Chapter 1 - Introduction and Basic Concepts
Chapter 1 - Introduction and Basic Concepts
THERMODYNAMICS
Introduction and Basic Concepts
(Chapter One)
Classical thermodynamics: A
macroscopic approach to the study of
thermodynamics that does not require a
knowledge of the behavior of individual
particles.
All activities in nature involve some interaction between energy and matter;
thus, it is hard to imagine an area that does not relate to thermodynamics in
some manner. Department of Energy Engineering
8
1.1 THERMODYNAMICS AND
ENERGY
Application Areas of Thermodynamics
Some basic dimensions such as mass m, length L, time t, and temperature T are
selected as primary or fundamental dimensions, while others such as velocity
V, energy E, and volume V are expressed in terms of the primary dimensions and
are called secondary dimensions, or derived dimensions.
English system: It has no apparent systematic numerical base, and various units
in this system are related to each other rather arbitrarily.
W weight
m mass
g gravitational
acceleration
Unity conversion ratios are identically equal to 1 and are unit less, and thus such
ratios (or their inverses) can be inserted conveniently into any calculation to
properly convert units.
Specific gravity
The ratio of the density of a substance to the density of some standard substance
at a specified temperature (usually water at 4°C).
Density is
mass per unit
Specific volume volume;
specific volume
is volume per
unit mass.
Specific weight
The weight of a unit volume of a substance.
It is a common experience that a cup of hot coffee left on the table eventually
cools off and a cold drink eventually warms up.
All temperature scales are based on some easily reproducible states such as the
freezing and boiling points of water, which are also called the ice point and the
steam point, respectively.
A mixture of ice and water that is in equilibrium with air saturated with vapor at 1
atm pressure is said to be at the ice point.
A mixture of liquid water and water vapor (with no air) in equilibrium at 1 atm
pressure is said to be at the steam point.
The temperature scales used in the SI and in the English system today are the
Celsius scale and the Fahrenheit scale, respectively.
These are often referred to as two-point scales since temperature values are
assigned at two different points.
A temperature scale that turns out to be nearly identical to the Kelvin scale is the
ideal-gas temperature scale.
Solution:-
Given Data:
𝑅𝑅𝑅𝑅𝑅𝑅𝑅𝑅 𝑖𝑖𝑖𝑖 𝑡𝑡𝑡𝑡𝑡𝑡𝑡𝑡𝑡𝑡𝑡𝑡𝑡𝑡𝑡𝑡𝑡𝑡𝑡𝑡𝑡𝑡 = ∆𝑇𝑇 ℃ = 10 ℃
As we know:
∆𝑇𝑇 𝐾𝐾 = ∆𝑇𝑇 ℃
∆𝑇𝑇 𝐾𝐾 = 10 𝐾𝐾
Now:
∆𝑇𝑇 𝑅𝑅 = 1.8∆𝑇𝑇 𝐾𝐾
∆𝑇𝑇 𝑅𝑅 = 1.8 10
∆𝑇𝑇 𝑅𝑅 = 18 𝑅𝑅
Similarly:
∆𝑇𝑇 ℉ = ∆𝑇𝑇 𝑅𝑅
∆𝑇𝑇 ℉ = 18 ℉
Discussion: Note that the units ℃ and K are interchangeable when dealing with
temperature differences.
Solution:-
Given Data:
𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶 𝑖𝑖𝑖𝑖 ℎ𝑒𝑒𝑒𝑒𝑒𝑒𝑒𝑒𝑒 = ℎ = 740 𝑚𝑚𝑚𝑚𝑚𝑚𝑚𝑚 = 0.740 𝑚𝑚
𝐺𝐺𝐺𝐺𝐺𝐺𝐺𝐺𝐺𝐺𝐺𝐺𝐺𝐺𝐺𝐺𝐺𝐺𝐺𝐺𝐺𝐺𝐺𝐺𝐺𝐺 𝑎𝑎𝑎𝑎𝑎𝑎𝑎𝑎𝑎𝑎𝑎𝑎𝑎𝑎𝑎𝑎𝑎𝑎𝑎𝑎𝑎𝑎𝑎𝑎 = 𝑔𝑔 = 9.805 𝑚𝑚/𝑠𝑠 2
𝑇𝑇𝑇𝑇𝑇𝑇𝑇𝑇𝑇𝑇𝑇𝑇𝑇𝑇𝑇𝑇𝑇𝑇𝑇𝑇𝑇𝑇 = 𝑇𝑇 = 10 ℃
𝐷𝐷𝐷𝐷𝐷𝐷𝐷𝐷𝐷𝐷𝐷𝐷𝐷𝐷 = 𝜌𝜌 = 13,570 𝑘𝑘𝑘𝑘⁄𝑚𝑚3
As we know:
𝑃𝑃𝑎𝑎𝑎𝑎𝑎𝑎 = 𝜌𝜌𝑔𝑔𝑔
1 𝑁𝑁 1 𝑘𝑘𝑘𝑘𝑘𝑘
𝑃𝑃𝑎𝑎𝑎𝑎𝑎𝑎 = 13,570 𝑘𝑘𝑘𝑘⁄𝑚𝑚3 9.805 𝑚𝑚/𝑠𝑠 2 0.740 𝑚𝑚
1 𝑘𝑘𝑘𝑘 � 𝑚𝑚⁄𝑠𝑠 2 1000 𝑁𝑁⁄𝑚𝑚2
𝐴𝐴 = 98.5 𝑘𝑘𝑘𝑘𝑘𝑘
Solution:-
Given Data:
𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶 𝑖𝑖𝑖𝑖 ℎ𝑒𝑒𝑒𝑒𝑒𝑒𝑒𝑒𝑒 = ℎ = 1.2 𝑚𝑚
𝐷𝐷𝐷𝐷𝐷𝐷𝐷𝐷𝐷𝐷𝐷𝐷𝐷𝐷 = 𝜌𝜌 = 1,020 𝑘𝑘𝑘𝑘⁄𝑚𝑚3
(a) Gage pressure of the blood
𝑃𝑃𝑎𝑎𝑎𝑎𝑎𝑎 = 𝑃𝑃𝑎𝑎𝑎𝑎𝑎𝑎 + 𝑃𝑃𝑔𝑔𝑔𝑔𝑔𝑔𝑔𝑔, 𝑎𝑎𝑎𝑎𝑎𝑎
𝑃𝑃𝑔𝑔𝑔𝑔𝑔𝑔𝑔𝑔, 𝑎𝑎𝑎𝑎𝑎𝑎 = 𝑃𝑃𝑎𝑎𝑏𝑏𝑏𝑏 − 𝑃𝑃𝑎𝑎𝑎𝑎𝑎𝑎
Problems (Exercise):
i. Problem 1–102
ii. Problem 1–104
iii. Problem 1–110