21-12-2024

9610ZJA801338240025 JA

PART-1 : PHYSICS

SECTION-I (i)

1) The equation of a projectile is . The angle of projection is :-

(A) 30º
(B) 60º
(C) 45º
(D) None

2) A stone of mass 1 kg tied to a light inextensible string of length L = m is whirling in a circular

path of radius L in a vertical plane. If the ratio of the maximum tension in the string to the minimum
tension in the string is 4 and if g is taken to be 10 m/sec2, the speed of the stone at the highest point
of the circle is

(A) 20 m/sec
(B) m/sec
(C) m/sec
(D) 10 m / sec

3) A system of two blocks A and B are connected by an inextensible massless strings as shown in
figure. The pulley is massless and frictionless. Initially the system is at rest when, a bullet of mass
'm' moving with a velocity 'u' as shown hits the block 'B' and gets embedded into it. The impulse

imparted by tension force to the block of mass 3m is :

(A)

(B)

(C)

(D)

4) A uniform rod of length l is placed symmetrically on two walls as shown in figure. The rod is in
equilibrium. If N1 and N2 are the normal forces exerted by the walls on the rod then :-

(A) N1 > N2
(B) N1 < N2
(C) N1 = N2
(D) N1 and N2 would be in the vertical directions

5) The interface of two liquids of densities ρ and 2ρ respectively lies at the point A in a U tube at

rest. The height of liquid column above A is where AB = a. The cross sectional area of the tube is
S. With what angular velocity the tube must be whirled about a vertical axis at a distance 'a' such

that the interface of the liquids shifts towards B by

(A)

(B)

(C)

(D)

6) A conducting sphere (of radius R) has concentric spherical cavity (radius ) with a charge (–q) at
its centre. A charge (+q) is placed at a distance 2R from the center. Mark the incorrect option :-

(A) Charge density on the outer surface is not uniform

(B) Charge density on the inner surface is uniform.
(C)
Electric field at the centre due to point charge (+q) is in magnitude.
(D) Potential difference between inner and outer surface of sphere is zero.

7) In the circuit shown in the figure, if the potential at point A is taken to be zero, the potential at

point B is :

(A) –2 V
(B) +1 V
(C) –1 V
(D) +2 V

8) There are two infinitely long straight current carrying conductors and they are held at right
angles to each other so that their common ends meet at the origin as shown in the figure given
below. The ratio of current in both conductor is 1 : 1. The magnetic field at point P is ____.

(A)

(B)

(C)

(D)

9) Monochromatic light is incident on a glass prism of angle A. If the refractive index of the material
of the prism is , a ray, incident at an angle , on the face AB would get transmitted through the

face AC of the prism provided:

(A)

(B)

(C)

(D)

10) 1 mole of a monoatomic gas undergoes the process PT = constant. Then the molar heat capacity
of the gas during the process will be equal to :-

(A) 4R
(B) 2.5 R
(C) 3.5 R
(D) 8 R/3

SECTION-I (ii)

1) A bullet of mass m = 1 kg strikes a block of mass M = 2kg connected to a light spring of stiffness
k=3N/m with a speed V0 = 3m/s. If the bullet gets embedded in the block then.

A linear momentum of bullet and block system is not conserve during impact because spring
(A)
force is impulsive.
Linear momentum of bullet and block system is conserve during impact because spring force is
(B)
non impulsive
(C) Maximum compression in the spring is 2m.
(D) The maximum compression in the spring is 1 m.

2) The torque on a body about a given point is found to be equal to × , where is a constant
vector and is the angular momentum of the body about that point. From this it follows that :-

(A)
is perpendicular to at all instants of time
(B) the component of in the direction of does not change with time
(C) the magnitude of does not change with time
(D) does not change with time

3) The vessel shown in the figure has two sections of areas of cross-section A1 and A2. A liquid of
density fills both the sections, up to a height h in each. Neglect atmospheric pressure:-
(A) The pressure at the base of the vessel is
The force exerted by the liquid on the base on the vessel is
(B)

(C) The weight of the liquid is

(D) The walls of the vessel at the level X exert a downward force on the liquid.

4) A tunnel is dug along a chord of the Earth at a perpendicular distance R/2 from the Earth's
centre. The wall of the tunnel may be assumed to be frictionless. A particle is released from one end
of the tunnel. The pressing force by the particle on the wall, and the acceleration of the particle
varies with x (distance of the particle from the centre of earth) according to :-

(A)

(B)

(C)
(D)

5) Two monochromatic sources of electromagnetic wave, P and Q emit waves of wavelength λ = 20

m and separated by 5m as shown. A,B and C are three points where interference of these waves is
observed. If phase of a wave generated by P is ahead of wave generated by Q by π/2 then (given

intensity of both waves is I) :

(A) phase difference of these waves at B is 180°

(B) intensities at A,B and C are in the ratio 2 : 0 : 1 respectively.
(C) intensities at A,B and C are in the ratio 1 : 2 : 0 respectively.
(D) phase difference at A is 0°.

SECTION-III

1) The figure shows a thin ring of mass M = 1 kg and radius R = 0.4 m spinning about a vertical

diameter. (Take . A small bead of mass m = 0.2 kg can slide without friction along the
ring. When the bead is at the top of the ring, the angular velocity is 5 rad/s. the angular velocity

when the bead slips halfway to is rad/s. Find n

2) A straight wire of length ‘ ’ carries ‘I’ current is moulded in the form of semicircular loop then its

magnetic moment (see figure) is found to be Find P + K

3) A dipole is placed at origin of coordinate system as shown in figure, the electric field at point P(0,

y) is . Find n.

4) A rod of length 12 m has specific gravity ρ (= 25/36). One end of the rod is tied to 5m long rope,
which in turn is tied to the floor of a pool 10 m deep as shown. Find the length (in m) of the part of
rod, which is out of water :

5) A certain planet of radius R is composed of a uniform material that, through radioactive decay,

generates a net power P such that heat per second , where r is radial distance from
centre. This results in a temperature differential between the inside and outside of the planet as
heat is transferred from the interior to the surface. The rate of heat transfer inside is governed by
conduction. It is found that thermal conductivity k is constant for the planet. For the following
assume that the planet is in a steady state; temperature might depend on position, but does not
depend on time. (Assuming black body radiation, and emissivity is 1) Find an expression for the
temperature difference between the surface of the planet (TS) and the centre of the planet (TC).

If your answer is fill value of (m + n + l)

PART-2 : CHEMISTRY

SECTION-I (i)

1) In the reaction sequence :

A B C C6H5OH, A, B and C are :

(A) Benzene, nitrobenzene, and aniline
(B) Nitrobenzene, aniline and azo-compound
(C) Nitrobenzene, benzene, and aniline
(D) Benzene, amino compound, aniline

2) Which one of the following tests can be used to identify primary amino group in a given organic
compound

(A) Iodoform test

(B) Victor Meyer's test
(C) Carbylamine reaction
(D) Libermann's reaction

3) Which is not the correct match?

(A) Carius method: Halogens

(B) Leibig's method: carbon and Hydrogen
(C) Kjeldahl's method: Nitrogen
(D) Lassaigne's test : Oxygen

4)
Q is :

(A)

(B)

(C)
(D)

5) Consider the following reactions of IA metals.

M + (x + y)NH3 → [M(NH3)x]+ + [e(NH3)y]–

Which of the following statement is INCORRECT ?

The blue color of the solution is due to the ammoniated electron which absorbs energy in
(A)
infrared region of light
(B) In concentrated solution, the blue color changes to bronze color
(C) If concentration increases, the solution turns diamagnetic from paramagnetic
(D) The deep blue solution is conducting in nature

6) The compressibility factor of a Vanderwaal gas is 0.5 at 27ºC and 24 atm. The value of
Vanderwaal constant 'a' (in atm-L2/mol2) is
(b = 0.10 L/mol, R = 0.08 L-atm/K-mol)

(A) 2.4
(B) 4.0
(C) 3.6
(D) 9.0

7) A sample of hydrogen atoms de-excites from 6th excited state to the ground state in one or more
electronic transitions. If no spectral line is obtained in the Paschen and Brackett series, then the
maximum number of spectral lines of different photon energies obtained will be -

(A) 21
(B) 15
(C) 10
(D) 7

8) Which of the following reduction methods is correctly matched against the given metals
(commercial process)?

(A)
(B) (Fe, Zn) → Electrolytic reduction
(C) (Cr, Mg) → Thermite reduction
(D) (Fe-Hg) → Carbon reduction
9) An equilibrium mixture contains 2.0 moles of A(g) and 4.0 moles of B(g). Now, 2.0 moles of A(g) is
added in this equilibrium mixture and the system is allowed to re-achieve equilibrium at constant
volume and temperature. Now, the volume of system is doubled at constant temperature. What
should be the moles of B(g) at new equilibrium? The reaction involved is
A(g) 2B(g)

(A) 3.86
(B) 5.86
(C) 4.86
(D) 6.58

10)
If Q is a colourless gas with rotten fish smell then select CORRECT statement.

(A) (Q) also produced on heating of H3PO4

(B) Structure of (P) is polymeric
(C) Only two oxy bridges are present in (S)
(D) Zero acidic hydrogen present in anionic part of (R)

SECTION-I (ii)

1)
Product in a given conversion are :

(A)

(B)
(C)

(D)

2)
Correct statements :

(A) P1 & P2 both are Diethyl ether

(B) P1 is diethyl ether
(C) P2 is ethene
(D) P1 & P2 both are ethene

3) An electrochemical cell is made by combining two half cells

(X) AgNO3(0.05) M ) | Ag(s) and
(Y) AgNO3 (0.01) M ) | Ag(s)
Choose the correct statement

(A) The Ecell can be increased if concentration of AgNO3 in half cell X is increased
(B) The Ecell will increase if concentration of AgNO3 in cell Y is increased
(C) The Ecell will increase if concentration of AgNO3 in cell X is decreased
(D) The Ecell will increase if concentration of AgNO3 in cell Y is decreased

4) 1 mol of NH3 gas (γ = 1.33) at 27° C is expanded reversibly under adiabatic conditions to increase
volume 8 times the initial volume. Correct option(s) is/are

(A) final temp. = 150 K

(B) work done = –400 cal
(C) final temp. = 250 K
(D) work done = –900 cal

5) Which of the following pairs produce same gas?

(A) (Ca3N2 + dil. HCl) and (NH4NO2 on heating)

(B) [(NH4)2Cr2O7 on heating] and (NH4NO2 on heating)
(C) (NH4NO3 on heating) and [Hg(NO3)2 on heating]
(D) (NH4Cl on heating) and [NaNO3 + Zn + (aq.) NaOH(aq) on heating]

SECTION-III

1)
How many optically active isomers of product are possible ?

2) Consider the following chemical reaction.

The number of sp2 hybridized carbon atom(s) present in the product is _______.

3) A decapeptide (Mol. Wt. 796) on complete hydrolysis gives glycine (Mol. Wt. 75), alanine and
phenylalanine. Glycine contributes 47.0 % to the total weight of the hydrolyzed products. The
number of glycine units present in the decapeptide is

4) No. of S – S linkage in S3O9 = m1

No. of P – P linkage in(HPO3)3 = m2
No. of S – S linkage in = m3
No. of O – O linkage in = m4
Find out m1 + m2 + m3 + m4

5) How many compounds will give positive iodoform test but negative Tollen's test?

(a) CH3CHO (b)

(c) (d)

(e) (f)

(g) CH3–CH2–OH (h) CH3–COOH

(i) PhCOCH3
 PART-3 : MATHEMATICS

SECTION-I (i)

1)

(A)

(B) 4
(C)

(D)

2) If a circle C passing through the point (4,0) touches the circle x2 + y2 + 4x – 6y = 12 externally at
the point (1, –1), then the radius of C is :

(A)
(B) 4
(C)
(D) 5

3) The eccentricity of the ellipse is

(A)

(B)

(C)

(D)

4) The number of real roots of the equation e6x – e4x – 2e3x – 12e2x + ex + 1 = 0 is :

(A) 2
(B) 4
(C) 6
(D) 1

5) Three urns A, B and C contain 7 red, 5 black; 5 red, 7 black and 6 red, 6 black balls, respectively.
One of the urn is selected at random and a ball is drawn from it. If the ball drawn is black, then the
probability that it is drawn from urn A is :

(A)
(B)

(C)

(D)

6) In a tetrahedron OABC, the edges are of lengths, |OA| = |BC| = a, |OB|=|AC| = b, |OC| =|AB|= c.
Let G1 and G2 be the centroids of the triangle ABC and AOC such that OG1 ⊥ BG2, then the value of

is (O being origin)

(A) 2
(B) 3
(C) 6
(D) 9

7) Let and then

(A) α = β
(B) 4α = 3β
(C) 3α = 4β
(D) None of these

8) The value of is :-

(A)

(B)

(C)

(D)

9) The value of is equal to

(A)
(B)
(C)
(D)
10) If , then the value of k is

(A) 19
(B) 20
(C) 21
(D) 22

SECTION-I (ii)

1) Let then possible value of is

(A)

(B)

(C)

(D)

2) There are 7 seats in a row. The number of ways three persons take seats so that middle seat is
always occupied and no two persons are consecutive is equal to n!, then which of the following
statements is(are) true -

Number of ways in which n points are selected from 12 distinct collinear points so that no two
(A)
of them are consecutive is 9C5
The number of (n + 1) digit numbers in which the digit in any place is greater than the digit to
(B)
the left of it is 9C5
(C) The number of odd proper divisors of 20412 is 3n + 1

(D)

3) For 3 × 3 matrices A and B, which of the following statement(s) is(are) correct?

(A) AB is skew symmetric if A is symmetric and B is skew symmetric.

(B) (adj A)T = adj AT for all invertible matrix A.
(C) AB + BA is symmetric for all symmetric matrices A and B.
(D) (adj A)–1 = adj (A–1) for all invertible matrix A.

4) Let A & B be two points in x-y plane with position vectors and

respectively. Let D be foot of perpendicular from origin on line AB, and

M and N be foot of perpendicular from D on OA and OB respectively. Now which of the following
holds good ? ('O' is origin)

(A)

(B)

(C)

(D)

5) Let ƒ(x) = max{|x2 – 2|x||, |x|} and g(x) = min{|x2 – 2|x||, |x|} then which of the following is/are
true ?

(A) ƒ(x) is non-differentiable at 5 points in x ∈ R

(B) g(x) is non-differentiable at 7 points in x ∈ R
(C) ƒ(x) is discontinuous and g(x) is continuous in x ∈ R
(D) ƒ(x) is non-differentiable at 6 points in x ∈ R

SECTION-III

1) If __________. (where denotes the greatest integer function)

2) If y(x) satisfies the equation y'(x) = y(x) + & y(0) = 1 then value of .

3) Out of 52 playing cards, the aces have been removed and remaining 48 cards are distributed

among 4 players equally. If the probability that a specified player holds all face cards is ,
then the value of K

4) A given quantity of metal is to be casted into a half cylinder i.e. with a rectangular base and
semicircular ends. The total surface is to be minimum, if the ratio of the height of the cylinder to the
diameter of the semi circular ends is give by π/(π +k), , then the value of k is.

5) If (where n1, n2, n3, n4 are natural numbers) then the value of
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4 5 6 7 8 9 10
A. B D D C B C B A C C

SECTION-I (ii)

Q. 11 12 13 14 15
A. B,D A,B,C A,B,C,D B,C A,B,D

SECTION-III

Q. 16 17 18 19 20
A. 6 4 3 2 7

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 21 22 23 24 25 26 27 28 29 30
A. B C D C A D C A D D

SECTION-I (ii)

Q. 31 32 33 34 35
A. A,C,D B,C A,D A,D B,D

SECTION-III

Q. 36 37 38 39 40
A. 8 7 6 0 5

PART-3 : MATHEMATICS

SECTION-I (i)

Q. 41 42 43 44 45 46 47 48 49 50
A. D D D A B B C C A C

SECTION-I (ii)

Q. 51 52 53 54 55
A. A,B,C A,B,C,D B,C,D A,B,D A,B
 SECTION-III

Q. 56 57 58 59 60
A. 1 4 9 2 3
 SOLUTIONS

PART-1 : PHYSICS

1) tan θ =
θ = 60º

2) Since the maximum tension TB in the string moving in the vertical circle is at the bottom and
minimum tension TT is at the top.

∴ TB = + mg and TT = – mg

∴ = = or =
or + gL = – 4gL but = + 4gL
∴ + 4gL + gL = – 4gL ⇒ = 9gL

∴ = 3 × g × L = 3 × 10 × or vT = 10 m/sec

3)

0 + J = 3 mv
mu –J1 = mv
J1 – J = mv

4)

∴ N1 = N2

5)
6)

Properties of conductor

7) KCL at point C gives i = 1A ⇒ VD – VC = 1(2)

⇒ VD = 3V
Hence potential at point C = 1V

8) Bdue to wire (1) =

= ……(1)

Bdue to wire (2) =

……(2)
Total magnetic field
B = B1 + B2
9)

When

As

Applying snell's law at 'R'

...(i)
Applying snell's law at 'Q'
...(ii)
But r1 = A – r2
So,
...(iii) [using (i)]
From (1)

...(iv)
By eq. (iii) and (iv)

on further solving we can show for ray not to transmitted through face AC

So, for transmission through face AC

10)
P2V = const.
PV1/2 = const.

m=

C=

11)
12)

is perpendicular to and

does not change magnitude of L.

angle between and is constant
rotates abovt in a cone-shape structure.

13) Pressure acts equally in all directions, and a liquid exerts forces on the walls of the
container normal to the walls. Hence the liquid exerting force on the sloping walls of the
conical flask will have a net upward component.

14) Pressing force by the particle on the wall of tunnel is and acceleration is mgsinθ. Pressing
force

= mgcosθ ⇒ ⇒
Pressing force is independent from 'x' thus it is constant

gsinθ =

x is increases from to R, thus acceleration increases

15) Δx = 5

ϕ due to Δx =
Hence phase differences at B = π
phase differences at A = 0

phase differences at C =
Intensity at A “IA” = 4I
Intensity at B “IB” = 0
Intensity at C “IC” = 2I

16)
17)

For wire πr + 2r = ; r =

∴ Magnetic moment, M = =

18)

19)
 20)

⇒ ⇒
4
⇒ P = 8πkRΔT = eAσTS

⇒ ΔT = ⇒ ΔT =
⇒ m = 1, n = 4, =2⇒m+n+ =7

PART-2 : CHEMISTRY

21)

22) R—NH2 + CHCl3 + 3 KOH → R — NC + 3KCl + 3H2O

23)

Lassaigne’s test = Test for N, S, X, and P

24)
25)

Blue colour of solution is due to ammoniated electron which absorb energy in visible region of
light

26)
Vm = 0.5 L/mole

a = 36 × 0.52 =

27)

6th excited state means = 7th state

- possible transition form 7th state 7 → 6, 7 → 5, 7 → 2, 7 → 1
- Possible transition from 6th state 6 → 5, 6 → 2, 6 → 1
- Possible transition from 5th state 5 → 2, 5 → 1
- Possible transition from 2nd state 2 → 1
- n → 3 & n → 4 not taken for paschen and brackett series.
- Since there is no transition to 3rd & 4th shell so transition from 3rd & 4th shell to lower shell
not observed.

28)

(A) Cu & Pb - self reduction

(B) Fe & Zn - Reduction by C & CO
(C) Cr - Thermit reduction
Mg - Electrolytic redution
(D) Hg - Thermal decomposition.

29)

A(g) 2 B(g)

Em
2mol

Aadded

New
V×2

New

Now,

or,
z2 + 8z – 12 = 0
z = 1.29
∴ moles of B at new

30)

P4 + NaOH + H2O → PH3 + NaH2PO2

White (Q)
phosphorres O2↓ Δ
P4O10
4H3PO3 H3PO4 + 3PH3
White phosphorus is monomeric structure

31)

32)

P1 : H3C–CH2–O–CH2–CH3 (diethyl ether)

P2 : H2C = CH2 (ethene)
33)

Cathode (x) Ag+ (0.05 M) + e– → Ag(s)

Anode (y) Ag → Ag+(g) (0.01 M) + e–
________________________________
Ag+ (0.05M) → Ag+(0.01 M)

Ecell =

Ecell =
Ecell increases when [cathode] increases and that [anode] decreases.
Half cell X is cathode, while Y is anode.

34)

T2 = T1 ,

=
= = – 900 Cal

35)

(B) both give N2

(D) both give NH3
(A) Ca3N2 + dil HCl → CaCl2 + NH3
NH4NO2 N2 + 2H2O
(B) (NH4)2Cr2O4 N2 + Cr2O3 + 4H2O
NH4NO2 N2 + 2H2O
(C) NH4NO3 N2O + 2H2O
Hg(NO3)2 Hg + NO2 + O2
(D) NH4Cl NH3 + HCl
NaNO3 + Zn + Aq. NaoH NH3 + Na2ZnO2

36)
Total optically active isomer = 2n–1 = 24–1 = 8
 37)
In benzaldehyde total number of sp2 'C' are 7.

38)

No. of peptide bonds = 9

Mass of hydrolysed products = 796 + 18 × 9 = 958 g

No. of glycine units =

39)

40) b, c, e, g, i

PART-3 : MATHEMATICS

41)

42) x2 + y2 + 4x – 6y – 12 = 0
Equation of tangent at (1, –1)
x – y + 2(x + 1) – 3(y – 1) – 12 = 0
3x – 4y – 7 = 0
∴ Equation of circle is
(x2 + y2 + 4x – 6y – 12) + λ(3x – 4y – 7) = 0
It passes through (4, 0) :
(16 + 16 – 12) + λ(12 – 7) = 0
⇒ 20 + λ(5) = 0
⇒ λ = –4
∴ (x2 + y2 + 4x – 6y – 12) – 4(3x – 4y – 7) = 0
or x2 + y2 – 8x + 10y + 16 = 0
 Radius =

43) (x – 3)2 + (y – 4)2 =

9(x – 3)2 + 8y2 – 72y + 144 = 0

44) e6x – e4x – 2e3x – 12e2x + ex + 1 = 0

⇒ No. of real roots = 2

45)

P(B) =

required probability =

46)

⇒
⇒
Now, and

Putting in the above result, we get

47)

⇒ 4β = 3α

48)

cot–1(1 + n(n + 1)) =

cot–1(1 + n(n + 1)) = tan–1(n + 1) – tan–1(n)

= tan–1(49) – tan–1(1)

49)
50)

Let Tr = ((r + 3)! – (r + 2)!)

3! – 2!
4! – 3!

21! – 20!
Sum = 21! – 2!
k! = 21!

51)

52) Required number of ways are

= (No. of ways middle position taken)
(rest of the positions)

= 24 = (4!) ⇒ n = 4
(A) 4 points are related out of 12 points so that no two are consecutive are 9C4.
(B) No. of 5 digit no's in ascending order is 9C4.
(C) 20412 = 22.36.71
no. of odd proper divisors
= (6 + 1)(1 + 1) – 1 = 13

(D)

= 32/3

53) (A) Let P = AB

Now, PT = (A B)T = BT AT = – B A ⇒ PT ≠ – P
∴ AB is not skew symmetric.
(B) we know that
= ⇒ (adj A)T AT = |A| I3 ⇒ (adj A)T = |A| (AT)–1
∴ (adj A)T = adj (AT), for all invertible matrix A.
(C) Let P = A B + BA
∴ PT = (AB + BA)T = (AB)T + (BA)T = BT AT + AT BT = BA + AB
= AB + BA = P
⇒ AB + BA is symmetric.

(D) As, adj (A–1) = ...(1)

 Also, A (adj A) = |A| I3
⇒ (adj A) = |A| A–1

⇒ (adj A)–1 = ...(2)

∴ From (1) and (2), we get
(adj A)–1 = adj (A–1)

54) ΔOAB is equilateral Δ. with side length unity

sin60° = 2DM ⇒
Now check options.

55) ƒ(x) = max {(|x|2 – 2|x|), |x|}

g(x) = min {(|x|2 – 2|x|), |x|}

ƒ(x) non differentiable at 5 points

g(x) non differentiable at 7 points

56)

57)

⇒ =y+a let

⇒ –y–a=0
I.F. = = e–x

Now e–x – ye–x – ae–x = 0

⇒ ye–x + ae–x + c = 0
⇒ y + a + cex = 0

a= =– = – a(1 – 0) – c = – a – c(e – 1)

y+ c=0

⇒ y = 1; x = 0 ⇒ c =

⇒ y(x) =

= =4

58)
so K = 9

59)

For Amin =

60)

= 15