Scribd Logo
Upload

Welcome to Scribd!

  • 1 views

    Salt Analysis 5

    Uploaded by

    aryansengar97

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd

    Salt Analysis 5

    Uploaded by

    aryansengar97
    1 views2 pages

    Copyright

    © © All Rights Reserved

    Available Formats

    DOCX, PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    1 views2 pages

    Salt Analysis 5

    Uploaded by

    aryansengar97

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    of 2

    SALT ANALYSIS

    EXPERIMENT NO. 11

    AIM:
    To analyse one acidic radical (anion) and one basic radical (cation) in given inorganic salt.
    MATERIAL REQUIRED:
    BaCl2 solution, conc. HCl, lead acetate solution, ammonium acetate solution, H2S gas, NH4OH,NaOH,
    [K4Fe(CN)6] , test tube holder, test tube, burner, filter paper and funnel.
    OBSERVATION TABLE:
    a. Table for acidic radical:
    S.NO. EXPERIMENT OBSERVATION INFERENCE
    1. To the pinch of salt, add diluted H2SO4. No gas evolved. CO32-, SO32-, S2-,
    NO2- absent.
    2. To the fresh pinch of salt, add conc. No gas evolved. Cl-, Br-, I-, NO3-
    H2SO4. absent.
    3. To the salt solution, add 1-2 mL of BaCl2 A white precipitate SO42- may be
    solution. is formed. present.
    4. To the above precipitate, add conc. HCl or The precipitate is SO42- confirmed.
    conc. HNO3. insoluble.
    5. To the salt solution, add lead acetate A white precipitate SO42- confirmed.
    solution. is formed.
    6. To the above precipitate, add ammonium The precipitate SO42- confirmed.
    acetate solution in excess. dissolved.

    CHEMICAL EQUATIONS:
    1. SO42- + BaCl2 BaSO4 + 2Cl-
    (white ppt. insoluble in conc.HCl or conc. HNO3)
    2. SO42- + Pb(CH3COO)2 PbSO4 + CH3COO-
    (white ppt.)
    3. PbSO4 + 2CH3COONH4 Pb(COOCH3)2 + (NH4)2SO4

    a. Table for basic radical


    S.NO EXPERIMENT OBSERVATION INFERENCE
    1. To the pinch of salt, add NaOH No smell of ammonia Zero group (NH4+)
    solution. absent.
    2. To the salt solution add diluted HCl. No precipitate is First group (Pb2+)
    formed. absent.
    3. Pass H2S gas through above solution. no ppt. Second group
    (Cu2+,Hg2+, As3+, Cd2+)
    absent.
    4. Boil off H2S gas completely. Cool and No ppt. Third group
    then add NH4Cl (solid) and NH4OH (Al3+,Fe3+) absent.
    solution in excess.
    5. Pass H2S gas through above solution White ppt. Fourth group (Zn2+
    present)
    6. Filter the ppt. and dissolve it in dil. HCl
    and boil off H2S gas completely. Divide
    the solution in two parts:
    a. To the first part, add NaOH White ppt. soluble in Zn2+ is confirmed
    excess of NaOH
    b. To the second part, add
    NH4OH solution till the Bluish white ppt. Zn2+ is confirmed
    solution is neutralised and
    then add K4[Fe(CN)6] to it.

    CHEMICAL REACTIONS:
    Zn2+ +H2S ZnS +2H+
    (white ppt.)
    ZnS +2HCl ZnCl2 +H2S
    ZnCl2 +2NaOH Zn(OH)2 +2NaCl
    (white ppt.)
    Zn(OH)2 +2NaOH Na2ZnO2 +2H2O
    (soluble sodium zincate)
    2ZnCl2 + K4[Fe(CN)6] Zn2[Fe(CN)6] +4KCl
    (bluish white ppt.)
    Zinc ferrocyanide
    RESULT: The given inorganic salt contains:
    a. Acidic radical: SO42- (sulphate ion)
    b. Basic radical: Zn2+ (zinc ion)
    ==============================================================================

    You might also like