Safety Data Sheet

AMINE O
Revision date : 2016/03/08 Page: 1/11
Version: 3.0 (30485535/SDS_GEN_US/EN)

1. Identification

Product identifier used on the label

AMINE O
Recommended use of the chemical and restriction on use
Recommended use*: additives for fuels and lubricants

* The “Recommended use” identified for this product is provided solely to comply with a Federal requirement and is not part of
the seller's published specification. The terms of this Safety Data Sheet (SDS) do not create or infer any warranty, express or
implied, including by incorporation into or reference in the seller's sales agreement.

Details of the supplier of the safety data sheet

Company:
BASF CORPORATION
100 Park Avenue
Florham Park, NJ 07932, USA

Telephone: +1 973 245-6000

Emergency telephone number

CHEMTREC: 1-800-424-9300
BASF HOTLINE: 1-800-832-HELP (4357)

Other means of identification

Chemical family: Pure product

2. Hazards Identification
According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200

Classification of the product

Acute Tox. 4 (oral) Acute toxicity

Skin Corr./Irrit. 1C Skin corrosion/irritation
STOT RE 2 Specific target organ toxicity — repeated
exposure
Eye Dam./Irrit. 1 Serious eye damage/eye irritation

Label elements

Pictogram:
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Signal Word:
Danger

Hazard Statement:
H302 Harmful if swallowed.
H373 May cause damage to organs (Digestive organs, Thymus gland)
through prolonged or repeated exposure.
H314 Causes severe skin burns and eye damage.

Precautionary Statements (Prevention):

P280 Wear protective gloves/protective clothing/eye protection/face
protection.
P260 Do not breathe dust/gas/mist/vapours.
P270 Do not eat, drink or smoke when using this product.
P264 Wash with plenty of water and soap thoroughly after handling.

Precautionary Statements (Response):

P310 Immediately call a POISON CENTER or doctor/physician.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P303 + P361 + P352 IF ON SKIN (or hair): Remove/Take off immediately all contaminated
clothing. Wash with plenty of soap and water.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for
breathing.
P301 + P330 + P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P301 + P330 IF SWALLOWED: rinse mouth.

Precautionary Statements (Storage):

P405 Store locked up.

Precautionary Statements (Disposal):

P501 Dispose of contents/container to hazardous or special waste collection
point.

Hazards not otherwise classified

If applicable information is provided in this section on other hazards which do not result in
classification but which may contribute to the overall hazards of the substance or mixture.

According to Regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200

Emergency overview

DANGER:
CORROSIVE.
Corrosive to skin and/or eyes.
Harmful if swallowed.
Repeated oral exposure may affect certain organs.
Avoid contact with the skin, eyes and clothing.
Eye wash fountains and safety showers must be easily accessible.
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3. Composition / Information on Ingredients

According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200

CAS Number Weight % Chemical name

95-38-5 90.0 - 100.0% 1H-Imidazole-1-ethanol, 2-(8-heptadecen-1-yl)-4,5-
dihydro-

According to Regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200

CAS Number Weight % Chemical name

95-38-5 90.0 - 100.0% 1H-Imidazole-1-ethanol, 2-(8-heptadecen-1-yl)-4,5-
dihydro-

4. First-Aid Measures

Description of first aid measures

General advice:
Immediately remove contaminated clothing. If the patient is likely to become unconscious, place and
transport in stable sideways position (recovery position). First aid personnel should pay attention to
their own safety.

If inhaled:
If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical
attention.

If on skin:
Remove contaminated clothing. Rinse skin immediately with plenty of water for 15 - 20 minutes.
Seek medical attention. Consult a skin specialist.

If in eyes:
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open,
consult an eye specialist.

If swallowed:
Rinse mouth immediately with water. Never induce vomiting or give anything by mouth if the victim is
unconscious or having convulsions. Do not induce vomiting due to aspiration hazard. Seek medical
attention.

Most important symptoms and effects, both acute and delayed

Symptoms: The most important known symptoms and effects are described in the labelling (see
section 2) and/or in section 11.
Further important symptoms and effects are so far not known.

Indication of any immediate medical attention and special treatment needed

Note to physician
Treatment: Treat according to symptoms (decontamination, vital functions), no
known specific antidote.
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5. Fire-Fighting Measures

Extinguishing media

Suitable extinguishing media:

water spray, dry powder, foam

Unsuitable extinguishing media for safety reasons:

water jet

Special hazards arising from the substance or mixture

Hazards during fire-fighting:
harmful vapours
Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of
fire.

Advice for fire-fighters

Protective equipment for fire-fighting:
Wear a self-contained breathing apparatus.

Further information:
The degree of risk is governed by the burning substance and the fire conditions. Contaminated
extinguishing water must be disposed of in accordance with official regulations.

Impact Sensitivity:
Remarks: Based on the chemical structure there is no shock-sensitivity.

6. Accidental release measures

Personal precautions, protective equipment and emergency procedures

Use personal protective clothing. Keep people away and stay on the upwind side. Breathing
protection required.

Environmental precautions
Contain contaminated water/firefighting water. Do not discharge into drains/surface
waters/groundwater.

Methods and material for containment and cleaning up

For large amounts: Pump off product.
For residues: Pick up with suitable absorbent material. Dispose of absorbed material in accordance
with regulations.

7. Handling and Storage

Precautions for safe handling

No special measures necessary provided product is used correctly.

Protection against fire and explosion:

No special precautions necessary.

Conditions for safe storage, including any incompatibilities

Further information on storage conditions: Keep container tightly closed and dry; store in a cool
place.
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8. Exposure Controls/Personal Protection

not determined

No occupational exposure limits known.

Advice on system design:

Ensure adequate ventilation.

Personal protective equipment

Respiratory protection:
Wear respiratory protection if ventilation is inadequate. Respiratory protection in case of
vapour/aerosol release. Wear a NIOSH-certified (or equivalent) organic vapour/particulate respirator.

Hand protection:
Wear chemical resistant protective gloves.

Eye protection:
Tightly fitting safety goggles (chemical goggles) and face shield.

Body protection:
Body protection must be chosen based on level of activity and exposure.

General safety and hygiene measures:

Handle in accordance with good industrial hygiene and safety practice. No eating, drinking, smoking
or tobacco use at the place of work.

9. Physical and Chemical Properties

Form: liquid
Odour: amine-like
Odour threshold: No applicable information available.
Colour: yellow to brown
pH value: 10.5
( 1 %(m))
(as a dispersion)
Melting point: <= -15 °C
boiling temperature: > 250 °C
Sublimation point: No applicable information available.
Flash point: approx. 174 °C
Flammability: not flammable
Lower explosion limit: For liquids not relevant for
classification and labelling. The lower
explosion point may be 5 - 15 °C
below the flash point.
Upper explosion limit: For liquids not relevant for
classification and labelling.
Autoignition: 330 °C
Vapour pressure: approx. 0.000001 hPa
( 20 °C)
Density: approx. 0.94 g/cm3
( 20 °C)
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Relative density: 0.929 (OECD Guideline
109)
Partitioning coefficient n- >6
octanol/water (log Pow):
Self-ignition not self-igniting
temperature:
Thermal decomposition: > 330 °C
Viscosity, dynamic: 107 mPa.s
( 40 °C)
Viscosity, kinematic: 35.85 mm2/s (OECD 114)
Particle size: The substance / product is marketed
or used in a non solid or granular
form.
Solubility in water: < 0.01 g/l
( 20 °C)
Solubility (qualitative): soluble
solvent(s): organic solvents,
Molar mass: 350.59 g/mol
Evaporation rate: Value can be approximated from
Henry's Law Constant or vapor
pressure.
Other Information: If necessary, information on other physical and chemical
parameters is indicated in this section.

10. Stability and Reactivity

Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.

Corrosion to metals:
No corrosive effect on metal.

Oxidizing properties:
not fire-propagating
Formation of Remarks: Forms no flammable gases in the
flammable gases: presence of water.

Chemical stability
The product is stable if stored and handled as prescribed/indicated.

Possibility of hazardous reactions

No hazardous reactions when stored and handled according to instructions.
The product is chemically stable.

Conditions to avoid
No special precautions other than good housekeeping of chemicals.

Incompatible materials
strong acids, strong bases, strong oxidizing agents

Hazardous decomposition products

Decomposition products:
Hazardous decomposition products: No hazardous decomposition products if stored and handled as
prescribed/indicated.
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Thermal decomposition:
> 330 °C

11. Toxicological information

Primary routes of exposure

Routes of entry for solids and liquids are ingestion and inhalation, but may include eye or skin
contact. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route
of entry for liquefied gases.

Primary routes of entry

Eyes
Skin
Inhalation.
Ingestion.

Acute Toxicity/Effects

Acute toxicity
Assessment of acute toxicity: Virtually nontoxic after a single skin contact. Of moderate toxicity after
single ingestion.

Oral
Type of value: LD50
Species: rat
Value: 1,265 mg/kg (OECD Guideline 401)

Inhalation
Study scientifically not justified.

Dermal
Type of value: LD50
Species: rabbit
Value: > 2,000 mg/kg
The product has not been tested. The statement has been derived from substances/products of a
similar structure or composition.

Assessment other acute effects

Assessment of STOT single:
Based on the available information there is no specific target organ toxicity to be expected after a
single exposure.

Irritation / corrosion
Assessment of irritating effects: Corrosive! Damages skin and eyes.

Skin
Species: rabbit
Result: Corrosive.
Method: OECD Guideline 404

Eye
Species: rabbit
Result: Corrosive.
Method: OECD Guideline 405
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Sensitization
Assessment of sensitization: No sensitizing effect.

other
Species: guinea pig
Result: Non-sensitizing.

Aspiration Hazard
No aspiration hazard expected.

Chronic Toxicity/Effects

Repeated dose toxicity

Assessment of repeated dose toxicity: Harmful: danger of serious damage to health by prolonged
exposure if swallowed. Deaths possible after prolonged exposure.

Genetic toxicity
Assessment of mutagenicity: No mutagenic effect was found in various tests with bacteria and
mammalian cell culture.

Carcinogenicity
Assessment of carcinogenicity: No data available concerning carcinogenic effects. The chemical
structure does not suggest a specific alert for such an effect.

Reproductive toxicity
Assessment of reproduction toxicity: The results of animal studies gave no indication of a fertility
impairing effect.

Teratogenicity
Assessment of teratogenicity: In animal studies the substance did not cause malformations. The
results were determined in a Screening test (OECD 421/422).

Symptoms of Exposure

The most important known symptoms and effects are described in the labelling (see section 2)
and/or in section 11.
Further important symptoms and effects are so far not known.

12. Ecological Information

Toxicity

Aquatic toxicity
Assessment of aquatic toxicity:
Very toxic (acute effect) to aquatic organisms. May cause long-term adverse effects in the aquatic
environment.

Toxicity to fish
LC50 (96 h) 0.3 mg/l, Brachydanio rerio (OECD Guideline 203)

Aquatic invertebrates
EC50 (48 h) 0.136 mg/l, Daphnia magna (OECD Guideline 202, part 1)

Aquatic plants
EC50 (72 h) 0.03 mg/l, Desmodesmus subspicatus (OECD Guideline 201)
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Chronic toxicity to fish

Study not necessary due to exposure considerations.

Chronic toxicity to aquatic invertebrates

Study not necessary due to exposure considerations.

Assessment of terrestrial toxicity

Study not necessary due to exposure considerations.

Microorganisms/Effect on activated sludge

Toxicity to microorganisms
OECD Guideline 209 activated sludge/EC50 (3 h): 26 mg/l

Persistence and degradability

Assessment biodegradation and elimination (H2O)

Not readily biodegradable (by OECD criteria).

Elimination information

(OECD 301B; ISO 9439; 92/69/EEC, C.4-C) Non-biodegradable.

Assessment of stability in water

According to structural properties, hydrolysis is not expected/probable.

Bioaccumulative potential

Assessment bioaccumulation potential

Accumulation in organisms is not to be expected.

Bioaccumulation potential
Accumulation in organisms is not to be expected.

Mobility in soil

Assessment transport between environmental compartments

Adsorption to solid soil phase is expected.

Additional information

Other ecotoxicological advice:

Do not discharge product into the environment without control.

13. Disposal considerations

Waste disposal of substance:
Dispose of in accordance with national, state and local regulations. Do not discharge into
drains/surface waters/groundwater.
It is the waste generator's responsibility to determine if a particular waste is hazardous under RCRA.

Container disposal:
Recommend crushing, puncturing or other means to prevent unauthorized use of used containers.
Dispose of in accordance with national, state and local regulations.

RCRA:
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This product may meet the Criteria for a D002 Waste (Characteristic of corrosivity). Test prior to
disposal.

14. Transport Information

Land transport
USDOT
Hazard class: 8
Packing group: II
ID number: UN 3267
Hazard label: 8, EHSM
Proper shipping name: CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. (contains 2-(2-
HEPTADEC-8-ENYL-2-IMIDAZOLIN-1-YL)ETHANOL)

Sea transport
IMDG
Hazard class: 8
Packing group: II
ID number: UN 3267
Hazard label: 8, EHSM
Marine pollutant: YES
Proper shipping name: CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. (contains 2-(2-
HEPTADEC-8-ENYL-2-IMIDAZOLIN-1-YL)ETHANOL)

Air transport
IATA/ICAO
Hazard class: 8
Packing group: II
ID number: UN 3267
Hazard label: 8
Proper shipping name: CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. (contains 2-(2-
HEPTADEC-8-ENYL-2-IMIDAZOLIN-1-YL)ETHANOL)

15. Regulatory Information

Federal Regulations

Registration status:
Chemical TSCA, US released / listed

EPCRA 311/312 (Hazard categories): Acute; Chronic

NFPA Hazard codes:

Health : 3 Fire: 1 Reactivity: 1 Special:

HMIS III rating

Health: 3¤ Flammability: 1 Physical hazard: 1
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16. Other Information

SDS Prepared by:
BASF NA Product Regulations
SDS Prepared on: 2016/03/08

We support worldwide Responsible Care® initiatives. We value the health and safety of our
employees, customers, suppliers and neighbors, and the protection of the environment. Our
commitment to Responsible Care is integral to conducting our business and operating our facilities in
a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring
the safe and environmentally sound handling of our products, and minimizing the impact of our
operations on society and the environment during production, storage, transport, use and disposal of
our products.

IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED

HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE , IT IS
PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT
PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU MAKE TESTS TO
DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR
TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING
WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE
MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION SET
FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USED
WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE
SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED
A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY
UNDERSTAND AND AGREE THAT THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION
FURNISHED BY OUR COMPANY HEREUNDER ARE GIVEN GRATIS AND WE ASSUME NO
OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMATION
GIVEN OR RESULTS OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK.
END OF DATA SHEET