Sec: Sr.

IIT_IZ Date: 27-01-19

Time: 02:00 PM to 05:00 PM Max.Marks:198
Name of the Student: ___________________ I.D. NO:

2012_PAPER-II
27-01-19_Sr.IIT_IZ_Jee-Adv_GTA-01_SYLLABUS
MATHS : Total Syllabus
PHYSICS : Total Syllabus
CHEMISTRY : Total Syllabus
Narayana IIT Academy 27-01-19_Sr.IIT_IZ_Ph-III_JEE-ADV_2012-P2_GTA-1_Q’P
JEE-ADVANCE-2012-P2-Model
Time: 3:00hours IMPORTANT INSTRUCTIONS Max Marks: 198
PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 8) Questions with Single Correct Choice 3 -1 8 24
Questions with Comprehension Type
Sec – II(Q.N : 9 – 14) 3 -1 6 18
(3 Comprehensions : 2+2+2 = 6Q)
Sec – III(Q.N : 15 – 20) Questions with Multiple Correct Choice 4 0 6 24
Total 20 66
CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 21 – 28) Questions with Single Correct Choice 3 -1 8 24
Questions with Comprehension Type
Sec – II(Q.N : 29 – 34) 3 -1 6 18
(3 Comprehensions : 3+3 = 6Q)
Questions with Multiple Correct
Sec – III(Q.N : 35 – 40) 4 0 6 24
Choice
Total 20 66
MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : (41 – 48) Questions with Single Correct Choice 3 -1 8 24
Questions with Comprehension Type
Sec – II(Q.N : (49 – 54) 3 -1 6 18
(3 Comprehensions : 2+2+2 = 6Q)
Sec – III(Q.N : 55 – 60) Questions with Multiple Correct Choice 4 0 6 24
Total 20 66

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Narayana IIT Academy 27-01-19_Sr.IIT_IZ_Ph-III_JEE-ADV_2012-P2_GTA-1_Q’P
PHYSICS Max. Marks: 66
SECTION – I
(SINGLE CORRECT CHOICE TYPE)
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of
which ONLY ONE is correct.
Marking scheme +3 for correct answer , 0 if not attempted and -1 in all other cases.
1. The density of a sphere is measured by measuring its mass and diameter. If, it is known
that the maximum percentage errors in the measurement are 2% and 3% respectively,
then find the maximum percentage error in the measurement of density?
A) 15% B) 18% C) 9% D) 11%
2. A shot is fired with velocity 2gh horizontally h m above the top of a mountain which
is in the form of hemisphere of radius r. The point on the mountain which can be
reached by the shot is at a distance (measured in a straight line) from top of the
mountain
    
A) r  r 2  4rh B) r  r 2  4rh C) r  r 2  4rh D) r  r 2  2rh   
3. A cart initially moving on a frictionless track filled with sand has a hole at its bottom
from where sand leaks out
Student A says : The velocity of cart remains constant although mass of sand in cart
decrease.
Student B says: Since mass is decreasing, the velocity of cart must increase.
A) Student –A is correct, Student –B is wrong
B) Student A is wrong, Student –B is correct
C) Both are correct D) Both are wrong
4. A block of mass 2kg was moving along a straight line on a smooth surface with a
speed of 5 m/s. At t=0, a force given by F=(3+2t) N directed in the direction of motion
of the body starts acting on the block. The kinetic energy of the block after 2sec is
A) 20J B) 200J C) 100J D) 120J
5. A ring of radius R rolls without sliding with a constant velocity with respect to ground.
The radius of curvature of the path followed by any particle of the ring at the highest
point of its path will be
A) R B) 2R C) 4R D) 9R

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Narayana IIT Academy 27-01-19_Sr.IIT_IZ_Ph-III_JEE-ADV_2012-P2_GTA-1_Q’P
6. Six starts of equal mass each m are moving about the centre of mass of the system
under mutual gravitational force of attraction such that they are always on the vertices
of a regular hexagon of side length a. Their common time period will be

a3 4 3a 3 3a 3 5 3a 3
A) 4 B) 2 C) 4 D) 2
Gm 
Gm 5 3  4  Gm 
Gm 5 3  4 
7. A right circular cylinder of specific gravity  floats in water with its axis vertical, one
third length above the water. If  be the sp. gr. of air then, choose the correct option.
A) 3  2   B) 3  1   C) 2  2   D) 3  2  2 
8. A particle is describing simple harmonic motion. If its speeds are v1 and v2 when the
displacements from the mean position are y1 and y2 respectively, then its time period is
y12  y22 v12  v12 v12  v22 y12  y22
A) 2 2 B) 2 2 C) 2 2 D) 2 2 2
v1  v22 y1  y22 y1  y22 v2  v1

SECTION - II
(COMPREHENSION TYPE)
This section contains 6 multiple choice questions relating to three paragraphs with two questions on each paragraph.
Each question has 4 choices A), B), C) and D) for its answer, out of which ONLY ONE is correct.
Marking scheme +3 for correct answer , 0 if not attempted and -1 in all other cases.
Paragraph for Questions 9 & 10
Waves y1  A cos 0.5 x 100t  and y2  A cos 0.46 x  92t  are travelling along x-

axis. (Here x is in m and t is in seconds)

9. Find the number of times intensity is maximum in time interval of 1s.
A) 4 B) 6 C) 8 D) 10
10. The wave velocity of louder sound is
A) 100m/s B) 192m/s C) 200m/s D) 96m/s

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Narayana IIT Academy 27-01-19_Sr.IIT_IZ_Ph-III_JEE-ADV_2012-P2_GTA-1_Q’P
Paragraph for Questions 11 & 12
Figure shows the variation of the internal energy U with the density  of one mole of
ideal mono atomic gas for a thermodynamic cycle ABCA. Here process AB is a part of
rectangular hyperbola.

11. The P-V diagram of above process

A) B)
P
C

A
B

C) D) V

12. The total amount of heat absorbed by the system for cyclic process is
10   10 
A)  ln 2.5  2U 0 B)  ln 0.4  2U 0
3  3 
10 
C) 50U 0 D)  ln 2.5  8U 0
3 
Paragraph for Questions 13 & 14
Three concentric conducting shells A,B and C are shown in figure. Radii of the shells
are R, 2R and 3R respectively. Initial charges given to the shells are Q, -Q and 3Q
respectively.

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Narayana IIT Academy 27-01-19_Sr.IIT_IZ_Ph-III_JEE-ADV_2012-P2_GTA-1_Q’P
13. If VA and VB are potentials of shells A and B respectively, then
A) VA  VB B) 2VA  3VB C) 3VA  2VB D) VA  2VB
14. If potential difference between A and B is VAB and between B and C is VBC, then
A) VAB  0 B) VBC  0 C) VAB  VBC D) 2VAB  3VBC
SECTION – III
(MULTIPLE CORRECT CHOICE TYPE)
This section contains 6 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of
which ONE OR MORE is/ are correct.
Marking scheme +4 for correct answer , 0 if not attempted and 0 in all other cases.
15. A large thin non conducting plate with uniform surface charge density  is moving
with constant speed v as shown in the figure. The magnetic field at a small distance
above or below the plate in the middle region is

0 v
A) 0 v in magnitude B) in magnitude
2
C) perpendicular to the plate D) parallel to plate
16. A non conducting ring of mass m and radius R has a charge Q uniformly distributed
over its circumference. The ring is placed on a rough horizontal surface such that the
plane of the ring is parallel to the surface. A vertical magnetic field B  B0t 2 tesla is
switched on. After 2 seconds from switching on the magnetic field, the ring is just
about to rotate about vertical axis through its centre. Then
A) the induced electric field is quadratic in time t
B) the torque on the ring is B0QR 2t
C) until 2 seconds, the friction force does not come into play.
2B0QR
D) the friction coefficient between the ring and the surface is
mg

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Narayana IIT Academy 27-01-19_Sr.IIT_IZ_Ph-III_JEE-ADV_2012-P2_GTA-1_Q’P
17. Two thin convex lenses are separated as shown. The focal length of lens L1 is 15cm
and that of lens L2 is 30cm. An object is placed at distance 30cm from lens L1 . The
location of image formed finally will be at

A) infinity B) 15 cm behind the lens L1

C) optical centre of lens L2 D) 60cm away from object
18. While light is used to illuminate the two slits in a Young’s double slit experiment. The
separation between the slits is b and the screen is at a distance d(>b) from the slits. At a
point on the screen directly in front of one of the slits, certain wavelengths are missing.
Some of these missing wavelengths are
b2 2b 2 b2 2b 2
A)   B)   C)   D)  
d d 3d 3d
238
19. The initial nucleus of uranium series is 92U and the final nucleus is 82 Pb 206 . When

uranium decays to lead by emitting  and  particles then number of

A)   particles produced is 8 B)   particles produced is 6
C)   particles produced is 6 D)   particles produced is 8
20. In an X-ray tube, if the accelerating potential difference is increased, then
A) the frequency of characteristic X-rays of a material will get changed.
B) number of electrons reaching the anode per second will change.
C) number of characteristics X-ray lines may increase.
D) the difference between 0 (minimum wavelength) and K (wavelength of K X-
ray) will get changed.
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Narayana IIT Academy 27-01-19_Sr.IIT_IZ_Ph-III_JEE-ADV_2012-P2_GTA-1_Q’P
CHEMISTRY Max. Marks: 66
SECTION – I
(SINGLE CORRECT CHOICE TYPE)
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of
which ONLY ONE is correct.
Marking scheme +3 for correct answer , 0 if not attempted and -1 in all other cases.
21. Consider the following statements.
I) Second law of thermodynamics helps in supporting the 3rd law of thermodynamics.
II) 2 H 2  g   O2  g   2 H 2O  l  ;  Rxn S  ve so we can conclude that reaction is

impossible.
III) Melting point of substances always increases with increase in pressure.
IV) C P  Cv  R is valid only for ideal gases.
The correct code is:
A) I, III & IV only B) I & IV only C) II, IV only D) II, III & IV
22. The only incorrect statement about enzyme catalysis is:
A) Enzymes do not alter the amount (or) nature of the product.
B) Enzymes retain identify at the end of the reaction, as in the beginning.
C) Most enzymes can’t work in either directions.
D) Enzymes are specific in their action.
23. Consider the following statements:
I) The measurement of cataphoresis of a hydrophobic colloid is more difficult than
hydrophilic colloid.
II) Brownian motion is responsible for the stability of colloidal solution.
III) Gelatin has a isoelectric point at PH =4.7. So, at PH = 4.7 the zeta potential is zero.
IV) The conductivity of an o/w emulsion is lesser than that of w/o emulsion.
The code for the correct statement is: (T – True, F – False)
A) F T T F B) T F F T C) F T F T D) T F T F
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Narayana IIT Academy 27-01-19_Sr.IIT_IZ_Ph-III_JEE-ADV_2012-P2_GTA-1_Q’P
24. In the specific conductance measurement, D.C (direct current) is not used because:
A) Ohm’s low can’t be applied to D.C
B) D.C heats up the solution.
C) D.C causes polarization at the electrode.
D) D. C is expensive.
25. The only incorrect statement is:
A) Rise in the compression factor with increasing pressure is due to the factors, ‘b’.
B) A gas can be liquefied at T = TC, P < PC.
C) Average speed of molecules of a gas in a container moving only in one dimension
will be zero.
D) For two gases, if pressures are equal, T1 = 2T2 and 2 = 21, then 1 > 2.
26. The correct set (T – True, F – False) about the following statement is:
I) All tetrahedral complexes are high – spin.
II) Tetrahedral complexes are favoured where the ligands are large and bulky.
III) Whenever dz2 and dx2  y2 orbitals are unequally occupied, Jahn – teller distortion
occurs in a non – linear molecule.
IV) An aqueous solution of Co  NH 3 5 Br  SO4 gives a white Precipitate of

BaSO4 with BaCl2 solution.

A) T T T T B) T F T F C) F F T T D) T T F F
27. The correct order of solvolysis of the following compounds.

Cl
Cl Cl Cl

(I) (II) (III) (IV)

A) I>II>III>IV B) II>III>I>IV C) II>III>IV>I D) IV>II>III>I

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Narayana IIT Academy 27-01-19_Sr.IIT_IZ_Ph-III_JEE-ADV_2012-P2_GTA-1_Q’P
28. The conversion of bromobenzene to benzoic acid is best achieved by
A) Heating with NaOH and CO2 under pressure
B) Heating with formic acid
C) Reaction with (i) Mg/Dry ether, then (ii) CO2
D) Reaction with (i) Mg/Dry ether, then (ii) HCHO
SECTION - II
(COMPREHENSION TYPE)
This section contains 6 multiple choice questions relating to two paragraphs with three questions on each paragraph.
Each question has 4 choices A), B), C) and D) for its answer, out of which ONLY ONE is correct.
Marking scheme +3 for correct answer , 0 if not attempted and -1 in all other cases.
Paragraph for Questions 29 & 30
Element (A) burns in nitrogen to give an ionic compound (B). Compound (B) reacts
with water to give (C) and (D). A solution of (C) becomes milky on bubbling CO 2. The
chloride of elements (A) imparts brick red colour to Bunsen flame.
Now answer the following questions:
29. The element (A) is:
A) Ca B) Mg C) Al D) K
30. The incorrect statement about aqueous solution of D is:

A) With Hg 22 , it gives black Precipitate.

B) It dissolves Cu 2  salt forming deep – blue colouration.

C) With Fe3 it forms a reddish – brown Precipitate which is soluble in excess of the
reagent (D).

D) With Ni 2  it forms a green Precipitate which dissolves in excess of the reagent (D).

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Paragraph for Questions 31 & 32
F
150o C
750atm H 2 ; Al
 
D  B 
o
 Na2 B4O7   
2 4  A  B 
H SO
H 2O Red Hot
740 C
C2 H 5OH

C 
Now answer the following questions:
31. The incorrect set is:
A) A  H 3 BO3 B) B  B2O3 C) C  B  OC2 H 5 3 D) D  Na2O

32. The incorrect statement(s):

A) (D) can be used to prepare brightner in washing powder.
B) (F) can undergo symmetrical cleavage with 1o – amines.
C) (C) gives green edged flame.
2:1
D) (F)  NH 3 
o

 compound (G), which can undergo
High temperature, 200 C

hydrolysis.
Paragraph for Questions 33 & 34
Observe the following reaction scheme and answer the following question regarding it.
O

NH2 OEt
EtONa, then H3O+ NaOH, then H3O+, heat
P S
Q
excess

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Narayana IIT Academy 27-01-19_Sr.IIT_IZ_Ph-III_JEE-ADV_2012-P2_GTA-1_Q’P
33. Identify the product ‘P’ in the above reaction scheme.
OEt
H
N O N

OEt OEt

A) O B) O
NH2
H
N

O
C) D) O

34. Identify the product ‘S’ in the above reaction scheme.

H O
N H
N
N N O

A) O B) C) O D)
SECTION – III
(MULTIPLE CORRECT CHOICE TYPE)
This section contains 6 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of
which ONE OR MORE is/ are correct.
Marking scheme +4 for correct answer , 0 if not attempted and 0 in all other cases.
35. Which of the following reactions will lead to the formation of N2?

A)  NH 4 2 SO4 
 B) NH 4Cl  NaOH 
 
C) NH 4 NO3 
 D) Ba  N 3 2 

36. Pick up the correct observations?

A) HPO42  Mg 2  NH 3  White Precipitate

B) Na2 B4O7  CaF2  H 2 SO4  Green flame
C) HO.SO2 .NH 2  HNO2  Nitrates

D) NH 4  PtCl62   No Precipitate

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Narayana IIT Academy 27-01-19_Sr.IIT_IZ_Ph-III_JEE-ADV_2012-P2_GTA-1_Q’P
37. The correct statement(s) is/are
A) HNO3 and H 2 SO4 behave as bases in anhydrous HF.
1
B) NH 3  Na  NaNH 2  H 2
2
In the above reaction, NH3 acts an acid.
C) On adding Li3 N to liquid NH 3 acidity will increase.
D) BF2Cl  BFCl2 (Lewis – acidic strength).
38. The correct statement(s) is / are:
1
A) CO  CO   C  O bond length  B) InCO32  , C  O bond order is 1
3

C) N3 is linear. D) B2 is paramagnetic.

39. The CORRECT statement(s) about carbene is (are).
A) Carbene is a neutral species.
B) Carbene is an intermediate in the Curtius rearrangement.
C) Carbene can insert into both  and  - bonds.
D) Carbene is generated from amines on reaction with nitrous acid.
40. Tetrapeptide(s) that gives (give) the following product on reaction with Sanger’s
reagent followed by hydrolysis is (are)

A) Ala-Gly-Leu-Phe B) Asp-Phe-Leu-Pro
C) Asp-Gly-Tyr-Phe D) Ala-Phe-Tyr-Pro

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Narayana IIT Academy 27-01-19_Sr.IIT_IZ_Ph-III_JEE-ADV_2012-P2_GTA-1_Q’P
MATHS Max. Marks: 66
SECTION – I
(SINGLE CORRECT CHOICE TYPE)
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of
which ONLY ONE is correct.
Marking scheme +3 for correct answer, 0 if not attempted and -1 in all other cases.
      2    3    4 
41. If tan  tan     tan     tan     tan     k 3 then the value of
15  15 5   15 5   15 5   15 5 

k is
A) 2 B)3 C) 4 D) 5

1 x 2  ax  1 1  1  2
42. Lt  tan   dx is equal to where k  N equals
a  a
0
l  x4 x k
A) 4 B) 8 C) 16 D) 32
43. The number of three digit numbers between the two A.P's 3, 11, 19, 27...... and 7, 30,
53..... that are common is
A) 5 B) 4 C) 6 D) 8
44. The abcissa of A and B on the circle x 2  y2  25 are respectively 5 and -5. Let MN be
a variable chord perpendicular to AB and if the locus of point of intersection of the
lines BM and AN is a conic then its eccentricity is
1
A) 1 B) 2 C) D) 8
5
1
x3
45. Let f  x   8x 3  3x and f 1  x  be the inverse function of f  x  , then Lt 1 
x  f  8x   f 1  x 
A) 0 B) 1 C) 2 D) 4
46. Number of ways in which 4A's, 1B, 1C and 1D can be distributed among 4 persons
such that everyone gets atleast one letter and no one gets all 4A's, is
A) 832 B) 2432 C) 2077 D) 608

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Narayana IIT Academy 27-01-19_Sr.IIT_IZ_Ph-III_JEE-ADV_2012-P2_GTA-1_Q’P
47. The minimum distance of the point (1, 1, 1) from the plane x + y + z = 1 measured
x  x1 y  y1 z  z1
perpendicular to the line   is
1 2 3
2 2 2 2
A) 21 B) 22 C) 23 D) 24
3 3 3 3
48. If the inequality sin 2 x  a cos x  a 2  1  cos x holds for any x  R , then range of values for
negative ’a’ is
A) a< -1 B) a < 0 C) a < -2 D) a  -2
SECTION - II
(COMPREHENSION TYPE)
This section contains 6 multiple choice questions relating to three paragraphs with two questions on each paragraph.
Each question has 4 choices A), B), C) and D) for its answer, out of which ONLY ONE is correct.
Marking scheme +3 for correct answer , 0 if not attempted and -1 in all other cases.
Paragraph for Questions 49 & 50
b b

 f  x  dx   f  a  b  x  dx
a a ,
a a

a
 f  x  dx  2 f  x  dx when f  x  is even
0

= 0 when f  x  is odd

sin 2 x
49.  x 5
 x 2  25
dx is equal to

  2
A) 0 B) C) D)
5 10 5

2
cos x
50.  dx is equal to
 
2
0 1  sin 2x

 1  2
A) B) C) D)
4 3 2 3

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Narayana IIT Academy 27-01-19_Sr.IIT_IZ_Ph-III_JEE-ADV_2012-P2_GTA-1_Q’P
Paragraph for Questions 51& 52
Let x 2  y 2  4x  3  0 be two fixed circles, A triangle ABC has vertices A(0, 2),
B  2, 2 3  2  , C  2, 2 3  2  . It starts moving downwards (i.e, in the negative direction

of y-axis) and stops when its sides touch the circles (AB at P1 and AC at P2)
51. The ratio in which P1 divides new positions of A and B is

3 3 4 3 1 3 2 3
A) B) C) D)
3 3 3 3
52. The ordinate of the new position of vertex A of the triangle ABC is
A) 2  3 B) 2  2 3 C) 2  2 3 D) 1  2 3
Paragraph for Questions 53 & 54
Suppose A,B,C are three-non collinear points corresponding to complex numbers
1
z0  ai , z1   bi, z2  1  ci  a, b, c  R  respectively .Now consider the curve
2
z  z0 cos 4 t  2 z1 cos 2 t.sin 2 t  z2 sin 4 t  t  R 
53. The locus of z is a
A) straight line B) straight line or parabola
C) parabola D) segment of a parabola
54. The number of points the curve z shares with the line passing through the midpoints of
AB and BC is
A) 0 B) 1 C) 2 D) infinite

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SECTION – III
(MULTIPLE CORRECT CHOICE TYPE)
This section contains 6 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of
which ONE OR MORE is/ are correct.
Marking scheme +4 for correct answer , 0 if not attempted and 0 in all other cases.
1 4
55. Equation of a plane which is at a distance of units from origin and at a distance of
5 5
units from 1, 2, 1 is ax  by  cz  d  0 . The plane also passes through the intersection
of x  y  z  3  0 , 2x  2y  z  5  0 and 4x  y  3z  6  0, a  0 . Then
A) c + d=0 B) a + b = 0 C) c = 0 D) a + b + c + d=0
56. If x sin A  y sin B  z sin C  0 and x 2 sin 2A  y 2 sin 2B  z 2 sin 2C  0 , then the value of
x 3 sin 3A  y3 sin 3B  z3 sin 3C ( where x,y,z, A,B,C  R and A  B  C   )

A) is equal to 0 B) depends on A,B,C

C) depends on x, y, z D) None of these
57. Let A be a 3x3 invertible matrix such that A3  pA 2  p 2 A  0 where p is a prime natural
number then
A) Number of factors of ( -det(A)) are 4
B) Adjoint of A is square of A
C) Trace of AA T is positive
D) A 4 is a scalar multiple of A
58. f  x   ex , 0  x  1
 2  ex 1 , 1  x  2
x
 x  e, 2  x  3 and g  x    f  t  dt, x  1, 3 then g  x  has
0

A) local maximum at x  1  ln 2 and local minima at x = e

B) local minima at x = 1 and local maxima at x = 3
C) no local maxima
D) no local minima

Sec: Sr. IIT_IZ Space for rough work Page 17

Narayana IIT Academy 27-01-19_Sr.IIT_IZ_Ph-III_JEE-ADV_2012-P2_GTA-1_Q’P
The value(s) of k for which f  x    k  x  e5 x  is differentiable at all x  R is
2
2
59.
1
A) 0 B) C) 1 D) 5
5
60. A circle touches the parabola y 2  4ax  a  0  at P. It also passes through the focus S of

the parabola and intersects its axis at Q . If angle SPQ is 900 . Then which of the
following is/are correct ?
A) abcissa of centre of the circle = 10 a
B) ordinate of centre of the circle = 0
C) radius of the circle = 4a
D) circle is passing through origin

Sec: Sr. IIT_IZ Space for rough work Page 18