PAWAN WAGH ACADEMY
Practice Paper-1
Topic- Chemical Kinetics
(50 m)
Section A (1 Mark Each)
Q.1 A) Choose the correct option (9m)
1. For an endothermic reaction X ⇌ Y, if Ef is the
activation energy of the forward reaction and Er
that for reverse reaction, which of the following is
correct?
a) Ef = Er b) Ef >Er
c) Ef<Er d) ∆H = Ef – Er is negative
2. The kinetic order of the following reaction is……
Pt
Reaction 2N2O(g) 2N2 + O2
(g) (g)
a) Third
b)First
c) Zero
d)Second
3. The slope of the graph In[A]t versus t for first order
reaction is
a) k b) –k/2.303 c) –k d) k/2.303
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4. Which of the flowing statement is true about a
catalyst?
a) It is formed during reaction mechanism.
b)It is used for altering the velocity of the reaction.
c) It alters the enthalpy change of the reaction.
d)It initiates a reaction.
5. Rate law for the reaction
aA + bB P is rate = k [A] [B]
The rate of reaction doubles if….
a) [A] is kept constant and [B] is halved
b)[A] is doubled and [B] is kept constant
c) Concentration of A and B are both doubled.
d)[B] is doubled and [A] is halved.
Q.1 B) Answer the following
6. Define Activation Energy.
7. Give any one example of zero order reaction.
8. State the units of rate constant of first order
reaction
9. Explain the term overall order of a reaction by
taking one example.
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Section B (2 Marks Each)
(Attempt any 7)
Q.1 A) Answer the following (14m)
1. The reaction A+B products is first order in
each of the reactants.
How does the rate of reaction changes, if the
concentration of A is increased by a factor 3?
2. Distinguish between molecularity and order of
reaction?
3. Calculate the activation energy for a reaction of
which rate constant becomes five times when
temperature changes from 200C to 600C Given R=
8.314J/K mole.
4. Explain pseudo first order reaction with suitable
example.
5. The rate of a first order reaction A→B is 5.8 x 10-5s-1
when [A] is 0.6. Calculate the rate constant of the
reaction.
6. Explain graphically, the effect of temperature on
the rate of reaction.
7. Derive the expression for the half life of zero order
reaction.
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8. Define elementary reaction and give its example.
[𝐴]0
9. Draw the graph of log versus time for a first
[𝐴]
t
order reaction?
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Section C (3 Marks Each)
(Attempt any 5)
Q.1 A) Answer the following (15m)
1. Write the rate law for the following reaction
A+B→P from the following data.
Sr.No [A] [B] Initial Rate
moles dm moles dm moles dm-3
-3 -3
sec-1 (Initial) sec-1 (Initial) sec-1
0.4 0.2 4.0x10-5
1
0.6 0.2 6.0x10-5
2
0.8 0.4 3.2 x10-4
3
2. Give the expression for the integrated rate law of
the first order Reaction and write any two
examples of first order reaction.
3. In a first order reaction, 80% of the reactant
decomposes in 50 minutes. Calculate the half life
period for the reaction.
4. Explain Arrhenius equation and also give the
graphical representation of Activation energy.
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5. A reaction occurs in the following steps.
i) NO2 + F2 → NO2+ F(g) (slow)
(g) (g)
ii) F(g) + NO2 → NO2F(g) (fast)
(g)
a) Write the equation of overall reaction.
b)Write down rate law.
c) Identify the reaction intermediate
6. Ammonia and oxygen react at high temperature as
4NH3 + SO2 → 4NO(g) + 6H2O(g)
(g)
In an experiment, the rate of formation of NO(g) is
3.6x10-3 mol.L-1 sec-1.
Calculate a) Rate of disappearance of NH3
b) Rate of formation of H2O
7. Define the following terms
a) Half life of reaction
b)Reaction intermediate
c) Complex reaction
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Section D (4 Marks Each)
(Attempt any 3)
Q.1 A) Answer the following (12m)
1. In the Arrhenius equation for a first order reaction,
the values of ‘A’ and Ea are 4x1012 sec-1 and
92KJ/mol respectively. At what temperature will its
half life period be 20 min?
[R=8.314 J/K mol]
2.
a) Define Bimolecular reaction with one example.
b)How catalyst increases the rate of the reaction?
Explain with the help of potential energy diagram
for catalysed and uncatalysed reaction.
3. The rate of the reaction
2A + B→2C + D is 6x10-4mol/dm3sec.
When [A]=[B]= 0.3 mol/dm3. If the reaction is of
first order in A and zero order in B, what is the rate
constant?
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4.
a) The decomposition of ammonia on platinum
metal is of zero order reaction? Why
b)The reaction below
C12H22O11 + H2O(l) → C6H12O6 + C6H12O6
aq
Sucrose excess Glucose fructose
Can it be of which order type? Explain with reason.
5.
a) The rate constant for a first order reaction are
0.9 s-1 at 343 K and 0.06 s-1 at 298K. What is the
activation energy of the reaction?
b)Write the expression for the integrated rate of
the zero order Reaction?
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