3c45f2de-2939-4670-bb06-ee8b3ccca0c9-1709810790239-4102576141477649
3c45f2de-2939-4670-bb06-ee8b3ccca0c9-1709810790239-4102576141477649
3c45f2de-2939-4670-bb06-ee8b3ccca0c9-1709810790239-4102576141477649
(a)
(b)
(c)
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(d)
2. Consider a uniform wire of mass M and length L. It is bent into a semicircle. Its moment of inertia about a line
perpendicular to the plane of the wire passing through the centre is :
2
(a)
ML
2
π
2
(b) 1
2
ML
π
2
(c) 1
4
ML
2
π
2
(d) 2
5
ML
2
π
ω
is:
(a) sin (ωt) 3
4. Consider a sample of oxygen behaving like an ideal gas. At 300 K, the ratio of root mean square (rms) to the
average velocity of gas molecule would be :
(Molecular weight of oxygen is 32 g/mol; R = 8.3 J K–1 mol–1)
−
−
(a) √
3
−−
(b) √
3π
8
−
−
(c) √
8
−−
(d) √
8π
5. If the angular velocity of earth’s spin is increased such that the bodies at the equator start floating, the duration of
the day would be approximately:
[Take g = 10 ms–2, the radius of earth, R = 6400 × 103 m, Take π = 3.14]
(a) does not change
(b) 1200 minutes
(c) 84 minutes
(d) 60 minutes
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6. A particle of mass m moves in a circular orbit under the central potential field, U (r) = −
C
, where C is a positive
r
constant.
The correct radius – velocity graph of the particle’s motion is :
(a)
(b)
(c)
(d)
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8. For an adiabatic expansion of an ideal gas, the fractional change in its pressure is equal to (where γ is the ratio of
specific heats) :
(a) − 1
γ
dV
(b) − γ
V
dV
(c) − γ
dV
(d) dV
9. The angular momentum of a planet of mass M moving around the sun in an elliptical orbit is L⃗ . The magnitude of
areal velocity of the planet is:
(a) L
(b) 2L
(c) L
2M
(d) 4L
10. A plane electromagnetic wave propagating along y-direction can have the following pair of electric field (E )⃗ and
magnetic field (B⃗ ) components.
(a) E , B or E , B
y y z z
(b) E , B or E , B
x y y x
(c) E , B or E , B
y x x y
(d) E , B or E , B
x z z x
11. A proton and an α−particle, having kinetic energies K and K respectively, enter into a magnetic field at
P α
right angles.
The ratio of the radii of trajectory of proton to that of α−particle is 2 : 1. the ratio of K : K is :
P
α
(a) 1 : 4
(b) 8 : 1
(c) 1 : 8
(d) 4 : 1
12. The speed of electrons in a scanning electron microscope is 1 × 10 ms . If the protons having the same
7 −1
speed are used instead of electrons, then the resolving power of scanning proton microscope will be changed by a
factor of :
(a) 1
1837
−−− −
(b) √1837
1
(c) √ 1837
(d) 1837
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14. The time taken for the magnetic energy to reach 25% of its maximum value, when a solenoid of resistance R,
inductance L is connected to a battery, is :
(a) L
ln 2
R
(b) L
ln 10
R
(c) L
ln 5
R
(d) infinite
15. Three rays of light, namely red (R), green (G) and blue (B) are incident on the face PQ of a right angled prism
PQR as shown in the figure.
The refractive indices of the material of the prism for red, green and blue wavelength are 1.27, 1.42 and 1.49
respectively. The colour of the ray(s) emerging out of the face PR is :
(a) green
(b) red
(c) blue and green
(d) blue
16. An ideal gas in a cylinder is separated by a piston in such a way that the entropy of one part is S1 and that of the
other part is S2. Given that S1 > S2. If the piston is removed then the total entropy of the system will be :
(a) S + S 1 2
(b) S − S 1 2
(c) S × S 1 2
S1
(d) S2
17. In a series LCR circuit, the inductive reactance (XL) is 10 Ω and the capacitive reactance (X C
) is 4 Ω. The
resistance (R) in the circuit is 6 Ω.
The power factor of the circuit is :
(a) 1
2
1
(b) 2√ 2
(c)
√3
2
1
(d) √2
18. An object of mass m1 collides elastically with another object of mass m2, which is at rest. After the collision the
objects move with equal speeds in opposite direction. The ratio of the masses m2 : m1 is :
(a) 3 : 1
(b) 2 : 1
(c) 1 : 2
(d) 1 : 1
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19. A solid cylinder of mass m is wrapped with an inextensible light string and, is placed on a rough inclined plane as
shown in the figure. The frictional force acting between the cylinder and the inclined plane is, if the coefficient of
static friction is μ = 0.4 :
s
(take the coefficient of kinetic friction and coefficient of static friction are equal)
(a) 0
(b) 5 mg
mg
(c) 5
(d) 7
mg
2
21. The radius of a sphere is measured to be (7.50 ± 0.85)cm. Suppose the percentage error in its volume is x.
The value of x, to the nearest x, is …………… .
22. Consider a 72 cm long wire AB as shown in the figure. The galvanometer jockey is placed at P on AB at a
distance x cm from A. The galvanometer shows zero deflection.
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23. An infinite number of point charges, each carrying 1 μC charge, are placed along the y-axis at y = 1 m, 2 m, 4 m,
8 m …………… .
The total force on a 1 C point charge which is placed at the origin, is x × 103 N.
The value of x, to the nearest integer, is ……………. .
1 9 2 2
[T ake = 9 × 10 N m /C ]
4π∈ 0
24. Two wires of same length and thickness having specific resistances 6 Ω cm and 3 Ω cm respectively are
connected in parallel. The effective resistivity is ρ Ωcm. The value of ρ, to the nearest integer, is ……………. .
25. A ball of mass 4 kg, moving with a velocity of 10 ms–1, collides with a spring of length 8 m and force constant
100 Nm–1. The length of the compressed spring is x(in m). The value of x, to the nearest integer, is …………….. .
26. Consider a water tank as shown in the figure. It’s cross-sectional area is 0.4 m2. The tank has an opening B near
the bottom whose cross-section area is 1 cm2. A load of 24 kg is applied on the water at the top when the height of
the water level is 40 cm above the bottom, the velocity of water coming out the opening B is ν ms . −1
–
The initial velocity of the particle is 5√2 m s and the air resistance is assumed to be negligible. The magnitude
−1
28. A sphere of radius R has a uniform distribution of electric charge in its volume. At a distance x from its centre,
(for x < R), the electric field is directly proportional to xn, where n is:
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29. If the area of each plate is A and the successive separations are d, 2d and 3d, then the equivalent capacitance
ε0 A
across A and B is , where n is:
nd
30. A point object O is placed on the principal axis of a convex lens of focal length 20 cm at a distance of 40 cm to
the left of it. The diameter (aperture) of the lens is 10 cm. If the eye is placed 60 cm to the right of the lens at a
distance h below the principal axis, then the maximum value of h (in cm) to see the image is:
31. In the reaction of hypobromite with amide, the carbonyl carbon is lost as :
(a) CO
(b) H C O −
(c) C O 2−
(d) C O 2
32.
33. The de-Broglie’s wavelength of electron present in first Bohr orbit of ‘H’ atom is:
(a) 0.529 Å
(b) 2π × 0.529 Å
(c) Å
0.529
2π
(d) 4 × 0.529Å
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34.
Consider the above reaction, the product ‘X’ and ‘Y’ respectively are:
(a)
(b)
(c)
(d)
35. Main product formed during a reaction of 1-methoxy naphthalene with hydroiodic acid are :
(a)
(b)
(c)
(d)
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36. The first ionization energy of magnesium is smaller as compared to that of elements X and Y, but higher than that
of Z. The elements X, Y and Z, respectively, are :
(a) chlorine, aluminium and sodium
(b) neon, sodium and chlorine
(c) argon, aluminium and sodium
(d) argon, chlorine and sodium
37. Following four solutions are prepared by mixing different volumes of NaOH and HCl of different concentrations,
pH of which one of them will be equal to 1?
(a) 100 mL
M M
H C l + 100 mL N aOH
10 10
(b) 75 mL
M
5
H C l + 25 mL
M
5
N aOH
(c) 60 mL
M
10
H C l + 40 mL
M
10
N aOH
(d) 55 mL
M
10
H C l + 45 mL
M
10
N aOH
38. At a certain temperature in a 5L vessel, 2 moles of carbon monoxide and 3 moles of chlorine were allowed to
reach equilibrium according to the reaction,
CO + Cl2 ⇌ COCl2
At equilibrium, if one mole of CO is present then equilibrium constant (Kc) for the reaction is:
(a) 2
(b) 2.5
(c) 3
(d) 4
Statement II: KCN and AgCN both will generate nitrile nucleophile with all
reaction conditions.
Choose the most appropriate option
(a) Both statement I and statement II are true.
(b) Statement I is false but statement II is true.
(c) Both statement I and statement II are false.
(d) Statement I is true but statement II is false.
41. For a first order reaction, A → P , t1/2 (half- life) is 10 days. The time required for 1
th
conversion of A (in
4
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(b) sp , sp, sp
3 2
(c) sp , sp , sp
3 2
(d) sp , sp , sp
3 2 2
(A) M n 2+
→ Mn
4+
(B) I → I
2
−
(C) P bS → P bS O 4
Choose the most appropriate answer from the options given below:
(a) (A), (B) only
(b) (A), (C) only
(c) (B) only
(d) (A) only
44. Which of the following best describes the diagram below of a molecular orbital?
45. In KO2, the nature of oxygen species and the oxidation state of oxygen atom are, respectively:
(a) Oxide and -2
(b) Superoxide and − 1
46. The correct order of spin-only magnetic moments among the following is:
(Atomic number: Mn =25, Co =27, Ni =28, Zn =30)
(a) [Z nC l ] > [N iC l ] > [C oC l ] > [M nC l ]
4
2−
4
2−
4
2−
4
2−
47. A hard substance melts at high temperature and is an insulator in both solid and in molten state. This solid is most
likely to be a/an :
(a) Covalent solid
(b) Molecular solid
(c) Ionic solid
(d) Metallic solid
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48. The oxidation states of nitrogen in NO,N O 2, N2 O and N O are in the order of :
−
3
2 2
3
2
49. The secondary valency and the number of hydrogen bonded water molecule(s) in C uS O 4 ⋅ 5H 2 O, respectively,
are :
(a) 6 and 5
(b) 6 and 4
(c) 5 and 1
(d) 4 and 1
50. An organic compound “A” on treatment with benzene sulphonyl chloride gives
compound B. B is soluble in dil. NaOH solution. Compound A is :
(a) C H − N H C H C H
6 5 2 3
(b) C H − N (C H )
6 5 3 2
(c)
(d) C6 H 5 − C H 2 N H C H 3
51. The total number of monohalogenated organic products in the following (including stereoisomers) reaction is
…………… .
(i) H 2 /N i/Δ
A −−−−−−−→
(ii) X 2 /Δ
The equilibrium constant KC for this reaction is ................ × 10–2. (Round off to the Nearest Integer).
[Use : R = 8.3 J mol–1 K–1, ln 10 = 2.3, log10 2 = 0.30, 1 atm = 1 bar]
53. In Tollen’s test for aldehyde, the overall number of electron(s) transferred to the Tollen’s reagent formula
[Ag(N H ) ] per aldehyde group to form silver mirror is ............ .
3 2
+
54. A reaction has a half life of 1 min. the time required for 99.9% completion of the reaction is .................... min.
(Round off to the Nearest Integer).
[Use: ln 2 = 0.69; ln 10 = 2.3]
55. 10.0 mL of N a C O solution is titrated 0.2 M HCl solution. The following titre values were obtained in 5
2 3
readings:
4.8 mL, 4.9 mL, 5.0 mL, 5.0 mL and 5.0 mL.
Based on these readings, and convention of titrimetric estimation the concentration of N a C O solution is 2 3
.................... mM.
(Round off to the Nearest Integer).
56. The number of species below that have two lone pairs of electrons in their central atom is .......
−
S F 4 , BF , C lF 3 , AsF 3 , P C l5 , BrF 5 , XeF 4 , S F 6
4
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57.
Consider the above reaction where 6.1 g of Benzoic acid is used to get 7.8 g of m-bromo benzoic acid. The
percentage yield of the product is .....................
(Round off to the Nearest Integer).
[Given: Atomic masses: C : 12.0 u, H : 1.0 u, O : 16.0 u, Br : 80.0 u]
58. The molar conductivities at infinite dilution of barium chloride, sulphuric acid and hydrochloric acid are 280, 860
and 426 S cm2 mol–1 respectively. The molar conductivity at infinite dilution of barium sulphate is ................... S
cm2 mol–1. (Round off to the Nearest Integer).
59. The solubility of CdSO in water is 8.0 × 10–4 mol L–1. Its solubility in 0.01 M H SO solution is ................... ×
4 2 4
10–6 mol L–1. (Round off to the Nearest Integer).
(Assume that solubility is much less than 0.01 M)
60. A solute A dimerizes in water. The boiling point of a 2 molal solution of A is 100.52ºC. The percentage
association of A is ................... . (Round off to the Nearest Integer).
[Use: Kb for water = 0.52 K kg mol–1 Boiling point of water = 100ºC]
61. ∣−
−→∣ ∣−
−→∣ ∣−
−→∣ −
−→ −
−→
In a triangle ABC, if ∣BC ∣ = 8, ∣C A∣ = 7, ∣AB∣ = 10, then the projection of the vector AB on AC is equal to :
∣ ∣ ∣ ∣ ∣ ∣
(a) 127
20
(b) 85
14
(c) 25
(d) 115
16
2x − y + z = 0
μx + 2y + 3z = 0, λ, μ ∈ R.
63. Let a⃗ and b ⃗ be two non-zero vectors perpendicular to each other and |a|⃗ =
⃗
|b|. If |a⃗ ×
⃗
b| = ⃗
|a |, then the
angle between the vectors (a⃗ + b ⃗ + (a⃗ × b)) ⃗
and a⃗ is equal to :
(a) sin
−1
(
1
√6
)
(b) cos
−1
(
1
)
√3
(c) sin
−1
(
1
)
√3
(d) cos
−1
(
1
)
√2
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1/2
5e
(b) (e2 +1)
2
3/2
−e
(c) 2
2
(e +1)
2
2e
(d) −
2
2
(1 + e )
65. If 15 sin 4
α + 10 cos α = 6,
4
for some α ∈ R, then the value of
27sec α +
6
8cosec α
6
is equal to
(a) 400
(b) 250
(c) 350
(d) 500
66. Let S : x + y = 9 and S : (x − 2) + y = 1. Then the locus of centre of a variable circle S which
1
2 2
2
2 2
√5
(a) (
1
2
, ±
2
)
–
(b) (0, ± √ 3)
(c) (2, ±
3
2
)
(d) (1, ± 2)
x−3
Let g : R → R be given as g (x) = 2x − 3. Then, the sum of all the values of x for which
f
−1
(x) + g
−1
(x) = is equal to.
13
(a) 2
(b) 7
(c) 5
(d) 3
68. Let S be the sum of first 2n terms of an arithmetic progression. Let S be the sum of first 4n terms of the same
1 2
arithmetic progression. If (S − S ) is 1000, then the sum of the first 6n terms of the arithmetic progression is
2 1
equal to :
(a) 3000
(b) 5000
(c) 7000
(d) 1000
(a) 27
(b) –27
(c) –23
(d) 23
–
70. Let a complex number be w = 1 − √3 i. Let another complex number z be such that |zw| = 1 and
. Then the area of the triangle with vertices origin, z and ω is equal to :
π
arg(z) − arg(w) =
2
(a) 4
(b) 1
(c) 2
(d) 1
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f (x) = ⎨b , if x = 0
⎪
⎪ √ x+bx 3−√ x
⎩
⎪
, if x > 0
5/2
b x
(b) – 3
(c) −
3
(d) – 2
(b)
3π
(c) 3π
(d) π
16
73. Let g (x) = ∫ f (t) dt, where f is continuous function in [0, 3] such that
x
⩽ f (t) ⩽
1
1 for all t ∈ [0, 1]
0 3
and 0 ⩽ f (t) ⩽ for all t ∈ (1, 3]. The largest possible interval in which g (3) lies is:
1
(a) [1, 3]
(b) [− , −1] 3
(c) [ , 2] 1
(d) [−1, − ] 1
74. Let in a series of 2n observations, half of them are equal to a and remaining half are equal to −a . Also by adding
a constant b in each of these observations, the mean and standard deviation of new set become 5 and 20,
respectively. The value of a + b is equal to : 2 2
(a) 925
(b) 250
(c) 650
(d) 425
75. The number of seven digit integers with sum of the digits equal to 10 and formed by using the digits 1, 2 and 3
only is :
(a) 35
(b) 82
(c) 77
(d) 42
76. Define a relation R over a class of n × n real matrices A and B as “ARB iff there exists a non-singular matrix P
such that P AP = B .
−1 ′′
77. Let C be the centre of the circle x + y − x + 2y = and P be a point on the circle. A line passes through
2 2 11
the point C, makes an angle of with the line CP and intersects the circle at the points Q and R. Then the area of
π
(a) 2
(b) 2√– 2
(c) 8 sin ( ) π
(d) 8 cos ( ) π
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78. Let the centroid of an equilateral triangle ABC be at the origin. Let one of the sides of the equilateral triangle be
along the straight line x + y = 3. If R and r be the radius of circumcircle and incircle respectively of ΔABC ,
then (R + r) is equal to :
–
(a) 3√2
–
(b) 2√2
9
(c) √2
–
(d) 7√2
79. A hyperbola has transverse axis along the major axis of the conic, + = 4 and has vertices at the foci of this
x
2
y
2
3 4
conic. If the eccentricity of the hyperbola is , then which of the following points does NOT lie on it ?
3
2
– –
(a) (√5, 2√2)
–
(b) (5, 2√3)
(c) (0, 2)
− − –
(d) (√10 , 2√3)
80. A natural number has prime factorization given by n = 2 3 5 , where y and z are such that y + z
x y z
= 5 and
, y > z. Then the number of odd divisors of n , including 1, is:
−1 −1 5
y + z =
6
(a) 6
(b) 6x
(c) 11
(d) 12
81. Let P (x) be a real polynomial of degree 3 which vanishes at x = −3. Let P (x) have Local minima at x = 1
1
local maxima at x = –1 and ∫ P (x) dx = 18, then the sum of all the coefficients of the polynomial P (x) is
−1
equal to ...................... .
83. Let the image of the point P (1, 2, 3) in the line L : = = be Q. let R
x−6 y−1 z−2
(α, β, γ) be a point that
3 2 3
divides internally the line segment PQ in the ratio 1 : 3. Then the value of 22 (α + β + γ) is equal to
84. Let f : R → R satisfy the equation f (x + y) = f (x) . f (y) all x, y ∈ R and f (x) ≠ 0 for any x ∈. If the
function f is differentiable at x = 0 and f (0) = 3, then lim
′
(f (h) − 1) is equal _______.
1
h
h → 0
85. If f (x) and g (x) are two polynomials such that the polynomial P 3
(x) = f (x ) + x g (x )
3
is divisible by
x + x + 1, then P (1) is equal to _______.
2
86. For p, q ∈ R, consider the real valued function f (x) = (x − p) − q, x ∈ R and q > 0. Let a , a , a 2
1 2 3
and a be in an arithmetic progression with mean p and positive common difference. If |f (a )| = 500 for all
4 i
88. 2 −1
Let I be an identity matrix of order 2 × 2 and P = [ ]. Then the value of n ∈ N for which
5 −3
P
n
= 5I − 8P is equal to _______.
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−−− −−−−−
89. Let y = y (x) be the solution of the differential equation xdy − ydx = √(x − y ) dx, 2 2
x ⩾ 1, with
y (1) = 0. If the area bounded by the line x = 1, x = e , y = 0 and y = y (x) is αe β, then the value of
π 2π
+
10 (α + β) is equal to _______.
90. 10
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Answer Key
1. C 2. A 3. C 4. B 5. C 6. C
7. C 8. C 9. C 10. D 11. D 12. D
13. B 14. A 15. B 16. A 17. D 18. A
19. C 20. C 21. 34.00 22. 48.00 23. 12.00 24. 4.00
25. 6.00 26. 3.00 27. 5.00 28. 1.00 29. 4.00 30. 2.50
31. C 32. C 33. B 34. B 35. B 36. D
37. B 38. B 39. C 40. D 41. C 42. D
43. A 44. D 45. B 46. D 47. A 48. A
49. D 50. C 51. 8.00 52. 2.00 53. 2.00 54. 10.00
55. 50.00 56. 2.00 57. 78.00 58. 288.00 59. 64.00 60. 100.00
61. B 62. D 63. B 64. C 65. B 66. C
67. C 68. A 69. C 70. B 71. C 72. B
73. C 74. D 75. C 76. B 77. B 78. C
79. B 80. D 81. 8.00 82. 4.00 83. 125.00 84. 3.00
85. 0.00 86. 50.00 87. 153.00 88. 6.00 89. 4.00 90. 210.00
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Solutions
1. (C)
v0
v = −( ) x + v0
x0
vdv
a =
dx
v0 v0
a = [− ( ) x + v0 ] [− ]
x0 x0
2 2
v0 v
0
a = ( ) x −
x0 x0
2. (A)
L
πr = L ⇒ r =
π
2
2 ML
I = Mr =
2
π
3. (C)
Time period T =
2π
ω
′
π 2π
=
ω ω
′
ω
′
= 2ω → Angular frequency of SHM
Option (c)
Angular frequency of SHM
π
3 cos( − 2ωt) is 2ω
4
4. (B)
−
−−−
3RT
vrms = √
M
−
−−−
8RT
vavg = √
πM
−−
v rms 3π
= √
v avg 8
5. (C)
For objects to float
mg = mω 2R
ω = angular velocity of earth
R = Radius of earth
−
−
g
ω = √ . . . . . (1)
R
Duration of day = T
2π
T = . . . . . (2)
ω
−
−
R
⇒ T = 2π√
g
−−−−−−
3
6400×10
= 2π√
10
T
⇒ = 83.775 minutes ≃ 84 minutes
60
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6. (C)
C
U = −
r
dU C
F = − = −
dr 2
r
2
mv
| F| =
r
2
C mv
=
2 r
r
2 1
v ∝
r
7. (C)
Statement (C) is correct because, the magnetic field outside the toroid is zero and they form closed loops inside the
toroid itself. Statement (E) is correct because we know that super conductors are materials inside which the net
magnetic field is always zero and they are
perfect diamagnetic.
μr = 1 + χ
χ = −1
μr = 0
For superconductor
8. (C)
= constant
γ
PV
Differentiating
γP
dP
= −
dV V
γdV
dP
= −
P V
9. (C)
1
dA = rdℓ
2
1
= rds sin θ
2
dA 1 ds vr sin θ
Areal velocity = = r sin θ =
dt 2 dt 2
dA 1 mvr sin θ L
= =
dt 2 m 2 m
10. (D)
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11. (D)
p q mα
mv α
r = = & = 2; = 4
qB qB q mp
p
rp p q
p α 2
= =
rα q p 1
p α
p 2q
p p 1
= = 2( )
p q 2
α α
p
p
= 1
p
α
2
Kp pp mα
= p
= (1) . (4)
Kα pα mp
12. (D)
Resolving power (RP) ∝ 1
h h
λ = =
P mv
mv
So (RP ) ∝
h
RP ∝ mv
RP ∝ m
(RP ) mp
p
=
(RP ) me
e
(RP )
p
= 1837
(RP )
e
13. (B)
It is possible only inside the nucleus and not otherwise.
14. (A)
1 2
Magnetic energy = Li = 25%
2
1 1 1 i0
2 2
ME ⇒ 25% ⇒ Li = ( Li o ) ⇒ i =
2 4 2 2
−Rt/L
i = i 0 (1 − e ) for charging
L
t = ℓn2
R
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15. (B)
Assuming that the right angled prism is an isosceles prism, so the other angles will be 45° each.
⇒ Each incident ray will make an angle of 45° with the normal at face PR.
⇒ The wavelength corresponding to which the incidence angle is less than the critical angle, will pass through PR.
⇒ θ C = critical angle
−1 1
⇒ θ C = sin ( )
μ
∘
⇒ If θ C ⩾ 45
16. (A)
Stotal = S1 + S2
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17. (D)
−−−−−−−−−−−
2 2
⇒ Z = √6 + (10 − 4)
–
⇒ Z = 6√ 2
6
cos ϕ =
6√ 2
1
cos ϕ =
√2
18. (A)
m1 v1 = −m1 v + m2 v
m2
v1 = −v + v
m1
(v 1 +v) m2
=
v m1
2v
e = = 1
v1
v1
v =
2
v 1 +v 1 /2 m2
=
v 1 /2 m1
m2
3 =
m1
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19. (C)
= μk N
∘
= μk mg cos 60
mg
=
5
20. (C)
Inductance = 2πf L = 2 × 3.14 × 60 × 0.2 = 75.4Ω
21. (34.00)
4 3
∵ v = πr
3
3×0.85
= × 100% = 34%
7.5
22. (48.00)
In Balanced conditions
12 x
=
6 72−x
x = 48 cm
23. (12.00)
1 1 1
F = k(1C )(1μC ) [1 + 2
+ + + …]
2 2
2 4 8
3 1 3
= 9 × 10 [ 1
] = 12 × 10 N
1−
4
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24. (4.00)
∵ In parallel
R1 R2
R net =
R 1 +R 2
ℓ ℓ
ρ ×ρ
ρℓ 1 2
A A
=
ℓ ℓ
2A
ρ +ρ
1 2
A A
ρ
6×3
= = 2
2 6+3
ρ = 4
25. (6.00)
Let's say the compression in the spring by : y.
So, by work energy theorem we have
1 2
1 2
⇒ ky mv =
2 2
−−
−
m
⇒ y = √ ⋅ v
k
−−− −
4
⇒ y = √ × 10
100
⇒ y = 2 m
26. (3.00)
m = 24 kg
A = 0.4 m2
a = 1 cm2
H = 40cm
Using Bernoulli's equation
mg 1
2
⇒ (P 0 + ) + ρgH + ρv
1
A 2
1 2
= P0 + 0 + ρv . . . . . (1)
2
⇒ Neglecting v1
−−−−−−−−−
2mg
⇒ v = √2gH +
Aρ
− −−−−−
⇒ v = √ 8 + 1.2
⇒ v = 3.033 m/s
⇒ v ≃ 3 m/s
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27. (5.00)
∣→∣ ∣→∣
u = v
∣ ∣ ∣ ∣
→
ˆ ˆ
u = u cos 45 i + u sin 45 j
→
ˆ ˆ
v = v cos 45 i − v sin 45 j
∣ →∣
∣ Δ P ∣ = |m(v ⃗ − u)|
⃗
∣ ∣
∘
ΔP = 2mu sin 45
– 1
−3
= 2 × 5 × 10 × 5√ 2 ×
–
√2
−3 −2 −1
= 50 × 10 = 5 × 10 kg m s
28. (1.00)
Field on the surface of the sphere of radius x
K.Q
Ex =
2
x
3 2
x
Ex ∝ x
29. (4.00)
ε A ε A
0 0
( )×( )
C1 C2 d 3d ε0 A
C eq = = =
ε A ε A
C1 +C2 0 0 4d
+
d 3d
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30. (2.50)
In the following ray diagram Δ s, ABC and CDE are symmetric
′
So, AB
BC
=
DE
CD
⇒
5
40
=
h
20
⇒ h = 2.5cm
31. (C)
32. (C)
Order of % yield
33. (B)
The de-Broglie's wavelength of electron present in first Bohr orbit of 'H' atom is 2π × 0.529Å
First Bohr orbit of 'H' atom has radius r = 0.529Å
Also, the angular momentum is quantized.
h
mvr =
2π
h
2πr = =λ
mv
λ = 2π × 0.529 Å
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34. (B)
35. (B)
36. (D)
Order of I.E.
3rd period → Na < Al < Mg < Si < S < P < Cl < Ar
37. (B)
M M
75 mL H C l + 25 mL N aOH
5 5
M M
25 mL N aOH will neutralise 25 mL HCl
5 5
M
75 − 25 = 50 mL H C l will rea m ain
5
+ M 50 M
[H ] = [H C l] = × =
5 100 10
+ M
pH = − log [H ] = −log =1
10 10
10
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38. (B)
Initially, 2 moles of CO are present.
At equilibrium, 1 mole of CO is present.
Hence, 2 - 1 = 1 mole of CO has reacted.
1 mole of CO will react with 1 mole of Cl2 to form 1 mole of COCl2.
3 - 1 = 2 moles of Cl2 remains at equilibrium.
The equilibrium constant
[C OC l2 ]
Kc =
[C O] [C l2 ]
1 mol
5 L
Kc =
1 mol 2 mol
×
5 L 5 L
Kc = 2.5
39. (C)
1) Bohr’s theory is applicable for uni-electronic species only, but Li+ has two electrons.
2) Bohr’s theory could not explain the splitting of spectral lines in the presence of an external magnetic field (Zeeman
effect)
Therefore,
S-1 is false
S-2 is True
40. (D)
⇒ C2H5OH & AgCN both can generate nucleophile
⇒ AgCN & KCN both not generate nitrite nucleophile in all reaction condition
because AgCN is covalent in nature so N is a donor.
41. (C)
The half-life t1/2 = 10 days
The decay constant k = 0.693
t 1
=
0.693
10 days
= 0.0693 day
−1
t = 4.1 days
42. (D)
a → sp3
b → sp2
c → sp2
43. (A)
(1) Oxidising action in basic medium
2Fe2+ + H2O2 → 2Fe3+ + 2OH–
Mn2+ + H2O2 → Mn4+ + 2OH–
(2) Reducing action in basic medium
I2 + H2O2 + 2OH– → 2I– + 2H2O + O2
2MnO4– + 3H2O2 → 2MnO2 + 3O2 + 2H2O +2OH–
44. (D)
An antibonding π orbital best describes the diagram of a molecular orbital. Two p orbitals laterally overlap to form π
bond. Out of phase combination of these two p orbitals give π ABMO.
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45. (B)
In KO2, the nature of oxygen species and the oxidation state of oxygen atom are, superoxide and − 1
2
respectively.
Superoxide ion is O −
46. (D)
The complex having higher number of unpaired electrons will have higher value of spin-only magnetic moment.
The correct order of spin-only magnetic moments is
[M nC l ] 4
2−
> [C oC l ] 4
2−
> [N iC l ] 4
2−
> [Z nC l ] 4
.2−
47. (A)
If substance is insulator in solid & molten both phase, then it can't be ionic or metallic solid. If melting pt. is higher,
then it can't be molecular solid.
Therefore, It should be covalent network solid.
48. (A)
O.S. of 'N'
NO → + 2
NO → + 4
2
N O → + 1
2
NO →+5
−
49. (D)
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50. (C)
51. (8.00)
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52. (2.00)
Using formula
∆Go = –RT lnKp
25200 = –2.3 × 8.3 × 400 log (Kp)
Kp = 10–3.3 = 10–3 × 0.501
= 5.01 × 10–4 Bar–1
= 5.01 × 10–9 Pa–1
KC
=
8.3×400
53. (2.00)
+ −
2[Ag(NH ) ] OH
3 2
−
2e
2Ag+ −→
− 2Ag
54. (10.00)
t99.9% =?
= 10 × t1/2
= 10 min
Derivation
1 100 1
t99.9% = ln{ } = ln(1000)
K 0.1 K
(t1/2 )
3
= ln(10) = 3 × ln(10)
K ln(2)
ln(10)
= 3 × (1 min) ×
ln(2)
3 3
= = ≃ 10 min
log(2) 0.3
55. (50.00)
Na2CO3 + HCI →
10ml, 0.2 M
M =? 5 ml
Meq. of Na2CO3 = Meq. of HCl
M × 10 × 2 = 0.2 × 5 × 1
M = 5 × 10–2M = 50 × 10–3M = 50 mM
Answer is 50
56. (2.00)
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57. (78.00)
122
1
20
mol
Mass of C6H4COOHBr = 201 × 1
gm
20
7.8
%yield = 201
× 100
20
= 77.612% ≃ 78
58. (288.00)
λ (BaCl2) = 280
∞
M
λ (H2SO4) = 860
∞
M
λ (HCl) = 426
∞
M
λ (BaSO4) =?
∞
M
59. (64.00)
+2 2−
CdSO4 (s) ⇌ C d (aq) + S O 4 (aq)
s s
60. (100.00)
2A → A2
n= 1
molality = 2; Tb = 100.52
∆Tb = 0.52
= i × Kb × m
0.52 = i × 0.52 × 2
i = = 1 + ( − 1)α
1
2
1
2
α 1
=
2 2
α=1
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61. (B)
2 2 2
10 +7 −8
cos A =
2.10.7
Projection of AB on AC = 10 cos A
85 85
⇒ 10. =
140 14
62. (D)
∣ 4 λ 2∣
∣ ∣
2 −1 1 = 0
∣ ∣
∣ μ 2 3∣
4 (−5) − λ (6 − μ) + 2 (4 + μ) = 0
−20 − 6λ + μλ + 8 + 2μ = 0
−12 − 6λ + μλ + 2μ = 0
−6 (λ + 2) + μ (λ + 2) = 0
(μ − 6) (λ + 2) = 0
μ = 6, λ ∈ R
63. (B)
→ ∣ →∣
Given ∣∣ a ∣∣ = ∣ b ∣
∣ ∣
∣→ →∣
∣ →∣
and If ∣ a × b ∣ =
∣
a
∣
∣ ∣
→ → → →
let ^
a = i,
^
b = j, and
^
a × b = k . . . (i)
∴ angle between
→ → → → →
( a + b + ( a × b )) and a is given by
→ →
→ → →
( a + b +( a × b ))⋅ a
= cos θ
→ →
∣→ → ∣
∣ a + b +( a × b )∣∣ ⃗
∣a∣
∣
∣ ∣
2
∣ ⃗
∣a∣
∣
= cos θ
→
∣ ∣
⃗
⃗ ⃗ b )∣∣ ⃗
∣a+ b+(a× ∣a∣
∣
∣ ∣
−1 1
∴ θ = cos ( )
√3
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64. (C)
2
x
dy 2
+ (y + 1) x = (y + 1) e 2 . . . (i)
dx
2
x
−2 dy −1
(y + 1) + (y + 1) x = e 2
dx
dy
Put (y + 1)
−1
= z ⇒ − 2
= dz
(y+1)
2 2
x x
dz dz
⇒ − + zx = e 2 ⇒ + (−x) z = −e 2
dx dx
2
x
I.F. = e
∫ −x dx
= e
−
2
2 2 2
x x x
Solution is (e −
2 ) z = ∫ −e 2 × e
−
2 dx
2
x
− −1
⇒ (e 2 ) (y + 1) = −x + c
Put x = 2 and y = 0
−2
e = −2 + c
1
c = 2 +
2
e
2
x
− −1 1
∴ (e 2 ) (y + 1) = −x + 2 +
2
e
Not at x = 1
−1
e 2 1
= 1 +
y+1 2
e
1 3
−
e 2 e 2
(y + 1) = = . . . . (ii)
e 2 +1 1+e
2
( )
e2
2
x
dy
Now,
2
+ (y + 1) x = (y + 1) e 2
dx
3 1
dy e 2 e
∴ + = 2
⋅ e 2
dx 2
1+e (1+e )
2
1 3
dy 3 2 2
e ⋅e e
= 2
−
dx 2
(1+e )
2 (1+e )
7 3
2
e 2 − e 2 (1 + e )
=
2
(1 + e 2 )
3
−e 2
=
2
(1 + e 2 )
65. (B)
4 4
15sin α + 10cos α = 6
2
4 2
⇒ 15sin α + 10(1 − sin α) = 6
4 2
⇒ 25sin α − 20sin α + 4 = 0
2
2
⇒ (5sin α − 2) = 0
2
2 2
3
⇒ sin α = , cos α =
5 5
Now 27cos 6
α + 8sec α = 27 (
6 125
27
) + 8(
125
8
) = 250
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66. (C)
P S1 = 3 − r
P S2 = 1 + r1
P S1 + P S2 = 4
2
2
(x−1) y
Equation of ellipse is 2
+
3
= 1 e =
1
2
2
2
⇒ b = 3
67. (C)
−1 −1 13
f (x) + g (x) =
2
3x − 2 x + 3 13
⇒ + =
x − 1 2 2
⇒ 2 (3x − 2) + (x − 1) (x + 3) = 13 (x − 1)
2
⇒ x − 5x + 6 = 0
⇒ x = 2 or 3
68. (A)
S4n − S2n = 1000
4n 2n
⇒ (2a + (4n − 1) d) − (2a + (2n − 1) d) = 1000
2 2
2
⇒ 2ab + 6n d − nd = 1000
6n
⇒ (2a + (6n − 1) d) = 3000
2
∴ S6n = 3000
69. (C)
16 [2 sin 4θ cos 2θ + cos 4θ]
2 2
16 [4 sin 2θcos 2θ + 2cos 2θ − 1]
Now :
1
sin θ + cos θ =
2
1
1 + sin 2θ =
4
3
sin 2θ = −
4
2 9 7
cos 2θ = 1 − =
16 16
3 7 7
16 [4 (− )( ) + 2( ) − 1]
4 16 16
−7
16 [ − 1] ⇒ −23
16
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70. (B)
Area of Δωoz= 1
2
× 2 ×
1
2
1
=
2
71. (C)
(a+1)
LHL = + 1 = b = f (0)
2
⇒ 2b = a + 3 . . . (i)
√ 1+bx 2−1
RHL = lim
2
+ bx
x→0
2
bx
= lim
+ 2
bx (√ 1+bx 2+1)
x→0
1
=
2
1
∴ b = ⇒ a = −2
2
3
a + b = −
2
72. (B)
2 2
4y = x (x − 4) (2 − x)
is defined for x
∈ [2, 4] ∪ {0}
−−−− −−−− −−−− −−−− −−−−−−−
2
2 |y| = |x| √(x − 4) (2 − x) = |x| √−x + 6x − 8
x ⩾ 0
−−−−−−−−−−
2
2 |y| = x√1 − (x − 3)
4 −−−−−−−−−−
x 2
A = −2 ∫ √1 − (x − 3)
2
2
4
3 4
1 x−3 −−−−−−−− −−−− 1 −1
= [( ((x − 4) (2 − x)) 2
) + 3 (( ) √(x − 4) (2 − x) + sin (x − 3))]
3 2 2
2
2
3π
A =
2
73. (C)
1 3 1 3
1 1
∫ dt + ∫ 0.dt ⩽ g (3) ⩽ ∫ 1.dt + ∫ dt
3 2
0 1 0 1
1
⩽ g (3) ⩽ 2
3
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74. (D)
Given series
(a, a, a. . . . . . . n times) , (−a, −a, −a. . . . . . . n times)
∑ xi
now x̄ = = 0
2n
as x → x + b
i i
then x̄ → x̄ + b
So, x̄ + b = 5 ⇒ b = 5
No. change in S.D. due to change in origin
∑ x
2 −−−−−−−
2 2
i 2na
σ = − (x̄) = √ − 0
2n 2n
− −
2
20 = √ a ⇒ a = 20
2 2
a + b = 425
75. (C)
Case 1: 1, 1, 1, 1, 1, 2, 3
ways = = 42
7!
5!
Case 2:1, 1, 1, 1, 2, 2, 2
ways = = 35
7!
4!.3!
Total ways = 42 + 35 = 77
76. (B)
For reflexive
−1
(A, A) ∈ R ⇒ A = P AP
For symmetry
As (A, B) ∈ R for matrix P
−1 −1 −1 −1
A = P BP ⇒ PA = PP BP ⇒ P AP = I BP P
−1 −1 −1
⇒ P AP = I BI ⇒ P AP = B ⇒ B = P AP
For transitivity
−1 −1 −1 −1
A = P BP and B = P CP ⇒ A = P (P CP ) P
2 −1
−1 2 2 2
⇒ A = (P ) CP ⇒ A = (P ) C (P )
∴ is transitive
R
So R is equivalence
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77. (B)
2 2 11
x + y − x + 2y =
4
2
1 2 2
(x − ) + (y + 1) = (2)
2
For Δ P QR
∘
1
PR = QR sin 2
2
π
= 4 ⋅ 6 sin
8
1
PQ = QR cos 22
2
π
= 4 cos
8
As Δ P QR =
1
2
PR × PQ
1 π π
= (4 sin ) (4 cos )
2 8 8
π 4 –
= 4 sin = = 2√ 2
4 √2
78. (C)
In equilateral triangle distance of any side from centroid is = r
3
r =
√2
R = 2r
9
R + r = 3r =
√2
79. (B)
2 2 2
y 2 y
x x
+ = 4 ⇒ + = 1
3 4 12 16
This is an ellipse whose major axis is along Y-axis and foci (0, ±√−16 − 12) i.e. (0, ±2)
−−−−−
Hence, for hyperbola transverse axis is along Y-axis and vertices (0, ±2)
So, equation of hyperbola is
2 2
x y
− = −1
2
a 4
2
2 9
a = 4( − 1) = 5
4
80. (D)
y + z = 5 ;
1
y
+
1
z
=
5
⇒ (y, z) = (2, 3) or (3, 2)
6
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81. (8.00)
′
P (x) = k (x + 1) (x − 1)
3
kx
P (x) = − kx + C . . . (i)
3
P (−3) = 0 ⇒ −9k + 3k + C = 0
⇒ C = 6k
1
∫ P (x) dx = 18
−1
1
3
kx
∫ − kx + 6k = 18 (put C = 6k in (i))
3
−1
12k = 18
18 3
k = =
12 2
3
x 3
f (x) = − x + 9
2 2
Sum of coefficients = 8
82. (4.00)
2022 1011
1 . (3 −1) −1
9
=
2 2
1011
(10−1) −1
=
2
100λ+ 10110−1−1
=
2
10108
= 50λ +
2
= 50λ + 5054
= 50λ + 50 × 101 + 4
Rem (50) = 4.
83. (125.00)
Since R is mid-point of PM
22 (α + β + γ) = 125
84. (3.00)
If f (x + y) = f (x) . f (y) and f
′
(0) = 3 then
x ′ x
f (x) = a ⇒ f (x) = a ln a
′ 3
⇒ f (0) = ln a = 3 ⇒ a = e
x
3 3x
⇒ f (x) = (e ) = e
f (x)−1 3x
e −1
lim = lim( ) = 1 × 3 = 3
x 3x
x→0 x→0
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3/7/24, 4:49 PM EklavyATS-2024-JMMT FT 17
85. (0.00)
Roots of x 2
+ x + 1 are ω and ω
2
now
P (ω) = f (1) + ωg (1) = 0
2 2
P (ω ) = f (1) + ω g (1) = 0
86. (50.00)
2
f (x) = 0 ⇒ (x − p) − q = 0.
|f (a 4 )| = 500
2
|(a 1 − p) − q| = 500
2
⇒ (a 1 − p) − q = 500
9 2
⇒ d − q = 500 . . . . (1)
4
and |f (a 1 )|
2
= |f (a 2 )|
2
2 2 2 2
((a 1 − p) − q) = ((a 2 − p) − q)
2 2 2 2
⇒ ((a 1 − p) − (a 2 − p) ) ((a 1 − p) − q + (a 2 − p) − q) = 0
2
9 2 d
⇒ d − q + − q = 0
4 4
2 2
10d 5d
2q = ⇒ q =
4 4
4q
2
⇒ d =
5
and 2√q = 2 ×
50
= 50
2
87. (153.00)
Let (2λ − 1, 3λ − 2, 2λ + 1) be any point on the line
2 2 2
(2λ − 5) + (3λ − 4) + (2λ − 6) = 26
λ = 1, 3
∣ → → ∣
Are of triangle P QR = 1/2 ∣P Q × P R∣
∣ ∣
− −−
= √ 153
88. (6.00)
n
P = 5I − 8P
1 0 2 −1
= 5[ ] − 8[ ]
0 1 5 −3
5 0 16 −8
= [ ] − [ ]
0 5 40 −24
−11 8
= [ ]
−40 29
2 −1 2 −1 −1 1
2
P = [ ][ ] = [ ]
5 −3 5 −3 −5 4
−1 1 −1 1 −4 3
4
P = [ ][ ] = [ ]
−5 4 −5 4 −15 11
−4 3 −1 1 −11 8
6
P = [ ][ ] = [ ]
−15 11 −5 4 −40 29
∴ n = 6
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3/7/24, 4:49 PM EklavyATS-2024-JMMT FT 17
89. (4.00)
−−−−−−
2 2
x dy − y dx = √x − y dx
x dy−y dx √ x 2 −y 2
⇒ = dx
2 2
x x
−−−−−−−
y 1 y 2
d( ) = √1 − ( ) dx
x x x
y
d( )
x
1
∫ = ∫ dx
2 x
y
√ 1−( )
x
−1 y
sin ( ) = ln|x| + C
x
y (1) = 0 ⇒ C = 0
−1 y
sin ( ) = ln|x|
x
y
= sin ln(|x|)
x
y = x sin ln|x|
π
e
Area = ∫ y dx
1
π
e
A = ∫ x sin ln x dx
1
t t
x = e ⇒ dx = e dt
π
t t
A = ∫ e sin(t)e dt
2t
A = ∫ e sin t dt
Let’s use ∫ e
ax
sin bx dx =
1
2
e
ax
[a sin bx − b cos bx] + 6
2
a +b
2t
π
e
A = [ [2 sin t − cos t]]
5
0
2π
e +1
A =
5
1 1
⇒ α = , β =
5 5
Required value 10 ( 1
+
1
) = 4
5 5
90. (210.00)
1/2 10
1/3 x +1
((x + 1) − ( ))
1/2
x
10
1/3 1
= (x − )
1/2
x
⇒ T5 =
10
C 4 = 210 .
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