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Reaction Intermediate
Organic chemistry by sudhir nama
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Reaction Intermediate
Organic chemistry by sudhir nama
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(tasjueqoaqy puy suonaeay 218310 241) ‘yedueaeh alle faeagy tle leptin WEN AypNg ‘cech ae’ car fas & faentfal & fare ldtre afarane abe frarfattr (The Organic Reactions And Mechanism) orteraat NCERT well 4 2 Previous 5 Year Board NEET Nees. li-Jee Solved Questions IIT-JEE \\ Sudhir Namaorg ferra—aeg, do mao 1 War ordi Tar (GOC) 1-13 2 aifafiear Head (Reaction Intermediates) 14-18 3 orf affftrare (Organic Reactions) 19-36 4 Sevedea Ud SoA (Halo Alkanes And Halo Arenes) 37-75 5 Uewlect (Alcohols) 76-98 6 fteifet (Phenols) 99-118 7 gar (Ethers) 119-126 8 ufeselgs Vd HCH (Aldehydes and ketones) 127-155 9 oraifeafere sitet (Caroboxylic Acids) 156-173 10 Wit (Amines) 174-204 Aegi Va SIsTat Airs (Nitro And Dizao Compounds) 205 ~ 217 fara asf & yea—aa eo afea— 218-2322 afafiear aeaadt Reaction Intermediates @Mitat ae sear aralderat (Carbonium Ion or Carbocation) feet ahftrar 4 ereeiziroran aero farigt feiss 8 wrt sneer whteftor fore ards ae eraraer ef rdtererery a ordifas oer ar order bed 8) ede 4 @rds & weioh Gre A dae Ge ed & eererH wid GT wWaeer SP? ela B wa P Her are gras Bl] lt al ace a He? H H H orieert ardkterr urate, facdiaw yd qa vor & ed 21 ® @ CH CH, — CH,-CH—CH, CH, C—CH, oH aren (1%) fetter (2°) haw 3°) (Primary) (Secondary) (Tertiary) aralPra ara wT wnPA (Stability of Carbonium ION) samara arate Pratt ar water gaag & Reta ger ag aT BT Fa we order ecagt gran agg GS ae Bad gr TYE A oda garages ye H owe aed 8 oe GU wale a aT 81 He aT q—c mS MAR AN aah aT aT wn aaa 81 epg —>— 42 ' EDG — Electron donating group EWG — Electron Withdrawing group le EWG —— c® praia wenfcr acid 81 apraifrere at wenftier werd 21(CHC > (CHCH > CHM, > CH 2 2 r Methyl writ sat a Tift (Classification of Carbonium ION) 1, sere @raife1 (Transient or Short lived Carbonium ION) arr shar ora aga a 8 wd aga A sara Panta ad 81 a ore afer A dae dpa eral Oo waa aad 81 os oniay oer & era oh ain ager err a onl 1 ® ® > (CHY,CH > CH,—CH, 2 r 2, wart @raifray TAT (Stable Carbonium TON) a order areas were ett & gaat facta wed seas feat on wend & Fs wnfaea Bt AEM PATS ERI @ oT wed 8) Qe oralran ores ger aiflles wa ete Bf a cra cay Ty GT BL §-5-6-6 ghiferert orert or verter 8-G.-9-O-G 0-0-9 yaar eta > Ae > C=C > LX > zig Pre ARrat @fbier erremt-argactter ARF ART — Eas __—_#H- (ck oralfray arert eenftrea aaEc Coouaey| g ® CH, = CH— CH > « Hye > (cHy.en > cHy ke > cH, feat eT 3. 8g wrefraT_ aT (NON-Classical or Bridged Carbonium ION) RY ears omer Faery ear ore eT a cee eri ache gen aT gl ne~ Pee a wafer arate ai Aer de are ef Sg eral sret aed B 1 H,C— CH, H,C— CH, H,C— CH, H-B-G-O=6 ordacorea ar @rétfrar (Carbanions) feet after & wewiatorn de & faerie frase ger Hrd We aeoMaer Ge Sr GiTeT fore Ge eeitoh are 4 8e- ete @ se FoR ards oe Uw ot dae after eat 81 H wie + y—de era t H ordre a wnfact (Stability of Carbanion) era Ye oar eHeAtaT atl 8 arc: Had water a ge wer & fery AOU HT AH Hea sae Star fire ste seme 4 aft ett ae scat ff afte wee err 1. gatagta orem wy (AR) SR -CN,-NO,, Ye =o ant amréreoart a wenfics a ward 1 2. sepre gre ards & aeonder at fleerftener grr aa aed wenfaca wt ast wad 8) sate ardscort > fede ardacorert > afere andar ay (2°) B’) e-Gbe Ly eecne n-Gid cmon, I ofBe orere 9 water wr BPral > gat > Ar > Yar > shir > anger > anger RI YEH (Free Radicals) Ra erg sre erg Free reer cee fer ete A water MT era Prmfor ae a reer TST ETT ar 1 SARZ me Sec ee , Schice B+ Se + CS gare eis BRI ZAG wt wifeea (Stability of Free Radicals) Ra agg Gt Sagi aren (41 IIR) AT aR STAT STAT aT wena gare 8 wR a eB ada ada coer a HRP TOT, MTT A BAB ATA AR oresy or ene gee (CH);€ > (CH),€ > CH,— CH, > CH. wleiet WeRT Yer : CH, Lone tH, +» éH,—cH= cH, get STAT hr oma eens A after yaa ym > We > 3 > > 1 > CH wrélt (Carbenes) corde Gen eckagia =yt wAettor & fore cord ay ah setae a gam cits dere wafer era 8 over Coe, 2 wath rer A Gem re By Hrs aE St Hrareter whettar GH ard onda at var a ett & 1. Yo Brats (Singlet Carbene) : wan cords 4 ett faker amor aret sera yo A warn A ond 81 ae ards wlgradia eel BI nn oR — Eas __—_#H- over - SP* SS XS reorafem ordi & ear aap are gcragta ST APT werer A od F srerfer gorag ia wary A argh et ATT ae organ ert 81 ware SP = u—-¢-H agg a gageloH (Nitrene or Imidogen) arggia We sagt =p wonfs 8 Pore arghory ueHIYY ve eh cs Bae wafer ee B Ak agg eit arggrt at wer a eth & 1. FH ASM (Singlet Nitrene): it Gs TR st wel A oT By) 2.fae argght (Triplet Nitrene): Yo cir ter var sern A ya cy wT ca are seaghs ArT meray FH aT By) P » Hore 6 Weer (Arynes) Saat Gee Gols teh etch z fore yo free A aafters eta 8 sit at Paeeer ards TeATMMBIT & SP? ae awaral & ured offeror 8 aera & aree are 81 H 4 i | wit goafear war sarewr @ INEET-2023} aC CHC x (ey fterafir ergs (6) Afifere teres (ota tenes (ay eReee tomes fret a aaa wer Tam & |NEET-2022] @ He om Hie & (6) OP sare aft gratia (0) 09,0,, 09. 03 aera # aera are 2, iste (d)C, 3] B Sta (Degenerate) x safbaa waret H4e ea 21 fer ata A a atten Wee ae INEET-2022] 7 "© ® "OO “O fixtaw afta atatderrt aH gern 4 ie afte water afte vert etn & wil? INEET-2020] (CH, # RHE ART (0) CH, REE S OTT Cosi 3 are (OCHS Ta ore Yeadon A get fren (6) @ ote (x) et A ween Per —_|NEET-2019] G@RrT0Tes (yf BTS (fren ne (a) fren 13-4 2-0 WET 5, (Competition Growth) vet 6. 1 uftemh ware ar wet ma 2 (R= titer |NEET-2018} <-OR<-P (b)-NR,<-OR<-F )>-OR>-F — (@)-NR,>-OR>-F ver 7, Pea 4 8 otra efalderad wat aftr ard) t [NEET-2018] No, No, “OO ‘9 ys vu No, NO, y NO ©y @H he were. gaaglowa @ dar we oe |NEET-2017] (@ BeR HES TH FOTOS wher Bed BR eeaptorger 8 gags me aed a a Per wae Oates w varia ees ¢ wi cafterirge 8 eeaghT mE HRs det a Frat aed 21 © sagtoga vanit a sane ett 2 we wgfterioma & etagit wen med dt a Frat at &1 ORBIoRa we aT wheat ew afters 8 edagia rem wd a oT frafor axa aire wr IUPAC ar [NEET-2017] (b)S-methyl-4-oxohex-2-en-5-al cto-2-methylhex-S-enal ceto-2-methylhex-4-enal —_ Es +____cc mCc ors ceca aa wrar a suited Fe 10. C1 seating or doer aa 8? INEET-2016) (a) SP? (b)SP* (osha (sp er 11, Pres staidberes a aifteigars a eer wera warm wae t InT-JEE-2011) CH,.@-CH,CH, (a) ae (o) ara (ow: oor Ber 12 afteiger ¥ fer warat ar afte eter a [HT-JEE-2008}, @o-0 ()0-P (nx-x @P-P wer 13, Ft A wena wr wT A [IT-JEF-2008) i) B oon OSA DA (vy (a) > Gii)> (iii) (iv) (b) Gi) > Gil) > Gy > (iv) G>@> Gil) @iv)> Gi)> Gi) >) wer 14, fet RA wa aa a ga sp? sp-sp ioe or won watt 2 IrT-2003] (©) CH, = (@ CH, @)m}m/@]@}@/o@]l@]@]@ wm] i2] a3 | os o|m|@]@ BUG f get 15, Pret ofan wget a on Cote Km a cn #80, «@ (By we 10. afte [a BY wear aA sh HOH wen, Irs co INEET-2023] Och I on cH, wer 17. Pret aftfrer Fo oere @ year aifir— INEET-2023} on 8 CogBrs HB, oe eure) Gi) MgSoRe iy H,0ou 3} a O « wet ie. Per 8 etre ma aeiktdota & ec A oar a [NEET-2022) NH, oD cu, Reka rect, on (FG) NaNO, HCL, Cucl wet 19, fet ates ar a TUPAC = B-|NEET-2022] (a) 1-4 Ares eines (by 6-aitrh-2 ae aarti (0) 6-4 Area aeIT eater () 1th saan a —trereo3sitet Ber 20, att det g de2-g or ar flr fre oer 8 [NEET-2021) (of Fran (ey tede Par (Roa fra (a) thera Frat Ber 21, gers: aga gE ore emt HF < HCI < HBr
CH,-Cl>CH,Br>CH,1 (@)CH,-Br>CH,-Cl> Cr wer 23, Pret aififirar Y Foe wea B-|NEET-2021] (C.H.CO).0, CH= CH=CH,+ HBr CBr — CH,—CH, CH—CH,— 0— COC\H, cu, oc aren Br PI taba A ata geo aiPfar A oreo veres vel Sh [NEET-2020] @n-8er (bn aaa (02,31 BA (a ned Pea a chat tats ctotten ot wy ratte Ah 8? INEET-2020] CH,—CH,—CH, CH, —CH,—CH, 55 CH, —CH=ch, Wer 24 Wer 25, CH, —CH.—CH, © @ — _ Eins ___#4-
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