(a) There are 33 questions in this question paper with internal choice.
(b) SECTION-A consists of 16 multiple -choice questions carrying 1 mark each.
(c) SECTION-B consists of 5 short answer questions carrying 2 marks each.
(d) SECTION-C consists of 7 short answer questions carrying 3 marks each.
(e) SECTION-D consists of 2 case - based questions carrying 4 marks each.
(f) SECTION-E consists of 3 long answer questions carrying 5 marks each.
(g) All questions are compulsory.
(h) Use of log tables and calculators is not allowed.
SECTION-A
The following questions are multiple choice questions with one correct answer. Each question carries 1 mark. There is no internal choice in this section.
Q1.How many Faradays of electricity is required for the reduction of one mole of Al2O3? (1)
a) 3F b) 6F c) 12F d) 1F
Q2.The unit of the rate constant for the reaction 2H2 + 2NO → 2H2O + N2 with rate = K|H2||NO|², is (1)
(a) mol L-1 s-1
(b) s-1
(c) mol-2 L² s-1
(d) mol L-1
Q3. What is the unit of molal elevation constant? (1)
a) K Kg-1 mol-1 b) K Kg-1 mol c) K Kg mol-1 d) K-1Kg mol-1 H+ Q4. CH3COOCH3 + H2O------------ CH3COOH + CH3OH (1) What is the Molecularity and order of the reaction? a) 2 , 2 b) 1 , 1 c) 2 , 1 d) 1 , 2
Q5. Identify the colour ions from it ( Zn2+ , Cr3+ , Ni2+, ) (1)
a) Zn2+ b) Ni2+ c) Cr3+ d) Both Cr3+ & Ni2+
Q6. Find out the paramagnetic ion from the ions (MnO4 –, MnO4 2- , CrO4 2- ) (1)
a) MnO4 – b) MnO4 2- c) CrO4 2- d) MnO4 2- & CrO4 2-
Q7. Potassium dichromate is stable in (1)
a) Acidic medium b) Basic medium c) Neutral medium d) Both Acidic & basic medium
Q8. What will be the Werner’s formula of the complex Co(NH3)4Cl3 if it reacts with one mole AgNO3 solution. (1)
a) [Co(NH3)4 Cl2]Cl b) [Co(NH3)4 Cl]Cl2 c) [Co(NH3)4 Cl3] d) [Co(NH3)3 Cl3]
Q9. Identify the non-ideal solution of positive deviation (1)
a) Chloroform and acetone
b) Water and HCl c) Water and ethanol d) Chloroform and benzene Q10. The reduction potential of dispositive ions of A, B, C and D are +2.04v, +3.10v, -1.10v and – 2.21v respectively, Which is the strongest reducing agent ? (1)
a) +2.04 v b) +3.10 v c) +2.00 v d) -2.21 v
Q11. Which one is more reactive towards nucleophilic addition reaction (1)
a) HCHO b) CH3CHO c) CH3CH2CHO d) CH3COCH3
Q12. What is the shape and hybridisation of ketones across carbonyl group ? (1)
a) Planar , SP3 b) Bent , SP2 c) Planar , SP2 d) Linear , SP
Q13. Assertion: Ethers behave as bases in the presence of mineral acids.
Reason: Due to the presence of lone pairs of electrons on oxygen. (1)
Select the most appropriate answer from the options given below:
(a) Both A and R are true and R is the correct explanation of A
(b) Both A and R are true but R is not the correct explanation of A.
(c) A is true but R is false.
(d) A is false but R is true.
Q14. Assertion : SN2 reaction of an optically active aryl halide with an aqueous solution of KOH always gives an alcohol with opposite sign of rotation. 2 Reason : SN reactions always proceed with inversion of configuration.
(a) Both A and R are true and R is the correct explanation of A (1)
(b) Both A and R are true but R is not the correct explanation of A.
(c) A is true but R is false.
(d) A is false but R is true.
Q15. Assertion : In case of phenol, bromination takes place even in absence of Lewis acid whereas bromination of benzene takes place in presence of Lewis acid like FeBr 3. Reason : – OH group attached to benzene ring is highly deactivating.
(a) Both A and R are true and R is the correct explanation of A (1)
(b) Both A and R are true but R is not the correct explanation of A.
(c) A is true but R is false.
(d) A is false but R is true.
Q16. Assertion: Aldehydes and ketones, both react with Tollens’ reagent to form silver mirror. Reason: Both, aldehydes and ketones contain a carbonyl group. (1)
(a) Both A and R are true and R is the correct explanation of A
(b) Both A and R are true but R is not the correct explanation of A.
(c) A is true but R is false.
(d) A is false but R is true.
SECTION-B
This section contains 5 questions with internal choice in one question. The following questions are very short answer type and carry 2 marks each.
Q17. Determine the osmotic Pressure of a solution prepared by dissolving 25 mg of K 2SO4 in 2 litre of water at 25 0C, assuming that it is completely dissociated. (2)
Q18. Write the possible isomers(structure) of the following complex. (2)
a) [Co(NH3)4 Cl Br] I b) [Co(en)3] 3+
(OR)
Calculate the ON and CN of metal atom in the complex [Cr(en)3] 3+
Q19. Explain with example (2)
a) Hydration isomer b) Coordination isomer
Q20. Explain (2)
a) p-dichlorobenzene has greater MP than ortho and meta, why?
b) SN1 reaction gives racemic mixture. Q21. Complete the reaction
NaBH4 a) CH3COCH3 ------------------- b) HCHO + NH2OH -----------
SECTION-C
This section contains 7 questions with internal choice in one question. The following questions are short answer type and carry 3 marks each.
Q22. Compare the properties ( in increasing order) (3)
a) Equimolar conc. Of NaCl , Na2SO4 , Glucose. (Boiling Point)
Q23. Two elements A and B form compounds of formula AB 2 and AB4. When dissolved in 20.0 g of benzene 1.0 g of AB2 lowers freezing point by 2.3 K whereas 1.0 g of AB 4 lowers freezing point by 1.3K . The Kf for benzene is 5.1 K Kg mol -1. Calculate atomic masses of A and B . (3)
Q24. Calculate standard free energy change for the following chemical reaction. (3)
Identify the anode and cathode in the given cell.
Q25. The following data were obtained for the reaction (3)
2NO(g) + Br(g) → 2NOBr(g)
Experiment initial conc initial rate
[NO] [Br2] (mol L-1 min -1)
I 0.10 0.10 1.3X10-6
II 0.20 0.10 5.2X10-6
III 0.20 0.30 1.56X10-5
Determine (i) the orders with respect to NO and Br2
(ii) the rate law and rate constant
Q26.Differentiate the following pairs of complex on the basis of magnetic nature (3) i) [Ni(CN)4]2- and Ni(CO)4
ii) [Fe(CN]6]4- and [Fe(Cl]6]4-
iii) [Cu(NH3)4] 2+ and [CuCl4] 2-
Q27. Write in increasing order (3)
a) 1-propanol , 2-propanol , 2-methyl-2-propanol ( reactivity towards lucas reagent)
b) Propanol , propanal , propanoic acid ( boiling point ) c) CH3OH , CH3OCH3 , Ph-OH ( C-O-H and C-O-C bond angle )
Q28. Write the chemical equation (3)
a) Iodoform test of ethanal
b) Cannizzarro’s reaction c) Esterification reaction (OR)
Complete the reactions
a) HCHO + HCN ----------------
b) CH3COOH + Cl2/ P4 --------- c) CH3CHO + NH2-NH2 ----------
SECTION-D
The following questions are case -based questions. Each question has an internal choice and carries 4 (1+1+2) marks each. Read the passage carefully and answer the questions that follow.
Q29. The dry cell consists of a zinc container that also acts as anode and the cathode is a carbon (graphite) rod surrounded by powdered manganese dioxide and carbon. The space between the electrodes is filled by a moist paste of ammonium chloride (NH 4Cl) and zinc chloride (ZnCl2). Ammonia produced in the reaction forms a complex with Zn2+ (a) How much electricity in terms of Faraday is required to carry out the oxidation of one mole of Zinc? (b) Why dry cell does not maintain constant voltage. (c) Write the cathodic reaction of dry cell. Why in the construction of dry cell ,zinc container is covered with steel. (1+1+2)
(OR) The Hg cell consists of zinc – mercury amalgam as anode and a paste of HgO and carbon as the cathode. The electrolyte is a paste of KOH and ZnO.
(a) How much electricity in terms of Faraday is required to carry out the reduction of 1 mole of HgO? (b) How much of voltage is produced by this cell. (c) Write the cell reaction of this cell. (1+1+2)
Q30. Chemical kinetics deals with rate of chemical reactions, how fast reactants get used up or how fast products are formed in the reaction. Differed chemical reactions have different speed. Rate of the reaction depends upon concentration of reactants, temperature, pressure especially in gaseous reactions and presence of catalyst. Chemical reaction takes place as a results of collision between reacting molecules. The rate of reaction does not depend upon total number of collisions rather it depends upon number of effective collisions. In a redox reaction, if E°cell is +ve, ∆G° will be –ve and ‘K’ equilibrium constant will be high i.e. products formed will be more than the reactants.
(a) From the graph,How the activation energy is related with energy of activated complex and reactant energy (b) How the slow and fast reaction is compared in terms of their activation energy? (c) Write two factors that affect the rate of reaction. (OR)
In the rate equation Rate = k [A]x [B]y X and Y indicate how sensitive the rate is to the change in concentration of A and B. Sum of these exponents, i.e., X + Y in ( gives the overall order of a reaction whereas x and y represent the order with respect to the reactants A and B respectively.
Hence, the sum of powers of the concentration of the reactants in the rate law expression is called the order of that chemical reaction. (a) What is the unit of K (rate constant) for zero order reaction?
(b) At what condition, the rate is equal to the rate constant?
(c) For the above rate equation, if X=2 and Y = 1, How much the rate will be changed if the concentration of A and B are increased by twice. What is order of the reaction? (1+1+2)
SECTION-E
The following questions are long answer type and carry 5 marks each. All questions have an internal choice.
Q31. Write the chemical equations in the preparation of potassium dichromate from chromites ore. Write the complete balanced equation in the reaction of acidified dichromate solution with (i) H2S gas (ii) KI solution (5) (OR)
( a) Complete and balance the following reactions (2 + 3)
i) Cu+ ion is not stable in aqueous solution. ii) Ni2+ ion has lower magnetic moment than Co2+.
iii) Mn2+ salts are more stable than Mn3+ salts.
Q32. (a) Predict ‘X’ ‘Y’ and ‘Z’ of the following: (5)
X(alkene) HBr CH3-CH(Br)-CH3 Alc.KOH Y HBr/peroxide Z
(b) Distinguish 1-chloropropane and 1-iodopropane
(c) Convert Benzene to Benzyl alcohol.
(OR)
a) Arrange in increasing order of reactivity of the following compounds in SN1 reaction.
1-chloropropane, 2-chloropropane, 2-chloro-2-methylpropane. b) Compare the Boiling point of o-dichlorobenzene, p-dichlorobenzene and m-dichlorobenzene. c) The nature of the product of SN1 reaction is always optically inactive, why? d) Write the mechanism of the following reaction. (1+1+1+2) CH3Cl + KOH ------------ CH3OH + KCl
Q33. (a) Distinguish phenol and methanol (5)
(b) Convert 1-propanol to 2-chloropropane
(c) Complete the reaction
(i) C6H5-OH + Br2/H2O----------
heat (ii) (CH3)3C-OH + Cu--------------
(iii) CH3Cl + CH3ONa -------------
(OR)
(a) Arrange in increasing order of boiling point of the following compounds
1-butanol , 2-butanol, 2-methyl-2-propanol.
(b) Compare the reactivity of 1-butanol , 2-butanol, 2-methyl-2-propanol.
(c) Distinguish 2-propanol and 1-propanol by lucas reagent.
(d) Write the mechanism of the following reaction. (1+1+1+2)
