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1 - Introduction and Basıc Concepts

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16 views59 pages

1 - Introduction and Basıc Concepts

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Because learning changes everything.

Chapter 1
Introduction And Basıc
Concepts

© 2020 McGraw-Hill Education. All rights reserved. Authorized only for instructor use in the classroom.
No reproduction or further distribution permitted without the prior written consent of McGraw-Hill Education.
Objectives
• Understand how thermodynamics and heat transfer are related to each other.

• Distinguish thermal energy from other forms of energy, and heat transfer from
other forms of energy transfer.

• Perform general energy balances as well as surface energy balances.

• Understand the basic mechanisms of heat transfer, which are conduction,


convection, and radiation, and Fourier's law of heat conduction, Newton's law of
cooling, and the Stefan–Boltzmann law of radiation.

• Identify the mechanisms of heat transfer that occur simultaneously in practice.

• Develop an awareness of the cost associated with heat losses.

• Solve various heat transfer problems encountered in practice.

© McGraw-Hill Education 2
1-1 Thermodynamics And Heat Transfer 1

Heat: The form of energy that can be transferred from one system to
another as a result of temperature difference.
Thermodynamics is concerned with the amount of heat transfer as a
system undergoes a process from one equilibrium state to another.
Heat Transfer deals with the determination of the rates of such energy
transfers as well as variation of temperature.
The transfer of energy as heat is always from the higher-temperature
medium to the lower-temperature one.
Heat transfer stops when the two mediums reach the same temperature.
Heat can be transferred in three different modes:
conduction, convection, radiation

© McGraw-Hill Education 3
1-1 Thermodynamics And Heat Transfer 2

Figure 1–1 Figure 1–2


We are normally interested in how long Heat flows in the direction
it takes for the hot coffee in a thermos of decreasing temperature.
bottle to cool to a certain temperature,
which cannot be determined from a
thermodynamic analysis alone.

© McGraw-Hill Education 4
1-1 Thermodynamics And Heat Transfer 3

Application Areas of Heat Transfer

(top left): ©Andrew Olney/age fotostock; (top middle): © Mcgraw-Hill Education/jill


Braaten, photographer; (top right); © Comstock images/Getty images; (bottom left): ©Eric
Tormey/Alamy; ©Raimundas/Shutterstock; ©Brand X pictures/Jupiter images; (bottom
Figure 1–3
middle): ©Malcom Fife/age fotostock; (bottom right): Mcgraw-Hill Education/Jill Braaten,
photographer; Some application areas of heat transfer.

© McGraw-Hill Education 5
1-1 Thermodynamics And Heat Transfer 4

Kinetic theory: Treats molecules as tiny balls


Historical Background that are in motion and thus possess kinetic
energy.
Heat: The energy associated with the random
motion of atoms and molecules.
Caloric theory: Heat is a fluidlike substance
called the caloric that is a massless, colorless,
odorless, and tasteless substance that can be
poured from one body into another.
It was only in the middle of the nineteenth
century that we had a true physical
understanding of the nature of heat.
Figure 1–4
In the early 19th century, heat was Careful experiments of the Englishman James
thought to be an invisible fluid P. Joule published in 1843 convinced the
called caloric that flowed from skeptics that heat was not a substance after all,
warmer bodies to cooler ones. and thus put the caloric theory to rest.

Access the text alternative for slide images.

© McGraw-Hill Education 6
1-2 Engineering Heat Transfer 1

Heat transfer equipment such as heat exchangers, boilers, condensers, radiators, heaters,
furnaces, refrigerators, and solar collectors are designed primarily on the basis of heat
transfer analysis.
The heat transfer problems encountered in practice can be considered in two groups: (1)
rating and (2) sizing problems.
The rating problems deal with the determination of the heat transfer rate for an existing
system at a specified temperature difference.
The sizing problems deal with the determination of the size of a system in order to transfer
heat at a specified rate for a specified temperature difference.
An engineering device or process can be studied either experimentally (testing and taking
measurements) or analytically (by analysis or calculations).
The experimental approach has the advantage that we deal with the actual physical system,
and the desired quantity is determined by measurement, within the limits of experimental
error. However, this approach is expensive, timeconsuming, and often impractical.
The analytical approach (including the numerical approach) has the advantage that it is fast
and inexpensive, but the results obtained are subject to the accuracy of the assumptions,
approximations, and idealizations made in the analysis.
© McGraw-Hill Education 7
1-2 Engineering Heat Transfer 2

Modeling in Engineering

Figure 1–7
Modeling is a powerful engineering
Figure 1–6 tool that provides great insight and
Mathematical modelling of simplicity at the expense of some
accuracy.
physical problems.
Access the text alternative for slide images.

© McGraw-Hill Education 8
1-3 Heat And Other Forms Of Energy 1

Energy can exist in numerous forms such as:


• thermal
• mechanical
• kinetic
• potential
• electrical
• magnetic
• chemical
• nuclear
Their sum constitutes the total energy E (or e on a unit mass basis) of a system.
The sum of all microscopic forms of energy is called the internal energy of a
system.

© McGraw-Hill Education 9
1-3 Heat And Other Forms Of Energy 2

• Internal energy: May be viewed as the sum of the kinetic and potential
energies of the molecules.
• Sensible heat: The kinetic energy of the molecules.
• Latent heat: The internal energy associated with the phase of a system.
• Chemical (bond) energy: The internal energy associated with the atomic
bonds in a molecule.
• Nuclear energy: The internal energy associated with the bonds within the
nucleus of the atom itself.

© McGraw-Hill Education 10
1-3 Heat And Other Forms Of Energy 3

• In the analysis of systems that


involve fluid flow, we frequently
encounter the combination of
properties u and Pv.
• The combination is defined as
enthalpy (h = u + Pv).
• The term Pv represents the flow
energy of the fluid (also called
the flow work).

Figure 1–8
The internal energy u represents the
microscopic energy of a nonflowing
fluid, whereas enthalpy h represents the
microscopic energy of a flowing fluid.
Access the text alternative for slide images.

© McGraw-Hill Education 11
1-3 Heat And Other Forms Of Energy 4

Specific Heats of Gases,


Liquids, and Solids
Specific heat: The energy required to raise the
temperature of a unit mass of a substance by one
degree.
Figure 1–9
Two kinds of specific heats: Specific heat is the energy required to raise
the temperature of a unit mass of a
• specific heat at constant volume cv . substance by one degree in a specified way.
• specific heat at constant pressure cp.

The specific heats of a substance, in general,


depend on two independent properties such as
temperature and pressure.
At low pressures all real gases approach ideal gas
Figure 1–10
behavior, and therefore their specific heats depend The specific heat of a substance changes
on temperature only. with temperature.
Access the text alternative for slide images.

© McGraw-Hill Education 12
1-3 Heat And Other Forms Of Energy 5

1 kJ/kg. C  1 J/g. C  1 KJ/kg.K  1 J/g.k

du = cv dT and dh = cpdT
u = cv ,avg T and h = cp ,avg T (J/g)

u = mcv ,avg T and H = mcp ,avg T (J)

• Incompressible substance: A substance


whose specific volume (or density) does not
change with temperature or pressure.
• The constant-volume and constant-pressure
specific heats are identical for
incompressible substances.
• The specific heats of incompressible Figure 1–11
substances depend on temperature only.
The cv and cp values of
incompressible substances are
ΔU = mcavg ΔT (J)
identical and are denoted by c.

© McGraw-Hill Education 13
1-3 Heat And Other Forms Of Energy 6

t
Energy Transfer Q =  Qdt
0
( J)
Energy can be transferred to or from a given mass by two When Q is constant:
mechanisms: Q = Qt ( J)
heat transfer and work.
Heat transfer rate: The amount of heat transferred per unit time. q=
Q
A
( w/m ) 2

Heat flux: The rate of heat transfer per unit area normal to the
direction of heat transfer.

Power: The work


done per unit time.

Q 24W
q= = 2
= 4W / m2
A 6m

Figure 1–12 Figure 1–13


The sensible and latent forms of internal energy can Heat flux is heat transfer per
be transferred as a result of a temperature difference, unit time and per unit area, and
and they are referred to as heat or thermal energy. is equal to q = Q / A when Q
is uniform over the area A.

© McGraw-Hill Education 14
1-4 The First Law Of Thermodynamics 1

The first law of thermodynamics (conservation of energy principle) states that


energy can neither be created nor destroyed during a process; it can only change
forms.

 Total energy   Total energy   Change in the  The net change (increase or decrease)
      in the total energy of the system during
 entering the  −  Leaving the  =  total energy of 
 system   system   the system  a process is equal to the difference
     
between the total energy entering and
the total energy leaving the system
Ein − Eout = Esystem (J ) during that process.
Net energy transfer by Change in internal,kinetic, The energy balance for any system
heat, work,and mass Potential, etc., energies
undergoing any process in the rate form.

Ein − Eout = dEsystem / dt (W)


Net energy transfer by Rate of Change in internal
heat, work,and mass kinetic,potential,etc.,energies

© McGraw-Hill Education 15
1-4 The First Law Of Thermodynamics 2

steady, rate form : Ein = Eout


Rate of net energy transfer in Rate of net energy transfer out
by heat,work, and mass by heat,work, and mass

In heat transfer problems it is convenient


to write a heat balance and to treat the
conversion of nuclear, chemical,
mechanical, and electrical energies into
thermal energy as heat generation.

Qin − Qout + Egen = Ethermal,system (J)


Net hear tranmsfer Heat Change in thermal
generation energy of the system
Figure 1–15
In steady operation, the rate of energy
transfer to a system is equal to the rate
of energy transfer from the system.

Access the text alternative for slide images.

© McGraw-Hill Education 16
1-4 The First Law Of Thermodynamics 3

Energy Balance for Closed Systems (Fixed Mass)


A closed system consists of a fixed mass.
The total energy E for most systems
encountered in practice consists of the internal
energy U.
This is especially the case for stationary
systems since they don’t involve any changes
in their velocity or elevation during a process.

Starionary closed system:


Ein − Eout = U = mcv T (J )
Figure 1–16
In the absence of any work
Stationary closed system, no work:
interactions, the change in the energy
content of a closed system is equal to
Q = mcv T (J )
the net heat transfer.
Access the text alternative for slide images.

© McGraw-Hill Education 17
1-4 The First Law Of Thermodynamics 4

Energy Balance for Steady-Flow Systems


A large number of engineering devices such
as water heaters and car radiators involve
mass flow in and out of a system, and are
modeled as control volumes.
Figure 1–17
Most control volumes are analyzed under The mass flow rate of a fluid at a cross section is
steady operating conditions. equal to the product of the fluid density, average
The term steady means no change with time fluid velocity, and the cross-sectional area.
at a specified location.
Mass flow rate: The amount of mass flowing
through a cross section of a flow device per
unit time.
Volume flow rate: The volume of a fluid
flowing through a pipe or duct per unit time. Figure 1–18
m = pVAc ( kg / s ) Under steady conditions, the net rate of energy
transfer to a fluid in a control volume is equal
v = VAc =
m
p
( m3 / s ) to the rate of increase in the energy of the fluid
stream flowing through the control volume.
Q = mh = mc p T ( kJ/s ) Access the text alternative for slide images.

© McGraw-Hill Education 18
1-4 The First Law Of Thermodynamics 5

Surface Energy Balance


A surface contains no volume or mass,
and thus no energy. Thereore, a surface
can be viewed as a fictitious system
whose energy content remains constant
during a process.
Surface energy balance : Ein = Eout

This relation is valid for both steady and Figure 1–19


transient conditions, and the surface energy Energy interactions at the outer wall
balance does not involve heat generation surface of a house.
since a surface does not have a volume.
Q1 = Q1 + Q3
When the directions of interactions are not known, all energy interactions can be assumed
to be towards the surface, and the surface energy balance can be expressed as Ein = 0. 
Note that the interactions in opposite direction will end up having negative values, and
balance this equation.
Access the text alternative for slide images.

© McGraw-Hill Education 19
1-5 Heat Transfer Mechanisms
Heat as the form of energy that can be transferred from one system to another as
a result of temperature difference.
A thermodynamic analysis is concerned with the amount of heat transfer as a
system undergoes a process from one equilibrium state to another.
The science that deals with the determination of the rates of such energy
transfers is the heat transfer.
The transfer of energy as heat is always from the higher-temperature medium to
the lower-temperature one, and heat transfer stops when the two mediums reach
the same temperature.
Heat can be transferred in three basic modes:
• Conduction.
• Convection.
• Radiation.
All modes of heat transfer require the existence of a temperature difference.

© McGraw-Hill Education 20
1-6 Conduction 1

Conduction: The transfer of energy from the more


energetic particles of a substance to the adjacent
less energetic ones as a result of interactions
between the particles.
In gases and liquids, conduction is due to the
collisions and diffusion of the molecules during
their random motion.
In solids, it is due to the combination of vibrations
of the molecules in a lattice and the energy
transport by free electrons.
The rate of heat conduction through a plane layer is
proportional to the temperature difference across
the layer and the heat transfer area, but is inversely
proportional to the thickness of the layer.

Rate of heat conduction 


( Area )( Temperature difference ) Figure 1–23
Thickness Heat conduction through a
T1 − T2 T large plane wall of thickness
Qcond = kA = −kA (W) x and area A.
x x
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© McGraw-Hill Education 21
1-6 Conduction 2

When x → 0

Qcond = −kA
dT Fourier’s law of
dx heat conduction
Thermal conductivity, k: A measure of
the ability of a material to conduct heat.
Temperature gradient dT / dx :
The slope of the temperature curve on a T-x
diagram.
Heat is conducted in the direction of decreasing
temperature, and the temperature gradient
becomes negative when temperature decreases Figure 1–24
with increasing x. The negative sign in the The rate of heat conduction through
equation ensures that heat transfer in the a solid is directly proportional to its
positive x direction is a positive quantity. thermal conductivity.

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© McGraw-Hill Education 22
1-6 Conduction 3

Figure 1–26
In heat conduction analysis, A
represents the area normal to the
direction of heat transfer.
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© McGraw-Hill Education 23
1-6 Conduction 4

Thermal Conductivity
Thermal conductivity: The rate of heat
transfer through a unit thickness of the
material per unit area per unit temperature
difference.
The thermal conductivity of a material is a
measure of the ability of the material to
conduct heat.
A high value for thermal conductivity
indicates that the material is a good heat L
k= Q
conductor, and a low value indicates that the A (T1 − T2 )
material is a poor heat conductor or
insulator. Figure 1–28
A simple experimental setup to
determine the thermal conductivity of a
material.
Access the text alternative for slide images.

© McGraw-Hill Education 24
1-6 Conduction 5

Material K,W/m.K*
Table 1-1 Diamond 2300
Silver 429
The thermal conductivities
Copper 401
of some materials at room
Gold 317
temperature
Aluminum 237
Iron 80.2
Mercury (l) 8.54
Glass 0.78
Brick 0.72
Water (l) 0.607
*Multiply by 0.5778 to Human skin 0.37
convert to Btc/h.ft.°F. Wood (oak) 0.17
Helium (g) 0.152
Soft rubber 0.13
Glass fiber 0.043
Air (g) 0.026
Urethane, rigid foam 0.026

© McGraw-Hill Education 25
1-6 Conduction 6

The range of
thermal
conductivity of
various materials
at room
temperature.

Figure 1–29
The range of thermal conductivity of
various materials at room temperature.
Access the text alternative for slide images.

© McGraw-Hill Education 26
1-6 Conduction 7

The thermal conductivities of gases such as air vary by a


factor of 104 from those of pure metals such as copper.
Pure crystals and metals have the highest thermal
conductivities, and gases and insulating materials the lowest.
Table 1-2 The thermal conductivity of an alloy is usually
much lower than the thermal conductivity of
either metal of which it is composed

Pure Metal or K, W/m.k


Alloy at 300 k
Copper 401
Nickel 91
Constantan
(55% cu, 45% Ni) 23
Copper 401
Figure 1–30 Aluminum 237
The mechanisms of heat Commercial bronze
conduction in different (90% Cu, 10% A1) 52
phases of a substance.
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© McGraw-Hill Education 27
1-6 Conduction 8

Table 1-3
Thermal conductivities of materials
vary with temperature

The variation of the thermal


Figure 1–31 conductivity of various solids,
The variation of the thermal conductivity of liquids, and gases with
various solids, liquids, and gases with temperature. temperature.

© McGraw-Hill Education 28
1-6 Conduction 9

Table 1-4: The thermal diffusivities of


Thermal Diffusivity some materials at room temperature
Material a, m 2 / s *
cp Specific heat, J/kg·°C: Heat capacity per unit mass Silver 149 10−6
Gold 127 10−6
cp Heat capacity, J/m3 . C: Heat capacity per unit
volume Copper 113 10−6
 Thermal diffusivity, m /s: Represents how fast
2
Aluminum 97.5 10−6
heat diffuses through a material Iron 22.8 10−6
Mercury (l) 4.7 10−6
=
Heat conduction
Heat storage
=
k
pc p
(m / s)
2
Marble 1.2 10−6
Ice 1.2 10−6
A material that has a high thermal conductivity or a
Concrete 0.75 10−6
low heat capacity will obviously have a large
Brick 0.52 10−6
thermal diffusivity.
Heavy Soil (dry) 0.52 10−6
The larger the thermal diffusivity, the faster the
Glass 0.34 10−6
propagation of heat into the medium.
Glass Wool 0.23 10−6
A small value of thermal diffusivity means that heat
Water (l) 0.14 10−6
is mostly absorbed by the material and a small
amount of heat is conducted further. Beef 0.14 10−6
Wood (oak) 0.13 10−6
© McGraw-Hill Education 29
1-7 Convection 1

Convection: The mode of energy transfer


between a solid surface and the adjacent
liquid or gas that is in motion, and it
involves the combined effects of
conduction and fluid motion.
The faster the fluid motion, the greater the
convection heat transfer.
In the absence of any bulk fluid motion,
heat transfer between a solid surface and
the adjacent fluid is by pure conduction.
Figure 1–34
Heat transfer from a hot surface to air
by convection.

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© McGraw-Hill Education 30
1-7 Convection 2

Forced convection: If the fluid is


forced to flow over the surface by
external means such as a fan, pump,
or the wind.
Natural (or free) convection: If the
fluid motion is caused by buoyancy
forces that are induced by density
differences due to the variation of
temperature in the fluid.
Figure 1–35
The cooling of a boiled egg by
forced and natural convection.

Heat transfer processes that involve change of phase of a fluid are also considered to be
convection because of the fluid motion induced during the process, such as the rise of the
vapor bubbles during boiling or the fall of the liquid droplets during condensation.

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© McGraw-Hill Education 31
1-7 Convection 3

Qconv = hAs (Ts − T ) (W) Newton’s law of cooling


h convection heat transfer coefficient, W/m 2 . C.
As the surface area through which convection heat transfer takes place.
Ts the surface temperature.
T the temperature of the fluid sufficiently far from the surface.

The convection heat transfer coefficient h


Table 1-5: Typical values of convection
is not a property of the fluid.
heat transfer coefficient
It is an experimentally determined
parameter whose value depends on all the Type of Convection h, W/m 2 .k *
variables influencing convection such as,
Free convection of gases 2-25
• the surface geometry. Free convection of liquids 10-1000
• the nature of fluid motion. Forced convection of gases 25-250
• the properties of the fluid. Forced convection of liquids 50-20,000
• the bulk fluid velocity. Boiling and condensation 2500-100,000
*Multiply by 0.176 to convert to Btu/h.ft 2 . F.

© McGraw-Hill Education 32
1-8 Radiation 1

• Radiation: The energy emitted by matter in the form of electromagnetic waves


(or photons) as a result of the changes in the electronic configurations of the
atoms or molecules.
• Unlike conduction and convection, the transfer of heat by radiation does not
require the presence of an intervening medium.
• In fact, heat transfer by radiation is fastest (at the speed of light) and it suffers
no attenuation in a vacuum. This is how the energy of the sun reaches the
earth.
• In heat transfer studies we are interested in thermal radiation, which is the
form of radiation emitted by bodies because of their temperature.
• All bodies at a temperature above absolute zero emit thermal radiation.
• Radiation is a volumetric phenomenon, and all solids, liquids, and gases emit,
absorb, or transmit radiation to varying degrees.
• However, radiation is usually considered to be a surface phenomenon for
solids.

© McGraw-Hill Education 33
1-8 Radiation 2

Table 1-6: Emissivities of some materials at 300 k


Qemit,max =  AsTs4 ( W ) Stefan–Boltzmann law Material Emissivity
Aluminum foil 0.07
 = 5.670 10−8 W/m 2 .K 4 Stefan–Boltzmann constant
Anodized aluminum 0.82
Blackbody: The idealized surface that emits Polished copper 0.03
radiation at the maximum rate. Polished gold 0.03
Qemit =  AsTs4 ( W ) Polished silver 0.02
Radiation emitted by real surfaces Polished stainless steel 0.17

Emissivity  : A measure of how closely a Black paint 0.98

surface approximates a blackbody for which White paint 0.90

 = 1 of the surface. 0   1. White paper 0.92−0.97


Asphalt pavement 0.85−0.93
Red brick 0.93−0.96
Human skin 0.95
Figure 1–38 Wood 0.82−0.92
Blackbody radiation represents the maximum Soil 0.93−0.96
amount of radiation that can be emitted from a Water 0.96
surface at a specified temperature. Vegetation 0.92−0.96

© McGraw-Hill Education 34
1-8 Radiation 3

Absorptivity : The fraction of the radiation energy incident on a surface that is


absorbed by the surface. 0   1.
A blackbody absorbs the entire radiation incident on it ( = 1).
Kirchhoff’s law: The emissivity and the absorptivity of a surface at a given
temperature and wavelength are equal.
Qabsorbed =  Qincident (W)

Figure 1–39
The absorption of radiation incident on an opaque surface of absorptivity .
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© McGraw-Hill Education 35
1-8 Radiation 4

Net radiation heat transfer: The When a surface is completely enclosed by a


difference between the rates of much larger (or black) surface at
radiation emitted by the surface and the temperature Tsurr separated by a gas (such as
air) that does not intervene with radiation,
radiation absorbed.
the net rate of radiation heat transfer
The determination of the net rate of between these two surfaces is given by
heat transfer by radiation between two Qrad =  As (Ts4 − Tsurr
4
) (W)
surfaces is a complicated matter since it
depends on,

• the properties of the surfaces.


• their orientation relative to each
other.
• the interaction of the medium
between the surfaces with radiation.
Radiation is usually significant relative Figure 1–40
to conduction or natural convection, but Radiation heat transfer between a surface
negligible relative to forced convection. and the surfaces surrounding it.
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© McGraw-Hill Education 36
1-8 Radiation 5

When radiation and convection occur simultaneously


between a surface and a gas:
Qtotal = hcombined As (Ts − T ) ( W )
Combined heat transfer coefficient hcombined
Includes the effects of both convection and radiation

Qtotal = Qconv + Qrad = hconv As (Ts − Tsurr ) +  As (Ts4 − Tsurr


4
)
Qtotal = hcombined As (Ts − T ) ( W )
hcombined = hconv + hrad = hconv +  (Ts + Tsurr ) (Ts2 + Tsurr
2
)

© McGraw-Hill Education 37
1-9 Simultaneous Heat Transfer
Mechanisms
Heat transfer is only by conduction in opaque solids, but by
conduction and radiation in semitransparent solids.
A solid may involve conduction and radiation but not
convection. A solid may involve convection and/or
radiation on its surfaces exposed to a fluid or other
surfaces.
Heat transfer is by conduction and possibly by radiation in
a still fluid (no bulk fluid motion) and by convection and
radiation in a flowing fluid.
In the absence of radiation, heat transfer through a fluid is
either by conduction or convection, depending on the
presence of any bulk fluid motion.
Convection = Conduction + Fluid motion
Heat transfer through a vacuum is by radiation.
Most gases between two solid surfaces do not interfere with
Figure 1–42
radiation. Although there are three mechanisms
Liquids are usually strong absorbers of radiation. of heat transfer, a medium may
involve only two of them
simultaneously.
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© McGraw-Hill Education 38
1-10 Aerogel—a Remarkable
Superinsulating Material 1

Aerogels—often called “frozen smoke”—are lightweight


and have an ethereal blue haze.
An aerogel in your hand feels like a piece of air—but it is a
solid.
What makes them so interesting is their unique nanoporous
structure.
This structure is formed through the sol-gel process,
whereby a sol (a particulate-containing solution) undergoes
a polymerization reaction to form a nanoporous wet gel.
The key to making an aerogel is to carefully dry the wet
gel.
Supercritical extraction is commonly used to make
aerogels.
Figure 1–48
Aerogels can be made from many different precursor
A silica aerogel insulates a
materials.
flower from the heat of a
The most common type of aerogel is the silica aerogel. Bunsen burner.

© McGraw-Hill Education 39
1-10 Aerogel—a Remarkable
Superınsulatıng Materıal 2

When an aerogel is made by the sol-gel


method, it forms a nanoporous structure
comprised of clusters of silica spheres on the
order of 5–10 nm that connect and form long,
chain-like connecting structures with pores
that range from 5 to 100 nm in size.
Silica aerogels are very porous: 90–99
percent air
Have low density:
0.05 − 0.4 g/cm3
Large surface areas:

Figure 1–49 500 − 1400 m 2 /g


Schematic representation of Highly translucent and have low thermal
an aerogel nanostructure. conductivity:
0.01 − 0.3 w/m.k
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© McGraw-Hill Education 40
1-10 Aerogel—a Remarkable
Superınsulatıng Materıal 3

Convection through an aerogel is hindered by the small pore size.


At low temperatures radiation is not significant.
The primary method for heat transfer through an aerogel is by conduction in both the solid
and gaseous phases.
Solid phase conduction is related to the thermal conductivity of the solid and the amount of
that solid.
Since aerogels are so porous, there is very little solid material, and what is there follows a
tortuous path with many dead ends (formed by the original sol-gel process).
For these reasons, the thermal conductivity of an aerogel is very low.
Aerogels are commercially available in an impregnated blanket form, as granules, or as
monolithic pieces.
They are used in a variety of applications, including comet dust collectors, oil spill clean-
up material, and chemical sensors.
The most common application for aerogels is as insulation where, for example, they are
used in daylighting products (insulating windows), high-performance clothing, and pipe
insulation.
© McGraw-Hill Education 41
1-10 Aerogel—a Remarkable
Superınsulatıng Materıal 4

Heat loss through a 6-mm -thick single-pane glass window

ΔT  W  (30 − 10 ) C = 133.3W
o

Q = kA = 1.0  ( 0.25m × 0.16m )


Δx  m.K  0.006 m

If we could make the window pane out of a monolithic aerogel under slight
vacuum, the heat loss would be:

ΔT  W  (30 − 10 ) C = 1.3W
o

Q = kA =  0.01  ( 0.25m × 0.16m )


Δx  m.K  0.006 m

© McGraw-Hill Education 42
1-11 Prevention Through Design 1

The first of the fundamental canons of ethics for engineers is to “hold paramount the
safety, health, and welfare of the public” when fulfilling their professional duties.
In 2007, the National Institute for Occupational Safety and Health (NIOSH)
launched the National Prevention through Design (PtD) initiative, with the mission
to prevent or reduce work-related injuries, illnesses, and fatalities by including
prevention considerations in all circumstances that impact individuals in the work
places.
As such, the concept of PtD involves applying the means of reducing risks and
preventing hazards in the design of equipment, tools, processes, and work facilities.
The concepts of PtD can also be rationally applied to preventing failures and
damages of devices, products, and systems. Since such failures and damages are
often led to negative impacts on the environment, profitability, and ultimately the
society at large.

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© McGraw-Hill Education 43
1-11 Prevention Through Design 2

Within the context of heat and mass transfer, the


PtD concepts can be presented along with the
physical mechanisms involved and practical
applications.
Issues such as prevention of thermal burn, fire
hazard, and thermal failure in systems are topics
that can relate the concepts of PtD with the basic
science of heat and mass transfer.
The process of solving heat and mass transfer
problems, along with the application of PtD
concepts, involves incorporating prescribed PtD
criteria, the prevention of burn injury, fire hazard,
or system failure, to the solutions.
To successfully arrive at a solution that satisfies
prescribed PtD criteria requires the understanding Figure 1–50
of how the physical mechanisms of heat and mass Process of solving problems with
transfer interrelate with the concepts of PtD. application of PtD concepts.
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© McGraw-Hill Education 44
1-12 Engineering Codes And Standards 1

Engineering codes and standards are ubiquitous.


When we consider any given device that we use daily, the path, from the design to the
prototype and finally to the production of the final product is guided by standards and
regulated by codes.
A product that has been manufactured to meet certain standards tells the user about the
product’s quality and that it has met certain levels of scrutiny set forth by those standards.
In essence, engineering standards communicate to the user that the product is expected to
function safely and meets quality objectives.
At the industrial level, engineering codes and standards provide efficiency in engineering
processes (from design to manufacturing), maintain safety and uniformity of products that
allows interchangeability, and improve commerce.
Engineering codes and standards are evolutionary—they are continually revised to reflect
technical advances, such as new technologies, new designs, new procedures, and new
materials.

© McGraw-Hill Education 45
1-12 Engineering Codes And Standards 2

The development of engineering codes and standards is rooted in the engineers’ code of
ethics to “hold paramount the safety, health, and welfare of the public” in their professions
(Code of Ethics for Engineers, 2007).
The founding of the American Society of Mechanical Engineers (ASME) in 1880 provided
a forum for engineers, designers, and machine shop managers to discuss and collaborate to
solve issues brought on by the industrial age.
Within four years, the first ASME standard, “Code for the Conduct of Trials of Steam
Boilers,” was issued.
This was the first ASME Performance Test Code (PTC). Today, there are close to 50 ASME
PTCs, and they cover components, systems, and facilities.
Performance test codes are used by manufacturers to ensure the reliability of their products,
and users can use the PTCs to protect themselves from products that function poorly.

© McGraw-Hill Education 46
1-12 Engineering Codes And Standards 3

Some of the very first engineering codes and standards were needed because of
engineering failures that caused the loss of life and property.
In 1905, a boiler exploded in a shoe factory in Brockton, Massachusetts. In the next year,
a similar incident happened in another shoe factory in Lynn, Massachusetts.
Within a decade, the first edition of the Boiler and Pressure Vessel Code (BPVC) was
issued by the ASME in 1914 and published in 1915.
Today, the ASME BPVC has been adopted by the United States and Canada, and it is
being used in over 100 countries around the world.
A recent study done by ASME Vision 2030 Project reveals that almost 50 percent of
engineers in their early career are unfamiliar with engineering codes and standards.
As companies and manufacturers expand operations globally, there is a greater need to
harmonize codes and standards across jurisdictions and disciplines.
The need for engineers to know about codes and standards is growing, and having this
knowledge allows engineers to innovate and manufacture competitive products.

© McGraw-Hill Education 47
1-12 Engineering Codes And Standards 4

In the subject of heat and mass transfer, there are several engineering codes and standards
that are relevant.
These codes and standards have been issued and published by professional associations,
such as the ASME and the ASHRAE, and standards organizations, such as ASTM
International, the ANSI, and the ISO.
For instance, the 2015 ASME Boiler & Pressure Vessel Code, Section IV (ASME BPVC
.IV-2015) provided the permitted O-ring materials and their temperature limits for water
tube attachments in hot water boilers.
Another example is the standard specification issued by ASTM International for
polyethylene insulation used on electrical cable (ASTM D1351-14, 2014), which is
important as overheating can rapidly deteriorate the insulation.
Extreme temperatures and thermal cycles can cause materials to deteriorate and thereby
affect the functionality of components.
The knowledge of heat and mass transfer, along with adherence to the relevant codes and
standards, allow engineers to analyze, design, and build components and systems to
function within the design conditions.
© McGraw-Hill Education 48
1-13 Problem-solving Technique 1

Step 1: Problem Statement


Step 2: Schematic
Step 3: Assumptions and Approximations
Step 4: Physical Laws
Step 5: Properties
Step 6: Calculations
Step 7: Reasoning, Verification, and Discussion

© McGraw-Hill Education 49
1-13 Problem-solving Technique 2

Figure 1–53
A step-by-step approach can Figure 1–54
greatly simplify problem solving. The assumptions made while solving
an engineering problem must be
reasonable and justifiable.

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© McGraw-Hill Education 50
1-13 Problem-solving Technique 3

Figure 1–55
The results obtained from an Figure 1–56
engineering analysis must be checked Neatness and organization are highly
for reasonableness. valued by employers.

© McGraw-Hill Education 51
1-14 Engineering Software Packages 1

All the computing power and the


engineering software packages available
today are just tools, and tools have
meaning only in the hands of masters.
Hand calculators did not eliminate the
need to teach our children how to add or
subtract, and sophisticated medical
software packages did not take the place
of medical school training.
Neither will engineering software
packages replace the traditional Figure 1–57
engineering education. They will simply An excellent word-processing program
cause a shift in emphasis in the courses does not make a person a good writer;
from mathematics to physics. it simply makes a good writer a better
and more efficient writer.

© McGraw-Hill Education 52
1-14 Engineering Software Packages 2

Equation Solvers
Despite its simplicity, Excel is commonly used in solving systems of equations in
engineering as well as finance. It enables the user to conduct parametric studies,
plot the results, and ask “what if ” questions. It can also solve simultaneous
equations if properly set up.
Engineering Equation Solver (EES) is a program that solves systems of linear or
nonlinear algebraic or differential equations numerically.
It has a large library of built-in thermodynamic property functions as well as
mathematical functions.
Unlike some software packages, equation solvers do not solve engineering
problems; they only solve the equations supplied by the user.
Therefore, the user must understand the problem and formulate it by applying
any relevant physical laws and relations.

© McGraw-Hill Education 53
1-15 Accuracy, Precision, And Significant
Digits 1

Accuracy error (inaccuracy): The value of


one reading minus the true value. In general,
accuracy of a set of measurements refers to
the closeness of the average reading to the
true value. Accuracy is generally associated
with repeatable, fixed errors.
Precision error: The value of one reading
minus the average of readings. In general,
precision of a set of measurements refers to
the fineness of the resolution and the
repeatability of the instrument. Precision is
generally associated with unrepeatable, Figure 1–60
random errors. Illustration of accuracy versus
precision. Shooter A is more precise,
Significant digits: Digits that are relevant but less accurate, while shooter B is
and meaningful. more accurate, but less precise.

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© McGraw-Hill Education 54
1-15 Accuracy, Precision, And Significant
Digits 2

Number Exponential Number of


Table 1-7: Notation Significant Digits
Significant 12.3 1.23×101 3
digits 123, 000 1.23×105 3
0.00123 1.23×10-3 3
40, 300 4.03×104 3
40,300 4.0300×104 5
0.005600 5.600×10-3 4
0.0056 5.6×10-3 2
0.006 6.×10-3 1

In engineering calculations, the information given is not


known to more than a certain number of significant
digits, usually three digits.
Figure 1–61
Consequently, the results obtained cannot possibly be
A result with more significant
accurate to more significant digits.
digits than that of given data
Reporting results in more significant digits implies falsely implies more accuracy.
greater accuracy than exists, and it should be avoided.
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© McGraw-Hill Education 55
Summary 1

Thermodynamics and Heat Transfer.


• Application areas of heat transfer.
• Historical background.

Engineering Heat Transfer.


• Modeling in engineering.
Heat and Other Forms of Energy.
• Specific heats of gases, liquids, and solids.
• Energy transfer.
The First Law of Thermodynamics.
• Energy balance for closed systems (Fixed Mass).
• Energy balance for steady-flow systems.
• Surface energy balance.
Heat Transfer Mechanisms.
© McGraw-Hill Education 56
Summary 2

Conduction:
• Fourier’s law of heat conduction.
• Thermal Conductivity.
• Thermal Diffusivity.

Convection:
• Newton’s law of cooling.
Radiation:
• Stefan–Boltzmann law.

© McGraw-Hill Education 57
Summary 3

Simultaneous Heat Transfer Mechanisms.

Aerogel – A Remarkable Superinsulating Material.

Prevention through Design.

Engineering Codes and Standards.

Problem Solving Technique.

Engineering Software Packages.

Accuracy, Precision and Significant Digits.

© McGraw-Hill Education 58
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