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Advanced Solid State Physics 2nd Edition Phillips Digital
Instant Download
Author(s): Phillips, Philip
ISBN(s): 9780521194907, 0521194903
Edition: 2
File Details: PDF, 27.16 MB
Year: 2012
Language: english
\
PHI Ll P PHIL Ll PS
University of IIlinois at Urbana-Champaign
m晶~CA悶BRIDGE
~,;,臨'iJ UNIVERSITY PRESS
CAMBRIDGE UNIVERSITY PRESS
Cambridge , New York, Me1bourne , Madri d, Cape Town ,
Singapore, São Pau10 , De1hi , Mexico City
Cambridge University Press
The Edinburgh Bui1ding, Cambridge CB2 8RU, UK
Published in the United States of Am erica by Cambridge University Press , New York
www.cambridge.org
Information on this title: www.cambridge.org/9780521194907
@ P. Phillips 2012
First edition pub1ished by Westview Press , a member ofthe Perseus Books Group , 2002
Second edition pub1ished by Cambridge University Press 2012
A catalog record for this publicα tion is α:vailable from the British Libra.門
11479
1 Introduction
1.1 Spontaneously broken symmet可
1.2 Tracking broken symme仕y: order parameter
1.3 Beyond broken symmet可
References
667023
1A-1--7
3 Born-Oppenheimer approximation
3.1 Basic Hamiltonian
3.2 Adiabatic approximation
3.3 Tight七inding approximation
』勻,“句,中
Prob1em
References
4.A 峙-LU
吋缸
4 Second quantization
J 呵,中 ?M
4.1 Bosons
4.2 Fermions
今卻司 3
勻/AVAV
4.3 Fermion operators
Problems
司3
References
司3
1111
5 Hartree-Fock approximation
司3
5.3 Diagrams
司3
Problem
司3
References
334
行/OOAV
V11
VIII Contents
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7 moments in metals
7.1 Local moments: phenomenology
7.2 Impurity density of states
7.3 Green functions
7 .4 Friedel's sum rule and local moments
Summary
Appendix to Chapter 7: Luttinger's theorem
J
勻/勻/
Problems
References
02374
OOOOOOOOAYAYAυAυnυ'111
8 Quenching of local moments: the Kondo problem
8.1 The Kondo Hamiltonian
8.2 Why is J negative?
8.3 Scattering and the resistivity minimum
8 .4 Electron-impuri句T scattering ampli個des
8.5 Kondo temperature
•••
A
唔,
Summary
EA4EEA
Appendix to Chapter 8: the Schrieffer-Wolfftransformation
唔,
Problems
EA
唔,
References
EA
9 5creening and plasmons 115
9.1 Thomas-Fermi screening 115
9.2 凹的ma oscillations and collective coordinates 117
9.3 Linear response theory 122
9 .4 Dielectric response function 127
9.5 Kubo formula: electrical conductivity 137
9.6 Stopping power of a plasma 140
Summary 143
Problems 144
References 145
10 Bosonization 146
10.1 Luttinger liquid 146
10.2 Bosonization ofLuttinger model 151
10.3 Pair binding: can electrons do it alone? 160
10 .4 Excitation spectrum 162
~ ~~~
Summary 167
Problems 167
References 168
lndex 400
In writing the second edition of this text, 1 have tried to accomplish three things. First,
correct all the typos in the first edition. This has turned out to be somewhat harder than 1
had anticipated. While 1 am certain my proofreaders and 1 corrected all mistakes we could
fin d, that might not have been su血cient. As there will undoubtedly be a second printing,
simply email me any errors you might find at [email protected]. Second, include all the
material that should have been in the first edition but that 1 had given up on writing. This
includes Green functions , Luttinger's theorem, renormalization of short-range interactions
for Fermi liquids , and symmetry. In keeping with this being a physics rather than a technique
or mathematics tract, these subjects are interwoven wherever they are first needed. For
examp扭, the section on Green functions is in Chapter 7 where the An derson impurity
problem is treated. For completeness , Luttinger's theorem is also presented in the same
chapter but in an appendix. Third, include new material that re:flects the fast-moving pace
of lï = 1 research in condensed matter physics. Here 1 made a judgement based on what 1
anticipate students would find most useful. Since there are no texts that present the pedagogy
oftopological insulators (though some excellent review articles exist) and Mott insulators ,
1 chose to focus on those topics. In writing the topological insulator section, 1 have tried
to stick to the formulations that require the fewest definitions and new concepts since
the physics of these systems is inherently simple. Regarding the Mott problem, 1 present
what 1 think is non-controversial but not written down anywhere in a single manuscript.
Chapter 16 starts with the band insulator in which the rigid-band picture is valid and then
demonstrates that the physics of the Mott problem stands apart because no such rigid-band
picture applies. While tomes have been written about rigid-band m。由Is , no text deals
with the breakdown ofthe rigid-band picture in strongly correlated electron problems. The
cuprate problem is discussed in this context. 1 had also intended to write a chapter on
quantum computing and extend the discussion in Chapter 14 to include the Bose-Hubbard
mode l. However, including such topics would have pushed the page count well over 600
pages , thereby making the book unwieldy. Further, such topics are not, in my estimation,
particularly suited to a core second-semester graduate class but rather to a more specialized
course. Perhaps 1 will think di在erently in a few years.
1 have benefitted from much input in the final editing of the current manuscript. Babak
Serac可 eh, Juan Jottar, and Taylor Hughes offered invaluable critiques of the topological
insulator section. Wei-Cheng Lee , Mohammad Edalati , and Taylor Hughes also read the
Mott chapter and caught several typos and inaccuracies. 1 also thank Mohammad for reading
and correcting the chapter on symmetries and Robert Leigh for his characteristically level-
headed and incisive remarks on strong coupling physics and symmetry. Wade deGottardi
offered numerous suggestions on the bosonization chapter. While 1 received emails from
XI
XII Preface
several students around the world detailing the typographical errors they have caught, 1
would especially like to thank Wei Han who found two key typos in two figures from the
first edition. Many thanks to Taylor Hughes for redrawing these figures. The duty of proof-
reading fell on my research group and other members ofthe ICMT gtoup at Urbana whose
arms are still recovering from the non-adiabatic distortions 1 applied to them. These include
Wei-Cheng Lee , Mohammad Edalati, Seungmin Hong , Wade deGottardi , Rodrigo Garrido ,
and Ki aran Dave. In addition, at the proof stage , Ki aran Dave , Ka Wai Lo , and Huihuo
Zheng read the entire manuscript and corrected it assiduously, in their relentless drive to
eliminate all typographical errors. 1 would like to thank Matthew Feickert for converting the
LaTeX files to the Cambridge style and for spotting several typographical errors along the
way, and the Cambridge staff, Mike Nugent, Simon Capelin, Claire Poole , Abigail Jones
and Frances Nex for their dedication to this project. Early influences without which this
book might not have been possible include my high school English teacher, Duane Kusler,
who encouraged me to write and my twin sisters Andi and Lyndi from whom 1 learned
many math tricks. My endearing thanks go to my family for their support and calming
presence.
Solid state physics grew out of applications of quantum mechanics to the problem of electron
conduction in solids. This seemingly simple problem defied solution because the presence
of an ion at each lattice site seemed to present an obvious impediment to conduction.
How the electrons avoid the ions was thus the basic question. Although the answer to this
question is well known, it does serve to illuminate the very essence of solid state physics:
there is organization in the many. Each electron adjusts its wavelength to take advantage of
the periodicity of the lattice. In the absence of impurities , conduction is perfect. Hence , by
understanding this simple fact that periodicity implies perfect conduction, it became clear
that the experimentally observed resistivity in a metal came not from electrons running
into each ofthe ions but rather from dirt (disorder) , thermal effects mediated by dynamical
motion of the ions , or electron-electron interactions. This book examines each of these
effects with an eye for identi有Ting underlying organizing principles that simplify the physics
of such interactions.
The search for organizing principles that help simpli身 the physics of many-body systems
is at the heart of modern solid state or, more generally, condensed matter physics. One such
to01 is symme仕y. Consider the simple case ofpermutation symme仕y typically taught in a
first class in quantum mechanics. This symmetry was introduced into quantum mechanics by
W Heisenberg in the context of the indistinguishability of identical particles. The permuta-
tion group has a finite number of elements and hence is associated with a discrete symmetry.
Permutation symmetry allows us to classi冉T fundamental particles into two groups. Bosons
are even with respect to interchange of two particles and fermions odd. This symmetry can
be generalized to include a non-integer phase when two particles are interchange d,的 we
will see in the context of the fractional quantum Hall effect.
To a 1arge extent, the symmetries that are most relevant in condensed matter systems are
typical1y continuous , for example rotationa1 symmetry. Spontaneously breaking a continu-
ous symmetry has a fundamental consequence. For example , the existence of phonons in
a solid or spin waves in a magnet fOllOWS from the spontaneous breaking of a continuous
symmetry. By spontaneous, we mean without the application of an external field. A periodic
arrangement of ions in a crysta1 breaks continuous translational and rotational symmetry.
Such spontaneous breaking of a continuous symmetry by the very existence of the lattice
is necessarily accompanied by a massless spinless bosonic excitation. That such massless
2 Introduction
唔,
/,
乙 =T-V((jJ),
z
EA
,/
•••
.
、、
consisting of a kinetic energy, T , and a potential energy, V ((jJ ), where we are allowing for
(jJ to be a complex function. The claim that such a system is invariant under a symmetry
operation is captured by
where E8 (jJ is the generator ofthe symmetry operation. Here εis an infinitesimal. We have
assumed for the moment that 8(jJ is independent of space. To illustrate what is meant by
this identity, consider a potential of the form V ((jJ) = EO I 利 2. This potential is invariant
under transformations of the form 月h → 4忱的. Let () be a small quantity completely inde-
pendent of space. Then we can expand the exponential and retain only the :first-order term.
Consequently, (jJ•(jJ (1 + i()) and we identi有TE8 (jJ asiθ (jJ; th的 is ,石= () and 8φ = i(jJ.
This symmetry, known as U (1), is present in models that preserve charge conservation.
Expansion of V ((jJ ) to linear order in εimplies that
8V
8(jJ-;:-;- 0, (1.3)
8(jJ
assuming that the symme仕y is intact. N ow assume explicitly that the symmetry is broken
such that V → V((jJ。十 χ) , where (jJo minimizes the potential and χcannot be written as
a generator of a symmetry operation as in Eq. (1 .2). Since the potential has a minimum, it
makes sense to expand
V(你 +χ) = 1
V ((jJ o) + ~ X 2 一一 I
"a 2 v I = V( (jJ o) + 一 χ 2m 2 , (l. 4)
2/
l
a
(jJ 2 I <þ=<þ。
truncating at the restoring term at second order. The second term, which can be used to
de :fine the mass (m) in a standard harmonic expansion, is i址lerently positive semi闖 definite
since we have expanded about the minimum. With this equation in hand, we differentiate
Eq. (1.3) ,
2
a8 (jJ 8V . '" a v
一一一一一 +8 (jJ 一一才 =0 (1 .5)
a(jJ 8(jJ , a(jJ 2
with respect toφThe :first term vanishes when evaluated at the minimum, implying that
a2 VI
(1 .6)
8(jJ a(jJ 2! <þ=<þo
1.1 Spontaneously broken symmetry
must identically vanish for any variation of cþ in the broken symme仕y state. Since 8cþ is
non-zero , Eq. (1 .6) is satisfied only if the second-order-derivative term vanishes or equiv-
alently if m 2 = O. That 站, the mass vanishes. This is Goldstone's theorem (G1961). A
zero mode exists for each generator of a continuously broken symme仕y. As a result ofthis
theorem, symmetry occupies a central place in all areas ofphysics , in particular particle and
condensed matter physics. Typically, the massless bosons th叫 arise in condensed matter
systems represent collective excitations ofthe entire many-body system. 1n fl自由, phonons
are purely longitudinal and arise from spontaneous breaking of Galilean invariance. 1n
solids , phonons are both transverse and longitudinal , though with no simple correspon-
dence with the spontaneous breaking of Galilean,仕anslational, and rotational symme仕y.
1n magnets , spin waves or magnons are the collective gapless excitations that emerge from
the spontaneous breaking of rotational symmet可﹒
We can of course relax the cons仕aint that () be independent of space. 1n so doing ,
we can entertain what happens under local rather than global (() independent of space)
transformations. While our analysis on the potential energy remains the same , the kinetic
energy,
does acquire a new term describing the spatial variation of the phase. 1f the U (1) symme仕y
is not broken by this transformation, then the second term must vanish. Demanding that
aμθ 止。 (1. 8)
if we interpret ψas the wavefunction for the superconducting state; that 站, ψ= b. e iθ .We
will see in the chapter on superconductivity precisely how this state of affairs arises. We will
interpret ψas the order parameter of a superconducting state. While the Bardeen-Cooper-
Sc趾ieffer (BCS) theory of superconductivity was certainly not formulated as an example
of a broken continuous symmetry , this is the basic principle that underlies this theory. 1n
fact , the key ingredients of superconductivity, charge 2e carriers and a supercurrent, all
follow from breaking U (1) symme仕y.
Massless bosons that emerge from broken symmetry typically generate new unexpected
physics. For example , phonons mediate pairing between electrons , thereby driving the onset
of superconductivity in metals such as Hg and more complicated systems , for example
MgB 2 . However, strict rules determine how such N ambu-Goldstone bosons can affect
4 Introduction
any system. As shown by Adler (A1965) , the interactions induced by massless bosons
arising from the breaking of a continuous symme仕y must be proportional to the transferred
momentum. More formally, interactions mediated by the exchange of a N ambu-Goldstone
boson can only obtain through derivative couplings. Consequently, the interaction vanishes
for zero exchanged momentum. This principle impliesthat the electron-phonon interaction
which mediates pairing in elemental superconductors is inherently dynamical in nature. We
will 而且有T this important principle in the context of the elec仕on-phonon coupling through
an explicit derivation. Hence , entirely 企om the existence of a lattice , phonons and the kinds
of interactions they mediate can be easily deduced.
The idea of an order parameter is another powerful concept in condensed matter physics.
Order parameters track broken sy虹rme仕y. That is , they are nonωzero in the broken sy虹立ne仕y
phase and zero otherwise. Consider a ferromagne t. Locally each spin can point along any
direction. This is the case at high temperature in which no symmetry is broken. In a phase
transition controlled by thermal fluctuations , typically it is the high-temperature phase
that has the higher symmetry. To quanti方 the order in a collection of spins , we sum the
z-component of each of the spin operators ,
../' --
Aυ
Il
、,/
M=jz(Sj) ,
、、
scaled by the number of spins , N. Here Sf is the z-compone凶 of the spin of the atom on
site i and the angle brackets indicate a thermal average over the states of the system. M is
the magnetization. At high temperature before any symme仕y is broken, the magnetization
is identically zero. At sufficiently low temperatur郎, the spins order and the magnetization
acquires a non-zero value. Consider iron for which the Curie or ordering temperature is
1340 K. It turns out that most parts of a block of iron below the magnetization tempera仇lre
have vanishing magnetization. This state of affairs obtains because the magnetization is
in general a function of space. As a result, a block of iron does not break the symmetry
uniformly. In fact , the actual magnetization in bulk magnets is not acquired spontaneously
but rather by some external means to align all of the individual magnetic domains. At the
boundary of a domain, the magnetization changes sign, creating a domain wall. Typical
domain sizes in iron are roughly 300 ions. Placing a chunk of Fe in a magnetic field will
orient all of the domains in the same direction, a state of affairs that will persist long after the
field is turned off. This is important since the re-oriented domain state does not constitute
a minimum energy state of the system. The domains lock into place by becoming pinned
to defects. One would expect then that as the magnetizing field is varie d, the magnetization
would not change continuously but by discontinuous jumps as domain walls de-pin from
defects. This is the essence of the Barkhaussen effect, the tiny discontinuous jumps the
magnetization makes in the presence of an external magnetic field and ultimately the reason
why the magnetization curve in a ferromagnet exhibits hysteresis as depicted in Fig. 1.1.
5 1.2 Tracking broken symmetry: order parameter 、
80
40
(2E
。
nu
1)這
-40
一2.5 0 2.5 5
H(kOe)
Hysteresis curve of the magnetization as a function of the applied field for a CoPtCrB thin film. Multilayer Co/Pt is used
in memory storage. Reprinted from Carpenter et al. , Phys. Re v. B72 , 052410 (2005).
That 白, ramping the field on and off is path dependent determined by which domains de-pin
sequentially.
What is crucial in the magnetic system is that locally there.are two degrees of freedom
for each of the spins. At high temperatu時, both states are accessible. At su血ciently low
temperatu間, one of the spin states is selected. Such state selectivity can be modeled with a
double-well potential ofthe form
--
、、‘',',
咀EI
f'a 4EEi
V(M)=-LM2+lyM4 , ••
、、、
2 4
where M is the magnetization and αand y are positive. The minima of this potential occur
at
厄hv
(1. 12)
Both of the minima are accessible at high temperature and no magnetization is possible.
Our choice ofα> 0 ensures that deviations of M away from M土 cost energy. As a result ,
the minimum energy of V is not zero but rather the non-zero value of 的 = -a 2 j4y. As it
stands , our theory is completely symmetrical with respect to the change M • -M. Surely
the physics cannot change if we were to recast our theory by shifting the scalar field M by
a constant such that M • M+ + cþ (x). The new potential
/ 1 3 吋\吋
V' 己的十 1\ 一一α
2 ~ 十一
2 yM~ ) cþ2
r H~+ J I
+ yM+cþ3 + ~ycþ4 (1 .13)
no longer looks symmetrical in terms of the new field cþ. Why? What we have done by
expanding around one of the minima of V is to hide the symmetry. Essentially we have
broken the symmetry by setting the magnetization to M+ . In the broken symmetry phase,
up and down spins are no longer equivalent. The field M functions as the measure of the
magnetic order. M is the order parameter. Unlike the old potential which was minimized by
6 Introduction
V(ψ)
伊1
Potential corresponding to the complex 5日 lar 有 eld <p. The minima correspond to circles satis句ing
<p i + <pi = α jy.
a non-zero value of M , the minima of V' take place at ø(x) = O. This corresponds to a 仕ue
vacuum. In classical models for ferromagnets , the magnetization turns on continuously,
乙 =•: M )川 … ( 叭 +竹叫
y州(圳
Our Lagrangian has the 剖 g 10
吋 ba
叫1 叮 m時et缸ry ♀ψ9 →♀ψ9冗e i8θ , where e is a constant. As a result of
s ym虹
妙
Energy-Ievel diagram for the ground sta妞, Eo , and first excited state,日, as a function of a coupling constant, 9. The
crossing at 9c signals a phase transition between the ground and the 莉的t excited state.
Our statement that the low-temperature phase 句pically has lower symmetry is only 仕的
classically. There are many examples of symme仕y breaking at T = 0 that have nothing
to do with thermal fluctuations. Such phase transitions are governed by fluctuations of the
vacuum, that is the uncertain句T principle. In general , such phase transitions are governed
by a transition among the quantum mechanical states of a many-body system simply by
changing some system parameter. Consider a 耳amiltonian H (g) , where g is a coupling
constant. A typical energy-level diagram for this system as a function of g is depicted
in Fig. 1.3. If, as a function of g , the first圓 excited and the ground states cross , a phase
transition obtains to the first吋xcited state. For the transition to be continuous , we must have
that 3Ej3g = o. These types ofsituation are discussed explicitly in Chapter 14.
1..3
Despite the utility of symmetry in classifying collective phenomena, physics is replete with
examples of transitions between states of matter that share the same symmetry but are ,
nonetheless , distinct. An obvious example is the liquid-gas transition or the formation of
the fractional quantum Hall state. However, the particular examples we focus on here , which
typi命 the physics of s甘ong coupling , are those in which the formation of some kind of
bound state is the distinguishing feature. Consider, for example , the vulcanization or cross-
linking transition in rubber. In the un-vulcanized state , rubber is a viscous liquid in which
long-chain monomers move independently. Cross-linking between neighboring monomers ,
resulting in the formation of a highly entangled enmeshed amorphous state , defines the
vulcanization transition. Although the monomers are localized in the vulcanized state , they
are randomly located. Consequently, there are no Bragg peaks. Nonetheless , one can define
an appropriate order parameter (GCZ 1996) which reflects the fact that at t = 0 and t = ∞,
the configuration of the monomer strands in the liquid changes while it is essentially static
in the amorphous state. The resulting resilience and emergent static modulus of rubber
both arise from the effective gluing together of the monomers. In high-energy physics ,
mesons or bound states of quarks are the propagating degrees of freedom at low energy
in nuclei. They arise without the breaking of any continuous symmetry. In problems more
8 Introduction
relevant for this text , a magnetic impurity in a non-magnetic host forms a bound state
with all the conduction electrons below a characteristic temperature , once again without
breaking any symmetry or even inducing a phase transition. The formation of such bound
states is the essence of the Kondo problem which stands as one of the key triumphs of
the renormalization group principle. As we will show 企om a systematic integration of
the high-energy degrees of 企eedom, a bound state emerges because the coupling constant
between the impurity and the host electrons diverges. Hence , at low temperatures it is not
correct to think of the magnetic and conduction electron degrees of freedom separately.
A new entity emerges at low energies that is not present in the starting ultraviolet (UV)-
complete Lagrangian, a characteristic feature of strong-coupling systems. Although new
degrees of freedom are present at strong coupling which are absent in the weakly coupled or
high-temperature regime , the two states are still adiabatically connected in that by varying
the system parameters , one can go smoothly from one phase to the other. Nonetheless ,
the phases are quite distinct. They possess different degrees of freedo血, and no unified
description exists of such systems in terms of a single entity. Bound-state formation is a
standard paradigm in strong coupling physics and,的 we will see , the Mott problem, an
insulating state in a partially filled band, is no exception.
Another key example is Fermi liquid theory. The primary tenet ofthis theory is that the
excited states of a metal stand in a one-to-one correspondence with those of a non“ interacting
electron gas. The interactions in a metal are of course non-zero. However, they are strongly
screened and can be treated as essentially short-ranged. The Landau (L1957) assertion is
that all such short-ranged repulsive interactions do not destroy the sharpness ofthe electron
excitations in the non-interacting electron gas. That this state of affairs obtains is perhaps
one of the most remarkable principles in nature. Why can the short-range interactions be
ignored in a metal? The answer lies in a fundamental renormalization principle which
we present in Chapter 12. The key to solving any many-body problem is to identify the
propagating degrees of freedom. Identifying that the propagating degrees of freedom are
"single electrons with a dispersion relation given by p2/2m in an interacting electron gas
is highly non-trivial. In fact , it cannot be deduced directly from the Hamiltonian. Some
further fact is needed. That further fact is the existence of a Fermi surface. As we will see ,
the fundamental principle that makes Fermi liquid theory work is that a Fermi surface is
remarkably resilient to short-range repulsive interactions. We will demonstrate explicitly
that all renormalizations (PI992; SM1991; BG1990) arising from such interactions are
towards the Fermi surface. As a result, such interactions can effectively be integrated out,
leaving behind dressed electrons or quasi-particles , thereby justifying the key Landau tenet
(L1957) that the low-energy electronic excitation spec仕um of a metal is identical to that
of a non-interacting Fermi gas. Consequently, breaking Fermi liquid theory in dimensions
greater than or equal to two is notoriously difficult. In one spatial dimension, interactions
are always relevant, as will be seen, and a new state of matter arises , termed a Luttinger
liquid, in which spin and charge move but with different velocities. In higher dimensions ,
the problem is open and stands as the key outstanding problem in solid state physics.
As Fermi liquid theory made the BCS theory of the superconducting state possible in
that it cleanly identified the propagating degrees of freedom , a similar identification of the
propagating degrees of freedom in the normal state of the copper-oxide high-temperature
9 References
Refere臨時S
[A1965] S. L. Ad1er, Phys. Rev. B 137, 1022 (1965); Phys. Rev. 139, B 1638 (1 965).
[BG 1990] G. Benefatlo and G. Gallavot位,J. S,的t. Phys. 59 , 541 (1 990).
[GCZ1996] P. M. Go1dba肘, H. E. Castillo, A. Zippelius, Adv. Phys. 45, 393 (1996).
[G1961] J. Go1dstone , Nuovo Cimento 19 , 154 (1961).
[N1960] Y. Nambu, Phys. Rω~ 117, 648 (1 960).
[L1957] L. D. Landau, Sov. Phys. JETP 3, 920 (1957); 5, 101 (1 957); 870 (1 959).
[P1992] J. Polchins姐, arXiv:hep-th/9210046.
[S孔11991] R. Shankar, Physica A177, 530 (1 991).
At the close of the previous chapter, we noted that one can understand the elementary
properties of metals in terms of non-interacting electrons and phonons. For example , the
low-temperature specifìc heat of a metal is the sum of a term linear in the tempera仙詞 , T ,
from the electrons and a term proportional to T 3 企 om the phonons. This result follows
from a non-interacting particle picture. The electrical conductivity limited by non-magnetic
impurity scattering is also well described by a non-interacting electron gas. In addition,
from a knowledge of single-electron band theor耳 one can discern qualitatively the diι
ferences between metals , insulators , and semiconductors. The remarkable success of the
non-interacting model is paradoxical because electrons and ions are strongly interacting
both with themselves and with one another. Along with its successes , the non-interacting
picture has colossal shortcomings , most notably its inability to describe old problems such
as cohesive energies , superconductivity, magnetism, and newer phenomena such as doped
Mott insulators , the Kondo problem, and the fractional quantum Hall effects. We fìrst review
the physics ofthe non-interacting electron gas. It is only after we develop methodology for
dealing with electron interactions than we can lay plain the reasons why the non-interacting
model works so well.
Electrons in metals are quantum mechanical particles with spin fï/2 obeying Fermi-Dirac
statistics. The Hamil扯tωonian ofa 剖 s ingle elect仕ron 臼
1 Sp2/ρ2mwher臼e 富 i臼st由
he electron momentu
(仰
opμer叫前呦叫
O r) and m 伽
the 耐
e圳
lec
e臼忱
ct
叫訓
t仕r昀
肋
∞
O nmas臼s. Its eigenstates are plane waves ofthe form eip .r / 1ï /.JV
times a spinor which speci在es the electron spin projection on a convenient axis (usually 2),
先σ/2 where σ: 士 1; here V is the system volume. The Hamiltonian (operator) for N such
non-interacting electrons ,
N 合至
H=L 氛, (2 .1)
is simply the sum of the kinetic energies of the individual particles. In this case , the
eigenstates are products ofthe occupied single-particle plane-wave states. Each plane-wave
state can be occupied at most by one electron of a given spin. We label these eigenstates
by the distribution ft肌tion fpa , which is 1 if the single-particle momentum-spin st前e
is occupied and 0 otherwise. In the ground st駒, the lowest N/2 single且particle st前的
are doubly occupied with electrons of opposite spin. Consequently, in the ground state
(temperature T 口 0) , the distribution function is
where e(x) is the Heaviside function , e(x > 0) 1, and 0 otherwise. Here μo is the
zero-temperature electron chemical potential , which in this case is simply the Fermi energy,
10
11 Non-interacting electron gas
Li Na K Rb Cs
the energy of the highest occ叩 ied state , p~/2 肌 where PF is the e1e∞ct
叫仕ronFe叮rm
盯
ml吐i 玟lOmen
前肌叫
tu
um
叫
The Fermi 紀t empe叮ra拍枷仇仙1虹re 丹
1全 eq
伊ua
站ls μ o/kB .
In terms of fpσ , the tota1 number of e1ectrons is given by
N=工九σ (2.3)
p,σ
In the ground state, we can rep1ace the sum by an integra1 and find the e1ectron density at
T =0:
N (T = 0) 2" '"1 [PF dp p~
巴= - ,- -/ = - ') . = 2 I 一一一-71-TT (2 .4)
v v 行于
V"--PF
o (2π fï)j 2 fïj3n
The average interparticle spacing is essentially the radius ,凡, of a sphere containing a sing1e
e1ectron,
4π r~
一一一-=-ne = 1 (2.5)
3
Thus , from Eq. (2 .4), the sca1e for the interparticle separation is
re = 問 1/3tzl 位 (2.6)
which is on the order ofthe 1attice spacing. For re 勾 1 rA , we find that the Fermi ve10city
VF = PF/m ~ !ï/m几何 108 c m/s 勾 c /300 , where c is the speed of 1ight. (Re1ativistic
effects are generally not important for the motion of e1ectrons in the ground state.) It is
conventiona1 to work with the dimensionless ratio rs - 几/旬, where αo =妒 /me2 is
the Bohr radius; this quantity provides a measure of the e1ectron density. The dense limit
corresponds to rs << 1 and the di1ute regime to rs >> 1. In meta1s , rs varies between 2 and 6.
Listed in Tab1e 2.1 are va1ues of rs for the a1ka1i meta1s. Cesium is , in fact , the most di1ute
of all meta1s. It is this 1arge va1ue of rs that is responsib1e for the inhomogeneities in the
density of Cs. In Chapter 5 , we will discuss further physics associated with 1arge 門, such
as the eventua1 formation of a Wigner crystal. We can a1so use Eq. (2 .4) to solve for the
zero-temperature chemica1 potentia1
主之2
ForNa, μo = 3.1 eV; typically in a meta1 , f-L o ranges between 1 and 5 eV.
12 Non-interacting electron gas
The total energy of the system is the sum over the occupied states weighted by the
single-particle energies ,句 = p2/2m:
Eo = .10mπ
~L
p2 V
r= -;Nμ。
') ,_'J
3
(2.9)
2ñ} 5
From the thermodynamic relation, P = 一 (ðE/ðV )r, N , we find the pressure in the ground
state , Po = 2μone/5. This quantity is of order 106 atm and arises entirely from the exclusion
principle between the particles.
At finite temperature , we de曲時 the distribution function which ranges between 0 and 1
and measures the average occupation of the single “ particle states. For a system in equilib-
rium at chemical potentialμ ,
S = kB lnW, (2.11)
consistent with the macroscopic thermodynamic state of the system. For the electron
problem, the microscopic states are indexed by a momentum p with occupancy 0 or 1. The
distribution function !pcJ' however, is a smooth function over all the momentum states. To
construct this function , we group the momentum states into cells , each cell containing gi
momentum states and ni particles. Because each cell contains gi states ,
Lgi'''=L (2.12)
p,σ
For the ith cell , the number of distinct ways of distributing ni particles in gi states is given
by the combinatoric factor wi = gi! /ni! (gi - ni) 1. Applying Stirling's approximation
lnN! ~ N (l nN - 1) (2 .1 3)
to 阱, we obtain
gi-ni
ln Wi 記 -ni ln 立一 (gi - ni) ln 一一一一 (2 .1 4)
gi gi
-gd 生 ln 全+ ( 1 一叫 ln ( 1 一叫| (2 .1 5)
Lgi gi \ g i/ \ g i/ J
where ni/ gi is the fraction of states occupied in cell number i. In fact , ni/ gi = fi is the
smooth distribution function we seek. If we substitute this expression into the equation for
13 Non-interacting electron gas
where we have converted the sum over cells to a sum over spin and momentum states by
using Eq. (2 .1 2). To obtain the distribution function , we maximize the entropy subject to
the constraint that the particle number and energy are :fixed. Extremizing S - E j T + μNjT
with respect to fp σ , 附
we n
1 岳缸
0= ε句pcJ
恥σ 一→
μ一k
站BT
川 ln (協
4l 一 1) , (2 .1 7)
which implies 由前 fpσis the Fermi distribution function in Eq. (2.10)
Let us now calculate the heat capacity from the thermodynamic relationship
/ âS\
Cv =T ( --;::;;;) . (2.18)
\âTJv
To compute the temperature derivative ofthe entropy, we consider the general variation of
the entropy,
with respect to the distribution fi肌tion fpσ ﹒ We can simplify this expression further by
introducing the single-particle density of states per unit volume
N(ε) = 2 {
J
/~ d~,
(2π 的.'>
'l 8 (在一句)
l"
(2.21)
1 r 外 dv
- ",τ I pL-!-8(在一句 )d句 (2.22)
π L.{ï.'> J '- d在 P t'/ l"
mv
N(Ep ) =τ云. (2.23)
aπ "'n-'
The key point here is that the single開particle density of states is a linear function of
momentum. An equivalent way of writing this quantity is N (句) = (dpjd句 )(p2 jπ2 先3).If
we rewrite 8S in terms ofthe density of states ,
Sommerfeld expansion
Consider an integral of the form
1= f 的州ε) (2.25)
14 Non-interacting electron gas
where h(ε) is any smooth function and f (ε) = 1/(e ß (在一μ) + 1). We integrate 1 by p缸ts:
1= f 州州 k (2 .2 6)
where
Because f'(ε) is strong1y peaked at the chemica1 potential , we can expand H in a Tay10r
series around ε=μ,
一
rep1ace the lower 1imit with 一∞. Lettingx =戶 (ε 一 μ) , we have
d …
l-F
fil
LJ JJ 'u
一
(2 .3 0)
Since the integrand is odd in x for j odd, only the even j' s survive. The first severa1 va1ues
of Lj are
Lo = 1, (2 .3 1)
一2
L 2 = 了(如 T)2 , (2 .3 2)
'ï 一 4
L4 = 二~(kBT)4. (2 .3 3)
15
Consequently, we systematically obtain the series expansion for 1:
fμ7 月
1= I
Jo
r h(E)dε+ 主(如 T)2h' (μ)+LEhrfhfff(μ)+
6 ,~/ ,,/ 360
(2.34)
For functions h independent oftemperature , the first term in this expansion is independent
of temperature and hence , at fixed μ,
f “f州 (2.35)
以 -3
局
N T
一-
pAU
qu CLEI CO
(2 .3 6)
scales as a linear function of temperature. This contribution arises entirely from the con-
duction electrons. The contribution per electron is
Cv 'J( 2k~mT 丌 2L T
(2.38)
ne = fi = 2κB 冗
Comparing this result with the classical heat capaci旬, 3kB /2 , we find that the quantum
mechanical value is smaller by a factor of 'J( 2T /3TF . In a metal, only a fraction of the
electrons are at the Fermi level. The ratio T / 丹 defines this fraction of electrons within
kB T of the Fermi energy. The further an electron is below the Fermi level , the smaller is its
contribution to the heat capacity.
We may use the Sommerfeld expansion to show that the chemical potential as a function
of density and temperature is given, at low T , by
/π2 ! T \2 、
μ(慌 , T) = μ (n e , 0) I1
\
一~ 1,
12 \ TF } I
, :" , (2.39)
where μ(慌, 0) =句﹒ The proof of this result is similar to that used to derive the en仕opy,
and we leave the derivation as an exercise (Problem 2.2). From Eq. (2.39) we see that the
first correction to the chemical potential at fixed ne is of order 戶, and hence this correction
can be ignored in calculating the low間temperature entropy, Eq. (2.36).
Pr串bl會酷$
Lj = J一∞ XJ(ex+1)2dx
It useful at the outset to consider the total Hamiltonian to understand how to separate the
electronic from the ionic motion. We denote the position and momentum of the ith ion by
Ri and P i , respectively, and that of the jth electron by rj and Pj . We assume that all the
ions have mass M and nuclear charge Ze. The total Hamiltonian is then
H=L 五 +EJz+
P;
一~L
,'" P] , (Ze)2
j ij|Rif-RIγ|
This Hamiltonian does not include extemal electric or magnetic fields or magnetic inter-
actions among the constituents. The last three terms are the i-i , e-e , and e-i interactions ,
respectively. To progress with this Hamiltonian, we divide the electrons into two groups
the core and the valence or conduction electrons - depending on the degree to which they
are bound. This separation is useful because core electrons move with the nuclei. Conduc-
tion or valence electrons 甘ansport throughout the solid. With this separation in mind, we
obtain
H= 丈丟 +ZLUi(|Ri-RI|)
心 jjfIZdelec|山JPi仲
16
17 3.2 Adiabatic approximation
。 o --E-- B 一----0
---ò--
。 \v 。
。 。 。
lon lattice with spacing a. Each ion oscillates in a harmonic well with a deviation from its home position that is small
relative to the ion spacing. The deviation is roughly ö rv (m /M) 1/4 a rv 1 。一切, where mis the electron mass and M
the mass of the ions. It is for this reasonthat the ions 日 n be treated essentially as 有 xed relative to the electronic
degrees of freedom. That the ions comprise a fixed , almost rigid background for the electron motion is the essence of
the Born-Oppenheimer approximation.
as the partitioned Hamiltonian. In Eq. (3.2) , Vi,i and Vei represent the effective potential
l
between the ions and the valence electrons with the ions , respectively. The energy of the
core electrons is Ecore. In the example of Na, the total Z is 口, with the orbital filling ls2
2S2 2p 6 3s. There is only one unpaired valence electron. The effective charge ofthe ion in
this representation is Z = 1.
To simpli勾T Eq. (3.2) , we separate the nuclear motion from that of the electrons , a sep-
aration that makes sense because the ions are much more massive than the electrons.
Typically m/M rv 1/2000 to 1/500000. The small parameter characterizing the expansion
is (m/M) 1/4. We now show that the ion velocity is related to the Fermi velocity by the ratio
(m/M)3 j 4. As a result, the ions can be treated as essentially static relative to the electrons.
This allows us to solve for the electron motion assuming 且rst that the ions are fixed at their
equilibrium positions. The effects of the ion motion can be treated as a perturbation; that
is , the electrons a吐just adiabatically to the ion motion. From the perspective of the ions , the
rapid motion of the electrons creates an overall average electron potential which they fee l.
This separation is the essence of the Bom-Oppenheimer approximation.
To understand the relative orders of magnitude of the ionic and elec仕on velocities and
energies , we assume , for the sake of the argument, that ions individually move in harmonic
wells (see Fig. 3.1) ofthe form 九sc 口 Mω2 R 2 /2 , where R measures the deviation of an ion
企om its home (or equilibrium) position. Consider displacing an ion by a lattice spacing,
α. The energy required to do so , rvλdω2α2/2 , is essentially that required to distort the
electron wavefunction, and thus the energy is of order fî2 /2ma 2 , which in tum is of the
order of the electron kinetic energ耳片 /2m. Thus Mw 2 a 2 /2 rv p~/2m. Solving for 的 we
find that
However, for an ion in a harmonic well , P2/2M = 缸。 /2 , or equivalently, the square of the
ion velocity is ñw/M. Combining this result with those for ω, we see that
Let us estimate how far the ions move 企om their equilibrium positions. For a displacement
8 , Mω28 2 /2 "-' ñw/2. Substituting ωrv (m/M) 1/2 ñ/ma 2, we find an ion displacement,
which is negligible ,的 illustrated in Fig. 3.1. As far as the electrons are conceme d, the ions
are static. We can calculate the role of the electronic degrees of freedom by developing a
perturbation series in the small quantity 8/αor (m / M) 1/4. N ote also that because P2/2M rv
他)/2 rv 句 (m/M)1/2 <<句, the ion kinetic energy is relatively small.
The formal development of the Bom-Oppenheimer approximation begins with the as-
sumption that the full wavefunction is a function of the many-electron positions r 三 {rj}
and ionic positions R 三 {Ri} , and can be expanded as
where the \IIe, n 付, R) (indexed by n) are the solutions to the electron-ion problem for a
fixed set of ion positions R. The ionic wavefunctions , φn (R) , on the one hand, describe
the amplitude for the ions to be found at positions R; on the other hand they can be re-
garded as expansion coe:fficients of the electronic wave加lctions. The \IIe ,n form a complete
orthonormal set. Consequently,
(\11付, R) I 中 (r , R)) = 1.
We determine each of the expansion coe :fficients from the equations of motion obeyed by
φ n and \11巴 , n' To procee d, we rewrite Eq. (3.2) 的
where there is a one-to-one correspondence between the terms in (3.9) and those in (3.2).
The eigenvalue equation for (3.9) is
We simplify this equation by noting that 1'e +九e + Vei on1y operates on the electron part
of the product wavefunction. Let Ee ,n(R) be the energy of the e1ectron system for a fixed
set of nuclear coordinates. As a consequence , the nuclear and the e1ectronic eigenvalue
equatlOns ,
and
can be separated.
Let us mu1tiply the nuclear eigenvalue equation by \Þ斗= (emlr , R) and integrate:
(3.14)
Because the matrix element (en Ij:-'ù (R) Iem) involves purely algebraic operators , it has only
diagonal elements. The kinetic energy term, however, has off-diagona1 elements; explicitly,
別的|品問
+叫叫
2川(v
可叭Rii
Because 苑
V孟 acωt 臼S 閃1us肘
u站
si
S位i的
如
ve
吻O∞nφ俄恥叫
nλ1(R
酌很酌
) in
叫 伽
t1he
旭e fir削 term 血
in
削t伽
蚓
he
1昀el帥g叫,
叭 帥
the
昀e 附u址枷
l
element 臼
i s pur
昀 el妙
y diagonal. For the moment , we ignore the last two terms in the kinetic
energy matrix e1ement and obtain
or, equivalently,
的 the eigenvalue equation for the nuclear degrees of freedom. Equations (3.13) and (3.17)
are the principa1 results in the Bom-Oppenheimer method. In the nuclear eigenvalue
equation, E,巴, 11 (R) serves as the effective nuclear potentia1 that results when the electronic
degrees of freedom are integrated out. The solutions to (3.17) will describe the phonon
modes of the ions.
20 Born-Oppenheimer approximation
To justify this 仕eatment ofthe ion kinetic energy term, we analyze the relative magnitude
of the three contributions in Eq. (3.15). We first need a reasonably accurate form for
the nuclear wavefunctions. For our purposes , the harmonic approximation we made in
conjunction with the derivation of the ion velocity is adequate. In this case ,
φ n '"'-J e…Mω(R_RO )2/ 2h , (3 .l 8)
where R O is the equilibrium position ofthe ion. Consequently,
民2 '1 ñ2 (Mω\ 2 / m \ 1/2
一u
2且![ R;
V K; <Þ "n ,n '"'-J一:-::1 一;::--8 I <Þ nWe.n
. Wev ," 2M \ ñ . J - " - v , H
'"'-J 1-:-:: 1
\M J 句 φ nWe.n. (3 .l 9)
Consider now the second term in Eq. (3.15). The inverse length scale on which the electron
wavefunctions change is VR '"'-J 1/α. As a consequence ,
先2 民2Mω8 / m \ 3/4
一;-; V R ; <Þ n ,n '"'-J一一一一-\丸, n 趴'"'-J I 一)
2且![ n , " . V R,; We ,"
u v 2M ñ a , " " \M J 在F <Þ n We ,n
v
(3.20)
and
民2 吋民21m
一一
2M φV主
- fl . K; W戶..一一一恥
- ", fl
"φ.. '"'-J M
2M α2 - 'V, rt - fl
-Evφ fl", Wρm
- 'v月 -l_" -
(3.21)
As is evident, the largest contribution to the nuclear kinetic ener喀gy matrix element arises
f企kOm ViiI? 丸 趴趴n. The prima
φ 叮ry reason why 吐thi
由臼S叫 m
叭i臼st由
hat
叫前tg叫i白er刮
a lts of φ n 侃
exceed 由
those of ψ削
by a f:臼ac叫to叮r of (σJ且M/mη1)1/4. Consequently, dropping the last two terms in Eq. (3 .l 5) incurs a
negligible error on the order of (m/M) 1/4.
To lowest order in m/M , we then neglect the ion kinetic energy and assume R = R O•
The ground electronic wavefunction is We, n=O 付, R 0 ); its corresponding energy, E巴, n=o(RO ) ,
obeys the Schrödinger equation
O
[丸+九巴十九i(r - R )] 中e, n=O (r , R O
= Ee , n=O (R ) 中e, n=O 付, R
O O
) ). (3.22)
The subsequent ground間state nuclear wavefunctions and energies can be found with the
effective potential E巴 , 11口。 (RO ). If deviations about the equilibrium ion positions are consid-
ered within a simple harmonic oscillator model , the total energy of each low-energy state
is given by
γ-2
+t inunHJHMnHnH3
EHH
、〈
、〈
nu3
、d
、d
V目,
J
J
21
Here Vï on (r) is the potential felt by the electrons produced by the ions in their equilibrium
positions. To a good approximation, this potential is periodic. Let us group all the one-body
terms together as he(r) 口五十Vïon (r). The reduced electronic Hamiltonian is then
H巳= he -lγ Vee ﹒ (3.26)
It is this Hamiltonian that we will primarily discuss in the remainder of this book.
A closer look at the one-body part of our Hamiltonian is warranted. In the previous
chapter, we 仕eated the electrons in a metal as if they were free particles not tethered to
any ions. Of course this is wrong. Electrons know about the ions and interact strongly with
them. Why then is it possible to regard the electrons as being free? It turns out that had
we started with the localized picture advanced by Wannier, we would still end up with the
same answer. The solution to the one-body part of the Hamiltonian is described by a set of
periodic Bloch waves ,
的叭的= e ik 叮nk (r) , (3.27)
for the nth band with momentum k. Here Cnk (r) is a function that has the periodicity ofthe
lattice. Since the Bloch functions are complete , we can form a state localized on a particular
lattice site R ,
峙, r)=hze叫nk(r) (3.28)
www
的
mm1-Nl-No句
對dR
白 wy
由
BH
w川
叫衍三
叫川
位m
咕"的
mR 'm mzJ
J-3
nitR e huky
r hd k x u
a'!k
叫到
(+ s
閃出
fk
eWAKm
R R
UM
PAC a i
MAnRK
9urAf--
a'
e
C U ohH
e
4
T且
可且口、 ujλ
: L
口b
4
UUiW 4
1 .I ri
•••
f
qu
rr
••• •••
r ffd
ZMZMn的
fij-e
…
r- *mk
d
一一一一一…
r r
r
/s 、、
,切
、,
••
12
、
2
仰
司3
/'
、tf
QVJ
E,
'
Z
、、、
as can be seen from a direct calculation. The statement that Wannier states form an or闖
thonormal basis is somewhat problematic. If we were to rewrite he in terms of the Wannier
states ,
by using the completeness relationship on the state vectors associated with the Wannier
states , IR) , we would have to conclude that there are no off-diagonal matrix elements of
our Hamiltonian. That is , if the Wannier states on two neighboring sites do not have any
overlap , any matrix element with the Hamiltonian should be zero. The statement that the
Wannier basis forms an orthornomal basis in practice means that beyond nearest neighbors ,
22 Born … Oppenheimer approximation
(RlheIR) =. Eo (3.31)
(RlheIR+ 8) 告 -t (3.32)
where 0 is a unit vector from site R to the nearest neighbors. Our Hamiltonian simplifies to
H
TB
= -t L IR)(R+ 81 +Eo L IR)(RI (3.33)
RδR
Regardless of the form of the underlying lattice , the tight-binding model can be solved
exactly by Fourier transforming,
IR) = ~L 戶 Rlk). (3 划
v ~. k
The energy band, E (k) , de宜nes the energy of a non-扛lteracting particle with momentum k
and hence is the TB analog of the free-particle dispersion. The TB model can be viewed as
the lattice analog of the free-parti cI e problem.
3.1 This problem concems the band s仕uc加re of a single sheet of carbon, graphene (see
Fig. 3.2). Nearest-neighbor atoms are connected by the set ofvectors
kx
Graphene lattice. The panel on the left shows the primitive lattice vecto時, ai, and nearest-neighbor lattice vectors ð i . ,
The labels Aand Brefer to the two kinds of carbon atoms in graphene. The panel on the rig 忱的 ows the first Brillouin
zone spanned by the lattice vectors bi .
You are to (a) write down the tight-binding Hamiltonian for this system and s01ve
it for the energy bands , (b) determine the va1ues (there are two) of k for which the
energy dispersion vanishes , (c) show that the dispersion can be written as
E(q) = 土 hVFlq l, (3 .4 1)
where VF = 3t /2 17,α~ 106 m/s and q is the deviation 仕om the va1ue of the momentum
at the zero crossing , and (d) show that the effective Hami1tonian near the zero crossings
can be written as
+o
。-
/it--\
oix oiy \ka--/ LA
“
﹒唔,
H --- LAU --
A
σ
們U
EI EI
1
OA
X
-4EA
OA
vd
3 TA 4gLLU
CIA vh OA mHmh
,1品
hM=-
戶LV
.們
+oOAY
、
O
/iz--\
\KEEF/
﹒唔,A
OA
x + oiy
恥九
一一
σ
、‘,/
/'‘\
們U
EA OA
U
., OA EI X x VJ
oix -A Y
一
臨睡f智體臨時$
4.1 8050臨$
holds. As in the case of the harmonic oscillator, we define the operator ao such that
That is , the operatorαo annihilates a single particle from the 泣的|的 and produces the
corresponding n 一 1 particle state. The a再joint operation in Eq. (4.2) suggests that
The choice of the factor of .Jïi will now become 由ar when we consider the ope則or
丸 =αμ。丸 is aH位血
(a~)n
In) = 一社汁。) . (4.8)
、/n!
執f扭
e see then that the construction of an n-particle state of bosons 臼
is directly ana
站logous to
伽叫臼叫臼
for creatir叭a
缸n口
mo
{旬 , abJ = 1 (4.9)
Analogous relationships hold for the creation operators. The generalized commutation
relations are
A final note on the application ofproducts ofboson operators to the state Ino , . . . , nj , . . .)
is“吋
s缸
innord位 B
i 加ωa
∞ 削吋
u
弘沾臼s鵬
u 閻
可切
吋b
e 加
枷Oωso
岫咖 肌
ns
1臼sc
∞ omml師1Í臼
e, 咖
op
阱
pera
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Let us assume now that the particles occupying the state Ino) are fermions. We are restricted
by the Pau1i exclusion princip1e that no = 0 , 1. Ana1ogous1y,
aol1) = 10) ,
必 10) = 11) (4.13)
。 r equivalently
{a1 , aj}=a1的 + a ja1 = 0 for j 利. (4 .1 9)
can be derived in an analogous fashion. The final quantity we should define is the number
operator,
方= La}aj (4.22)
j
We now tum to the task of writing one- and two-body fermion operators in their second
quantized form. A straightforward way of accomplishing this is to consider their action on
a fully antisymmetrized many-particle state. Consider 何10 single-particle states <!>I and <fJ2.
The normalized wavefunction that is antisymmetric with respect to particle interchange is
Dirac (D1929; D1958) and Slater (S1929) showed that the general rule for constructing an
antisymmetric wavefunction out of n single-particle states is
Dn戶=叫寸(仕
川
r
-v 叫
n !ι7
Complete antisymmetry under particle interchange is built into this many-body state as
a result of the anticommuting property of the fermion oper泣的﹒ Note there is no -JnT
normalization factor. In first quantization, however, an explicit -JnT factor appears , because
particles are placed in particular single-particle states and all possible permutations are
summed over. In second quantization, no labels are attached to the particles.
Let us now return to our initial goal. Consider the one-body operator H 1 . The matrix
element of a one-body operator between two many-particle states is non-zero only if the two
Exploring the Variety of Random
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“What—has—prevented—him?” I roared.
“Look out—your van will be in the ditch.”
And turning quickly I was just in time to pull the tiresome brute of a
horse, who never could be left to himself an instant, straight again.
I walked on shrugging my shoulders. Menzies-Legh was without any
doubt as ill-conditioned a specimen of manhood as I have ever come across.
At the four crossroads beyond Brede, on the party’s pausing as usual to
argue over the signpost while Fate, with Frogs’ Hole Farm up her sleeve,
laughed in the background, I laid my hand on Jellaby’s arm—its thinness
quite made me jump—and said, “Where is Lord Sigismund?”
“Gone home, I believe, with his father.”
“Why is he not coming back?”
“He’s prevented.”
“But by what? Is he ill?”
“Oh, no. He’s just—just prevented, you know.”
And Jellaby slipped his arm out of my grasp and went to stare with the
others up at the signpost.
On the road we finally decided to take, while they were all clustering
round the labourer I have mentioned who directed us to the deserted farm, I
approached Frau von Eckthum who stood on the outer fringe of the cluster,
and said in the gentler voice I instinctively used when speaking to her, “I
hear Lord Sigismund is not coming back.”
Gently as my voice was, it yet made her start; she generally did start
when spoken to, being unusually (it adds to her attractiveness) highly strung.
(“She doesn’t when I speak to her,” said Edelgard, on my commenting to
her on this characteristic.
“My dear, you are merely another woman,” I replied—somewhat sharply,
for Edelgard is really often unendurably obtuse.)
“I hear Lord Sigismund is not coming back,” I said, then, very gently, to
the tender lady.
“Oh?” said she.
For the first time I could have wished a wider range of speech.
“He has been prevented, I hear.”
“Oh?”
“Do you know what has prevented him?”
She looked at me and then at the others absorbed by the labourer with a
funny little look (altogether feminine) of helplessness, though it could not of
course have been that; then, adding another letter but not unfortunately
another word to her vocabulary, she said “No”—or rather “N-n-n-o,” for she
hesitated.
And up bustled Jellaby as I was about to press my inquiries, and taking
me by the elbow (the familiarity of this sort of person!) led me aside to
overwhelm me with voluble directions as to the turnings to Frogs’ Hole
Farm.
Well, it was undoubtedly a blow to find by far the most interesting and
amiable member of the party (with the exception of Frau von Eckthum)
gone, and gone without a word, without an explanation, a farewell, or a
regret. It was Lord Sigismund’s presence, the presence of one so
unquestionably of my own social standing, of one whose relations could all
bear any amount of scrutiny and were not like Edelgard’s Aunt Bockhügel
(of whom perhaps more presently) a dark and doubtful spot round which
conversation had to make careful détours—it was undoubtedly,
Gentle as my voice was, it yet made her start
I say, Lord Sigismund who had given the expedition its decent air of
being just an aristocratic whim, stamped it, marked it, raised it altogether
above mere appearances. He was a Christian gentleman; more, he was the
only one of the party who could cook. Were we, then, to be thrown for future
sustenance entirely on Jellaby’s porridge?
That afternoon, dining in the mud of the deserted farmyard, we had
sausages; a dinner that had only been served once before, and which was a
sign in itself that the kitchen resources were strained. I have already
described how Jellaby cooked sausages, goading them round and round the
pan, prodding them, pursuing them, giving them no rest in which to turn
brown quietly—as foolish a way with a sausage as ever I have seen. For the
second time during the tour we ate them pink, filling up as best we might
with potatoes, a practice we had got quite used to, though to you, my
hearers, who only know potatoes as an adjunct, it will seem a pitiable state
of things. So it was; but when one is hungry to the point of starvation a hot
potato is an attractive object, and two hot potatoes are exactly doubly so.
Anyhow my respect for them has increased tenfold since my holiday, and I
insist now on their being eaten in much larger quantities than they used to be
in our kitchen, for do I not know how thoroughly they fill? And servants
quarrel if they have too much meat.
“That is poor food for a man like you, Baron,” said Menzies-Legh,
suddenly addressing me from the other end of the table.
He had been watching me industriously scraping—picture, my friends,
Baron von Ottringel thus reduced—scraping, I say, the last remnants of the
potatoes out of the saucepan after the ladies had gone, accompanied by
Jellaby, to begin washing up.
It was so long since he had spoken to me of his own accord that I paused
in my scraping to stare at him. Then, with my natural readiness at that sort of
thing, I drew his attention to his bad manners earlier in the afternoon by
baldly answering “Eh?”
“I wonder you stand it,” he said, taking no notice of the little lesson.
“Pray will you tell me how it is to be helped?” I inquired. “Roast goose
does not, I have observed, grow on the hedges in your country.” (This, I felt,
was an excellent retort.)
“But it flourishes in London and other big towns,” said he—a foolish
thing to say to a man sitting in the back yard of Frogs’ Hole Farm. “Have a
cigarette,” he added; and he pushed his case toward me.
I lit one, slightly surprised at the change for the better in his behaviour,
and he got up and came and sat on the vacant camp-stool beside me.
“Hunger,” said I, continuing the conversation, “is the best sauce, and as I
am constantly hungry it follows that I cannot complain of not having enough
sauce. In fact, I am beginning to feel that gipsying is a very health-giving
pursuit.”
“Damp—damp,” said Menzies-Legh, shaking his head and screwing up
his mouth in a disapproval that astonished me.
“What?” I said. “It may be a little damp if the weather is damp, but one
must get used to hardships.”
“Only to find,” said he, “that one’s constitution has been undermined.”
“What?” said I, unable to understand this change of attitude.
“Undermined for life,” said he, impressively.
“My dear sir, I have heard you myself, under the most adverse
circumstances, repeatedly remark that it was healthy and jolly.”
“My dear Baron,” said he, “I am not like you. Neither Jellaby, nor I, nor
Browne either, for that matter, has your physique. We are physically,
compared to you—to be quite frank—mere weeds.”
“Oh, come now, my dear sir, I cannot permit you—you undervalue—of
slighter build, perhaps, but hardly——”
“It is true. Weeds. Mere weeds. And my point is that we, accordingly, are
not nearly so likely as you are to suffer in the long run from the privations
and exposure of a bad-weather holiday like this.”
“Well now, you must pardon me if I entirely fail to see——”
“Why, my dear Baron, it’s as plain as daylight. Our constitutions will not
be undermined for the shatteringly good reason that we have none to
undermine.”
My hearers will agree that, logically, the position was incontrovertible,
and yet I doubted.
Observing my silence, and probably guessing its cause, he took up an
empty glass and poured some tea into it from the teapot at which Frau von
Eckthum had been slaking her thirst in spite of my warnings (I had, alas, no
right to forbid) that so much tea drinking would make her still more liable to
start when suddenly addressed.
“Look here,” said he.
I looked.
“You can see this tea.”
“Certainly.”
“Clear, isn’t it? A beautiful clear brown. A tribute to the spring water
here. You can see the house and all its windows through it, it is so perfectly
transparent.”
And he held it up, and shutting one eye stared through it with the other.
“Well?” I inquired.
“Well, now look at this.”
And he took another glass and set it beside the first one, and poured both
tea and milk into it.
“Look there,” he said.
I looked.
“Jellaby,” said he.
I stared.
Then he took another glass, and poured both tea and milk into it, setting it
in a line with the first two.
“Browne,” said he.
I stared.
Then he took a fourth glass, and filled it in the same manner as the
second and third and placed it at the end of the line.
“Myself,” said he.
I stared.
“Can you see through either of those three?” he asked, tapping them one
after the other.
“No,” said I.
“Now if I put a little more milk into them”—he did—“it makes no
difference. They were muddy and thick before, and they remain muddy and
thick. But”—and he held the milk jug impressively over the first glass—“if I
put the least drop into this one”—he did—“see how visible it is. The
admirable clearness is instantaneously dimmed. The pollution spreads at
once. The entire glass, owing to that single drop, is altered, muddied,
ruined.”
“Well?” I inquired, as he paused and stared hard at me.
“Well?” said he. “Do you not see?”
“See what?” said I.
“My point. It’s as clear as the first glass was before I put milk into it. The
first glass, my dear Baron, is you, with your sound and perfect constitution.”
I bowed.
“Your splendid health.”
I bowed.
“Your magnificent physique.”
I bowed.
“The other three are myself, and Jellaby, and Browne.”
He paused.
“And the drop of milk,” he said slowly, “is the caravan tour.”
I was confounded; and you, my hearers, will admit that I had every
reason to be. Here was an example of what is rightly called irresistible logic,
and a reasonable man dare not refuse, once he recognizes it, to bow in
silence. Yet I felt very well. I said I did, after a pause during which I was
realizing how unassailable Menzies-Legh’s position was, and endeavouring
to reconcile its unassailableness with my own healthful sensations.
“You can’t get away from facts,” he answered. “There they are.”
And he indicated with his cigarette the four glasses and the milk jug.
“But,” I repeated, “except for a natural foot-soreness I undoubtedly do
feel very well.”
“My dear Baron, it is obvious beyond all argument that the more
absolutely well a person is the more easily he must be affected by the
smallest upset, by the smallest variation in the environment to which he has
got accustomed. Paradox, which plays so large a part in all truths, is rampant
here. Those in perfect health are nearer than anybody else to being seriously
ill. To keep well you must never be quite so.”
He paused.
“When,” he continued, seeing that I said nothing, “we began caravaning
we could not know how persistently cold and wet it was going to be, but
now that we do I must say I feel the responsibility of having persuaded you
—or of my sister-in-law’s having persuaded you—to join us.”
“But I feel very well,” I repeated.
“And so you will, up to the moment when you do not.”
Of course that was true.
“Rheumatism, now,” he said, shaking his head; “I greatly fear
rheumatism for you in the coming winter. And rheumatism once it gets hold
of a man doesn’t leave him till it has ravaged each separate organ, including,
as everybody knows, that principal organ of all, the heart.”
This was gloomy talk, and yet the man was right. The idea that a holiday,
a thing planned and looked forward to with so much pleasure, was to end by
ravaging my organs did not lighten the leaden atmosphere that surrounded
and weighed upon Frogs’ Hole Farm.
“I cannot alter the weather,” I said at last—irritably, for I felt ruffled.
“No. But I wouldn’t risk it for too long if I were you,” said he.
“Why, I have paid for a month,” I exclaimed, surprised that he should
overlook this clinching fact.
“That, set against an impaired constitution, is a very inconsiderable
trifle,” said he.
“Not inconsiderable at all,” said I sharply.
“Money is money, and I am not one to throw it away. And what about the
van? You cannot abandon an entire van at a great distance from the place it
belongs to.”
“Oh,” said he quickly, “we would see to that.”
I got up, for the sight of the glasses full of what I was forced to
acknowledge was symbolic truth irritated me. The one representing myself,
into which he had put but one drop of milk, was miserably discoloured. I did
not like to think of such discolouration being my probable portion, and yet
having paid for a month’s caravaning what could I do?
The afternoon was chilly and very damp, and I buttoned my wraps
carefully about my throat. Menzies-Legh watched me.
“Well,” said he, getting up and looking first at me and then at the glasses
and then at me again, “what do you think of doing, Baron?”
“Going for a little stroll,” I said.
And I went.
CHAPTER XVII
M Y hearers will I hope appreciate the frankness with which I show them
all my sides, good and bad. I do so with my eyes open, aware that some
of you may very possibly think less well of me for having been, for
instance, such a prey to supernatural dread. Allow me, however, to point out
that if you do you are wrong. You suffer from a confusion of thought. And I
will show you why. My wife, you will have noticed, had on the occasion
described few or no fears. Did this prove courage? Certainly not. It merely
proved the thicker spiritual skin of woman. Quite without that finer
sensibility that has made men able to produce works of genius while women
have been able only to produce (a merely mechanical process) young, she
felt nothing apparently but a bovine surprise. Clearly, if you have no
imagination neither can you have any fears. A dead man is not frightened.
An almost dead man does not care much either. The less dead a man is the
more do possible combinations suggest themselves to him. It is imagination
and sensibility, or the want of them, that removes you further or brings you
nearer to the animals. Consequently (I trust I am being followed?) when
imagination and sensibility are busiest, as they were during those moments I
lay waiting and listening in my berth, you reach the highest point of
aloofness from the superiority to the brute creation; your vitality is at its
greatest; you are, in a word, if I may be permitted to coin an epigram, least
dead. Therefore, my friends, it is plain that at that very moment when you
(possibly) may have thought I was showing my weakest side I was doing the
exact opposite, and you will not, having intelligently followed the argument,
say at the end of it as my poor little wife did, “But how?”
I do not wish, however, to leave you longer under the impression that the
deserted farmhouse was haunted. It may have been of course, but it was not
on that night of last August. What was happening was that a party from the
parsonage—a holiday party of young and rather inclined to be noisy people,
which had overflowed the bounds of the accommodation there—was
utilizing the long, empty front room as an impromptu (I believe that is the
expression) ball-room. The farm belonged to the pastor—observe the fatness
of these British ecclesiastics—and it was the practice of his family during
the holidays to come down sometimes in the evening and dance in it. All this
I found out after Edelgard had dressed and gone across to see for herself
what the lights and stamping meant. She insisted on doing so in spite of my
warnings, and came back after a long interval to tell me the above, her face
flushed and her eyes bright, for she had seized the opportunity, regardless of
what I might be feeling waiting alone, to dance too.
“You danced too?” I exclaimed.
“Do come, Otto. It is such fun,” said she.
“With whom did you dance, may I inquire?” I asked, for the thought of
the Baroness von Ottringel dancing with the first comer in a foreign farm
was of course most disagreeable to me.
“Mr. Jellaby,” said she. “Do come.”
“Jellaby? What is he doing there?”
“Dancing. And so is everybody. They are all there. That’s why their
caravans were so quiet. Do come.”
And she ran out again, a childishly eager expression on her face, into the
night.
“Edelgard!” I called.
But though she must have heard me she did not come back.
Relieved, puzzled, vexed, and curious together, I did get up and dress,
and on lighting a candle and looking at my watch I was astonished to find
that it was only a quarter to ten. For a moment I could not credit my eyes,
and I shook the watch and held it to my ears, but it was going, as steadily as
usual, and all I could do was to reflect as I dressed on what may happen to
you if you go to bed and to sleep at seven o’clock.
And how soundly I must have done it. But of course I was unusually
weary, and not feeling at all well. Two hours’ excellent sleep, however, had
done wonders for me so great are my recuperative powers, and I must say I
could not help smiling as I crossed the yard and went up to the house at the
remembrance of Menzies-Legh’s glass of tea. He would not see much milk
about me now, thought I, as I strode, giving my moustache ends a final
upward push and guided by the music, into the room in which they were
dancing.
The dance came to an end as I entered, and a sudden hush seemed to fall
upon the company. It was composed of boys and young girls attired in
evening garments next to which the clothes of the caravaners, weather-
beaten children of the road, looked odd and grimy indeed. The tender lady, it
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