Unit-05-রাসায়নিক বন্ধন
Unit-05-রাসায়নিক বন্ধন
Unit-05-রাসায়নিক বন্ধন
Chemical Bond 5
f~wgKv (Introduction)
c`v_© gvÎB AmsL¨ cigvYyi GK mv‡_ AYy wn‡m‡e Ave× _vKvi GKwU ¯’vqx Ae¯’v| Z‡e wbw®Œq M¨vm¸‡jv GK
cigvYyK Abyiƒ‡c cÖK„wZ‡Z ¯’vqxiƒ‡c Ae¯’vb K‡i| Avgv‡`i Pvwicv‡k¦© evqy‡Z †h bvB‡Uªv‡Rb Aw·‡Rb, nvB‡Wªv‡Rb,
†K¬vwib BZ¨vw` M¨vm¸‡jv Av‡Q Giv cÖ‡Z¨‡KB †gŠwjK M¨vm AYy| †gŠwjK M¨v‡mi AYy¸‡jv wØcigvYyK AYy| †hgb-
N 2 , O2 , H 2 , F2 , Cl2 BZ¨vw`| I‡Rvb O3 , dmdivm P4 , mvjdvi S8 GivI †gŠwjK AYy wKš‘ eny
cigvYyK AYy| Avevi cvwb H 2O , Lvevi jeY NaCl Kve©b WvB-A·vBW CO2 , wg‡_b CH 4 ,
A¨v‡gvwbqv NH3 , A¨v‡gvwbqvg †K¬vivBW NH 4Cl cÖf…wZ †hŠ‡Mi AYy‡Z wfbœ wfbœ †gŠ‡ji cigvYy wg‡j
AYyMVb K‡i‡Q| Zvn‡j Avgiv wbðqB ej‡ev GKB ai‡bi `yB ev Z‡ZvwaK cigvYy GK‡Î wgwjZ n‡q †gŠ‡ji
GKwU AYy m„wó K‡i Ges wfbœ ai‡bi `yB ev Z‡ZvwaK cigvYyi ms‡hvR‡bi d‡j †hŠ‡Mi AYy Drcbœ K‡i| me AYyi
g‡a¨B cigvYy¸‡jv GK we‡kl AvKl©b e‡ji Øviv ci¯úi ci¯ú‡ii mv‡_ hy³ _v‡K| Gfv‡e GKB ev wfbœ wfbœ
†gŠ‡ji `yB ev Z‡ZvwaK cigvYy wgwjZ n‡q ivmvqwbK e܇bi m„wó nq| Avevi GKB †gŠ‡ji AmsL¨ cigvYy
ci¯úi hy³ n‡qI ivmvqwbK eÜb m„wó Ki‡Z cv‡i| †hgb- avZe eÜb|
GB BDwb‡Ui cvVmg~n
cvV - 5.1 : ivmvqwbK eÜb I ivmvqwbK eÜb MV‡bi KviY
cvV - 5.2 : AvqwbK eÜb
cvV - 5.3 : mg‡hvRx eÜb
cvV - 5.4 : AvqwbK I mg‡hvRx †hŠ‡Mi ˆewkó¨
cvV - 5.5 : avZe eÜb
I‡cb ¯‹zj GmGmwm †cÖvMÖvg
D‡Ïk¨
gyL¨ kã AvqwbK eÜb, †hvR¨Zv ¯Íi, AóK wbqg, `yB Gi wbqg, AvKl©Y, myw¯’Z, †kqvi
cÖ‡Z¨KwU wbw¯Œq M¨v‡mi me©ewn:¯’ K‡ÿ ns2 np6 B‡jKUªb eZ©gvb| GLv‡b n 2,3,4 BZ¨vw`| me©ewn:¯’ K‡ÿ
Giƒc ns2 np6 B‡jKUªb web¨vmB wbw¯Œq M¨v‡m cigvYyi AwaK myw¯’wZi KviY| G MVbB wb¤œ kw³ m¤úbœ| Ab¨vb¨
†gŠ‡ji cigvYy¸‡jvI B‡jKUª‡bi `vb, MÖnY, †kqvi ev Ab¨ †h †Kv‡bv fv‡e wbw¯Œq M¨v‡mi B‡jKUªb MVb KvVv‡gv
jv‡fi cÖebZv †`Lvq A_v©r cigvYyi me©ewn:¯’ kw³¯Í‡ii AóK Ac~Y©Zv †_‡K AóK c~Y©Zv cÖvwßi cÖebZv †`Lvq|
GUvB ivmvqwbK eÜb MV‡bi g~j KviY| cÖK…Zc‡ÿ cigvYy¸‡jv eÜb MV‡bi gva¨‡gB w¯’wZkxj nq| G Kvi‡b
mvaviYZ avZe-AavZe †gŠj AvqwbK eÜb, AavZe †gŠj-AavZe †gŠj mg‡hvRx eÜb Ges avZe L‡Ûi g‡a¨
avZe cigvYy¸‡jv avZe e܇bi gva¨‡g ci¯ú‡ii mv‡_ Ave× _v‡K|
Avgiv wbðq wjw_qvg, Li 3 I †K¬vwib, Cl 17 Gi B‡jKUªb web¨vm Rvwb| Zvn‡j G `ywU †gŠ‡ji B‡jKUªb
web¨vm K‡i †`wL-
Li 3 1s 2 2s1 ev He2 s1
Cl 17 1s2 2s2 2 p6 3s2 3 p5
Li cigvYy GKwU gvÎ B‡jKUªb‡K `vb K‡i Li Avq‡b cwibZ nq Ges wbw¯Œq †gŠj He Gi B‡jKUªb MVb jvf
K‡i|
Li 3 Li He e
wecixZfv‡e Cl cigvYy GKwU gvÎ B‡jKUªb‡K MÖnY K‡i Cl Avq‡b cwiYZ nq Ges wbw®Œq †gŠj Ar Gi
B‡jKUªbxq MVb jvf K‡i|
Cl 17 e Cl Ar
Li Avq‡bi †ÿ‡Î He Gi MVb I Cl Avq‡bi †ÿ‡Î Ar Gi MVb KvVv‡gv cÖvwßi gva¨‡g AwaK w¯’wZkxj
nq|
Li Avqb I Cl Avqb w¯’i ˆe`y¨wZK AvKl©b e‡ji gva¨‡g hy³ n‡q LiCl †hŠM MVb K‡i|
Avgiv Av‡iv GKwU mnR D`vniY D‡jøL Kwi| †mvwWqvg, Na 11 I †K¬vwib, Cl 17 Gi †ÿ‡Î
Na 11 1s2 2s2 2 p6 3s1 ev Ne 3s1
Cl 17 1s2 2s2 2 p 6 3s2 3 p5
Na cigvYyi †hvR¨Zv¯Íi 3q kw³| G ¯Í‡ii 3s AiweUv‡j GKwU gvÎ B‡jKUªb eZ©gvb, Na cigvYy GKwU gvÎ
B‡jKUªb‡K `vb K‡i Na Avq‡b cwiYZ nq Ges wbw®Œq †gŠj Ne Gi B‡jKUªbxq MVb cÖvß nq| Avi Cl
cigvYy, Na Gi `vb Kiv B‡jKUªb‡K MÖnY K‡i Cl Avq‡b cwiYZ nq Ges wbw¯Œq †gŠj Ar Gi B‡jKUªbxq
MVb cÖvß nq|
Na 11 Na Ne e
Cl 17 e Cl Ar
Na Avq‡bi †ÿ‡Î Ne Gi MVb I Cl Avq‡bi †ÿ‡Î Ar Gi MVb KvVv‡gv cÖvwßi gva¨‡g AwaK w¯’wZkxj
nq| Na Avqb I Cl Avqb w¯’i ˆe`y¨wZK AvKl©Y e‡ji gva¨‡g hy³ n‡q NaCl †hŠM MVb K‡i|
ivmvqwbK eÜb 71
I‡cb ¯‹zj GmGmwm †cÖvMÖvg
G‡Zv †Mj `vb Avi MÖnY| Gevi hw` H cigvYyi K_v awi, Z‡e H -cigvYy †hŠ‡Mi ev †gŠ‡ji AYy MV‡bi mgq
wbwðqB †m Zvi wbKUgZ wbw®Œq †gŠj He Gi B‡jKUªbxq MVb jvf Ki‡Z PvB‡e| GRb¨ H -cigvYy
¯^vfvweKfv‡e GKwU B‡jKUªb MÖnY Ki‡e A_ev H -cigvYyi B‡jKUªbwU Ab¨ Avi GKwU cigvYyi B‡jKUª‡bi
mv‡_ †kqvi Ki‡e|
H 2 AYyi MV‡bi †ÿ‡Î-
H 1 1s1
x
H + H > H x H mJ
ev H H ev H2
G †_‡K Avgiv Kx eyS‡Z cvijvg? wewfbœ †gŠ‡ji cigvYy wb‡R‡`i g‡a¨ B‡jKUªb `vb-MÖnY Ges †kqv‡ii gva¨‡g
cigvYyi †kl kw³¯Í‡i 2 wU A_ev †ewki fvM‡ÿ‡Î AvUwU B‡jKUª‡bi web¨vm jvf K‡i| Gfv‡e cigvYyi †hvR¨Zv
¯Í‡i He Gi B‡jKUªbxq MVb KvVv‡gv jvf Kiv‡K `yB Gi wbqg Duplet or duet Rule Ges †hvR¨Zv ¯Í‡i 8
wU B‡jKUªb web¨vm jvf Kiv‡K AóK wbqg Octet Rule e‡j|
g‡b ivL‡eb-
1| †Kv‡bv †gŠ‡ji cigvYyi †hvR¨Zv¯Í‡ii B‡jKUªb eÜb MV‡b Ask MÖnb K‡i|
2| me cigvYyi jÿ¨ GKwU B‡jKUªb MÖnb, eR©b ev †kqv‡ii gva¨‡g Zvi wbKUeZ©x wbw®Œq †gŠ‡ji B‡jKUªbxq MVb
cÖvß nIqvi cÖebZv|
3| cigvYy ivmvqwbK e܇b AskMÖn‡bi gva¨‡g `yB Gi wbqg ev AwaK wbqg c~Y© K‡i _v‡K|
ivmvqwbK eÜb MV‡bi Kvib Av‡jvPbv n‡jv, Gevi wbwðqB Avcbviv ivmvqwbK eÜb Kv‡K e‡j eyS‡Z †c‡i‡Qb|
†h AvKl©Y e‡ji Øviv AYy‡Z ev †Kv‡bv c`v‡_© cigvYy ev Avqb¸‡jv hy³ _v‡K Zv‡K ivmvqwbK eÜb
Chemical bond e‡j|
mvi-ms‡¶c :
`yB Gi wbqg: †gŠ‡ji cigvYy wb‡R‡`i g‡a¨ B‡jKUªb `vb ev MÖnY ev †kqv‡ii gva¨‡g cigvYyi †kl
kw³¯Í‡i 2wU B‡jKUªb jvf K‡i| A_v©r He Gi B‡jKUªbxq MVb KvVv‡gv jvf K‡i|
AóK wbqg: cigvYy wb‡R‡`i g‡a¨ B‡jKUªb `vb, MÖnY Ges †kqv‡ii gva¨‡g cigvYyi †kl kw³¯Í‡i 8wU
B‡jKUªb web¨vm jvf Kiv‡K AóK wbqg e‡j|
†hvR¨Zv: †Kv‡bv GKwU cigvYyi eÜb MV‡bi ÿgZv‡K Zvi †hvR¨Zv e‡j|
†hvR¨Zv B‡jKUªb: †Kv‡bv cigvYyi me©ewn:¯’ kw³¯Í‡i eZ©gvb B‡jKUªb ¸‡jv‡K †hvR¨Zv B‡jKUªb e‡j|
cv‡VvËi g~j¨vqb-5.1
ivmvqwbK eÜb 73
I‡cb ¯‹zj GmGmwm †cÖvMÖvg
Na Avqb I Cl Avqb `ywU wecixZ ag©x Avavb hy³ Avqb| G wecixZagx© Avav‡bi g‡a¨ w¯’i ˆe`y¨wZK AvKl©Y
e‡ji gva¨‡g AvqwbK e܇bi m„wó nq Ges NaCl AYy MwVZ nq|
MgCl2 AYyi †ÿ‡ÎI AvqwbK e܇bi gva¨‡g AYy MVb KvVv‡gv m„wó nq|
Mg 12 1s2 2s2 2 p 6 3s 2 ev Ne 3s 2
Cl 17 1s2 2s 2 2 p 6 3s 2 3 p5
`ywU cigvYy hLb KvQvKvwQ Av‡m ZLb g¨vM‡bwmqvg cigvYy Zvi †hvR¨Zv¯Íi Z…Zxq kw³¯Í‡ii 3s AiweUv‡ji
B‡jKUªb `ywU †K¬vwib cigvYy‡K `vb K‡i| †K¬vwib `vb K…Z B‡jKUªb‡K MÖnY K‡i Cl Avq‡b cwiYZ nq| Mg
cigvYy 3q kw³¯Í‡ii 3 p AiweUv‡j B‡jKUªb `ywU‡K ¯’vb †`q| Mg 2 I Cl AóK bxwZ Abymib K‡i|
Mg 2 Avqb I Cl Avqb `ywU hy³ n‡q MgCl2 Drcbœ K‡i|
ivmvqwbK eÜb 75
I‡cb ¯‹zj GmGmwm †cÖvMÖvg
mvi-ms‡¶c :
AvqwbK eÜb: `ywU wecixZagx© Avav‡bi g‡a¨ w¯’i ˆe`y¨wZK AvKl©‡Yi gva¨‡g †h e܇bi m„wó nq Zv‡K
AvqwbK eÜb e‡j|
K¨vUvqb: abvZœK Avavb hy³ cigvYyi Avqb‡K K¨vUvqb e‡j|
A¨vbvqb: FYvZœK Avavb hy³ cigvYyi Avqb‡K A¨vbvqb e‡j|
cv‡VvËi g~j¨vqb-5.2
+ +
A B
x
H + H > ev H H
H x H mJ
wPÎ 1: B‡jKUªb †kqvi K‡i H2 AYy MVb|
ivmvqwbK eÜb 77
I‡cb ¯‹zj GmGmwm †cÖvMÖvg
GKwU †d¬vwib F cigvYyi wØZxq kw³¯Íi ev †hvR¨Zv¯Í‡i mvZwU B‡jKUªb eZ©gvb _v‡K|
F 9 1s 2 2s 2 2 p5
F cigvYyi †hvR¨Zv¯Í‡ii we‡Rvo B‡jKUª‡bi mv‡_ H cigvYyi we‡Rvo B‡jKUªb †kqvi Ki‡j F Gi AóK
bxwZ c~Y©Zv nq Ges H Gi `yB Gi bxwZ c~Y©Zv nq|
H F H F
.. .. ..
.. F . + . . .
..
F
ev . F
> . .F. F mJ .. F ev
F2
O cigvYyi †hvR¨Zv¯Íi 2q kw³¯Íi| G ¯Í‡i `ywU we‡Rvo B‡jKUªb eZ©gvb| `ywU H cigvYyi cÖ‡Z¨‡Ki 1s
AiweUv‡ji we‡Rvo B‡jKUª‡bi mv‡_ O Gi `ywU we‡Rvo B‡jKUªb †kqvi K‡i cvwb H2 O Gi AYyi m„wó nq|
H 2O AYy‡Z Aw·‡Rb cigvYy AóKbxwZ Ges cÖwZwU nvB‡Wªv‡Rb cigvYy `yB Gi bxwZ †g‡b P‡j‡Q|
g‡b ivL‡eb: †Kv‡bv cigvYyi †hvR¨Zv¯Í‡ii we‡Rvo B‡jKUªb eÜb MV‡b Ask MÖnY K‡i| cigvYyi †hvR¨Zv¯Í‡ii
†Rvo B‡jKUªb eÜb MV‡b Ask MÖnY K‡i bv| G B‡jKUªb‡K wb:m½ B‡jKUªb †Rvo ev gy³ †Rvo B‡jKUªb e‡j|
H 2O AYy‡Z O cigvYy‡Z 2wU wb:m½ B‡jKUªb †Rvo _v‡K| Avevi NH3 AYy‡Z N cigvYyi 1wU wb:m½
B‡jKUªb †Rvo _v‡K| HF AYy‡Z F cigvYyi wb:m½ B‡jKUªb †Rv‡oi msL¨v wZbwU|
G Av‡jvPbvi ci wbwðqB Avgiv eyS‡Z †c‡iwQ mg‡hvRx eÜb Avm‡j Kx? Avmj K_v n‡jv `ywU cigvYyi
ivmvqwbK ms‡hv‡Mi mgq hw` Dfq cigvYy mgvb msL¨K B‡jKUªb †kqvi K‡i GK ev GKvwaK B‡jKUªb †Rvo
MVb K‡i Ges G B‡jKUªb †Rvo Dfq cigvYy mgvb fv‡e †kqvi K‡i Df‡qB wbw®Œq M¨v‡mi MVb KvVv‡gv jvf
K‡i Z‡e Gi d‡j Zv‡`i g‡a¨ †h ivmvqwbK e܇bi m„wó nq Zv‡K mg‡hvRx eÜb e‡j|
mg‡hvRx e܇bi †ÿ‡Î GKwU gvÎ B‡jKUªb †Rvo †kqvi K‡i MwVZ eÜb‡K GKK eÜb e‡j| †hgb-
H 2 , F2 , Cl2 , HF , HCl cÖf…wZ AYy‡Z GKK eÜb eZ©gvb| GKBfv‡e `ywU I wZbwU B‡jKUªb †Rvo †kqvi K‡i
MwVZ eÜb‡K h_vµ‡g wØeÜb I wÎeÜb e‡j| D`vniY¯^iƒc O2 , CO, CO2 , CH 2 CH 2 cÖfw… Z AYy‡Z wØeÜb
Ges N 2 I CH CH AYy‡Z wÎeÜb eZ©gvb|
we›`y I µ‡mi mvnv‡h¨ O2 AYyi MVb †`Lv‡bv hvK- O cigvYyi cvigvYweK msL¨v 8 Ges Dnvi B‡jKUªb
web¨vm-
O 8 1s 2 2s 2 2 p4
.. .. ..
. O. + .. O mJ O = O ev
..
O > O
.. ev ..
O2
GLv‡b O2 AYy‡Z `ywU Aw·‡Rb cigvYy cÖ‡Z¨‡K `ywU K‡i we‡Rvo B‡jKUªb †kqvi K‡i AóK bxwZ c~Y© K‡i‡Q|
Avevi `ywU Aw·‡Rb cigvYyi †kqv‡i Ask MÖnbKvix PviwU B‡jKUªb wØeÜb MVb K‡i‡Q|
we›`y I µ‡mi mvnv‡h¨ N 2 AYyi MVb †`Lv‡bv hvK N cigvYyi cvigvYweK msL¨v 7 Ges Dnvi B‡jKUªb web¨vm-
N 7 1s 2 2s 2 2 p3
.. .. ..
.N . .. O
= ev
.. + mJ O O N2
O O
N > O
N N ev N
.. N
..
GLv‡b N 2 AYy‡Z `ywU bvB‡Uªv‡Rb cigvYy cÖ‡Z¨‡K wZbwU K‡i we‡Rvo B‡jKUªb †kqvi K‡i AóKbxwZ c~Y© K‡i‡Q|
Avi `ywU bvB‡Uªv‡Rb cigvYyi †kqv‡i AskMÖnYKvix QqwU B‡jKUªb wÎeÜb MVb K‡i _v‡K|
wb‡R wb‡R Kiæb:
wkÿv_©xi KvR WU I µ‡mi mvnv‡h¨ CO, CH 2 CH 2 , CO2 , CH CH AYyi MVb KvVv‡gv
†`Lvb|
mg‡hvRx e܇bi d‡j MwVZ †gŠwjK AYy †hgb H 2 , F2 , Cl2 , O2 , N 2 G‡`i‡K mg‡hvRx AYy e‡j| mg‡hvRx
e܇bi d‡j MwVZ †hŠM‡K mg‡hvRx †hŠM e‡j| †hgb- CO, CO2 , NH 3 , H 2O, CH 4 , CH 3 CH 3 (B‡_b),
CH 2 CH 2 (Bw_b), CH CH (B_vBb) BZ¨vw`| mg‡hvRx †hŠ‡Mi AYy Kÿ ZvcgvÎvq M¨vmxq, Zij I
KwVb G wZb Ae¯’v‡ZB _vK‡Z cv‡i| CO, CO2 , NH 3 , CH 4 , CH 3 CH 3 , CH 2 CH 2 , CH CH Gi
ivmvqwbK eÜb 79
I‡cb ¯‹zj GmGmwm †cÖvMÖvg
mvi-ms‡¶c :
mg‡hvRx eÜb: `ywU AavZe †gŠ‡ji cigvYyi †hvR¨Zv ¯Í‡ii we‡Rvo B‡jKUªb‡K Dfq cigvYyB †kqvi K‡i
†h ivmvqwbK eÜb m„wó K‡i Zv‡K mg‡hvRx eÜb e‡j|
eÜb MVb: cigvYyi †hvR¨Zv¯Í‡ii we‡Rvo B‡jKUªb eÜb MV‡b AskMÖnY K‡i|
GKK eÜb: `ywU cigvYyi cÖ‡Z¨‡Ki 1wU K‡i B‡jKUª‡bi †kqv‡ii gva¨‡g GKK e܇bi m„wó nq|
cv‡VvËi g~j¨vqb-5.3
(1) †fŠZ Ae¯’v: AvqwbK †hŠ‡M c„_K Avjv`v AYy wn‡m‡e †Kv‡bv KYvi Aw¯ÍZ¡ _v‡K bv| wecixZ Avavb hy³
Avqb¸‡jv wÎgvwÎKfv‡e web¨¯Í n‡q we‡kl R¨vwgwZK AvKvi hy³ †Kjvm MVb K‡i| AvqwbK †hŠM Kÿ ZvcgvÎv I
Pv‡c mvaviYZ KwVb nq| †hgb Lv`¨ jeY NaCl , Zzu‡Z CuSO4 .5H 2O cVvwmqvg bvB‡UªU KNO3 ,
wbkv`j NH 4Cl cÖf…wZ KwVb Ae¯’vq _v‡K|
mg‡hvRx †hŠM mvaviYZ GKK AYy wn‡m‡e _v‡K| G AYy¸‡jvi g‡a¨ cvi¯úwiK AvKl©Y ej LyeB bMb¨ nIqvq
mvaviY ZvcgvÎv I Pv‡c Giv cÖavbZ M¨vmxq, Zij ev big KwVb Soft solid c`v_© wn‡m‡e _v‡K| †hgb
CO2 , CH 4 , NH 3 , SO2 , Giv M¨vmxq| cvwb H 2O , †K‡ivwmb, wW‡Rj, B_vbj CH 3 CH 2 OH Giv
Zij| Møy‡KvR C6 H12O6 , BDwiqv H 2 N CO NH 2 , evwj©, gq`v BZ¨vw` big KwVb|
(3) `ªve¨Zv:
AvqwbK †hŠM¸‡jv mvaviYZ †cvjvi `ªve‡K `ªeYxq| mg‡hvRx †hŠM¸‡jv A‡cvjvq `ªve‡K `ªeYxq| cvwb ( H 2O )
†cvjvi `ªveK| Kve©b WvB-mvjdvBW CS 2 , Kve©b †UUªv‡K¬vivBW CCl4 , †ebwRb C6 H 6 A‡cvjvi `ªveK|
Gevi `ywU cwi®‹vi Kuv‡Pi weKvi wbb| `ywU weKv‡iB A‡a©‡Ki GKUz †ewk K‡i cvwb wbb| cÖ_g weKv‡ii g‡a¨ Avav
ivmvqwbK eÜb 81
I‡cb ¯‹zj GmGmwm †cÖvMÖvg
Pvg‡Pi Kg cwigvb Lv`¨ jeY NaCl wb‡q bvovPvov Kiæb| Kx †`L‡jb? jeY cvwb‡Z `ªexf‚Z n‡q wM‡q‡Q|
Gevi H weKv‡ii g‡a¨ Av‡iv Avav PvgP Kvco KvPv †mvWv Na2CO3.10H 2O †hvM K‡i GKB fv‡e bvovPvov
Kiæb| GwUI `ªexf~Z n‡q †Mj| Gevi Gi g‡a¨ Avav PvgP Zzu‡Z †hvM Kiæb| Zzu‡Z cvwb‡Z `ªexf‚Z n‡q †Mj Ges
`ªe‡bi eY© my›`i bxj n‡q †Mj| Lv`¨ jeY, Kvco KvPv †mvWv, Zzu‡Z Giv cÖ‡Z¨‡KB AvqwbK †hŠM| G Rb¨ Giv
cvwb‡Z `ªexf‚Z n‡q‡Q|
wØZxq weKv‡ii cvwb‡Z mvgvb¨ †K‡ivwmb †Zj, b¨vc_vwj‡bi ¸uov, gq`v ev AvUvi ¸uov †hvM K‡i bvovPvov Kiæb|
Kx †`L‡jb? †Kv‡bv Dcv`vbB `ªexf‚Z nq bvB| G Dcv`vb ¸‡jv meB mg‡hvRx †hŠM| Giv cvwb‡Z A`ªeYxq| Z‡e
wPwb C12 H 22 O11 , Møy‡KvR C6 H12O6 , B_vbj CH 3 CH 2OH , BDwiqv H 2 N CO NH 2 ,
A¨v‡gvwbqv NH3 , nvB‡Wªv‡Rb †K¬vivBW mg‡hvRx †hŠM n‡jI Giv cvwb‡Z `ªeYxq| KviY Giv nq cvwbi mv‡_
wewµqv K‡i, bv nq cvwbi mv‡_ hy³ n‡q we‡kl GK ai‡bi eÜb m„wó K‡i _v‡K| G eÜb‡K nvB‡Wªv‡Rb eÜb
e‡j| G m¤ú‡K© Avcbviv Dc‡ii †kÖwY‡Z A‡bK wkL‡Z cvi‡eb|
Lv`¨ jeY
AvqwbK †hŠ‡Mi cvwb‡Z `ªexf‚Z nIqvi †ÿ‡Î AvqwbK †hŠ‡Mi abvZœK cÖvšÍ cvwbi AYyi FYvZœK cÖvšÍ Øviv AvK…ó
nq| Avevi AvqwbK †hŠ‡Mi FYvZœK cÖvšÍ cvwbi AYyi abvZœK cÖvšÍ Øviv AvK…ó nq| G ai‡bi AvKl©‡Yi Kvi‡Y
†hŠ‡Mi abvZœK I FYvZœK cÖvšÍ ci¯úi †_‡K wew”Qbœ n‡q cvwbi †cvjvi AYyi wecixZ cÖvšÍ G‡K wN‡i iv‡L|
Gfv‡e Giv cvwb‡Z `ªexfzZ nq|
Gevi `ywU weKvi wbb| cÖ_g weKv‡i A‡a©‡Ki Kg cvwb wb‡q Zv‡Z GK PvgP Lv`¨ jeY `ªexf‚Z Kiæb| wØZxq
weKv‡i GKB cwigvb cvwb wb‡q Zv‡Z GK PvgP wPwb `ªexf‚Z Kiæb| cÖ_g weKv‡ii `ªe‡Yi g‡a¨ `ywU MÖvdvBU `Û
wbb| `Û `ywU‡K e¨vUvwi I ev‡j¦i mv‡_ hy³ K‡i c~Y© eZ©bx ˆZix Kiæb| †`Lyb wbðqB evj¦ R¡‡j D‡V‡Q|
MÖvdvBU `Û MÖvdvBU `Û
wKQz AvqwbK †hŠ‡Mi ùwUK †Kjvm Av‡Q †hgb, A¨vjywgwbqvg †K¬vivBW (Al2O3), g¨vM‡bwmqv (MgO) G‡`i
MjbvsK A‡bK †ewk| 15000C ZvcgvÎvq G‡`i ùwUK AcwieZx©Z Ae¯’vq _v‡K| Kg ZvcgvÎvq AvqwbK
†hŠMmg~n mvaviYZ KwVb Ae¯’vq _v‡K| G Ae¯’vq B‡jKUªb PjvPj Ki‡Z bv cvivq Giv we`y¨r cwienb K‡i bv|
Avevi Kve©‡bi iƒc‡f` wniK we`y¨r cwienb K‡i bv wKš‘ MÖvdvB‡U gy³ B‡jKUªb _vKvq Bnv we`y¨r cwienb K‡i|
ivmvqwbK eÜb 83
I‡cb ¯‹zj GmGmwm †cÖvMÖvg
1| GKwU Kvu‡Pi Møv‡m A‡a©K cwigvY cvwb wb‡q mvgvb¨ †K‡ivwmb †Zj †hvM
wkÿv_©xi KvR Kiæb| djvdj LvZvq wjLyb|
2| GK Møvm cvwb‡Z GK PvgP NaCl †hvM K‡i djvdj LvZvq wjLyb|
mvi-ms‡¶c :
`ªve¨Zv: †Kv‡bv wbw`©ó ZvcgvÎvq MÖv‡g cÖKvwkZ †h cwigvY `ªe 100g `ªve‡K `ªexf‚Z n‡q m¤ú„³ `ªeY Drcbœ
K‡i, `ª‡ei H cwigvY‡K H ZvcgvÎvq H `ªve‡K H `ª‡ei `ªve¨Zv e‡j|
†Kjvm: `vbv`vi c`v_©‡K †Kjvm e‡j| †Kjv‡m mgmË¡ I mywbw`©ó R¨vwgwZK AvKvi _v‡K|
we`y¨Z cwievwnZv: †h me c`v‡_©i †fZi w`‡q we`y¨r PjvPj Ki‡Z cv‡i †m me c`v_©‡K we`y¨r cwievnx
Ges B‡jKUª‡bi cwienY‡K we`y¨r cwievwnZv e‡j|
cv‡VvËi g~j¨vqb-5.4
D‡Ïk¨
avZe eÜb
Avgiv mK‡jB †jvnvi iW, A¨vs‡Mj, cvZ, KovB, N‡ii QvDwb wn‡m‡e wUb, wcZ‡ji Kjmx, KovB,
NwU, Møvm, A¨vjywgwbqv‡gi ˆZwi `iRv Rvbvjv, cvZ, A¨vjywgwbqv‡gi nvwo-cvwZj, KovB, A¨vjywgwbqvg d‡qj,
wewfbœ ai‡bi avZe †KŠUv| Av‡iv KZwKQz †`‡L _vwK| Giv cÖ‡Z¨‡KB avZz| Gme avZe †gŠ‡ji cigvYy¸‡jv wKQz
mvaviY cÖPwjZ †gŠj ev †hŠ‡Mi AYy‡Z †h iK‡gi eÜb †`wL wVK †miK‡gi e܇b hy³ _v‡K bv| GgbwK Giv
GKK eÜb, wØeÜb, wÎeÜb A_ev wØcigvYyK, wÎcigvYyK AYy wn‡m‡eI _v‡Kbv| Giv Lye e‡ov AvKv‡i wbR wbR
†gŠ‡ji cigvYy¸‡jv GKmv‡_ cvkvcvwk Ae¯’vb K‡i| Gme‡ÿ‡Î mvaviYZ cÖwZwU avZe cigvYyi Pvwicv‡k 8 †_‡K
12 wU GK ai‡bi avZe cigvYy Ae¯’vb K‡i wewfbœ AvKv‡ii KvVv‡gv ˆZwi K‡i| Zvn‡j Giv †Kvb e܇bi gva¨‡g
Giƒc Ae¯’vq Ave× _v‡K? ej‡eb mg‡hvRx eÜb ev AvqwbK eÜb bv, Gi †KvbwUB bq|
Avmj K_v n‡jv avZzi cigvYy ¸‡jvi †hvR¨Zv ¯Í‡ii B‡jKUªb LyeB `ye©jfv‡e wbDwK¬qv‡mi mv‡_ hy³ _v‡K|
†hvR¨Zv¯Í‡ii B‡jKUªb¸‡jv †Kv‡bv GKwU wbw`©ó cigvYy Øviv cwi‡ewóZ bv †_‡K Zv wewfbœ cigvYyi g‡a¨
mÂviYkxj _v‡K| A_©vr avZe †Kjv‡mi †ÿ‡Î G B‡jKUªb¸‡jv cigvYyi Kÿc_ †_‡K †ewo‡q mg¯Í avZeL‡Û
gy³fv‡e PjvPj K‡i| Avm‡j G B‡jKUªb¸‡jv Avi †Kv‡bv mywbw`©ó cigvbyi wbDwK¬qv‡mi Aax‡b _v‡Kbv| mg¯Í
avZe L‡Ûi n‡q hvq| cÖKZ … c‡ÿ †hvR¨Zv¯Í‡ii B‡jKUªb‡K
nvwi‡q avZe cigvby¸‡jv abvZœK Avq‡b cwibZ n‡q GK
wÎgvwÎK †Kjv‡m Ae¯’vb K‡i| gy³ B‡jKUªb¸‡jv mg¯Í avZe
UzKivi g‡a¨ mÂiYkxj _v‡K| avZe Avqb¸‡jv Wz‡e _v‡K
GK B‡jKUªb gnvmvM‡ii g‡a¨| abvZœK avZe Avqb¸‡jvi
gv‡S Ae¯’vb K‡i FYvZœK Avavb hy³ B‡jKUªb¸‡jv| wecixZ
Avavbhy³ e‡ji g‡a¨ GK ai‡bi w¯’i ˆe`y¨wZK AvKl©b e‡ji
m„wó nq hv Zv‡`i hy³ K‡i †Kjvm MVb K‡i| Gfv‡e m„wó wPÎ 1: avZe †Kjv‡m Avqb I B‡jKUªb
eÜb avZe eÜb bv‡g cwiwPZ|
avZe UzKivi g‡a¨ mÂviYkxj B‡jKUª‡bi Kvi‡Y avZe LÛ D”P Zvc I we`y¨r cwievwn, bgbxqZv, D¾¡jZv,
NvZmn cÖf…wZ ˆewk‡ó¨i nq| avZe †Kjv‡mi †fZ‡ii B‡jKUªb¸‡jvI ¯^vaxbfv‡e PjvPj K‡i| avZe Zvi‡K
e¨vUvixi mv‡_ hy³ K‡i eZ©bx c~Y© Ki‡j avZe L‡Ûi gy³ B‡jKUªb¸‡jv mn‡RB eZ©bxi FYvZœK cÖvšÍ †_‡K
abvZœK cÖv‡šÍi w`‡K PjvPj Ki‡Z _v‡K Ges we`y¨r cwienY K‡i|
ivmvqwbK eÜb 85
I‡cb ¯‹zj GmGmwm †cÖvMÖvg
avZe Zvi
A¨v‡bvW
+ K¨v‡_vW
KcvicvZ
†jvnvi cvZ
Zzu‡Zi `ªeY
mvi-ms‡¶c :
avZe eÜb: avZe cv‡Îi g‡a¨ wecixZ Avavb hy³ Avqb¸‡jvi ga¨ w`‡q ˆe`y¨wZK AvKl©Y e‡ji gva¨‡g †h
e܇bi m„wó nq Zv‡K avZe eÜb e‡j|
mÂviYkxj B‡jKUªb: avZe †Kjv‡mi g‡a¨ gy³ B‡jKUªb¸‡jv mg¯Í †Kjvm Ry‡o Ae¯’vb K‡i| G
B‡jKUªb‡K mÂviYkxj B‡jKUªb e‡j|
cv‡VvËi g~j¨vqb-5.5
P~ovš— g~j¨vqb
m„Rbkxj cÖk-œ 1
+
+
A B
K) ivmvqwbK eÜb Kv‡K e‡j? 1
L) cigvYy †Kb ivmvqwbK eÜb MVb K‡i-e¨vL¨v Kiæb| 2
M) DÏxc‡Ki A †gŠjwUi wØcigvYyK AYyi e܇bi cÖK…wZ Av‡jvPbv Kiæb| 3
N) A †gŠjwUi mg‡hvRx I AvqwbK eÜb MVb Ki‡jI B †gŠjwU AvqwbK I avZe eÜb MVb K‡i- we‡kølY Kiæb|
4
m„Rbkxj cÖk-œ 2
A + D AD
B + D BD
A, B I D wZbwU KvíwbK †gŠj| I‡`i cvigvbweK msL¨v h_vµ‡g 1, 11 I 17|
K) cvigvYweK †hvR¨Zv¯Íi Kx? 1
L) `yB Gi wbqg I AóK wbq‡gi cv_©K¨ Kx? 2
M) AD I BD †hŠM `ywUi MVb cÖK…wZ e¨vL¨v Kiæb 3
N) AD I BD †hŠ‡Mi eÜb m¤ú~Y© wfbœ cÖK…wZi- we‡kølY Kiæb| 4
DËigvjv
cv‡VvËi g~j¨vqb-5.1 : 1| M 2| N 3| N
cv‡VvËi g~j¨vqb-5.2 : 1| L 2| N 3| M 4| K
cv‡VvËi g~j¨vqb-5.3 : 1| L 2| L 3| N
cv‡VvËi g~j¨vqb-5.4 : 1| N 2| M 3| N
cv‡VvËi g~j¨vqb-5.5 : 1| N 2| N
ivmvqwbK eÜb 87