Vidyamandir Classes

Chemistry Atomic Structure Class Assignment

1. Which of the following is the correct graphical representation based on photoelectric effect?

(I) (II) (III) (IV)

(A) I and II (B) II and III (C) III and IV (D) II and IV
2. The work function of platinum is twice that of the work function of calcium. If the minimum photon energy
required to emit photoelectrons from the surface of platinum is E, then that for the surface of calcium
would be:
(A) 2E (B) 3E/2 (C) E/2 (D) Cannot be determined
3. A metal surface is first irradiated with UV light and then with IR light of same intensity. What will be the
change in K.E. of the emitted photoelectrons and in the no. of photoelectrons emitted?
(A) K.E. will remain same but no. of photoelectrons emitted will decrease
(B) K.E. will increase and no. of photoelectrons emitted will remain same
(C) K.E. will decrease and no. of photoelectrons emitted will also decrease
(D) K.E. will decrease and no. of photoelectrons emitted will remain same
4. If the total energy of electron in the second Bohr orbit of H atom is 3.4 eV , then energy of fourth orbit of
He ion would be:
(A)  3.4eV (B)  0.85eV (C) 13.64 eV (D)  3.4 eV

5. The no. of photons of light of V  2.5 106 m 1 necessary to provide 1J of energy are:
(A) 2  1018 (B) 2  1017 (C) 2  10 20 (D) 2  1019

6. The I.E. of hydrogen atom is 13.6 eV . Hydrogen atoms in the ground state are excited by monochromatic
light of energy 12.1eV . When the atom comes back to the ground state, the spectral lines which can't be
emitted will be:
(A) n  3 to n  1 (B) n  3 to n  2 (C) n  2 to n  1 (D) n  4 to n  1

7. In the hydrogen atom, the transition that gives radiation in the visible region is:
(A) from n  1 to n  2 (B) from n  2 to n  2
(C) from n  2 to n  1 (D) from n  3 to n  3
8. Bohr’s model of the atom included the idea that:
(A) The electron cannot have only certain energies, including a lowest-level ground state.
(B) Electrons absorb energy as light when higher energy orbits
(C) Electrons emit energy as light when they move to lower energy orbits
(D) B and C are correct

VMC | Class Assignment 1 Chemistry | Atomic Structure

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9. Bohr’s atomic model is based upon:
(A) Einstein’s relative theory (B) Classical theory
(C) Planck’s Quantum theory (D) Both (B) and (C)

10. Many elements have nonintegral atomic masses because:

(A) they have isotopes
(B) their isotopes have non-integral masses
(C) their isotopes have different masses
(D) the constituents, neutrons, protons and electrons combine to give fractional masses

11. The expression of Rydberg constant is:

(A) 22 mh 3c / (e2 / 40 ) 2 (B) 22 m (e2 / 4 0 ) 2 / h 3c
(C) (e2 / 40 )2 / 22 mh3 c (D) 22 mh 3c / (e2 / 40 )

12. The ratio of kinetic energy and total energy of an electron in a Bohr orbit of a hydrogen-like species is:
(A) 1/2 (B) –1/2 (C) 1 (D) –1

13. The ionization energy of hydrogen atom in terms of Rydberg constant (RH) is given by the expression:
(A) RHhc (B) RHc (C) 2RHhc (D) RHNAhc
14. The expression of velocity of an electron in a Bohr orbit of a hydrogen-like species is:
2(Ze2 / 40 ) 2nh
(A) v (B) v
2
nh (Ze / 40 )
2nh (Ze2 / 40 )
(C) v (D) v
2 (Ze2 / 40 ) 2nh

15. Which of the following electronic transitions requires that the greatest quantity of energy be absorbed by a
hydrogen atom?
(A) n = 1 to n = 2 (B) n = 2 to n = 4 (C) n = 3 to n = 6 (D) n = 1 to n = ∞
16. If shortest wavelength of H atom in Lyman series is x, then longest wavelength in Balmer series of He+ is:
(A) 9x/5 (B) 36x/5 (C) x/4 (D) 5x/9
17. To move the electron in one H atom from the ground state to the second excited state, 12.084 eV are
needed. How much energy is needed to cause 1 mol of H atoms to undergo this transition?
(A) 728 kJ (B) 984 kJ (C) 1036 kJ (D) 1164 kJ
18. Which of the following statements is not true?
(A) Lyman spectral series of hydrogen atom lies in the ultraviolet region of electromagnetic radiation
(B) Balmer spectral series of hydrogen atom lies in the visible region of electromagnetic radiation
(C) Paschen spectral series of hydrogen atom lies in the visible region of electromagnetic radiation
(D) Brackett spectral series of hydrogen atom lies in the infrared region of electromagnetic radiation

19. The wavelength of a spectral line for an electronic transition is inversely related to:
(A) the number of electrons undergoing the transition
(B) the square of nuclear charge of the atom
(C) the difference in the energy of the energy levels involved in the transition
(D) the velocity of electron undergoing the transition

VMC | Class Assignment 2 Chemistry | Atomic Structure

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20. The energy of an electron in the first Bohr orbit for hydrogen is –13.6 eV. Which one of the following is a
possible excited state for electron in Bohr orbit of hydrogen atom?
(A) –3.4 eV (B) –6.8 eV (C) –1.7 eV (D) 13.6 eV

21. The maximum energy is present in any electron at:

(A) Nucleus (B) Ground state
(C) First excited state (D) Infinite distance from the nucleus

22. Which electronic level would allow the hydrogen atom to absorb a photon but not to emit a photon?
(A) 3s (B) 2p (C) 2s (D) 1s

23. The third line in Balmer series corresponds to a transition between which Bohr’s orbits in hydrogen:
(A) 53 (B) 52 (C) 43 (D) 42

24. Correct set of four quantum numbers for valence electron of rubidium (Z = 37) is:
1 1 1 1
(A) 5, 0, 0,  (B) 5, 1, 0,  (C) 5, 1, 1,  (D) 6, 0, 0, 
2 2 2 2

25. The orbital diagram in which the Aufbau’s principle is violated is:
2s 2p x 2p y 2pz 2s 2p x 2p y 2pz
(A)    (B)    
2s 2p x 2p y 2pz 2s 2p x 2p y 2pz
(C)     (D)    

26. The total number of neutrons in dipositive zinc ions with mass number 70 is:
(A) 34 (B) 40 (C) 36 (D) 38

27. Which of the following sets of quantum numbers represent an impossible arrangement?
n  m ms n  m ms
(A) 3 2 2 1/2 (B) 4 0 0 1/2
(C) 3 2 3 1/2 (D) 5 3 0 1/2

28. The explanation for the presence of three unpaired electrons in the nitrogen atom can be given by:
(A) Pauli’s exclusions (B) Hund’s rule
(C) Aufbau’s principle (D) Uncertainty principle

29. The electronic configuration of an element is 1s2 2s2 2p6 3s2 3p 6 3d5 4s1 . The state it represents is:
(A) Excited state (B) Ground state (C) Cationic form (D) None of these
30. Which of the following has maximum number of unpaired electrons? [Atomic number of Fe = 26]
(A) Fe (B) Fe (II) (C) Fe (III) (D) Fe (IV)
31. Which quantum number is not related with Schrodinger equation?
(A) Principle (B) Azimuthal (C) Magnetic (D) Spin

32. If  0 is the threshold wavelength for photoelectric emission,  wavelength of light falling on the surface
of metal, and m mass of electron, then de-Broglie wavelength of emitted electron is:
1 1 1 1
 h  0   2  h  0     2  h    0   2  h  0  2
(A)   (B)   (C)   (D)  2mc 
 2mc  0      2mc   0    2mc   0    

VMC | Class Assignment 3 Chemistry | Atomic Structure

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33. It is known that atom contains protons, neutrons and electrons. If the mass of neutron is assumed to half of
its original value where as that of proton is assumed to be twice of its original value, then the atomic mass
14
of 6C will be:
(A) Same (B) 25% more (C) 14.28% more (D) 28.5% more
34. Give the correct order of initials T (true) or F (false) for following statements:
I. If an ion has 2 electrons in K shell, 8 electrons in L shell and 6 electrons in M shell, then number of
s- electrons present in that element is 6.
II. The maximum number of electrons in a subshell is given by 2n 2 .
III. If electron has magnetic quantum number 1 , then it cannot be present in s-orbital.
IV. Only one radial node is present in 3p orbital.
(A) TTFF (B) FFTF (C) TFTT (D) FFTF
35. Question: Is the species paramagnetic?
Statement I : The atomic number of species is 29.
Statement II : The charge on the species is +1.
(A) Statement I alone is sufficient but statement II is not sufficient
(B) Statement II alone is sufficient but statement I is not sufficient
(C) Both statements together are sufficient but neither statement alone is sufficient
(D) Statement I & II together are not sufficient

VMC | Class Assignment 4 Chemistry | Atomic Structure

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Answers to Assignment | Atomic Structure

1 2 3 4 5 6 7 8 9 10

D C D A A D B D D C

11 12 13 14 15 16 17 18 19 20

B D A A D A D C C A

21 22 23 24 25 26 27 28 29 30

D D B A A B C B B C

31 32 33 34 35

D A D C C

VMC | Class Assignment 5 Chemistry | Atomic Structure