MSQ

Which one or more of the following statement(s) is/are CORRECT?

A. Any real gas behaves as an ideal gas at sufficiently low pressure or
sufficiently high temperature.
B. For ideal gas, compressibility factor is unity.
C. van der Waals equation of state is explicit in specific volume.
D. Pressure, Temperature, enthalpy all are intensive properties.
MSQ
A piston-cylinder has 0.5 kg air at
2000 kPa, 1000 K as shown in figure below.
The cylinder has stops so that minimum
possible volume is 0.03 m3 . The air now cools
to 400 K by heat transfer to ambient. Which
one or more of the following statement(s)
is/are CORRECT?
A. Final volume of air is 0.03 m3 to 0.03 m3 .
B. Final pressure of air is 1910.3 kPa to
1916.3 kPa.
C. Work done on the air is 82.5 kJ to 84.5 kJ.
D. Heat rejected by the air 196.8 kJ to 200.8 kJ.
NAT
A 10 m high cylinder with a cross-
sectional area of 0.1 m2 , has a thin mass
less piston with air at one side & water
on other side as shown in the figure
below. Air at 300 K, with a volume of
0.3 m3 , under the piston is heated so that
the piston moves up, spilling the water
out over the side. The total heat transfer
to the air, when all the water has been
pushed out is _____ kJ (round off to one
decimal place).
MSQ
A piston - cylinder arrangement as
shown in the figure below, contains air at
250 kPa & 300°C. The 50 kg piston has a
diameter of 0.1 m and initially pushes
against the stops. The atmospheric
pressure is 100 kPa and the temperature
is 20°C. The cylinder air cools as the heat
is transferred to the ambient. Which one
or more of the following statement(s)
is/are CORRECT?

[Continue to Next Slide]

A. The temperature at which piston begin to move down is 371.34 K
to 373.34 K.
B. Piston drops by 52.3 mm to 54.3 mm, when the temperature
reaches ambient.
C. Total work done on the air is 67 J to 69 J.
D. Total heat rejection by the air is 599 J to 601 J.
MSQ
A 100 m3 storage tank with fuel gases is at 20°C, 100 kPa containing
a mixture of acetylene C2 H2 , propane C3 H8 and butane C4 H10 . A test
shows partial pressure of the C2 H2 is 15 kPa and that of C3 H8 is
65 kPa. Which one or more of the following statement(s) is/are
CORRECT?
A. Total mass of the mixture is 180.04 kg to 182.04 kg.
B. Total number of moles of the mixture is 4.005 kmoles to
4.205 kmoles.
C. Molar mass of the mixture is 44.0 kg/kmole to 44.2 kg/kmole.
D. Characteristic gas constant of the mixture is 0.2875 kJΤkg-K to
0.2895 kJΤkg-K.
MSQ
A tank has a volume of 1 m3 with oxygen at 15°C, 300 kPa. Another
tank contains 4 kg oxygen at 60°C, 500 kPa. The two tanks are
connected by a pipe and valve which is opened allowing the whole
system to come to a single equilibrium state with the ambient at
20°C. Which one or more of the following statement(s) is/are
CORRECT?
A. The final pressure of oxygen in the tanks is 359.3 kPa to
361.3 kPa.
B. Change in internal energy for the oxygen in the tanks is 89.9 kJ to
91.9 kJ.
C. Heat supplied to the oxygen in the tanks is 89.9 kJ to 91.9 kJ.
D. Heat rejected by the oxygen in the tanks is 89.9 kJ to 91.9 kJ.
MSQ
Air in a piston-cylinder assembly at 200 kPa & 600 K is
expanded in a constant pressure process to twice the
initial volume. The piston is then locked with a pin and
heat is rejected to a final temperature of 600 K. Which
one or more of the following statement(s) is/are
CORRECT?
A. When the piston is locked temperature is 1200 K to
1200 K.
B. Work transfer is both processes is 170.2 kJ/kg to
174.4 kJ/kg.
C. Heat transfer in both processes is 170.2 kJ/kg to
174.4 kJ/kg.
D. Internal energy first decreases becomes minimum
then increases.
MSQ
A cylinder has a thick piston initially
held by a pin, as shown in the figure
below. The cylinder contains carbon
dioxide at 150 kPa and ambient
temperature. Density of the metal piston
is 8000 kg/m3 and atmospheric
pressure is 101 kPa. The pin is now
removed, allowing the piston to move. If
the carbon dioxide after a while is again
ambient temperature, which one or
more of the following statement(s)
is/are CORRECT? [Continue on Next Slide]
A. Piston will move upward.
B. Piston will move downward.
C. Finally piston will rest against the stoppers.
D. Finally piston will not rest against the stoppers.
MSQ
A rigid vessel having a volume of 3 m3 initially contains an ideal gas
mixture at 21°C, 1 bar consisting of 79% N2 and 21% O2 on molar basis.
Helium is allowed to flow into the vessel until the pressure reaches to
2 bar. The final temperature of the mixture within the vessel is 27°C. Take
MN 2 = 28 kg/kmol, MO 2 = 32 kg/kmol and MHe = 4 kg/kmol. Which one
or more of the following statement(s) is/are TRUE?
A. The number of moles of Helium gas present in the vessel is 117.2 mole
to 118.2 mole.
B. The number of moles of Helium gas present in the vessel is 96.2 mole
to 96.8 mole.
C. Mass of oxygen gas present in the vessel is 0.7954 kg to 0.8456 kg.
D. Mass of oxygen gas present in the vessel is 0.4716 kg to 0.4971 kg.
NAT
A closed system consisting of diatomic perfect gas is at 10 bar and
700 K. Consider the following processes.
I. Gas undergoes an internally reversible isothermal expansion
process to a final pressure of 1.8 bar.
II. Gas undergoes an isentropic expansion process to a final pressure
of 1.8 bar.
The work done during the internally reversible isothermal process is
k% higher than the internally reversible isentropic process for the
same initial condition.
The value of k is __________ (round off to one decimal place).
MSQ
A stationary piston – cylinder arrangement with a set of stops initially
contains 3 kg of air at 200 kPa, 27°C. At this state, the piston is resting on
a pair of stops, as shown below. The mass of the piston is such that a
400 kPa pressure is required to move it. Now, the air undergoes a heat
addition process until its final volume becomes double of its initial
volume. Which one or more of the following statement(s) is/are
CORRECT? Take cv = 0.8 kJ/kg-K.
A. Initial volume of air is 1.25 m3 to 1.35 m3 .
B. Final temperature of air is 1450 K to 1460 K.
C. Work done by the air is 514 kJ to 518 kJ.
D. Heat added to the air is 2672 kJ to 2680 kJ.
NAT
A gas obeying the Clausius equation of state is isothermally compressed
from 5 MPa to 15 MPa in a closed system at 400 K. The Clausius equation
RT
of state is P = where P is the pressure, T is the temperature, v is
v−b T
the molar volume and R is the universal gas constant. The parameter b in
the above equation varies with temperature as b T = b0 + b1 T with
b0 = 4 × 10−5 m3 mol−1 and b1 = 1.35 × 10−7 m3 mol−1 K −1 . The effect of
pressure on the molar enthalpy (h) at a constant temperature is given by
𝜕h 𝜕v
=v−T . Let hi and hf denote the initial and final molar
𝜕P T 𝜕T P
enthalpies, respectively. The change in the molar enthalpy hf −
hi (in J mol−1 , rounded off to the first decimal place) for this process is
_______ [GATE-2016-CH]
MSQ
A spring loaded, vertical piston – cylinder
arrangement (system) having 10 g of
nitrogen. The spring constant is 1 kN/m
and the piston diameter is 10 cm. When the
spring exerts no force against the piston,
the nitrogen is at 120 kPa & 27°C. Now, the
system is heated until its volume is 10
percent greater than the original volume.
Which one or more of the following
statement(s) is / are CORRECT? Assume
nitrogen to be an ideal gas with cp =
1.039 kJ/kg-K & R = 0.2968 kJ/kg-K. [Continue on Next Slide]
A. The change in specific internal energy is 43.9 kJ/kg to 49.9 kJ/kg.
B. The change in specific internal energy is 60.5 kJ/kg to 65.5 kJ/kg.
C. The change in specific enthalpy is 62.5 kJ/kg to 68.5 kJ/kg.
D. The change in specific enthalpy is 51.5 kJ/kg to 55.5 kJ/kg.
MSQ
A piston cylinder arrangement contains 2 kg
of air at 27°C, 200 kPa as shown in the figure
below. Initially linear spring just touches the
piston. Stops are mounted such that, if the
piston is about to hit the stops pressure and
volume of air will be 600 kPa and 3 m3
respectively. If the air is heated to
1500 K, which one or more of the following
statement(s) is/are CORRECT?

[Continue on Next Slide]

A. Final volume of air is 1.944 m3 to 2.144 m3 .
B. Final pressure of air is 420.23 kPa to 422.23 kPa.
C. Work done by the air is 365.46 kJ to 369.146 kJ.
D. Heat supplied to air is 2988.66 kJ to 2992.66 kJ.
MCQ
Two uninsulated, rigid tanks (tank A , tank B) contains air are connected by a
valve which is closed initially. Initially, tank A is having 0.45 kg of air at 800 K
and tank B is having 0.9 kg of air at 500 K. The initial pressure in each tank is
maintained at 345 kPa. The valve is opened and the contents of the two tanks
are allowed to mix. Eventually, the contents of the tanks come to equilibrium at
the temperature of surroundings, 289 K . The heat interaction for the system
and the final pressure of air in both tanks are respectively. Assume the
contents of the tanks are _____________ & ___________ considered as closed system
and air behaves like an ideal gas. Neglect the kinetic & potential energy effects.
A. −199.8 kJ ; 166.175 kPa
B. −301.4 kJ ; 157.525 kPa
C. −199.8 kJ ; 154.255 kPa
D. −301.4 kJ ; 166.175 kPa
NAT
An insulated rigid tank of unknown volume is divided into two parts
by a partition. One side of the tank contains an ideal gas of volume V
at 927°C. The other side of the tank is evacuated and has a volume
2V. Now, the partition is removed & the gas expands to fill the entire
tank. Now the insulation is removed & the heat is added to the gas
until the final pressure of the gas becomes equal to the initial
pressure. The final temperature of the gas is _________°C (round off to
nearest integer).
MSQ
The rate of heat transfer between a certain electric motor and its
surroundings varies with time as Qሶ = −0.2 1 − e−0.05t where t is
in seconds and Qሶ is in kW. The shaft of the motor rotates at a
constant speed of 100 rad/s and applies a constant torque of 18 Nm
to an external load. The motor draws a constant electrical power
input of 2 kW. Which one or more of the following statement(s)
is/are CORRECT ?

Continue to next slide….,

A. The expression for the time rate of change of energy of the motor
dE
is dt = −0.2e0.05 t .
B. The expression for the time rate of change of energy of the motor
dE
is dt = 0.2e−0.05 t .
C. The expression for change in energy of the motor in
0 to t time intervel is, ΔE = 4 (1 − e−0.05t ).
D. At steady state, the value of Qሶ is constant at −0.2 kW.
NAT
A mixture of gases consists of 1 kmol of CO2 , 1 kmol of N2 and
0.3 kmol of O2 . The mixture is compressed in a reversible isothermal
process from 10 kPa, 27°C to a final pressure of 100 kPa. The work
required to compress the mixture will be ____________ MJ (round off to
one decimal place). Assume N2 , CO2 and O2 are ideal gases. Take
MCO 2 = 44 kg/kmol, MN2 = 28 kg/kmol and MO2 = 32 kg/kmol.
NAT
A flexible spherical balloon contains gas at 429.3 kPa, 0.3485 m3 .
The gas inside the balloon is heated until the pressure reaches to
600 kPa. During the heating process, the pressure of gas inside the
balloon is proportional to the diameter squared. The work
interaction during the process will be _________ kJ (round off to one
decimal place).
MSQ
A closed rigid vessel contains 10 kg of oxygen gas at 290 K. The heat
supplied to the gas until its final pressure becomes two times of its
initial pressure. Which one or more of the following statement(s)
is/are CORRECT? Assume oxygen to be a perfect gas.
A. Specific heat at constant volume is 0.6395 kJΤkg - K to
0.6595 kJΤkg-K.
B. Change in internal energy is 1881.55 kJ to 1885.55 kJ.
C. Change in enthalpy is 2634.97 kJ to 2638.97 kJ.
D. Heat interaction is 2634.97 kJ to 2638.97 kJ.
MSQ
0.45 kg of a perfect gas initially at 187°C undergoes reversible
adiabatic expansion process until the final volume of gas becomes
three times of its initial volume. During the process, the decrease in
the temperature is 160°C. The work done during the process is 53 kJ.
Which one or more of the following statement(s) is/are CORRECT?
A. Adiabatic index is 1.369 to 1.409.
B. Characteristic gas constant is 0.312 kJ/kg-K to 0.316 kJ/kg-K.
C. Molar mass of the gas is 28.5 kg/kmol to 29.5 kg/kmol.
D. Specific heat at constant pressure is 0.814 kJ/kg-K to 0.816 kJ/kg-
K.
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