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Peter Woit
Quantum Theory,
Groups and
Representations
An Introduction
Quantum Theory, Groups and Representations
Peter Woit
123
Peter Woit
Department of Mathematics
Columbia University
New York, NY
USA
This book began as course notes prepared for a class taught at Columbia
University during the 2012–13 academic year. The intent was to cover the
basics of quantum mechanics, up to and including relativistic quantum field
theory of free fields, from a point of view emphasizing the role of unitary
representations of Lie groups in the foundations of the subject. It has been
significantly rewritten and extended since that time, partially based upon
experience teaching the same material during 2014–15.
The approach to this material is simultaneously rather advanced, using
crucially some fundamental mathematical structures discussed, if at all, only
in graduate mathematics courses, while at the same time trying to do this in
as elementary terms as possible. The Lie groups needed are (with one crucial
exception) ones that can be described simply in terms of matrices. Much
of the representation theory will also just use standard manipulations of
matrices. The only prerequisite for the course as taught was linear algebra
and multivariable calculus (while a full appreciation of the topics covered
would benefit from quite a bit more than this). My hope is that this level of
presentation will simultaneously be useful to mathematics students trying to
learn something about both quantum mechanics and Lie groups and their
representations, as well as to physics students who already have seen some
quantum mechanics, but would like to know more about the mathematics
underlying the subject, especially that relevant to exploiting symmetry
principles.
The topics covered emphasize the mathematical structure of the subject
and often intentionally avoid overlap with the material of standard physics
courses in quantum mechanics and quantum field theory, for which many
excellent textbooks are available. This document is best read in conjunction
with such a text. In particular, some experience with the details of the physics
not covered here is needed to truly appreciate the subject. Some of the main
differences with standard physics presentations include the following:
v
vi Preface
• The role of Lie groups, Lie algebras, and their unitary representations is
systematically emphasized, including not just the standard use of these
to derive consequences for the theory of a “symmetry” generated by
operators commuting with the Hamiltonian.
• Symplectic geometry and the role of the Lie algebra of functions on
phase space in the classical theory of Hamiltonian mechanics are
emphasized. “Quantization” is then the passage to a unitary represen-
tation (unique by the Stone–von Neumann theorem) of a subalgebra of
this Lie algebra.
• The role of the metaplectic representation and the subtleties of the
projective factor involved are described in detail. This includes phe-
nomena depending on the choice of a complex structure, a topic known
to physicists as “Bogoliubov transformations.”
• The closely parallel story of the Clifford algebra and spinor represen-
tation is extensively investigated. These are related to the Heisenberg
Lie algebra and the metaplectic representation by interchanging com-
mutative (“bosonic”) and anticommutative (“fermionic”) generators,
introducing the notion of a “Lie superalgebra” generalizing that of a Lie
algebra.
• Many topics usually first encountered in physics texts in the context of
relativistic quantum field theory are instead first developed in simpler
non-relativistic or finite dimensional contexts. Non-relativistic quan-
tum field theory based on the Schrödinger equation is described in
detail before moving on to the relativistic case. The topic of irreducible
representations of space–time symmetry groups is first addressed with
the case of the Euclidean group, where the implications for the
non-relativistic theory are explained. The analogous problem for the
relativistic case, that of the irreducible representations of the Poincaré
group, is then worked out later on.
• The emphasis is on the Hamiltonian formalism and its
representation-theoretical implications, with the Lagrangian formalism
(the basis of most quantum field theory textbooks) de-emphasized. In
particular, the operators generating symmetry transformations are
derived using the moment map for the action of such transformations
on phase space, not by invoking Noether’s theorem for transformations
that leave invariant a Lagrangian.
• Care is taken to keep track of the distinction between vector spaces and
their duals. It is the dual of phase space (linear coordinates on phase
space) that appears in the Heisenberg Lie algebra, with quantization a
representation of this Lie algebra by linear operators.
Preface vii
• The distinction between real and complex vector spaces, along with the
role of complexification and choice of a complex structure, is system-
atically emphasized. A choice of complex structure plays a crucial part
in quantization using annihilation and creation operator methods,
especially in relativistic quantum field theory, where a different sort of
choice than in the non-relativistic case is responsible for the existence of
antiparticles.
Some differences with other mathematics treatments of this material are as
follows:
• A fully rigorous treatment of the subject is not attempted. At the same
time, an effort is made to indicate where significant issues arise should
one pursue such a treatment, and to provide references to rigorous
discussions of these issues. An attempt is also made to make clear the
difference between where a rigorous treatment could be pursued rela-
tively straightforwardly and where there are serious problems of prin-
ciple making a rigorous treatment hard to achieve.
• The discussion of Lie groups and their representations is focused on
specific examples, not the general theory. For compact Lie groups,
emphasis is on the groups Uð1Þ; SOð3Þ; SUð2Þ and their finite dimen-
sional representations. Central to the basic structure of quantum
mechanics are the Heisenberg group, the symplectic groups Spð2n; R)
and the metaplectic representation, as well as the spinor groups and the
spin representation. The geometry of space–time leads to the study of
Euclidean groups in two and three dimensions, and the Lorentz (SO
(3,1)) and Poincaré groups, together with their representations. These
examples of non-compact Lie groups are a fundamental feature of
quantum mechanics, but not a conventional topic in the mathematics
curriculum.
• A central example studied thoroughly and in some generality is that
of the metaplectic representation of the double cover of Spð2n; R) (in
the commutative case), or spin representation of the double cover of
SOð2n; R) (anticommutative case). This specific example of a repre-
sentation provides the foundation of quantum theory, with quantum
field theory involving a generalization to the case of n infinite.
• No attempt is made to pursue a general notion of quantization, despite
the great mathematical interest of such generalizations. In particular,
attention is restricted to the case of linear symplectic manifolds. The
linear structure plays a crucial role, with quantization given by a rep-
resentation of a Heisenberg algebra in the commutative case and a
Clifford algebra in the anticommutative case. The very explicit methods
used (staying close to the physics formalism) mostly do not apply to
viii Preface
0.1 Acknowledgements
The students of Mathematics W4391-2 at Columbia during 2012–13 and
2014–15 deserve much of the credit for the existence of this book and for
whatever virtues it might have. Their patience with and the interest they
took in what I was trying to do were a great encouragement, and the many
questions they asked were often very helpful. The reader should be aware that
the book they have in their hands, whatever its faults, is a huge improvement
over what these students had to put up with.
The quality of the manuscript was dramatically improved over that of
early versions through the extreme diligence of Michel Talagrand, who early
on took an interest in what I was doing, and over a long period of time
carefully read over many versions. His combination of encouragement and
extensive detailed criticism was invaluable. He will at some point be pub-
lishing his own take on many of the same topics covered here ([91]), which I
can’t recommend enough.
At some point I started keeping a list of those who provided specific
suggestions, it includes Kimberly Clinch, Art Brown, Jason Ezra Williams,
Mateusz Wasilewski, Gordon Watson, Cecilia Jarlskog, Alex Purins, James
Van Meter, Thomas Tallant, Todor Popov, Stephane T’Jampens, Cris
Moore, Noah Miller, Ben Israeli, Nigel Green, Charles Waldman, Peter
Grieve, Kevin McCann, Chris Weed, Fernando Chamizo, and various
anonymous commenters on my blog. My apologies to others who I’m sure
that I’ve forgotten.
The illustrations were done in TikZ by Ben Dribus, who was a great
pleasure to work with.
Much early enthusiasm and encouragement for this project was provided
by Eugene Ha at Springer. Marc Strauss and Loretta Bartolini have been the
ones there who have helped to finally bring this to a conclusion.
Preface ix
Preface . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . v
0.1 Acknowledgements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . viii
1 Introduction and Overview . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
1.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
1.2 Basic principles of quantum mechanics . . . . . . . . . . . . . . . 3
1.2.1 Fundamental axioms of quantum mechanics . . . . . 3
1.2.2 Principles of measurement theory . . . . . . . . . . . . . 5
1.3 Unitary group representations . . . . . . . . . . . . . . . . . . . . . . 6
1.3.1 Lie groups . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
1.3.2 Group representations . . . . . . . . . . . . . . . . . . . . . . 7
1.3.3 Unitary group representations . . . . . . . . . . . . . . . . 10
1.4 Representations and quantum mechanics . . . . . . . . . . . . . 11
1.5 Groups and symmetries . . . . . . . . . . . . . . . . . . . . . . . . . . 12
1.6 For further reading . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
2 The Group Uð1Þ and its Representations . . . . . . .. . . . . . . . . . . 15
2.1 Some representation theory . . . . . . . . . . . . .. . . . . . . . . . . 16
2.2 The group Uð1Þ and its representations . . . .. . . . . . . . . . . 19
2.3 The charge operator . . . . . . . . . . . . . . . . . .. . . . . . . . . . . 21
2.4 Conservation of charge and Uð1Þ symmetry . . . . . . . . . . . 24
2.5 Summary . . . . . . . . . . . . . . . . . . . . . . . . . .. . . . . . . . . . . 25
2.6 For further reading . . . . . . . . . . . . . . . . . . .. . . . . . . . . . . 26
3 Two-state Systems and SUð2Þ . . . . . . . . . . . . . . . . . . . . . . . . .. 27
3.1 The two-state quantum system . . . . . . . . . . . . . . . . . . . .. 28
3.1.1 The Pauli matrices: observables of the two-state
quantum system . . . . . . . . . . . . . . . . . . . . . . . . .. 28
3.1.2 Exponentials of Pauli matrices: unitary
transformations of the two-state system . . . . . . .. 30
xi
xii Contents
1.1 Introduction
A famous quote from Richard Feynman goes “I think it is safe to say that
no one understands quantum mechanics.” [22]. In this book, we will pursue
one possible route to such an understanding, emphasizing the deep connec-
tions of quantum mechanics to fundamental ideas of modern mathematics.
The strangeness inherent in quantum theory that Feynman was referring
to has two rather different sources. One of them is the striking disjunction
and incommensurability between the conceptual framework of the classical
physics which governs our everyday experience of the physical world, and the
very different framework which governs physical reality at the atomic scale.
Familiarity with the powerful formalisms of classical mechanics and electro-
magnetism provides deep understanding of the world at the distance scales
familiar to us. Supplementing these with the more modern (but still “classi-
cal” in the sense of “not quantum”) subjects of special and general relativity
extends our understanding into other much less familiar regimes, while still
leaving atomic physics a mystery.
Read in context though, Feynman was pointing to a second source of dif-
ficulty, contrasting the mathematical formalism of quantum mechanics with
that of the theory of general relativity, a supposedly equally hard to under-
stand subject. General relativity can be a difficult subject to master, but its
mathematical and conceptual structure involves a fairly straightforward ex-
tension of structures that characterize nineteenth-century physics. The fun-
damental physical laws (Einstein’s equations for general relativity) are ex-
pressed as partial differential equations, a familiar if difficult mathematical
subject. The state of a system is determined by a set of fields satisfying these
equations, and observable quantities are functionals of these fields. The math-
ematics is largely that of the usual calculus: differential equations and their
real-valued solutions.
c Peter Woit 2017 1
P. Woit, Quantum Theory, Groups and Representations,
DOI 10.1007/978-3-319-64612-1 1
2 1 Introduction and Overview
likely seem rather mystifying to those meeting them for the first time. As we
work through basic examples in the coming chapters, a better understanding
of the overall picture described here should start to emerge.
We will sometimes use the notation introduced by Dirac for vectors in the
state space H: Such a vector with a label ψ is denoted
4 1 Introduction and Overview
|ψ
d
i |ψ(t) = H|ψ(t) (1.1)
dt
The operator H has eigenvalues that are bounded below.
is large. This is true for the energy and time scales encountered in everyday
life, but it can also always be achieved by taking → 0, and this is what will
often be referred to as the “classical limit.” One should keep in mind though
that the manner in which classical behavior emerges out of quantum theory
in such a limit can be a very complicated phenomenon.
This principle identifies the states we have some hope of sensibly associ-
ating a label to (the eigenvalue), a label which in some contexts corresponds
to an observable quantity characterizing states in classical mechanics. The
observables with important physical significance (for instance, the energy,
momentum, angular momentum, or charge) will turn out to correspond to
some group action on the physical system.
Principle (The Born rule). Given an observable O and two unit-norm states
|ψ1 and |ψ2 that are eigenvectors of O with distinct eigenvalues λ1 and λ2
c1 |ψ1 + c2 |ψ2
will not have a well-defined value for the observable O. If one attempts to
measure this observable, one will get either λ1 or λ2 , with probabilities
|c21 |
|c21 |+ |c22 |
and
|c22 |
|c21 | + |c22 |
respectively.
The Born rule is sometimes raised to the level of an axiom of the theory, but
it is plausible to expect that, given a full understanding of how measurements
work, it can be derived from the more fundamental axioms of the previous
section. Such an understanding though of how classical behavior emerges in
experiments is a very challenging topic, with the notion of “decoherence”
playing an important role. See the end of this chapter for some references
that discuss these issues in detail.
Note that the state c|ψ will have the same eigenvalues and probabilities
as the state |ψ, for any complex number c. It is conventional to work with
states of norm fixed to the value 1, which fixes the amplitude of c, leaving
a remaining ambiguity which is a phase eiθ . By the above principles, this
phase will not contribute to the calculated probabilities of measurements.
We will, however, not take the point of view that this phase information can
just be ignored. It plays an important role in the mathematical structure, and
the relative phase of two different states certainly does affect measurement
probabilities.
If the set has a finite number of elements, this is called a “finite group.”
The theory of these and their use in quantum mechanics is a well-developed
subject, but one we mostly will bypass in favor of the study of “Lie groups,”
which have an infinite number of elements. The elements of a Lie group make
up a geometrical space of some dimension, and choosing local coordinates on
the space, the group operations are given by differentiable functions. Most of
the Lie groups we will consider are “matrix groups,” meaning subgroups of
the group of n by n invertible matrices (with real or complex matrix entries).
The group multiplication in this case is matrix multiplication. An example
we will consider in great detail is the group of all rotations about a point
in three-dimensional space, in which case such rotations can be identified
with 3 by 3 matrices, with composition of rotations corresponding to the
multiplication of matrices.
and
e·x=x
(g · f )(x) = f (g −1 · x) (1.3)
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