → 2H2O (l)
D) 2H2 (g) + O2 (g) → 2H2O (g)
E) none of the above
Answer: E
Diff: 2 Var: 1 Page Ref: Sec. 5.7
LO: 5.7
GO: G4

35) For which one of the following reactions is the value of ΔH°rxn equal to ΔH°f for the
product?

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A) H2 (g) + 1/2 O2 (g) → H2O (l)
B) H2 (g) + O2 (g) → H2O2 (l)
C) 2C (s, graphite) + 2H2 (g) → C2H4 (g)
D) 1/2 N2 (g) + O2 (g) → NO2 (g)
E) all of the above
Answer: E
Diff: 2 Var: 1 Page Ref: Sec. 5.7
LO: 5.7
GO: G4

36) With reference to enthalpy changes, the term standard conditions means ________.
(a) P = 1 atm
(b) some common temperature, usually 298 K
(c) V = 1 L
A) a only
B) b only
C) c only
D) a and c
E) a and b
Answer: E
Diff: 1 Var: 1 Page Ref: Sec. 5.7
LO: 5.7
GO: G2

37) The energy released by combustion of 1 g of a substance is called the ________ of the
substance.
A) specific heat
B) fuel value
C) nutritional calorie content
D) heat capacity
E) enthalpy
Answer: B
Diff: 2 Var: 1 Page Ref: Sec. 5.8
LO: 5.7
GO: G2

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38) Fuel values of hydrocarbons increase as the H/C atomic ratio increases. Which of the
following compounds has the highest fuel value?
A) C2H6
B) C2H4
C) C2H2
D) CH4
E) C6H6
Answer: D
Diff: 1 Var: 1 Page Ref: Sec. 5.8
LO: 5.7
GO: G7

39) Of the substances below, the highest fuel value is obtained from ________.
A) charcoal
B) bituminous coal
C) natural gas
D) hydrogen
E) wood
Answer: D
Diff: 2 Var: 1 Page Ref: Sec. 5.8
GO: G7

40) Which one of the choices below is not considered a fossil fuel?
A) anthracite coal
B) crude oil
C) natural gas
D) hydrogen
E) petroleum
Answer: D
Diff: 2 Var: 1 Page Ref: Sec. 5.8
GO: G7

41) The most abundant fossil fuel is ________.

A) natural gas
B) petroleum
C) coal
D) uranium
E) hydrogen
Answer: C
Diff: 1 Var: 1 Page Ref: Sec. 5.8
GO: G7

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5.2 Bimodal Questions

1) Calculate the kinetic energy in J of an electron moving at 6.00 × 106 m/s. The mass of an
electron is
9.11 × 10-28 g.
A) 4.98 × 10-48 J
B) 3.28 × 10-14 J
C) 1.64 × 10-17 J
D) 2.49 × 10-48 J
E) 6.56 × 10-14 J
Answer: C
Diff: 2 Var: 1 Page Ref: Sec. 5.1
LO: 5.1
GO: G4

2) Calculate the kinetic energy in joules of an automobile weighing 2135 lb and traveling at
55 mph.
(1 mile = 1.6093 km, 1lb = 453.59 g).
A) 1.2 × 104 J
B) 2.9 × 105 J
C) 5.9 × 105 J
D) 3.2 × 106 J
E) 3.2 × 10-6 J
Answer: B
Diff: 3 Var: 1 Page Ref: Sec. 5.1
LO: 5.1
GO: G4

3) Calculate the kinetic energy in joules of an automobile weighing 4345 lb and traveling at
75 mph.
(1 mile = 1.6093 km, 1lb = 453.59 g).
A) 5.5 × 105 J
B) 5.5 × 10-5 J
C) 1.1 × 106 J
D) 2.2 × 106 J
E) 2.2 × 10-6 J
Answer: C
Diff: 3 Var: 1 Page Ref: Sec. 5.1
LO: 5.1
GO: G4

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4) The kinetic energy of a 7.3 kg steel ball traveling at 18.0 m/s is ________ J.
A) 1.2 × 103
B) 66
C) 2.4 × 103
D) 1.3 × 102
E) 7.3
Answer: A
Diff: 2 Var: 1 Page Ref: Sec. 5.1
LO: 5.1
GO: G4

5) The kinetic energy of a 10.3 g golf ball traveling at 48.0 m/s is ________ J.
A) 1.20 × 103
B) 66
C) 11.9
D) 1.3 × 102
E) 23.7
Answer: C
Diff: 2 Var: 1 Page Ref: Sec. 5.1
LO: 5.1
GO: G4

6) Calculate the kinetic energy in joules of a 150 lb jogger (68.1 kg) traveling at 12.0
mile/hr (5.36 m/s).
A) 1.96 × 103 J
B) 365 J
C) 978 J
D) 183 J
E) 68.1 J
Answer: C
Diff: 2 Var: 1 Page Ref: Sec. 5.1
LO: 5.1
GO: G4

7) Calculate the kinetic energy in joules of an 80.0 g bullet traveling at 300.0 m/s.
A) 3.60 × 106 J
B) 1.20 × 104 J
C) 3.60 × 103 J
D) 12.0 J
E) 80.0 J
Answer: C
Diff: 2 Var: 1 Page Ref: Sec. 5.1
LO: 5.1
GO: G4

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8) The kinetic energy of a 23.2-g object moving at a speed of 81.9 km/hr is ________ J.
A) 1900
B) 77.8
C) 145
D) 1.43 × 10-3
E) 6.00
Answer: E
Diff: 3 Var: 1 Page Ref: Sec. 5.1
LO: 5.1
GO: G4

9) The kinetic energy of a 23.2-g object moving at a speed of 81.9 km/hr is ________ kcal.
A) 1.43 × 10-3
B) 6.00
C) 1900
D) 454
E) 0.0251
Answer: A
Diff: 3 Var: 1 Page Ref: Sec. 5.1
LO: 5.1
GO: G4

10) A 100-watt electric incandescent light bulb consumes ________ J of energy in 24 hours.
[1 Watt (W) = 1 J/sec]
A) 2.40 × 103
B) 8.64 × 103
C) 4.17
D) 2.10 × 103
E) 8.64 × 106
Answer: E
Diff: 3 Var: 1 Page Ref: Sec. 5.1
LO: 5.1
GO: G4

11) The ΔE of a system that releases 12.4 J of heat and does 4.2 J of work on the
surroundings is
________ J.
A) 16.6
B) 12.4
C) 4.2
D) -16.6
E) -8.2
Answer: D
Diff: 2 Var: 1 Page Ref: Sec. 5.2
LO: 5.2
GO: G4

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12) The ΔE of a system that absorbs 12.4 J of heat and does 4.2 J of work on the
surroundings is
________ J.
A) 16.6
B) 12.4
C) 4.2
D) -16.6
E) 8.2
Answer: E
Diff: 2 Var: 1 Page Ref: Sec. 5.2
LO: 5.2
GO: G4

13) The change in the internal energy of a system that absorbs 2,500 J of heat and that
does 7,655 J of work on the surroundings is ________ J.
A) 10,155
B) 5,155
C) -5,155
D) -10,155
E) 1.91 ×
Answer: C
Diff: 2 Var: 1 Page Ref: Sec. 5.2
LO: 5.2
GO: G4

14) The change in the internal energy of a system that releases 2,500 J of heat and that
does 7,655 J of work on the surroundings is ________ J.
A) -10,155
B) -5,155
C) -1.91 × 107
D) 10,155
E) 5,155
Answer: A
Diff: 2 Var: 1 Page Ref: Sec. 5.2
LO: 5.2
GO: G4

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15) The value of ΔH° for the reaction below is -72 kJ. ________ kJ of heat are released when
80.9 grams of HBr is formed in this reaction.

H2 (g) + Br2 (g) → 2HBr (g)

A) 144
B) 72
C) 0.44
D) 36
E) -72
Answer: D
Diff: 2 Var: 1 Page Ref: Sec. 5.4
LO: 5.4
GO: G4

16) The value of ΔH° for the reaction below is -126 kJ. ________ kj are released when 2.00
mol of NaOH is formed in the reaction?

2Na2O2 (s) + 2H2O (l) → 4NaOH (s) + O2 (g)

A) 252
B) 63
C) 3.9
D) 7.8
E) -126
Answer: B
Diff: 2 Var: 1 Page Ref: Sec. 5.4
LO: 5.4
GO: G4

17) The value of ΔH° for the reaction below is -790 kJ. The enthalpy change accompanying
the reaction of 0.95 g of S is ________ kJ.

2S (s) + 3O2 (g) → 2SO3 (g)

A) 23
B) -23
C) -12
D) 12
E) -790
Answer: C
Diff: 3 Var: 1 Page Ref: Sec. 5.4
LO: 5.4
GO: G4

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18) The value of ΔH° for the reaction below is -6535 kJ. ________ kJ of heat are released in
the combustion of 16.0 g of C6H6 (l)?

2C6H6 (l) + 15O2 (g) → 12CO2 (g) + 6 H2O (l)

A) 1.34 × 103
B) 5.23 × 104
C) 669
D) 2.68 × 103
E) -6535
Answer: C
Diff: 3 Var: 1 Page Ref: Sec. 5.4
LO: 5.4
GO: G4

19) The value of ΔH° for the reaction below is -482 kJ. Calculate the heat (kJ) released to
the surroundings when 38.5 g of O2 (g) reacts with excess CO.

2CO (g) + O2 (g) → 2CO2 (g)

A) 2.65 × 103 kJ
B) 482 kJ
C) 580. kJ
D) 65.7 kJ
E) 210. kJ
Answer: C
Diff: 3 Var: 1 Page Ref: Sec. 5.4
LO: 5.4
GO: G4

20) The value of ΔH° for the reaction below is -336 kJ. Calculate the heat (kJ) released to
the surroundings when 23.0 g of HCl is formed.

CH4 (g) + 3Cl2 (g) → CHCl3 (l) + 3HCl (g)

A) 177 kJ
B) 2.57 × 103 kJ
C) 70.7 kJ
D) 211 kJ
E) -336 kJ
Answer: C
Diff: 3 Var: 1 Page Ref: Sec. 5.4
LO: 5.4
GO: G4

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21) The value of ΔH° for the reaction below is -186 kJ. Calculate the heat (kJ) released from
the reaction of 25 g of Cl2.

H2 (g) + Cl2 (g) → 2HCl (g)

A) 66 kJ
B) 5.3 × 102 kJ
C) 33 kJ
D) 47 kJ
E) -186 kJ
Answer: A
Diff: 3 Var: 1 Page Ref: Sec. 5.4
LO: 5.4
GO: G4

22) The enthalpy change for the following reaction is -483.6 kJ:

2H2 (g) + O2 (g) → 2H2O (g)

Therefore, the enthalpy change for the following reaction is ________ kJ.
4H2 (g) + 2O2 (g) → 4H2O (g)
A) -483.6
B) -967.2
C) 2.34 × 105
D) 483.6
E) 967.2
Answer: B
Diff: 2 Var: 1 Page Ref: Sec. 5.4
LO: 5.4
GO: G4

23) The value of ΔH° for the reaction below is +128.1 kJ:

CH3OH (l) → CO (g) + 2H2 (g)

How many kJ of heat are consumed when 15.5 g of CH3OH (l) decomposes as shown in the
equation?
A) 0.48 kJ
B) 62.0 kJ
C) 1.3 × 102 kJ
D) 32 kJ
E) 8.3 kJ
Answer: B
Diff: 3 Var: 1 Page Ref: Sec. 5.4
LO: 5.4
GO: G4

24) The value of ΔH° for the reaction below is +128.1 kJ:

CH3OH (l) → CO (g) + 2H2 (g)

How many kJ of heat are consumed when 5.10 g of H2 (g) is formed as shown in the
equation?
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A) 162 kJ
B) 62.0 kJ
C) 128 kJ
D) 653 kJ
E) 326 kJ
Answer: A
Diff: 3 Var: 1 Page Ref: Sec. 5.4
LO: 5.4
GO: G4

25) The value of ΔH° for the reaction below is +128.1 kJ:

CH3OH (l) → CO (g) + 2H2 (g)

How many kJ of heat are consumed when 5.10 g of CO (g) is formed as shown in the
equation?
A) 0.182 kJ
B) 162 kJ
C) 8.31 kJ
D) 23.3 kJ
E) 62.0 kJ
Answer: D
Diff: 3 Var: 1 Page Ref: Sec. 5.4
LO: 5.4
GO: G4

26) The value of ΔH° for the reaction below is +128.1 kJ:

CH3OH (l) → CO (g) + 2H2 (g)

How many kJ of heat are consumed when 5.75 g of CO (g) is formed as shown in the
equation?
A) 23.3 kJ
B) 62.0 kJ
C) 26.3 kJ
D) 162 kJ
E) 8.3 kJ
Answer: C
Diff: 3 Var: 1 Page Ref: Sec. 5.4
LO: 5.4
GO: G4

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27) The value of ΔH° for the reaction below is -1107 kJ:

2Ba (s) + O2 (g) → 2BaO (s)

How many kJ of heat are released when 5.75 g of Ba (s) reacts completely with oxygen to
form BaO (s)?
A) 96.3 kJ
B) 26.3 kJ
C) 46.4 kJ
D) 23.2 kJ
E) 193 kJ
Answer: D
Diff: 3 Var: 1 Page Ref: Sec. 5.4
LO: 5.4
GO: G4

28) The value of ΔH° for the reaction below is -1107 kJ:

2Ba (s) + O2 (g) → 2BaO (s)

How many kJ of heat are released when 5.75 g of BaO (s) is produced?
A) 56.9 kJ
B) 23.2 kJ
C) 20.8 kJ
D) 193 kJ
E) 96.3 kJ
Answer: C
Diff: 3 Var: 1 Page Ref: Sec. 5.4
LO: 5.4
GO: G4

29) The value of ΔH° for the reaction below is -1107 kJ:

2Ba (s) + O2 (g) → 2BaO (s)

How many kJ of heat are released when 15.75 g of Ba (s) reacts completely with oxygen to
form BaO (s)?
A) 20.8 kJ
B) 63.5 kJ
C) 114 kJ
D) 70.3 kJ
E) 35.1 kJ
Answer: B
Diff: 3 Var: 1 Page Ref: Sec. 5.4
LO: 5.4
GO: G4

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30) The molar heat capacity of a compound with the formula C2H6 SO is 88.0 J/mol-K. The
specific heat of this substance is ________ J/g-K.
A) 88.0
B) 1.13
C) 4.89
D) 6.88 × 103
E) -88.0
Answer: B
Diff: 3 Var: 1 Page Ref: Sec. 5.5
LO: 5.5
GO: G4

31) The specific heat capacity of lead is 0.13 J/g-K. How much heat (in J) is required to raise
the temperature of 15 g of lead from 22 °C to 37 °C?
A) 2.0 J
B) -0.13 J
C) 5.8 × 10-4 J
D) 29 J
E) 0.13 J
Answer: D
Diff: 3 Var: 1 Page Ref: Sec. 5.5
LO: 5.5
GO: G4

32) The temperature of a 15-g sample of lead metal increases from 22 °C to 37 °C upon the
addition of 29.0 J of heat. The specific heat capacity of the lead is ________ J/g-K.
A) 7.8
B) 1.9
C) 29
D) 0.13
E) -29
Answer: D
Diff: 3 Var: 1 Page Ref: Sec. 5.5
LO: 5.5
GO: G4

33) The specific heat of bromine liquid is 0.226 J/g-K. The molar heat capacity (in J/mol-K)
of bromine liquid is ________.
A) 707 J/mol-K
B) 36.1 J/mol-K
C) 18.1 J/mol-K
D) 9.05 J/mol-K
E) 0.226 J/mol-K
Answer: B
Diff: 3 Var: 1 Page Ref: Sec. 5.5
LO: 5.5
GO: G4

34) The specific heat of liquid bromine is 0.226 J/g-K. How much heat (J) is required to
raise the temperature of 10.0 mL of bromine from 25.00 °C to 27.30 °C? The density of
liquid bromine: 3.12 g/mL.
A) 5.20 J
B) 16.2 J
C) 300 J
D) 32.4 J

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E) 10.4 J
Answer: B
Diff: 4 Var: 1 Page Ref: Sec. 5.5
LO: 5.5
GO: G4

35) ΔH for the reaction

IF5 (g) → IF3 (g) + F2 (g)

is ________ kJ, give the data below.

IF (g) + F2 (g) → IF3 (g) ΔH = -390 kJ

IF (g) + 2F2 (g) → IF5 (g)ΔH = -745 kJ

A) +355
B) -1135
C) +1135
D) +35
E) -35
Answer: A
Diff: 3 Var: 1 Page Ref: Sec. 5.6
LO: 5.6
GO: G4

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36) Given the following reactions

Fe2O3 (s) + 3CO (s) → 2Fe (s) + 3CO2 (g) ΔH = -28.0 kJ

3Fe (s) + 4CO2 (s) → 4CO (g) + Fe3O4 (s) ΔH = +12.5 kJ

the enthalpy of the reaction of Fe2O3 with CO

3Fe2O3 (s) + CO (g) → CO2 (g) + 2 Fe3O4 (s)

is ________ kJ.
A) -59.0
B) 40.5
C) -15.5
D) -109
E) +109
Answer: A
Diff: 3 Var: 1 Page Ref: Sec. 5.6
LO: 5.6
GO: G4

37) Given the following reactions

N2 (g) + 2O2 (g) → 2NO2 (g) ΔH = 66.4 kJ

2NO (g) + O2 (g) → 2NO2 (g) ΔH = -114.2 kJ

the enthalpy of the reaction of the nitrogen to produce nitric oxide

N2 (g) + O2 (g) → 2NO (g)

is ________ kJ.
A) 180.6
B) -47.8
C) 47.8
D) 90.3
E) -180.6
Answer: A
Diff: 3 Var: 1 Page Ref: Sec. 5.6
LO: 5.6
GO: G4

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38) Given the following reactions

2NO → N2 + O2 ΔH = -180 kJ

2NO + O2 → 2NO2 ΔH = -112 kJ

the enthalpy of the reaction of nitrogen with oxygen to produce nitrogen dioxide

N2 + 2O2 → 2NO2

is ________ kJ.
A) 68
B) -68
C) -292
D) 292
E) -146
Answer: A
Diff: 3 Var: 1 Page Ref: Sec. 5.6
LO: 5.6
GO: G4

39) Given the following reactions

2S (s) + 3O2 (g) → 2SO3 (g) ΔH = -790 kJ

S (s) + O2 (g) → SO2 (g) ΔH = -297 kJ

the enthalpy of the reaction in which sulfur dioxide is oxidized to sulfur trioxide

2SO2 (g) + O2 (g) → 2SO3 (g)

is ________ kJ.
A) 196
B) -196
C) 1087
D) -1384
E) -543
Answer: B
Diff: 3 Var: 1 Page Ref: Sec. 5.6
LO: 5.6
GO: G4

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40) Given the following reactions

CaCO3 (s) → CaO (s) + CO2 (g) ΔH = 178.1 kJ

C (s, graphite) + O2 (g) → CO2 (g) ΔH = -393.5 kJ

the enthalpy of the reaction

CaCO3 (s) → CaO (s) + C (s, graphite) + O2 (g)

is ________ kJ.
A) 215.4
B) 571.6
C) -215.4
D) -571.6
E) 7.01 × 104
Answer: B
Diff: 3 Var: 1 Page Ref: Sec. 5.6
LO: 5.6
GO: G4

41) Given the following reactions

H2O (l) → H2O (g) ΔH = 44.01 kJ

2H2 (g) + O2 (g) → 2H2O (g) ΔH = -483.64 kJ

the enthalpy for the decomposition of liquid water into gaseous hydrogen and oxygen

2H2O (l) → 2H2 (g) + O2 (g)

is ________ kJ.
A) -395.62
B) -527.65
C) 439.63
D) 571.66
E) 527.65
Answer: D
Diff: 3 Var: 1 Page Ref: Sec. 5.6
LO: 5.6
GO: G4

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42) Given the following reactions

N2 (g) + O2 (g) → 2NO (g) ΔH = +180.7 kJ

2NO( g) + O2 (g) → 2NO2 (g) ΔH = -113.1 kJ

the enthalpy for the decomposition of nitrogen dioxide into molecular nitrogen and oxygen

2NO2 (g) → N2 (g) + 2O2 (g)

is ________ kJ.
A) 67.6
B) -67.6
C) 293.8
D) -293.8
E) 45.5
Answer: B
Diff: 3 Var: 1 Page Ref: Sec. 5.6
LO: 5.6
GO: G4

43) Given the following reactions

N2 (g) + O2 (g) → 2NO (g) ΔH = +180.7 kJ

2NO (g) + O2 (g) → 2NO2 (g) ΔH = -113.1 kJ

the enthalpy of reaction for

4NO (g) → 2NO2 (g) + N2 (g)

is ________ kJ.
A) 67.6
B) 45.5
C) -293.8
D) -45.5
E) 293.8
Answer: C
Diff: 3 Var: 1 Page Ref: Sec. 5.6
LO: 5.6
GO: G4

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44) Given the following reactions

N2 (g) + O2 (g) → 2NO (g) ΔH = +180.7 kJ

2N2O (g) → O2 (g) + 2N2 (g)ΔH = -163.2 kJ

the enthalpy of reaction for

2N2O (g) → 2NO (g) + N2 (g)

is ________ kJ.
A) 145.7
B) 343.9
C) -343.9
D) 17.5
E) -145.7
Answer: D
Diff: 3 Var: 1 Page Ref: Sec. 5.6
LO: 5.6
GO: G4

45) The value of ΔH° for the reaction below is -186 kJ.

H2 (g) + Cl2 (g) → 2HCl (g)

The value of ΔH°f for HCl (g) is ________ kJ/mol.

A) -3.72 × 102
B) -1.27 × 102
C) -93.0
D) -186
E) +186
Answer: C
Diff: 2 Var: 1 Page Ref: Sec. 5.7
LO: 5.7
GO: G4

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46) The value of ΔH° for the following reaction is -3351 kJ:

2Al (s) + 3O2 (g) → 2Al2O3 (s)

The value of ΔH°f for Al2O3 (s) is ________ kJ.

A) -3351
B) -1676
C) -32.86
D) -16.43
E) +3351
Answer: B
Diff: 2 Var: 1 Page Ref: Sec. 5.7
LO: 5.7
GO: G4

47) Given the data in the table below, ΔH°rxn for the reaction

Ca(OH)2 + 2H3AsO4 → Ca(H2AsO4)2 + 2H2O

is ________ kJ.

A) -744.9
B) -4519
C) -4219
D) -130.4
E) -76.4
Answer: D
Diff: 3 Var: 1 Page Ref: Sec. 5.7
LO: 5.7
GO: G4

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48) Given the data in the table below, ΔH°rxn for the reaction

4NH3 (g) + 5O2 (g) → 4NO (g) + 6H2O (l)

is ________ kJ.

A) -1172
B) -150
C) -1540
D) -1892
E) The ΔH°f of O2 (g) is needed for the calculation.
Answer: A
Diff: 3 Var: 1 Page Ref: Sec. 5.7
LO: 5.7
GO: G4

49) Given the data in the table below, ΔH°rxn for the reaction

C2H5OH (l) + O2 (g) → CH3CO2H (l) + H2O (l)

is ________ kJ.

A) -79.0
B) -1048.0
C) -476.4
D) -492.6
E) The value of ΔH°f of O2 (g) is required for the calculation.
Answer: D
Diff: 3 Var: 1 Page Ref: Sec. 5.7
LO: 5.7
GO: G4

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50) Given the data in the table below, ΔH°rxn for the reaction

3NO2 (g) + H2O (l) → 2HNO3 (aq) + NO (g)

is ________ kJ.

A) 64
B) 140
C) -140
D) -508
E) -64
Answer: C
Diff: 3 Var: 1 Page Ref: Sec. 5.7
LO: 5.7
GO: G4

51) Given the data in the table below, ΔH°rxn for the reaction

IF5 (g) + F2 (g) → IF7 (g)

is ________ kJ.

A) 1801
B) -1801
C) 121
D) -121
E) -101
Answer: E
Diff: 3 Var: 1 Page Ref: Sec. 5.7
LO: 5.7
GO: G4

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52) Given the data in the table below, ΔH° for the reaction

2CO (g) + O2 (g) → 2CO2 (g)

is ________ kJ.

A) -566.4
B) -283.2
C) 283.2
D) -677.0
E) The ΔH°f of O2 (g) is needed for the calculation.
Answer: A
Diff: 3 Var: 1 Page Ref: Sec. 5.7
LO: 5.7
GO: G4

53) The value of ΔH° for the following reaction is 177.8 kJ. The value of ΔH°f for CaO(s) is
________ kJ/mol.
CaCO3 (s) → CaO (s) + CO2 (g)

A) -1600
B) -813.4
C) -635.5
D) 813.4
E) 177.8
Answer: C
Diff: 3 Var: 1 Page Ref: Sec. 5.7
LO: 5.7
GO: G4

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54) Given the data in the table below, ΔH°rxn for the reaction

2Ag2S (s) + O2 (g) → 2Ag2O (s) + 2S (s)

is ________ kJ.

A) -1.6
B) +1.6
C) -3.2
D) +3.2
E) The ΔH°f of S (s) and of O2 (g) are needed for the calculation.
Answer: D
Diff: 3 Var: 1 Page Ref: Sec. 5.7
LO: 5.7
GO: G4

55) Given the data in the table below, ΔH°rxn for the reaction

Ag2O (s) + H2S (g) → Ag2S (s) + H2O (l)

is ________ kJ.

A) -267
B) -370
C) -202
D) -308
E) More data are needed to complete the calculation.
Answer: A
Diff: 3 Var: 1 Page Ref: Sec. 5.7
LO: 5.7
GO: G4

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56) Given the data in the table below, ΔH°rxn for the reaction

2SO2 (g) + O2 (g) → 2SO3 (g)

is ________ kJ.

A) -99
B) 99
C) -198
D) 198
E) The ΔH°f of O2 (g) is needed for the calculation.
Answer: C
Diff: 3 Var: 1 Page Ref: Sec. 5.7
LO: 5.7
GO: G4

57) Given the data in the table below, ΔH°rxn for the reaction

SO3 (g) + H2O (l) → H2SO4 (l)

is ________ kJ.

A) -132
B) 1496
C) 704
D) -704
E) -2.16 × 103
Answer: A
Diff: 3 Var: 1 Page Ref: Sec. 5.7
LO: 5.7
GO: G4

58) Given the data in the table below, ΔH°rxn for the reaction

3 Cl2 (g) + PH3 (g) → PCl3 (g) + 3 HCl (g)

is ________ kJ.
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Copyright © 2015 Pearson Education
A) -385.77
B) -570.37
C) 570.37
D) 385.77
E) The ΔH°f of Cl2 (g) is needed for the calculation.
Answer: B
Diff: 3 Var: 1 Page Ref: Sec. 5.7
LO: 5.7
GO: G4

59) Given the data in the table below, ΔH°rxn for the reaction

PCl3 (g) + 3 HCl (g) → 3Cl2 (g) + PH3 (g)

is ________ kJ.

A) -570.37
B) -385.77
C) 570.37
D) 385.77
E) The ΔH°f of Cl2 (g) is needed for the calculation.
Answer: C
Diff: 3 Var: 1 Page Ref: Sec. 5.7
LO: 5.7
GO: G4

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60) Given the data in the table below and ΔH°rxn for the reaction

SO2Cl2 (g) + 2H2O (l) → H2SO4 (l) + 2HCl (g) ΔH° = -62 kJ

ΔH°f of HCl (g) is ________ kJ/mol.

A) -184
B) 60
C) -92
D) 30
E) Insufficient data are given.
Answer: C
Diff: 4 Var: 1 Page Ref: Sec. 5.7
LO: 5.7
GO: G4

61) A 25.5-g piece of cheddar cheese contains 37% fat, 28% protein, and 4% carbohydrate.
The respective fuel values for protein, fat, and carbohydrate are 17, 38, and 17 kJ/g,
respectively. The fuel value for this piece of cheese is ________ kJ.
A) 450
B) 330
C) 790
D) 99
E) 260
Answer: A
Diff: 3 Var: 1 Page Ref: Sec. 5.8
GO: G4

62) The average fuel value of sugars is 17 kJ/g. A 2.0 L pitcher of sweetened Kool-Aid®
contains 400 g of sugar. What is the fuel value (in kJ) of a 500 mL serving of Kool-Aid®?
(Assume that the sugar is the only fuel source.)
A) 4.2 × 104 kJ
B) 1.7 × 103 kJ
C) 1.7 × 106 kJ
D) 1.7 × 102 kJ
E) 17 kJ
Answer: B
Diff: 3 Var: 1 Page Ref: Sec. 5.8
GO: G7

63) A meal containing a burger, fries, and a milkshake contains 53.0 grams of fat, 38.0
grams of protein, and 152 grams of carbohydrate. The respective fuel values for protein,
fat, and carbohydrate are 17, 38, and 17 kJ/g, respectively. If swimming typically burns
1100.0 kJ/hour, ________ minutes of swimming are required to completely burn off the meal.
A) 4.78
B) 33.5
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C) 62.5
D) 10.5
E) 286
Answer: E
Diff: 3 Var: 1 Page Ref: Sec. 5.8
GO: G7

64) A slice of apple pie contains 14.0 grams of fat, 2.00 grams of protein, and 52.0 grams of
carbohydrate. The respective fuel values for protein, fat, and carbohydrate are 17, 38, and
17 kJ/g, respectively. If cycling typically burns 1000.0 kJ/hour, ________ minutes of cycling
are required to completely burn off the slice of pie.
A) 1.45
B) 4.66
C) 8.25
D) 87.0
E) < 1
Answer: D
Diff: 3 Var: 1 Page Ref: Sec. 5.8
GO: G7

5.3 Algorithmic Questions

1) The kinetic energy of a 26.9-g object moving at a speed of 81.9 m/s is ________ J.
A) 145
B) 0.950
C) 90.2
D) 90200
E) 1450
Answer: C
Diff: 2 Var: 7 Page Ref: Sec. 5.1
LO: 5.1
GO: G4

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2) The kinetic energy of a 23.2-g object moving at a speed of 98.7 m/s is ________ J.
A) 145
B) 113
C) 1450
D) 0.950
E) 113000
Answer: B
Diff: 2 Var: 7 Page Ref: Sec. 5.1
LO: 5.1
GO: G4

3) At what velocity (m/s) must a 19.9 g object be moving in order to possess a kinetic
energy of 1.0 J?
A) 0.35 m/s
B) 2.8 m/s
C) 0.13 m/s
D) 0.031 m/s
E) 0.016 m/s
Answer: A
Diff: 2 Var: 50+ Page Ref: Sec. 5.1
LO: 5.1
GO: G4

4) At what velocity (m/s) must a 417.3 g object be moving in order to possess a kinetic
energy of 3.2 J?
A) 0.12 m/s
B) 26 m/s
C) 0.015 m/s
D) 0.0038 m/s
E) 0.00024 m/s
Answer: A
Diff: 2 Var: 50+ Page Ref: Sec. 5.1
LO: 5.1
GO: G4

5) When work is done on a system, w will be a ________ value.

A) positive
B) negative
C) very large
D) very small
E) There is not enough information given to determine the answer.
Answer: A
Diff: 3 Var: 4 Page Ref: Sec. 5.2
LO: 5.2
GO: G4

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6) The value of ΔE for a system that performs 139 kJ of work on its surroundings and gains
54kJ of heat is ________ kJ.
A) -85
B) 193
C) 7506
D) 85
E) -193
Answer: A
Diff: 2 Var: 50+ Page Ref: Sec. 5.2
LO: 5.2
GO: G4

7) The value of ΔE for a system that performs 19 kJ of work on its surroundings and loses
9kJ of heat is ________ kJ.
A) -28
B) 28
C) 171
D) 10
E) -10
Answer: A
Diff: 2 Var: 50+ Page Ref: Sec. 5.2
LO: 5.2
GO: G4

8) Calculate the work (kJ) done during a reaction in which the internal volume expands
from 19 L to 48 L against an outside pressure of 2.5 atm.
A) -7.3 kJ
B) 17 kJ
C) 7.3 kJ
D) -17 kJ
E) 0 kJ; No work is done.
Answer: A
Diff: 3 Var: 50+ Page Ref: Sec. 5.2
LO: 5.2
GO: G4

9) Calculate the work (kJ) done during a reaction in which the internal volume expands
from 14 L to 50 L against a vacuum (an outside pressure of 0 atm).
A) 0; kJ No work is done.
B) 3.6 kJ
C) -3.6 kJ
D) 6.5 kJ
E) -6.5 kJ
Answer: A
Diff: 3 Var: 50+ Page Ref: Sec. 5.2
LO: 5.2
GO: G4

10) Calculate the work (kJ) done during a reaction in which the internal volume contracts
from 83 L to
13 L against an outside pressure of 4.4 atm.
A) 31 kJ
B) 43 kJ
C) -31 kJ
D) -43 kJ
E) 0 kJ; No work is done.
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Copyright © 2015 Pearson Education
Answer: A
Diff: 3 Var: 50+ Page Ref: Sec. 5.2
LO: 5.2
GO: G4

11) The value of ΔE for a system that performs 151 kJ of work on its surroundings and loses
79 kJ of heat is ________ kJ.
A) +230.
B) -230.
C) +72
D) -72
E) -151
Answer: B
Diff: 2 Var: 9 Page Ref: Sec. 5.2
LO: 5.2
GO: G4

12) Calculate the value of ΔE in joules for a system that loses 115 J of heat and has 150 J of
work performed on it by the surroundings.
A) -115 J
B) -35 J
C) +35 J
D) +265 J
E) -265 J
Answer: C
Diff: 2 Var: 10 Page Ref: Sec. 5.2
LO: 5.2
GO: G4

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13) The value of ΔH° for the reaction below is -72 kJ. ________ kJ of heat are released when
5.5 mol of HBr is formed in this reaction.

H2 (g) + Br2 (g) → 2HBr (g)

A) 144
B) 72
C) 0.44
D) 198
E) -72
Answer: D
Diff: 2 Var: 12 Page Ref: Sec. 5.4
LO: 5.4
GO: G4

14) The value of ΔH° for the reaction below is -126 kJ. The amount of heat that is released
by the reaction of 10.0 g of Na2O2 with water is ________ kJ.

2Na2O2 (s) + 2H2O (l) → 4NaOH (s) + O2 (g)

A) 8.08
B) 16.2
C) 67.5
D) 32.3
E) -126
Answer: A
Diff: 3 Var: 9 Page Ref: Sec. 5.4
LO: 5.4
GO: G4

15) The value of ΔH° for the reaction below is -482 kJ. Calculate the heat (kJ) released to
the surroundings when 10.0 g of CO (g) reacts completely.
2CO (g) + O2 (g) → 2CO2 (g)

A) 2410 kJ
B) 172 kJ
C) 86.0 kJ
D) 482 kJ
E) -482 kJ
Answer: C
Diff: 3 Var: 8 Page Ref: Sec. 5.4
LO: 5.4
GO: G4

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16) In the presence of excess oxygen, methane gas burns in a constant-pressure system to
yield carbon dioxide and water:

CH4 (g) + 2O2 (g) → CO2 (g) + 2H2O (l) △H = -890.0 kJ

Calculate the value of q (kJ) in this exothermic reaction when 1.80 g of methane is
combusted at constant pressure.
A) -100.1 kJ
B) 0.0324 kJ
C) -0.0100 kJ
D) 30.9 kJ
E) -1.00 × 105 kJ
Answer: A
Diff: 3 Var: 10 Page Ref: Sec. 5.4
LO: 5.4
GO: G4

17) Hydrogen peroxide decomposes to water and oxygen at constant pressure by the
following reaction:

2H2O2 (l) → 2H2O (l) + O2 (g) △H = -196 kJ

Calculate the value of q (kJ) in this exothermic reaction when 1.50 g of hydrogen peroxide
decomposes at constant pressure?
A) -8.65 kJ
B) -4.32 kJ
C) -0.0578 kJ
D) 3.84 kJ
E) -8.65 × 103 kJ
Answer: B
Diff: 3 Var: 10 Page Ref: Sec. 5.4
LO: 5.4
GO: G4

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18) The combustion of titanium with oxygen produces titanium dioxide:

Ti (s) + O2 (g) → TiO2 (s)

When 0.610 g of titanium is combusted in a bomb calorimeter, the temperature of the

calorimeter increases from 25.00 °C to 50.50 °C. In a separate experiment, the heat
capacity of the calorimeter is measured to be 9.84 kJ/K. The heat of reaction for the
combustion of a mole of Ti in this calorimeter is ________ kJ/mol.
A) 2.09
B) 4.14
C) -311
D) -0.154
E) -1.98 × 104
Answer: E
Diff: 4 Var: 15 Page Ref: Sec. 5.5
LO: 5.5
GO: G4

19) A sample of aluminum metal absorbs 11.2 J of heat, upon which the temperature of the
sample increases from 23.2 °C to 30.5 °C. Since the specific heat capacity of aluminum is
0.90 J/g-K, the mass of the sample is ________ g.
A) 72
B) 1.7
C) 10.
D) 65
E) 7.3
Answer: B
Diff: 3 Var: 8 Page Ref: Sec. 5.5
LO: 5.5
GO: G4

20) A sample of calcium carbonate [CaCO3 (s)] absorbs 40.3 J of heat, upon which the
temperature of the sample increases from 20.8 °C to 27.3 °C. If the specific heat of calcium
carbonate is 0.82 J/g-K, what is the mass (in grams) of the sample?
A) 7.6 g
B) 5.1 g
C) -7.6 g
D) 0.13 g
E) 5.3 g
Answer: A
Diff: 3 Var: 50+ Page Ref: Sec. 5.5
LO: 5.5
GO: G4

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21) The temperature of a 11.8 g sample of calcium carbonate [CaCO3 (s)] increases from
24.8 °C to 38.0 °C. If the specific heat of calcium carbonate is 0.82 J/g-K, how many joules
of heat are absorbed?
A) 130 J
B) 0.92 J
C) -130 J
D) -0.92 J
E) 11 J
Answer: A
Diff: 3 Var: 50+ Page Ref: Sec. 5.5
LO: 5.5
GO: G4

22) An 6.11 g sample of calcium carbonate [CaCO3 (s)] absorbs 84 J of heat, upon which
the temperature of the sample increases from 19.2 °C to 35.9 °C. What is the specific heat
of calcium carbonate?
A) 0.82 J/g-K
B) -0.82 J/g-K
C) 31 J/g-K
D) 230 J/g-K
E) 8600 J/g-K
Answer: A
Diff: 3 Var: 50+ Page Ref: Sec. 5.5
LO: 5.5
GO: G4

23) A sample of iron absorbs 81.0 J of heat, upon which the temperature of the sample
increases from 19.7 °C to 28.2 °C. If the specific heat of iron is 0.450 J/g-K, what is the
mass (in grams) of the sample?
A) 21.2 g
B) 4.29 g
C) -21.2 g
D) 0.0472 g
E) 3.83 g
Answer: A
Diff: 3 Var: 50+ Page Ref: Sec. 5.5
LO: 5.5
GO: G4

24) The temperature of a 35.1 g sample of iron increases from 24.5 °C to 31.8 °C. If the
specific heat of iron is 0.450 J/g-K, how many joules of heat are absorbed?
A) 115 J
B) 0.0936 J
C) -115 J
D) 0.722 J
E) 3.29 J
Answer: A
Diff: 3 Var: 50+ Page Ref: Sec. 5.5
LO: 5.5
GO: G4

25) A 22.9 g sample of iron absorbs 155 J of heat, upon which the temperature of the
sample increases from 23.9 °C to 38.9 °C. What is the specific heat of iron?
A) 0.451 J/g-K
B) -0.451 J/g-K
C) 237 J/g-K
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D) 102 J/g-K
E) 53,200 J/g-K
Answer: A
Diff: 3 Var: 50+ Page Ref: Sec. 5.5
LO: 5.5
GO: G4

26) The specific heat capacity of liquid water is 4.18 J/g-K. How many joules of heat are
needed to raise the temperature of 7.25 g of water from 20.0 °C to 44.1 °C?
A) 41.8 J
B) 730 J
C) 1.94 × 103 J
D) 2.39 × 10-2 J
E) 66.8 J
Answer: B
Diff: 3 Var: 15 Page Ref: Sec. 5.5
LO: 5.5
GO: G4

27) The specific heat capacity of methane gas is 2.20 J/g-K. How many joules of heat are
needed to raise the temperature of 7.25 g of methane from 22.0 °C to 57.0 °C?
A) 115 J
B) 558 J
C) 1.26 × 103 J
D) 8.67 × 10-3 J
E) 41.3 J
Answer: B
Diff: 3 Var: 15 Page Ref: Sec. 5.5
LO: 5.5
GO: G4

28) The specific heat capacity of liquid mercury is 0.14 J/g-K. How many joules of heat are
needed to raise the temperature of 6.00 g of mercury from 25.1 °C to 65.3 °C?
A) 1.7 × 103 J
B) 34 J
C) 76 J
D) 5.8 × 10-4 J
E) 2.2 J
Answer: B
Diff: 3 Var: 15 Page Ref: Sec. 5.5
LO: 5.5
GO: G4

29) The specific heat capacity of solid copper metal is 0.385 J/g-K. How many joules of heat
are needed to raise the temperature of a 2.12-kg block of copper from 25.0 °C to 99.9 °C?
A) 4.12 × 105 J
B) 61.1 J
C) 6.11 × 104 J
D) 2.42 × 10-6 J
E) 0.00242 J
Answer: C
Diff: 3 Var: 15 Page Ref: Sec. 5.5
LO: 5.5
GO: G4
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Copyright © 2015 Pearson Education
30) A 4.50-g sample of liquid water at 25.0 °C is heated by the addition of 133 J of energy.
The final temperature of the water is ________ °C. The specific heat capacity of liquid water
is 4.18 J/g-K.
A) 149
B) 25.1
C) -17.9
D) 32.1
E) 7.07
Answer: D
Diff: 3 Var: 20 Page Ref: Sec. 5.5
LO: 5.5
GO: G4

31) The ΔH for the solution process when solid sodium hydroxide dissolves in water is 44.4
kJ/mol. When a 12.6-g sample of NaOH dissolves in 250.0 g of water in a coffee-cup
calorimeter, the temperature increases from 23.0 °C to ________°C. Assume that the
solution has the same specific heat as liquid water, i.e., 4.18 J/g-K.
A) 35.2
B) 24.0
C) 36.4
D) 35.7
E) 40.2
Answer: D
Diff: 4 Var: 8 Page Ref: Sec. 5.5
LO: 5.5
GO: G4

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32) A 50.0-g sample of liquid water at 25.0 °C is mixed with 23.0 g of water at 79.0 °C. The
final temperature of the water is ________ °C.
A) 123
B) 27.3
C) 52.0
D) 231
E) 42.0
Answer: E
Diff: 3 Var: 30 Page Ref: Sec. 5.5
LO: 5.5
GO: G4

33) A 5.00-g sample of copper metal at 25.0 °C is heated by the addition of 133 J of energy.
The final temperature of the copper is ________°C. The specific heat capacity of copper is
0.38 J/g-K.
A) 35.1
B) 25.0
C) 45.0
D) 95.0
E) 70.0
Answer: D
Diff: 3 Var: 20 Page Ref: Sec. 5.5
LO: 5.5
GO: G4

34) The temperature of a 24.3 g sample of gold increases from 23.7 °C to 31.5 °C. If the
specific heat of gold is 0.129 J/g-K, how many joules of heat are absorbed?
A) 24.5 J
B) 0.0414 J
C) -24.5 J
D) 0.293 J
E) 1.01 J
Answer: A
Diff: 3 Var: 50+ Page Ref: Sec. 5.5
LO: 5.5
GO: G4

35) What is the enthalpy change (in kJ) of a chemical reaction that raises the temperature
of 250.0 mL of solution having a density of 1.25 g/mL by 3.33 °C? (The specific heat of the
solution is 3.74 J/g-K.)
A) -7.43 kJ
B) -12.51 kJ
C) 8.20 kJ
D) -3.89 kJ
E) 6.51 kJ
Answer: D
Diff: 4 Var: 10 Page Ref: Sec. 5.5
LO: 5.5
GO: G4

36) A 5-ounce cup of raspberry yogurt contains 6.0 g of protein, 2.0 g of fat, and 16.3 g of
carbohydrate. The fuel values for protein, fat, and carbohydrate are 17, 38, and 17 kJ/g,
respectively. The fuel value of this cup of yogurt is ________ kJ.
A) 460
B) 520
C) 280
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D) 720
E) 72
Answer: A
Diff: 3 Var: 9 Page Ref: Sec. 5.8
GO: G7

5.4 Short Answer Questions

1) ________ is defined as the energy used to move an object against a force.

Answer: Work
Diff: 2 Var: 1 Page Ref: Sec. 5.1
LO: 5.1
GO: G4

2) Given the equation

H2O (l) → H2O (g) ΔHrxn = 40.7 kJ at 100 °C

Calculate the mass of liquid water (in grams) at 100 °C that can converted to vapor by
absorbing 2400 J of heat.
Answer: 1.061 grams
Diff: 3 Var: 1 Page Ref: Sec. 5.5
LO: 5.5
GO: G4

3) Given the equation

H2O (l) → H2O (g) ΔHrxn = 40.7 kJ at 100 °C

Calculate the heat required to convert 3.00 grams of liquid water at 100 °C to vapor.
Answer: 6.78 kJ
Diff: 3 Var: 1 Page Ref: Sec. 5.5
LO: 5.5
GO: G4

4) When 0.800 grams of NaOH is dissolved in 100.0 grams of water, the temperature of the
solution increases from 25.00 °C to 27.06 °C. The amount of heat absorbed by the water is
________ J. (The specific heat of water is 4.18 J/g-°C.)
Answer: 868
Diff: 3 Var: 1 Page Ref: Sec. 5.5
LO: 5.5
GO: G4

5) Given the equation:

CH4 (g) + 2 O2 (g) → CO2 (g) + H2O (l) ΔH = -890.0 kJ

The heat liberated when 34.78 grams of methane (CH4) are burned in an excess amount of
oxygen is ________ kJ.
Answer: 1929 kJ
Diff: 3 Var: 1 Page Ref: Sec. 5.5
LO: 5.5
GO: G4

6) The standard enthalpy change of a reaction is the enthalpy change when all reactants
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and products are at ________ pressure and a specific temperature.
Answer: 1 atm
Diff: 2 Var: 1 Page Ref: Sec. 5.7
LO: 5.7
GO: G2

7) Coal contains hydrocarbons of high molecular weight as well as compounds containing

________, oxygen, or nitrogen.
Answer: sulfur
Diff: 2 Var: 1 Page Ref: Sec. 5.8
GO: G7

5.5 True/False Questions

1) Work equals force times distance.

Answer: TRUE
Diff: 1 Var: 1 Page Ref: Sec. 5.1
LO: 5.1
GO: G2

2) One joule equals 1 kg-m2/s2.

Answer: TRUE
Diff: 2 Var: 1 Page Ref: Sec. 5.1
LO: 5.1
GO: G2

3) Units of energy include newtons, joules, and calories.

Answer: FALSE
Diff: 1 Var: 1 Page Ref: Sec. 5.1
LO: 5.1
GO: G2

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Copyright © 2015 Pearson Education
4) The primary component of natural gas is propane.
Answer: FALSE
Diff: 1 Var: 1 Page Ref: Sec. 5.8
GO: G2

5) Renewable energy sources are essentially inexhaustible.

Answer: TRUE
Diff: 1 Var: 1 Page Ref: Sec. 5.8
GO: G2

6) Petroleum is a liquid composed of hundreds of compounds.

Answer: TRUE
Diff: 2 Var: 1 Page Ref: Sec. 5.8
GO: G2

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