HHHHH
HHHHH
PART- I Workdone W T1 T2
Sol.
PHYSICS (Section-1) Heat sup plied Q T1
This section contains 20 questions numbered 1 to 20. 800 600 300
Each question has 4 choices (1), (2), (3) and (4), out of
Q 600
which ONLY ONE is correct.
Q = 1600 J
1. The temperature of a furnace is 2324o C and the
intensity is maximum in its radiation spectrum 5. If the total number of H 2 molecules is double
o
nearly at 12000 A . If the intensity in the that of the O 2 molecules then the ratio of total
spectrum of a star is maximum nearly at 4800 kinetic energies of H 2 to that of O 2 at 300 K is:
o
A , then the surface temperature of star is (1) 1: 1 (2) 1 : 2 (3) 2 : 1 (4) 1 : 16
Ans. 1
(1) 8400o C (2) 7200o C
f
(3) 6219.5o C (4) 5900o C Sol. Total K.E. = NKT
2
Ans. 3 T. K.E. N (no. of gas molecule)
1 o o
Sol. m 2593K 12000 A 4800 A T2
T R
o 6. For a gas 0.67 . This gas is made up of
T2 6592.5K 6219.5 A Cv
molecules which are
2. If the system takes 100 Cal. heat, and releases 80 (1) Diatomic
cal to sink, if source temperature is 127°C find (2) Mixture of diatomic and polyatomic
the sink temp molecules
(1) 47° C (2) 127° C (3) 67° C (4) 107° C (3) Monoatomic
Ans. 1 (4) Polyatomic
Q T Ans. 3
Sol. 1 2 1 2
Q1 T1 R
Sol. 0.67
Cv
T2 Q 2
T1 Q1 R 100 3
Cv R R
T2 80 0.67 67 2
So, f = 3
400 100
T2 320KK 47 o C 7. The lowest pressure (the best vaccum) that can
be created in laboratory at 27°C is 1011 mm of
3. A 2100 W continuous flow geyser (instant
Hg. At this pressure, the number of ideal gas
geyser) has water inlet temperature = 10°C while
molecules per cm3 , will be
the water flows out at the rate of 20 g/sec. The
outlet temperature of water must be (1) 3.22 1012 (2) 1.611012
(1) 20°C (2) 30°C (3) 35°C (4) 40°C (3) 3.21106 (4) 3.22 105
Ans. 3 Ans. 1
Sol. Water flow rate = 20 gm/sec Sol. PV NKT(P hg)
for 1 sec , Q = 2100 = 20 × 4.2 (t – 10)
N P hg 13.6 103 1011 103 10
t = 35°C
V KT KT 1.38 1023 300
N
4. A carnot engine working between 300 K and 600 32.8 1010 molecules / m3 or
K has work out put of 800 J per cycle. The V
amount of heat and energy supplied to the engine 32.8 104 molecules / cm3
from source per cycle will be
(1) 800 J (2) 1600 J (3) 1200 J (4) 900 J
Ans. 2
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JMTS PT-10 (26-Nov-24) 2
8. N molecules of an ideal gas at temperature T1 Ans. 1
and pressure P1 are contained in a closed box. If Sol. R1 (600) 4 (200) 4
the molecules in the box gets doubled, Keeping R 2 (400) 4 (200) 4
total kinetic energy as same then if new pressure
R 2 16 4 16 4 20 12
is P2 and temperature is T2 , Then
R1 36 4 36 4 40 32
(1) P2 P,T2 T1 (2) P2 P1 ,T2 T1 / 2
3
(3) P2 2P1 ,T2 T1 (4) P2 2P1 ,T2 T1 / 2 R2 R
16
Ans. 1
f
Sol. KE NKT same 12. A black body emits radiations of maximum
2 o
1 intensity at 5000 A when its temperature is
NT = constant T
N 1227o C . If its temperature is increased by
f 1000o C then the maximum intensity of emitted
KE PV same
2 radiation will be at:
V = const. then pressure is also constant. o o
(1) 2754.8 A (2) 3000 A
o o
9. For a black body at temperature 727°C, its
(3) 3500 A (4) 4000 A
radiating power is 60 watt and temperature of
Ans. 2
surrounding is 227°C. If temperature of black
Sol. m1T1 m2T2
body is changed to 1227°C then its radiating
power will be 5000 × 1500 = m2 2500
(1) 304 W (2) 320 W (3) 240 W (4) 120 W o
Ans. 2 m 2 3000 A
60 1000 500
4 4
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JMTS PT-10 (26-Nov-24) 4
20. Two elastic rods are joined between fixed 4
23. The volume of a poly-atomic gas
supports as shown in the figure. Condition for no 3
change in the lengths of individual rods with the
1
increase of temperature ( 1 , 2 = linear compressed adiabatically to th of the original
8
expansion co-efficient A1 ,A2 = Area of rods volume. If the original pressure of the gas is P0
y1 , y2 = Young modulus ) then new pressure is xP0 then find the value of
x.
Ans. 16
V
Sol. P1V1 P2 V2 P2 1 xP1
V2
4/3
A1 1 y1 A1 L11 y1 V
(1) (2) P2 xP0 16P0
A 2 2 y2 A 2 L22 y2 V /8
A1 L 2 2 y 2 A1 2 y 2
(3) (4) 24. On mixing 1 gm mole of a monoatomic with 1
A 2 L11 y1 A 2 1 y1
gm mole of a diatomic gas the specific heat of
Ans. 4
mixture at constant volume is xR then find the
Sol. Since tension is the two rods will be same, hence
value of x
A1y11 A2 y22 A1y11 A2 y22
Ans. 2
(Section-2) 1CV1 2 CV2
This section contains 5 questions numbered 21 to 25. Sol. CVmix
1 2
The answer of each question is a numeric
3 5
value/Integer type. 1 R 1 R
21. Two spheres P and Q, of same colour having CVmix 2 2 2R
11
radii 8 cm and 2 cm are maintained at
P1V1 P2 V2
temperatures 127°C and 527°C rspectively. The
ratio of energy radiated by P and Q is
Ans. 1
2 4 25. A liquid cools from 70ºC to 60ºC in 5 minutes.
E1 r12 T14 8 400
Sol. . Find the time (in minutes, in nearest integer) in
E 2 r22 T24 2 800 which it will further cool down to 50 ºC, if its
E1 surrounding is held at a constant temperature of
1
E2 30ºC.
Ans. 7
22. The work done by a gas taken through the closed 70 60 70 60
Sol. K 30
process ABCA, see figure, is xP0 V0 then find the 5 2
value of x 10
K[65 30] .....(i)
5
60 50
now K[65 30] ......(ii)
t
Dividing equation (i) and (ii)
t 35
5 25
Ans. 6 7
t 5 7 min
1 5
Sol. W 4P0 3V0 6P0 V0
2
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JMTS PT-10 (26-Nov-24) 5
PART- II Ans. 2
CHEMISTRY (Section-1) Sol. nCH2 CH2 (CH2 CH2 )n H 100KJ / mole
This section contains 20 questions numbered 26 to Double bond of ethylene converted to two single
45. Each question has 4 choices (1), (2), (3) and (4), out bonds.
of which ONLY ONE is correct. H 100 B.E.CC 2B.E.CC
26. The ratio of P to V at any instant is constant and 100 600 2 B.E.CC
is equal to 1, for a monoatomic ideal gas under
B.E.CC 350KJ / mole
going a process. What is the molar heat capacity
of the gas.
29. The reaction of chloroform with alcoholic KOH
3R 5R
(1) (2) 2R (3) (4) 0 and p–toluidine form
2 2
Ans. 2 (1)
Sol. From first law of Thermodynamics,
(2)
E q w nCvdT nCdT PdV .....(1)
Now according to process, P = V and according
(3)
to ideal gas equation, PV = nRT
We have, V2 nRT (4)
On differentiating, 2VdV = nRdT and PdV =
nRdT Ans. 4
VdV = Sol. It is carbylamine reaction.
2
So, from first equation we have,
nRdT
nCv dT nCdT
2
R
So, Cv C
2 30. A quantity of 1 g of water on evaporation at
4R atmospheric pressure forms 1671 cm3 of steam.
Hence, C
2 Heat of vaporization is 540 cal/g. The
approximate increase in internal energy is (1 L –
27. The enthalpy of neutralization of 40.0 g of NaOH atm = 24 cal)
by 60.0 g of CH3COOH will be (1) 250 cal (2) 500 cal
(1) 57.1 kJ eq 1 (3) 1000 cal (4) 1500 cal
Ans. 2
(2) less than 57.1 kJ eq 1
(3) more than 57.1 kJ eq 1 31. Predict which of the following reaction (s) has a
1 positive entropy change?
(4) 13.7 kJ eq
Ans. 2 I. Ag (aq) Cl (aq) AgCl(s)
Sol. Since it is neutralisation of a weak acid with II. NH4Cl(s) NH3 (g) HCl(g)
strong base. III. 2NH3 (g) N2 (g) 3H2 (g)
(1) I and II (2) III
28. Enthalpy of polymerisation of ethylene, as
(3) II and III (4) II
represented by the reaction,
Ans. 3
nCH2 CH2 (CH2 CH2 )n is -100 kJ per
mole of ethylene. Given bond enthalpy of C=C 32. If S O2 SO2 ; H 298.2kJ / mol
bond is 600 kJ mol1 , enthalpy of C-C bond (in 1
kJ/mol) will be : SO2 O2 SO3 ; H 98.7kJ / mol
2
(1) 116.7 (2) 350 SO3 H2O H2SO4 ; H 130.2kJ / mol
(3) 700 (4) indeterminate
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JMTS PT-10 (26-Nov-24) 6
1 136
H 2 O2 H 2O; H 287.3kJ / mol (3) (4) None of these
2 41
Then the enthalpy of formation of H2SO4 at 298 Ans. 1
K is- 5
C2 H5 O 2 2CO 2 H 2 O
(1) 814.4KJ (2) 650.3KJ Sol. 2
(3) 320.5KJ (4) 433.5KJ 4 mol 10 mol
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JMTS PT-10 (26-Nov-24) 7
(3) (4)
(3) (4)
Ans. 4
(1) Formation of A is electrophilic substitution 43. Given below are two statements, one is labelled
reaction as Assertion (A) and other is labelled as:- Reason
(2) Formation of B is nucleophilic substitution (R).
reaction Assertion (A): Gabriel phthalimide synthesis
(3) B is a brown colour dye cannot be used to prepare aromatic primary
(4) B is form by electrophilic substitution amines.
reaction Reason (R) : Aryl halides do not undergo
Ans. 4 nucleophilic substitution reaction.
In the light of the above statements, choose the
40. Product (D) will be : correct answer form the options given below.
(1) (A) is true but (R) is false
(2) (A) is false but (R) is true
(3) Both (A) and (R) are true but (R) is not the
correct explanation of (A).
(4) Both (A) and (R) are true and (R) is correct
(1) (2) explanation of (A).
Ans. 4
(3) (4) 44. Consider the reactions given below. On the basis
of these reactions find out which of the algebric
Ans. 3
relations given in options (A) to (D) is correct?
(a) C(g) 4H(g) CH 4 (g) ; r H x kJ mol 1
41. The structure of product X in the following
reaction is : (b) C(graphite,s) 2H 2 (g) CH 4 (g) ; r H y kJ mol 1
(1) x = y (2) x = 2y (3) x > y (4) x < y
Ans. 3
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JMTS PT-10 (26-Nov-24) 8
This section contains 10 questions numbered 46 to
50. The answer of each question is a numeric
value/Integer type.
46. For isothermal expansion of an ideal gas into
vacuum, among the following how many are
zero U, H, T,q, p ext , Ssur , Stotal , G sys , W
Ans. 68
Ans. 6 50. A sample of argon at 1 atm pressure and 27ºC
Sol. For free expansion since Ssys is non zero expands reversibly and adiabatically from
so Stotal & G sys are non zero. 1.25 dm3 to 2.50 dm 3 . Calculate the enthalpy
change in this process. (Use 22/3 1.587 )
47. Molecular weight of final product (Y) is Ans. –115.3
PART- III
MATHEMATICS (Section-1)
This section contains 20 questions numbered 51 to
Ans. 75 70. Each question has 4 choices (1), (2), (3) and (4), out
of which ONLY ONE is correct.
51. The number of permutations which can be
formed out of the letters of the word "SERIES"
Sol.
taking three letters together is
(1) 120 (2) 60 (3) 42 (4) none
Ans. 3
Sol. Number of Alphabets in the word SERIES
Molecular weight of Y = 75
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JMTS PT-10 (26-Nov-24) 9
P A B C P A P A B P A B C (1)
125
(2)
64
(3)
25
(4)
79
3p 287 127 287 192
P A B C p2 Ans. 1
2
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JMTS PT-10 (26-Nov-24) 10
Sol.
9! 9.8.7!
Number of possible arrangement 6.7!
2!3! 12
2 1 5 2 10 3 17 4 Arrangement of Boxes = 3!;
34 2 34 5 34 8 34 11 Arrangement of Balls in Box 3 = 4!
1 30 68 1 15 68 Total number of arrangement when no balls are
1 2 3
34 8 11 34 4 11 separated =3!.4!
Therefore number of arrangement when at least
1 132 165 272 569
one ball is separated = 6(7!-4!)
34 44 1496
61. The number of ways in which 15 apples & 10
58. Two dice are rolled simultaneously. The
oranges can be distributed among three persons,
probability that the sum of the two numbers on
each receiving none, one or more is
the top faces will be atleast 10 is
(1) 5670 (2) 7200
1 1 1 (3) 8976 (4) none of these
(1) (2) (3) (4) none
6 12 18 Ans. 3
Ans. 2 Sol. Distribution of ‘n’ identical balls into ‘k’ distinct
Sol. Favorable cases are (4,6), (6, 4), (5, 5), (5,6), (6, n r 1
boxes = Cr 1
5), (6,6) i.,e., total 6 favorable cases
Total cases = 6 × 6 = 36
Required probability = 6/36 = 1/6
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JMTS PT-10 (26-Nov-24) 11
63. Number of different words that can be formed Hence number of ways =
using all the letters of the word "DEEPMALA" 2 * C1 * 2!* C 4 * 4! 8 * 5!
2 5
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JMTS PT-10 (26-Nov-24) 12
7! 315 90 3 408 1
Total number of cases
3! 816 816 816 816 2
When three Es are clubbed and treated as a single
Pix Mean
2
Variance 2
i
entity
2
315 180 9 1 21 1 83
816 816 816 2 34 4 136
6!
Total number of cases
3!
Using Inclusion Exclusion
8! 7! 6! 6! 56 36 70. The number of triangles whose vertices are at the
20 C3
6
vertices of a regular decagon but none of whose
3!3! 3! 3! 3! 3!
sides is a side of the decaagon is -
(1) 45 (2) 50 (3) 55 (4) 60
68. Three randomly chosen non-negative integers x,
Ans. 2
y and z are found to satisfy the equation x + y +
z = 10. Then the probability that z is even, is
1 36 6 5
(1) (2) (3) (4)
2 55 11 11
Ans. 3 Sol.
Sol. x + y + z = 10 We have to choose 3 points from vertices of
z 0, x y 10 1031C31 12 C2 66 decagon such that no two chosen points are
For favourable cases, i.e., when z is even consecutive.
Required number of ways
z 0, x y 10 10 21C21 11C1 11cases
z 2, x y 8 8 21C 21 9 C1 9cases
z 4, x y 6 6 21C 2 1 7 C1 7cases
z 6, x y 4 5cases
z 8, x y 2 3cases
z 10, x y 0 1case
120 - 60 - 10 = 50
Favourable cases = 36
(Section-2)
36 6
? required probaility This section contains 10 questions numbered 71 to
66 11
75. The answer of each question is a numeric
value/Integer type.
69. Three rotten apples are accidently mixed with
71. There were two women participating in a chess
fifteen good apples. Assuming the random
tournament. Every participant played two games
variable x as the number of rotten apples in a
with the other participants. The number of games
draw of three apples, find variance of x
that the men played between themselves proved
47 83 1
(1) (2) (3) (4) None to exceed by 66 the number of games that the
153 136 4
men played with the women. The number of
Ans. 2
participants is
Sol. x = number of rotten apples in a draw of 3 apples
Ans. 13
x = 0, 1, 2, 3
Sol. Let there be n men participants. Then the
x 0 1 2 3
number of games that the men play between
15 3 3
C3 C1 15C1 3
C2 15
C1 C3 themselves is 2 . n C 2 and the number of games
P(x) 18 18 18 18
C3 C3 C3 C3
that the men played with the women is 2. (2n).
3 15 3 3
C 15C1
C C1 C
Mean Pi x i 181 2 182 3 18 3 2.n C2 2. (By hypothesis)
C3 C3 C3
2n 66
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JMTS PT-10 (26-Nov-24) 13
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JMTS PT-10 (26-Nov-24) 14
Recall Baye’s theorem
B
P P A
A
P
A
B P B
if K stands for KRISHNAGIRI and D for
DHARMAPURI
1
P K P D
2
We have two pairs of ‘RI’ in KRISHNAGIRI
We have one pairs of ‘RI’ in DHARMAPURI
RI 2 RI 1
P ison theletter , P ison theletter
K 10 D 9
RI
P isontheletter P K
K
P isontheletter
K
RI P RIisontheletter
2 1 2
10 2 9
10
2 1 1 1 2 1 14
10 2 9 2 10 9
*******
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