JE

ManzilJEE (2025)
Physics
DPP: 3
Motion in a Straight Line
t
b
Q1
A particle is moving with speed v = b √ time sec
erewill e eball te 2
x along positive x-axis. Calculate the
speed of the particle at time t = τ At h/2 fro t he g un
(assume that the particle is at origin at t (B) At h/4 from the ground
= 0) (C) Depends upon mass and volume of
(A) b2τ the body

(B) b2τ (D) At 3h/4 from the ground

4
(C) b2τ 2 Q5 A particle moving in a straight line has velocity

(D) displacement equation as v = 5 √ 1 + x .

b Here vis in m/sec and x in metre. Select the
2
correct alterative
τ
(A) Particle is initially at rest.
√
2 (B) Initial velocity of the particle is 5 m/sec
and the particle has a constant acceleration
Q2 A particle is dropped from a certain height.
The time taken by it to fall through of 12.5 m/sec2.
(C) Particle moves with uniform velocity.
successive distances of 1 km each will be:
(D) None of these.
(A)
All equal, being equal to
Q6 The motion of a body falling from rest in
integers 1 : √2 : √3 a viscous medium is described by
roots of the integers,i.e., √ 1, ( √ 2 −√
(C) In the ratio of the di ff erence in the
dv
( √3 − √2), ( √4 − √3) = A − Bv , where A and B are constants.
dt
(D) In the ratio of the reciprocals of the The velocity at time t is given by:
square (A)
, , , (1 − e −Bt
)
√1 √2 √3 B
(B)
−B2t
Q3 A body starts to fall freely under gravity.
A (1 − e )
The distances covered by it in first, second (C) ABe−t
and third second are in ratio: (D) AB2 (1 − t)
(A) 1:3:5 (B) 1:2:3 Q7
(C) 1:4:9 (D) 1:5:6 For a stationary object at x = 40 m ,
the position-time graph is
Q4 A body is released from the top of a tower
of height h. It takest sec to reach the ground.

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(B )(I → P), (II → P), (III → Q), (IV
→ R)
(C) (I → R), (II → Q), (III → P), (IV
→ S)
(D) (I → Q), (II → R), (III → P), (IV
→ S)

(A) (B) Q10 Match the list-I with list-II (symbols have
A B usual meanings)

Water drops fall at regular intervals from a tap

Q
which is 5 m above the ground. The third drop
is leaving the tap at the instant the first drop
touches the ground. How far above the ground
is the second drop at that instant? (Take

g = 10 ms−2 )
(A)
m
4
(B) 4 m
(C)
5 m (A) II III-P
2
m (B) II III-S
4
(C) II- III-R
The velocity-time graph of a particle moving (D) I-P II-R III-T IV-Q
Q
along X -axis is shown in figure. Match the Q11 The accelerations of a particle as seen
entries of Column I with entries of Column II
from two frames S1 and S2 have equal
magnitude
4 m/s2.
(A) The frames must be at rest with respect
to each other.
(B) The frames may be moving with respect
to each other but neither should be
accelerated with respect to the other.
(C) The acceleration of S2 with respect to
S1 may either be zero or 8 m/s 2 .
(D) The acceleration of S2 with respect to S1
may be anything between zero and 8
m/s2
.
(A) (I → P, R), (II → Q), (III → S),
Q12 A scooter starting from rest moves with a
(IV → P)
constant acceleration for a time Δt 1 , then with

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a constant velocity for the next Δt 2 and finally after t and that of the second body by x 2
with a constant deceleration for the next Δt 3
(t) after the same time interval. Which of
to come to rest. A 5 0 0 N man sitting on the
the
scooter behind the driver manages to stay at
rest with respect to the scooter without following graphs correctly describes (x1 −
touching any other part. The force exerted by (x 2 ) as a function of time t ?

the seat on the man is-

( A ) 5 0 0 N throughout the journey
( B ) less than 5 0 0 N throughout the journey
(C) more than 500 N throughout the journey
(D) > 500 Nfor time Δt1 and Δt3 and 500
N for Δt 2 .
Q13 From a tower of height H , a particle is thrown
vertically upwards with a speed u . The time (
taken by the particle to hit the ground is n
times that taken by it to reach the highest
point of its path. The relation between H, u
and n is given by
(A) gH = (n − 2)u2
(
(B) 2gH = n2u2
(C) gH = (n − 2)2u2
(D) 2gH = nu2 (n − 2)

Q14 A ball projected from ground vertically upward

is at same height at time t1 and t2. The speed
of projection of ball is [Neglect the e ff ect of air
(
resistance]
(A) g[t2 − t 1] (B)
2
(C) g[t2 −t1] (D) g[t1 + t2]
2

Q15 A body is at rest at x = 0 . At t = 0 , it starts

moving in the positive x -direction with a
constant acceleration. At the same instant
Q16 The graph given shows the POSITION of two
another body passes through x = 0 moving in
the positive x-direction with a constant speed. cars, A and B, as a function of time. The cars
move along the x -axis on parallel but
The position of the first body is given by x1 (t) separate

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tracks so that they can pass each other's
(A)
position without colliding.
1 + V1 +
(B)
1 − V1 +

(C) 1/2
1+
(D) 1/2
1−

At which instant do the two cars have Q20 A particle of unit mass undergoes one
the same velocity? dimensional motion such that its velocity

(A) t1 varies according to v(x) = βx − 2 n where β

(B) t2 and n are constants and x is the position of
(C) t3 the particle. The acceleration of the particle
as a function of x , is given by:
(D) t4 (A) 2 −4n − 1
−2nβ x
Q17 A ball is bouncing elastically with a speed
(B)
1 m / s between walls of a railways −2nβ2e−4n+1
(C)
compartment of size 10 m in a direction −2β2x−2n+1
perpendicular to walls. The train is moving at (D)
−2nβ2x−2n − 1
10 m/s along the diretion of motion of ball.
As seen from the ground which statement is Q21 A man is going up in a lift (open at the top)
incorrect. moving with a constant velocity 3 m / s . He
(A) The direction of motion of ball throws a ball up at 5 m/sec relative to the lift
changes every 10seconds when the lift is 50 m above the ground.
(B) speed of ball changes every 10 seconds Height of the lift when the ball meets it during
its
(C) Average speed of ball over any 20
seconds interval is fixed downward journey is (g = 10 m/s 2 )
(D) The acceleration is the same as seen
(A) 53 m
from the train (B) 58 m
(C) 56 m
Q18 A particle starting from rest with constant (D) 68 m
acceleration travels a distance x in first 2s Q22 A particle moves along a straight line such
and a distance y in next 2 s , then that its displacement S varies with time t as
(A) y =x (B)y = 2x S = α + βt + γt2
(C) y = 3x (D) y = 4x
Q19 A ball is thrown vertically upwards from the
top of a tower of height h with velocity v . The
ball strikes the ground after time.

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(A) I-P, II-Q, III-S, IV-R

(B) I-Q, II-P, III-R, IV-Q The acceleration-displacement of
(C) I-P, II-Q, III-R, IV-S graph bicycles motion is best
(D) I-Q, II-P, III-S, IV-R (
A point object traverses half the distance with
Q
velocity v 0 . The remaining part of the distance
is covered with velocity v 1 for the halftime and
with velocity v 2 for the rest half. The average
velocity of the object for the whole journey is
(A) 2v1 (v0+v2)
(
(v0+2v1+2v2)
(B) 2v(v0+v1)
(v0+v1+v2)
(C) 2v0
(v1+v2)
(v1+v2+2v (
0)

(D) 2v2
(v0+v1)
(v1+2v2+v
0)

A ball is thrown up vertically with a certain

Q
velocity so that, it reaches a maximum height (

h. Find the ratio of the times in which it is at

height while going up and coming down
respectively
(A) √2 − 1

√2+1
√
(B) √3 −
2
√3+√2
(C) √3 − 1
√3+1
1
(D) 3

The velocity-displacement graph describing

Q the motion of a bicycle is shown in the figure.

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ManzilJEE (2025)
Physics
DPP: 2
Electric Charges & Fields

Q1
(C) Q = 4q
There exists an electric field of 1 N/Calong
(D) Q = 3q
y direction. The fl ux passing through the
square of 1 m placed in xy plane inside Q4 Two electrons each are fi xed at a distance 2 d .
the electric field is A third charge proton placed at the midpoint is
displaced slightly by a distance ( x < < d )
(A) 1.0 N/m2
perpendicular to the line joining the two fixed
(B)
10.0 Nm2 /C charges. Proton will execute simple harmonic

(C)
motion having angular frequency: ( m=
2.0 Nm2 /C mass of charged particle)
(D) Zero
(A) 2 2
1

Q2 A charge q is placed at one corner of a cube

as shown in figure. The fl ux of electrostatic (B) 2
field E though the shaded area is: 3

(C) 3
2

(D)
1

(B) q
Q5 The electric field above a uniformly charged
nonconducting sheet is E . If the
(A) q
nonconducting sheet is now replaced by a
48ϵ0
conducting sheet, with the charge same as
8ϵ0 before, the new electric field at the same point
(C)
q is E then x will be:
2
4
ϵ0 Q6 Two charged thin infinite plane sheets of
(D) uniform surface charge density σ+ and σ
q
4 − , where |σ + | > |σ − | , intersect at right
∈ angle. Which of the following best
0
represents the electric field lines for this
Q3 A certain charge Q is divided into two parts q system:

andQ(Q= − q) . How should the chargesQ

and q be 2divided so that q and (Q − q)
placed at a certain distance apart
experience maximum Android App
electrostatic repulsion?
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(A) Q8 Two point charges A and B, having
(B) charges +Q and −Q respectively, are
(C) placed at
(D) certain distance apart and force acting

Q7 1 0 cm has
A spherical conductor of radius between them is F. If 2 5 % charge of A
−7 is transferred to B , then force between
a charge of 3.2 × 10 C distributed the charges becomes :
uniformly. What is the magnitude of electric
field at a (A) F
(B) 9 F
16
(C) 16
F
9
(D) 4
F
3

Q9 The electric field at a point on the equatorial

plane at a distance r from the centre of a
→
dipole having dipole moment P is given by, (
r >> separation of two charges forming
the dipole, ϵ0 - permittivity of free space)
(A) →
→ 2P
E = 4πϵ0r3
(B) → →
P
E = −
4πϵ0 r
(C) → →
P
E= −
4πϵ0r3
(D) → →
P
E =
4πϵ0r3

Q10 What will be the magnitude of electric field at

point 15 cm from the centre of the point O as shown in the figure? Each side of
sphere?
the figure is l and perpendicular to each
= 9 × 109 N m2 /C2 ). other?

(A) 1.28 × 105 N/C

(B) 1.28 × 106 N/C
(C)
1.28 × 107 N/C
(D) 1.28 × 104 N/C

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(C) 7 μC, 3 μC
(A) 1 q
4πε0 l2 (D) 8 μC, 2 μC
(B) 1 q

(2√2 Q14 Two identical tennis balls each having mass

4πε0 (2l2 )
‘m’ and charge ‘q’ are suspended from a fixed
(C) q
4πε0 point by threads of length ‘l’. What is the
(2l2 ) equilibrium separation when each thread
(D) 1 2q makes a small angle ‘θ’ with the vertical?
(
4πε0 (2l2 )
(A) 1/2
x=
Q11 A particle of charge q and mass mis
subjected to an electric fi eldE =
E0 (1 − (B) 1/3
2
ax ) in the x -direction, where a and E 0 x=
are constants.
(C) 1/3
Initially the particle was at rest at x = 0 . x=
Other than the initial position the kinetic
(D) 1/3
energy of q2
the particle becomes zero when the
x= ( )
2πε0 m2g
distance of the particle from the origin is:
Q15 A point charge of 10μC is placed at the
(A) √ 1
a origin. At what location on the X-axis should
(B) a point charge of 40μC be placed so that the
net
(C) a
(D) electric fieldis zero at x = 2cm on the X-axis?
(A) x = 6 cm
(B) x = 4 cm
Q12 An oil drop of radius 2 mm with a density
−3
(C) x = 8 cm
3 g cm is held stationary under a
constant (D) x = –4 cm
−1
electric field 3.55 ×105Vm in the Q16 Charges Q1 and Q2are at points A and B of
Millikans
oil drop experiment. What is the number of a right angle triangle OAB (see figure). The
excess electrons that the oil drop will resultant electric field at point O is
2
possess? (consider g = 9.81 m/s ) perpendicular to the hypotenuse, then
Q 1 / Q 2 is proportional to

(A) 48.8 × 1011

(B)
1.73 × 1010
(C)
17.3 × 1010
(D) 1.73 × 1012

Q13 A 1 0 μ C charge is divided into two parts and

placed at 1 cm distance so that the repulsive (A) (B)
3 2
force between them is maximum. The charges x
of the two parts are: 1 x
2
3
(A) 9 μC, 1 μC
x 2
2 x
(B) 5 μC, 5 μC

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For a uniformly charged ring of radius R, Determine the electric dipole moment of the
Q Q
the electric field on its axis has the largest system of three charges, placed on the
vertices of an equilateral triangle, as shown in
magnitude at a distance h from its centre.
the

Then value of his figure.

(A) R (B)
√5 √2
(C) R (D)
R √2
Figure shows the field lines of a point negative
Q
charge. In going from B to A , the kinetic
energy of a small negative charge will

(
A 2qlj^
)
^ ^
(ql)
(A) increase ( ^ ^
(B) decrease C
) √3ql
(C) remain constant
( D ) data insuffi cient. ^
− √3qlj
Q
A thin conducting ring of radius R is given The electric field is 100 V/m , at a distance of
Q
a charge +Q . The electric field at the 20 cm from the centre of a dielectric sphere
centre O of the ring due to the charge on
of radius 10 cm. Then electric field (E) at 3
the part
cm distance from the centre of sphere is :-
AKB of the ring is E . The electric field at
the (A) 100 V/m
centre due to the charge on the part (B) 125 V/m
ACDB
(C) 120 V/m
(D) Zero

Q Two point charges A and B , having

charges +Q and −Q respectively, are
placed at
certain distance apart and force acting
(A) E
along
KO (B) 3E between them is F. If 2 5 % charge of A
along OK (C) is transferred to B , then force between
3E along KO the charges becomes
(D) E along
OK
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(A) 4F negative charges. The magnitude of
3
these charges is (Atomic mass of Al =
(B) F
26.98 g)
(C)
9
F (A)
1 3.47 ×
6 104 C (B)
(D) 3.47 × 102
1
6
F
C (C) 1.67 ×
9 1020C
Q23 Under the influence of the electric field of a
fi xed charge + Q , a charge − qis moving
around it in an elliptical orbit. Which of the
following statements is/are correct in this
situation :
(A) The angular momentum of the charge −q
is constant
(B) The linear momentum of the charge −q is
constant
( C ) The angular velocity of the charge −q
is constant
( D ) The linear speed of the charge −q
is constant

Q24 A copper (density of Cu = ρ C ) ball of

diameter d is immersed in oil of density ρ0 .
What is the charge on the ball if, in a
homogeneous electric field E directed
vertically upward, it is suspended in the oil?

(k ≡ πd3 )
(A)
k (1 −
(B)
k (1 −

(C)
k (1 −
(D)
k (1 −

Q25 A coin is made up of aluminium and weighs

0.75 g . It has a square shape and its diagonal
measures 1 7 mm. It is electrically neutral and
contains equal amounts of positive and

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ManzilJEE (2025)
Physics
DPP 0 1
Units and Measurements + Mathematical Tools

Q1 The relative density of material of a body is

found by weighing it first in air and then in

(5.00 ± 0.05)
water. If the weight in air is
newton and weight in water is (4.00 ±0.05 ) What are the diameter and cross-
newton. Then the relative density along with sectional area of the wire measured
the maximum permissible percentage error is using the screw gauge?

(A) 5.0 ± 11% (A) 2.22 ± 0.02 mm, π(1.23 ±

(B) 5.0 ± 1%
0.02)mm2 (B) 2.22 ± 0.01 mm,
(C) 5.0 ± 6%
π(1.23 ± 0.01)mm2 (C) 2.14 ±
(D) 1.25 ± 5%
0.02 mm, π(1.14 ± 0.02)mm2
Q2 The SI unit of energy is J = Kg m2 s − 2 that of (D) 2.14 ± 0.01 mm, π(1.14 ±
0.01)mm2
−1 −2
speed is ms and of acceleration a isms .
Which of the formula for kinetic energy (K) Q4 A quantity is measured repeatedly many
given below can you rule out on the basis of times with an instrument. The readings are
dimensional arguments (m stands for the shown in figure where T represent true
(
value of
mass of the body).
the measurement. Which of the
2 2
I. K = m v following measurement is imprecise but
II. K = (1/2)mv2 (
III. K = ma
IV. K = (3/16)mv2
(C)
2
V. K= + ma
(A) I and II (B) Only II
(C) II and IV (D) I, III
(D)
Q3 Area of the cross-section of a wire is measured
using a screw gauge. The pitch of the main
scale is 0.5 mm. The circular scale has 100
divisions and for one full rotation of the
circular scale, the main scale shifts by two Q5 A bus travels distance x 1 when
accelerates from rest at constant rate a2
divisions. The measured readings are listed for some time and after that travels a
below. distance x 2 when

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decelerates at a constant rate a 2 to come to (A) If both statement I and statement II
rest. A student established a relation
are true and statement II is the
x1 + x2 = . correct
Choose the correct option(s). explanation of statement I.
(A) The relation is dimensionally correct (B) If both statement I and statement II
(B) The relation is dimensionally incorrect are true but statement II is not the
(C) The relation may be dimensionally correct correct explanation of statement I.
(D) None of the above
(C) If statement I is true but statement II
is false.
Q6 (D) If both statement I and statement II
are false.

Q9 There are two Vernier calipers both of which

The value of n is(You may use dimensional have 1 cm divided into 10 equal divisions
analysis to solve the problem.) on the main scale. The Vernier scale of
one of the calipers (C 1 ) has 10 equal
(A) 0
(B) − 1 divisions that
(C) 1 correspond to 9 main scale divisions. The
( D ) none of these. Vernier scale of the other caliper (C 2 ) has
10 equal divisions that correspond to 11
Q7 In the following question, a statement of main
assertion (A) is followed by a statement of scale division. The readings of the two
reason (R) calipers are shown in the figure. The
A: Displacement gradient is a dimensionless measured values (in cm) by calipers C1 and
quantity.
R : Displacement is dimensionless quantity.
(A) Both Assertion & Reason are true and the
reason is the correct explanation of the
assertion.
(A) 2. 87 and 2. 86
(B) Both Assertion & Reason are true but the
(B) 2. 85 and 2. 82
reason is not the correct explanation of the (C) 2. 87 and 2. 87
assertion. (D) 2. 87 and 2. 83
(C) Assertion is true statement but Reason Q10 If P and Q have di ff erent non-zero
is false. dimensions. which of the following
(D) Both Assertion and Reason are operation is possible:
false statements.
(A) P2 + Q 2
Q8 Statement I: Angle and angular displacement (B) PQ2
are dimensionless quantities. (C) P2 − Q2
Statement II: Angle is equal to arc length ( D ) All of these

divided by radius.
Choose the correct option from the following.

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A physical quantity of the dimensions of length frequency, F= force, and S= area, match
Q
Column I with Column II and mark the
that can be formed out of c, G and is [ c correct option from the codes given below.
is velocity of light, G is universal constant of
gravitation and e is charge]:
(A) 1/2
c2 [ G
(B) 1/2
1
c
2
e2
(C) 1 G 4πε0
c2
(A) i-a; ii-b; iii-c; iv-d
(D) 1/2 (B) i-c; ii-a; iii-b; iv-d
G
(C) i-b; ii-a; iii-d; iv-c
A student measuring the diameter of a pencil (D) i-a, b; ii-c, d; iii-a; iv-b
Q
of circular cross-section with the help of a
Q15 The Sun's angular diameter is measured to
vernier scale records the following four
′′
be 1920 . The distance D of the Sun from
readings 5.50 mm, 5.55 mm, 5.45 mm;
the
5.65 mm. The average of these four
readings is 5.5375 mm and the standard Earth is 1.496 × 1011 m. What is the
deviation of the data is 0.07395 mm. The diameter of the Sun?
average (A) 1.39 × 109 m
diameter of the pencil should therefore
(B) 1.5 × 109 m
be recorded as
(C) 1.9 × 109 m
(A) (5.5375 ± 0.0739)mm (D) 3.6 × 109 m
(B) (5.54 ± 0.07)mm
Q16 Planck's constant (h), speed of light in
(C) (5.538 ± 0.074)mm
vacuum
(D) (5.5375 ± 0.0740)mm
(c) and Newton's gravitational constant
If the value of force is 1 0 0 N and value of (G) are three fundamental constants.
Q
Which of the following combinations of these
acceleration is 0.001 ms−2 , what is the value
of mass in this system of units? has the
dimension of length?
(A) 103 kg
(A) √hG
(B) 104 kg
c3/2
(C) 105 kg
(B) √hG
(D) 6
10 kg c5/2
(C)
Q If β = bulk modulus of electricity, A= √
amplitude, K= angular wave number, r= radius, h
c
Y = Young's modulus, m= mass, ω = angular
G
Android App (D)

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 JE

Q The pitch of screw gauge is 1 mm and there

are 100 divisions on circular scale. Screw
gauge is zero error free. While measuring

diameter of a wire, the main scale reads 1

mm and 48th division on circular scale
coincides with the reference line. The length
of wire is
(A) I-(p); II-(p); III-(s); IV-(r)
5.0 cm . Find the volume of the wire.
(B) I-(p); II-(q); III-(r); IV-(s)
(A) 2.6 cm3
(C) I-(r); II-(p); III-(q); IV-(s)
( D ) None of these (B) 0.086 cm3
(C) 0.026 cm3
Q18 Suppose two students are trying to make
(D) 0.036 cm3
a new measurement system so that they
can Find out the incorrect statement from below
Q
use it like a code measurement system and (A) log(1 × 2 × 3) = log 1 + log 2 +
others do not understand it. Instead of
log 3 (B) log(2 + 3) = log(2 × 3)
taking 1 kg, 1 m and 1sec. as basic
unit they took unit of mass as α kg, the unit (C) log10 10 = 1
of length as β m and unit of time as γ (D) log10 1 = 0
second. They called
power in new system as SHAKTI then Q Find the value of tan 135 ∘
(A) 1 (B) -1
(C) ∞ (D) None

(A) A − (q);B − (p); C − (r);D The slope of graph in figure at point A, B and
Q
C is mA, mB and mC respectively, then:
(B) A − (p);B − (q); C − (r);D
(C) A − (q);B − (p); C − (s);D − (r)
(D) A − (p);B − (r); C − (q);D − (s)

Q19 In a Vernier calipers, one main scale division

(A) mA> mB> mC
is x cm and n division of the Vernier scale
(B) mA< mB< mC
coincide with (n − 1) division of the main
(C) mA = mB = mC
scale. The least count (in cm) of the calipers
(D) mA = mB< mC
(A)
is: ( )x ˆˆ
Q
(B) A force (2 + 2 i j)N displaces an object
( )
(C) x n ˆ ˆ
through a displacement (2 i –3 j )m .
(D)
( )
→
The work done is (work done = F. S)

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(A) 2 J (B) –2 J
(C) 5 J (D) 13 J

Q25 A truck travelling due north with 2 0 m / s turns

towards west and travels at the same speed.
Then the change in velocity is -

(A) 40 m/s north-west

(B)
20√2 m/s north-west
(C) 40 m/s south-west
(D)
20√2 m/s south-west

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Manzil JEE (2025)

Maths
DPP: 1
Matrice
(B) skew-symmetric
Q1 If A and B are symmetric matrices of the
(C) neither symmetric nor skew-symmetric
same order and X = AB + BA and
T (D) data not adequate
Y = AB − BA , then (XY) is equal to
(A) XY (B) Y X
Q7 Let A, B be two 2 × 2 matrices. Let
(C) −Y X (D) none of these
α = det(A) + det(B) − det(A + B)
and β = tr(AB) − (trA)(tr B) , then
Q2 How many 3 × 3 matrices M with entries from
(A) α = β
{0,1,2} are there, for which the sum of
(B) α + β = 0
the diagonal entries of M T M is 5 ?
(A) 198 (B) 162 (C) α2 = β

(C) 126 (D) 135 (D) α = β 2

Q8 Let α be a root of equation x2 + x + 1 = 0 and

Q3 Let A and B be two non- singular matrices
3
such that A ≠ I, B = I and AB = BA ,
2 ⎡11 1 1 ⎤
the matrix A = α α2 , then the
where I is the identity matrix, the least value ⎦⎥
of k such that 1 α2 α4
matrix A31 is equal to :
A k = I is 3
(A) 3 (B) 5 (A) A (B) A2
(C) 7 (D) 9 (C) I3 (D) A

Q9 If A is a square matrix of order 5 and

Q 4 A square matrix P satisfi es P2 = I − P ,
2 A − 1 = AT , then the remainder when
where I is identity matrix. If P n = 5I − 8P , then n
is : |adj. (adj. (adj. A))| is divided by 7 is
(A) 4 (B) 5 (A) 2 (B) 3
(C) 6 (D) 7 (C) 4 (D) 5

⎣c a Q10
−1
If A = [ ] then
and abc = λ (< 0) . 0 2 ,
2
The equation whose roots are a, b, c, is ∣A + 3A + 2I + tr(B + C) ∣ where B and
(A) x 3 − 2x 2 + λ = 0 C are matrices of order 2 with integer elements
(B) x3 − λx2 + λx + λ = 0 and A = B 3 + C 3 , is
(C) x 3 − 2x 2 + 2 λ x + λ = 0 (A) -3 (B) 3
(D) x 3 ± x 2 − λ = 0 (C) 0 (D) 2

Q11 If A and B are two non-singular matrices of order

Q6 If A1 , A 3 , … , A 2n − 1 are n skew-
symmetric matrices of same order, then 3 such that AA T = 2I and A − 1 = A T − A ⋅
2r − 1 adj. (2B − 1 ), then det. (B) is equal
– to
B = 1
1 (2r − ) (A 2r − 1 )
(A) 4 (B) 4√2 –
will be (A) symmetric
(C) 16 (D) 16√2

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0 α
Q12 Let M and N be two 3 × 3 nonsingular
Let A = [ ] and
0 0 skew- symmetric matrices such that MN =
50 a NM. If PT denotes the transpose of P,
b then
(A + I) − 50A = [ ] . Then the value −1 T
c d M 2 N 2 (MTN) (MN− 1 ) is equal to
(A) M2
of a + b + c + d is (B) −N2
(A) 2 (C) −M 2
(C) 4 (B) 1none of these
(D) (D) MN

2
4a 1 l if(−1) l A is a 2 × 2 matrix such that A
Q13 i 4a
If ' 4b 2
4b 1 ''f(1) Q 1
l 2 」l 」 and A2 ]= [ ] .
4c 4c 1 f(2)
3a 1 0
2 3a
'i l' The sum of the elements of A is
= 3b 2 3b , f(x) is a quadratic
l 3c2 + 3c 」
function and its maximum value occurs at a point (A) -1 (B) 0
V . A is a point of intersection of y = f(x) with (C) 2 (D) 5
the x-axis and point B is such that chord AB 1
subtends a right angle at V. The value of f(1) is: Q 0 0 l'
(A) 3/4 (B) −3/4
'i
(C) 1 (D) None of these Let P = l 16 4 41 10 」 and I be the
matrix of order 3. If Q = [qij] is a matrix
2 such that P50 − Q = I , then
Q14 isin α 0 0 l equals
−1
If A = ' 0
l 2 sin2 β 0 」 (A) 52 (B) 103
2
0 0 sin γ
'ico α 0 0 l' (C) 201 (D) 205
−1 Q
B = 0 cos 2 β 0 where
Let A and B be two 3 × 3 matrices such that
0 l 0 cos γ 」 2
AB = I and |A| = , then |adj (Badj
α , β , γ are any real numbers and
C = (A −5 + B −5 ) (2A))| is equal to
+ 5A −1 B −1
(A −3 + B −3 ) (A) 16 (B) 32
Q20
+ 10A−2 B −2
(A−1 + B−1) then find |C|. (C) 64 (D) 128
o
(A) 0 (B) c s
Q15 1 1 sin
Let P = I ] and α, β , γ
1] – sin c os
Let P = ,A= [ and
3 0 1
a be
T T 2007
Q = PAP . If P Q P = [
c non-zero real numbers such that
b
] , then αP 6 + βP 3 + γI is the zero matrix.
d Then the value of
(C) 2007 (D) 2006
(α – β) (β – γ) (γ – α)
(α2 + β2 + γ2 )
Q16

Q
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0 1
A = [ ] and (x + y + z) where I is a unit matrix of
2 0 order 3.
(A 8 + A 6 + A 4 + A 2 + I) V = (A) 1 (B) 2
31 (C) 3 (D) 4
[ ]
6
(where I is the (2 × 2) identity matrix),then the
product of all elements of matrix V is
(A) 2 (B) 1
(C) 3 (D) 6

Q22 If α and β are the roots of the equation

2 2 4
1 – 1
[1 5] [ 3 ] [ ] [ 3 ] ,
x 4 7 1
4 7
x2 – 5 + 5
[ ] = [– 4]
3
then the value of (2 – α) (2 – β) is
(A) 51 (B) –12
(C) 12 (D) –7

Q23 If A & B are two matrices of order 3 such that

2 A + 3 BBT = I and B– 1 = AT . Let
α = det (A –1 – 3B 3 + BA) and
β = Tr ( A –1 – 3B 3 – BA) then value of
is

(A) 9 (B)
18

Q24 If A is a nilpotent matrix of order 3 , such that

| A – 3I | = 27, A2 = O and =
10 2 1
K[ Σ ((– 1)n (Σr ( ( n – 1 ) 2 + r ) ))]
n = 1 1

Then value of K, is equal to

(A) 0.27

(B) 0.36

(C) 0.45

(D) 0.89

Q25 Let A be a 3 × 3 matrix such that

a11 = a33 = 2 and all other aij = 1. Let
A–1 = xA2 + yA + zI, then the value of

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Manzil JEE (2025 )

Chemistry
DPP: 1
Some Basic Concepts of Chemistry

Q1
ng of substance X reacts with m g of Rearrange the following (I to IV) in the order of
substance Y to formp g of substance R and increasing masses:
qg of substance S. This reaction can be
represented as, X + Y = R + S . The (I) 0.5 moles of CO2
relation which can be established in the (Il) 0.5gm atom of oxygen
amounts of the reactants and 23
(Ill) 3.011 × 10 molecules of O2
the products will be (IV) 5.6 litre of CO2 at 1 atm and 273
K (A) II < IV < III < I
(A) n −m=p−q (B) n +m=
p+q
(C) n = m (D) p =q (B) II < I < IV < III
(C) IV < II < III < I
Q2 Among the following pairs of compounds, (D) II < III < IV < I
the one thatisillustrates the law of multiple
proportions Q7 Total number of electrons present in 4.4 g
2 −
oxalate ion(C2 O4 ) is
(A) NH3 and NCl3
(B) H2 S and SO2 (A) 0.05 NA
(C) CuO and Cu2 O (B) 2.3 NA
(D) CS2 and FeSO4 (C) 2.2 NA
(D) 2.1 NA
Equal masses of oxygen, hydrogen and
methane are taken in identical conditions. Q8 A compound contains 11.99% N, 13.70% O,
Q3 9.25% B and 65.06% F. Its empirical formula
What is the ratio −1
(molar mass of B is 10.8 g mol )
of the volumes of the gases under identical
(A) NOBF2
conditions? (B) NOBF4
(A) 16 : 1 :8 (B) 1 : 16 : 2 (C) N2 OF2
(C) 1 : 16 :8 (D) 2 : 16 : 1 (D) NO2 F2
Average atomic mass of magnesium is
Q4 24.31amu. This magnesium is composed of
79
mole % of24Mg and remaining 21 mole% Q9 Haemoglobin contains 0.33% of iron by
of weight. The molecular weight of haemoglobin is
25
Mg and26Mg. Calculate mole % approximately 67200 . The number of iron atoms
of26Mg. (A) 10 (B) 11 (at. wt. of Fe = 56 ) present in one molecule of
(C) 15 (D) 16
haemoglobin is
21
If 10 molecules are removed from 200mg (A) 6
Q5 (C) 2 (D) 4
of CO2 , then the number of moles of CO2
left are
−3 Density of 2. 05M solution of acetic acid in
(A) 2.88 × 10 Q10
(B) 28.8 × 10−3 water is 1.02 g/mL. The molality of same
−3 solution is
(C) 0.288 × 10
−2 (A) 1.14 mol kg − 1
(D) 1.68 × 10 (B) 3.28 mol kg
−1

Q6

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(C) 2.28 mol kg − 1 Q17 Fe2 O 3 reacts with excess CO at a high

−1 temperature according to the equation below:
(D) 0.44 mol kg

Q11 A solution of ethanol in water is 10% by Fe2 O 3 + 3 CO ⟶ 2 Fe + 3 CO2

volume. If the solution and pure ethanol have
If 6.50 g of Fe2 O3 yields 3.85 g of Fe, what is
densities of 0.9866 g/cc and 0.785 g/cc
the percentage yield of the reaction?
respectively. The
(A) 59.2% (B) 69.9%
percent by weight is nearly?
(C) 76.3% (D) 84.7%
(A) 7.95% (B) 17%
(C) 9.86% (D) 16.2% Q18 5 moles of A, 6 moles ofZ are mixed with
− suicient amount of C to finally produce F . Then
Q12 What is the [ OH ] in the fi nal solution
find the maximum moles of F which can be
prepared by mixing 20.0 mL of 0.050 M
produced. Assuming that the product formed
HCl with
can also be reused. Reactions are
30.0 mL of 0.10 M Ba(OH) 2 ?
(A)0.10 M
A + 2Z ⟶ B
(B) 0.40 M
B + C ⟶ Z + F
(C) 0.0050 M
(D) 0.12 M (A) 3 moles (B) 4.5 moles
(C) 5 moles (D) 6 moles
Q13 A gaseous mixture of H2 and CO2 gases
Q19 Based on the following consecutive reactions
contains 66 mass % of CO2 . The vapour density
of the mixture is:
(A) 6.1 (B) 5.4
2 KClO3 → 2 KCl + 3 O 2
(C) 2.7 (D) 10.8
4Al + 3O 2 → 2Al2 O 3

2 moles of KClO3 of 5 0 % purity on strong

Q14 The density of a 56.0% by mass aqueous heating and then with excess of Al, Al2 O3
solution of 1 - propanol ( CH3 CH2 CH2 OH) formed is
is 0.8975 g/cm3. What is the mole fraction (A) 2 mol
of the
1-propanol? (B) 1 mol
(A) 0.292 (B) 0.227 (C) 3 mol
(C) 0.241 (D) 0.276 (D) 1.5 mol

Q20 In the following set of reactions

Q15 Find the volume contraction if 10 L of Δ
Butane (C 4 H 10 ) under combustion with CaCO3 ⟶ CaO + CO2 ( 7 5 % yield )
suicient Δ
amount of oxygen? CO2 + C ⟶ 2 CO( 5 0 % yield )
(A) 35 L CO formed at STP from 10 g of CaCO3is
(A) 2.24 L
(B) 25 L
(C) 15 L (B) 11.2 L
(C) 1.12 L
(D) 3.5 L
(D) 1.68 L
Q16 For the reaction: 2X + 3Y ⟶ 3Z ,
the combination of 2 . 0 0 moles of X with 2 . 0 0 Q21 NH3 is formed in the following step:
moles of Y produces 1.75 moles of Z. What is I. Ca + 2C → CaC2 (50% yield )

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II. CaC2 + N 2 → CaCN2 + C(100% yield
)
III.
CaCN2 + 3H 2 O → 2NH3 + CaCO3 (50%
yield)

2 moles of NH3 are formed if we take

(A) 1 molCa
(B) 2 molCa
(C) 3 molCa
(D) 4 molCa

Q22 10 g of a hydrocarbon exactly

A quantity of
requires 40 g oxygen for complete combustion.
The products formed are CO2 and water. When
CO2 gas formed is absorbed completely in lime
water, the mass of solution increases by 27.5 g.
What is the mass of water formed simultaneously
in the combustion?
(A) 22.5 g
(B) 27.5 g
(C) 50 g
(D) 10 g

Q23 25.4 g of iodine and 14.2 g of chlorine are

made to react completely to yield a mixture of
ICl and ICl3. Calculate the number of moles of
ICl and ICl 3 formed.
(A) 0.1 mole, 0.1 mole
(B) 0.1 mole, 0.2 mole
(C) 0.5 mole, 0.5 mole
(D) 0.2 mole, 0.2 mole

Q24 When 1 0 0 g of ethylene polymerises entirely to

polyethene, the weight of polyethene formed as
per the equation
n ( C 2 H 4 ) ⟶ ( − CH2 − CH2 − ) n is:
(A) (n/2)g (B) 100g
(C) (100/n)g (D) 100ng

Q25 Which of the following result has four significant

figures?
(A) 27.9 ± 0.3
(B) 4.567 × 109
−6
(C) 3.4236 × 10
(D) 0.00493

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Manzil JEE (2025 )

CHEMISTRY
DPP: 2
Classification of Elements and Periodicity in Properties
10
(B) ns2 (n − 1)d
Q1 The nuclei of elements X, Y and Z have same 10
(C) (n − 1)d s2
number of protons, but diferent numbers of 2 5
(D) ns np
neutrons. According to Mendeleev periodic table,
the elements X, Y and Z Q6 In 6 th period of the modern periodic table,
electronic energy levels is in the order :
(A) belong to the same group and the
(A) 6 s, 4f, 5 d, 6p
same period (B) 6 s, 6p, 4f, 5 d
(B) belong to diferent groups and diferent (C) 4f, 5d, 6s, 6p
(D) None
periods
(C) belong to the same group and diferent Q7 The correct order of radii is
periods (A) N < Be < B
−
( D ) are isotopes, which do not have (B) F < O2 − < N 3 −
(C) Na < Li < K
diferent positions
(D) Fe3+ < Fe2+ < Fe4+

Q2 Which of the following species have the same Q8 Among the following species,
number of electrons in its outermost as well O2 − , P3 − , Cl− 1 , S− 1 , Ca+2 , K + .
2
as penultimate shell? How many have their ionic size greater than S
2+ −
(A) Mg ion?
3−
(B) O (A) 1 (B) 2
−
(C) F (C) 3 (D) 4
(D) Ca2+

Q3 Which is mismatched regarding the position of

Q9 [N3 − , O− , Na+ ]; Series-II:
Series-I:
[N+ , C+ , O+ ] Choose the species of lowest
the element as given below?
I.P. from Series-I and highest I.P. from Series-II
(A) X(Z = 89) − f block. 6th
period (B) Y(Z = 100) − f respectively
block. 7th period (C) Z(Z = 115) (A) N
3−
, O+
− d block. 7th period +
(B) Na , C
+
3−
(D) Both (A) & (C) (C) N , N+
− +
(D) O , C
Q4 An element has 56 nucleons in nucleus and
if it is isotonic with 30 Y 60 . Which group and Q10 The decreasing order of second ionization
period potential of K, Ca, Ba is
does it belong to? (A) K > Ca > Ba
(B) Ca > Ba > K
(A) 8th group, 4th period (C) Ba > K < Ca
th rd
(B) 14 group. 3 period (D) K > Ba > Ca
th rd
(C) 12 group. 3 period
th th
(D) 12 group. 4 period
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(A) ns1 −2 (n − 1)d1 − 10
 JE

Q11 Correct order of first ionization energy is Q17 The X − X bond length is 1. 00 Å and C −
C bond length is 1. 54 Å. If
(A) B > Tl > Ga > Al > In electronegativities of X and C are 3.0 and 2.0
(B) B > Al > Ga > Tl > In respectively, the C − X
(C) Al > Ga > Tl > In > B bond length is likely to be
(D) B > Ga > Al > In > Tl ° °
(A) 1.27A (B) 1. 18A
° °
Q12 The second electron ainity is zero for
(C) 1. 08A (D) 1. 28A
(A) Alkali metals
(B) Halogens Q18 The screening efect of inner electrons of the
(C) Noble gases
nucleus causes
(D) Transition metal (A) Decrease in the ionisation energy
(B) Increase in the ionisation energy
Q13 For the formation of covalent bond, the
(C) No efect on the ionisation energy
diference in the value of electronegativities
(D) Increases in the attraction of the nucleus to
should be:
the electrons
(A) Less than 1.7
(B) More than 1.7 Q19 The increasing order of electron ainity of
(C) 1.7 or more
the electronic configurations of element is:
(D) None of the above (I) 1s22s22p63s23p5
(II) 1 s2 2 s2 2p3
Q14 Pauling's equation for determining the (III) 1 s2 2 s2 2p5
electronegativity of an element, if XA , XB = (IV) 1s22s22p63s1
electronegativity values of elements A, B and Δ (A) II < IV < III < I
represents polarity of A − B bond (B) I < II < III < IV
(C) I < III < II < IV
(A) XA − XB = 0.208√
(D) IV < III < II < I
(B) XA + XB = 0.208√
(C) XA − XB = 0.208Δ2 Q20 Which one of the following statements is
(D) XA − XB = √
incorrect?
Q15 An atom with high EA generally has (A) Greater is the nuclear charge, greater
(A) Tendency to form +ve ions is magnitude of electron gain enthalpy
(B) High ionization energy (B) Nitrogen has almost zero electron ainity
(C) Large atomic size (C) Electron gain enthalpy decreases from
(D) Low electron ainity fluorine to iodine in the group
(D) Chlorine has highest magnitude of electron
Q16 Assign TRUE (T) or FALSE(F) for the following
gain enthalpy
statements and select CORRECT option for
your
Q21 In the compound M − O − H, the M − O
answer. bond will be broken if:
I. I.P of O(g)is less than I.P. of O− (g) (A) Δ (E.N.) of M and O < Δ (E.N.) of O and
+ H (B) Δ (E.N.) of M and O = Δ (E.N.) of O
II. I.P of Ne(g) is greater than I.P. of Ne
+
(g) III. E.A. of O (g) is greater than and H (C) Δ (E.N.) of M and O > Δ (E.N.) of
E.A. of O(g) IV. I.P of N(g) is greater than O and H
+ (D) Cannot be predicted according Δ (E. N.) data
I.P. of N (g)
(A) F, F, T, F Q22 The ionization energy of boron is less than that
(B) T, T, T, T of beryllium because
(C)F,
(D) T,T,T,F,T,TF

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(A) beryllium has a higher nuclear charge than
boron
(B) beryllium has a lower nuclear charge than
boron
(C) the outermost electron in boron occupies a
2p orbital
(D) the 2s and 2p-orbitals of boron are
degenerate

Q23 The first four I.

E. values of an element are
284, 412, 656 and 3210 kJ mol − 1. The
number of valence electrons in the element are:
(A) one (B) two
(C) three (D) four

Q24 Amphoteric oxide combinations are in

(A) ZnO, K2 O, SO3
(B) ZnO, P2 O5 , Cl2 O7
(C) SnO2 , Al2 O3 , ZnO
(D) PbO2 , SnO2 , SO3

Q25 Which of the following elements show diagonal

relationship?
(A) Li with Mg
(B) Hwith Na
(C) Be withAl
(D) B with Si

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Manzil JEE (2025)

Maths
DPP: 2
Basic

Q1 Number of positive integral values of x satisfying Q7 Solution of the quadratic equation

the inequality
≤ 0 is (3|x| − 3)2 = |x| + 7, which belongs to the
−
domain of the function y = √ x− is :
(C) 2 (D) 3

(B)
Q2 The value of expression
(C)
(D) −

(A) 2 (B) 3 Q8 Number of real solution (x) of the equation

(C) 4 (D) 5 3x2 −10x+3
|x − 3| = 1 is
(A) exactly four (B) exactly three
Q3 The number of integral solution of equation (C) exactly two (D) exactly one
(x 2 +3x+2)
(x 2 − 2x − 4) = 1 is/are
Q9 The number of real values of x satisfying the
(A) One (B) Two
equation
(C) Three (D) Four
3|x − 2| + |1 − 5x| + 4|3x + 1| = 13 is:
Q4 Solution set of x − 4 < √ −+− −−− (A) 1 (B) 4
is (A) x ∈ [4, ∞) (C) 2 (D) 3
(B) x ∈ (– ∞, – 6] ∪ [2, ∞) 2 2
Q10 If ∣f(x) + 6 − x ∣ = |f(x)| + ∣4 − x ∣ +
(C) x ∈ R 2, then f(x) is necessarily non-negaive for :
(D) x ∈ (– 8, – 3] ∪ [6, ∞) ∪ {4} (A) x ∈ [−2, 2]
Q5 If x = , then value of + is (B) x ∈ (−∞,– −2)– ∪ (2, ∞)
equal to (C) x ∈ [−√6 , √6]
(A) 0 (B) 1 (D) x ∈ [−5, −2] ∪ [2, 5]
(C) 2 (D) 4
Q11 The set of values of K(K ∈ R) for which the
2 2
7 equation x − 4 |x| + 3 − K∣ − 1 ∣ = 0
Q6 If x − = 3 then value of x − equals will have exactly four real roots is
(A) 4287 (B) 4283
(A) (−2, 4)
(C) 4285 (D) 4281
(B) (−4, 4)
(C) (−2, 2)
(D) (−1, 0)
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Q Consider the system of P= + + is defined. Then

equations log3 (log2 x) +
log1/3 (log1/2 y) = 1 and the value of P is
xy2 = 9. The value of x lies (A) 1
in the interval (B) 2
(A) (B) (400）500)
(200）300) Q18 If a, b, c are distinct real number such that
(D) none of
(C) a+ -= = ）then
- evaluate abc.
Q Let (x0）y0 ) be the solution of the - 2
following (A) ±v (B) v2 — 1
equations (2x)ln 2 = (3y)ln 3 (C) v3 (D) ±1
3ln x = 2lny Then x0 is
(A) Q19 The number of negative integral solutions of the
equation
(B)
x22x+1 + 2|x—3|+2 = x2 . 2|x—3|+4 + 2x —
1
is
(C)
(A) 0 (B)
1
Q If the complete set of values of x satisfying the
Q20 If a, b,2 c, x, y, z are 2non-zero real2 number
inequali and x (y+z) y (z+x) z (x+ y)
- = = =
————————————————
2 xyz
Vlog 2 x — 5 |log2 x| + 6 ≤ 2v5 = 1
3
a3 b c3 abc
is then find the value of a3 + b3 + c3 + abc.
(A) 0 (B)
1
then value of a + b + c is equal to
(A) 0 (B) 140 Q21 Consider the equation where P, Q, R
(C) 136 (D) 272 ereal number
Q15
PQR + 3P + 3QR = 121
If x = log2a ）y = log3b ） PQR + 3R + 3PQ = 59
z = log4c and w = log5d
PQR + 3Q + 3PR = 63
and + + + = logabcd Find the value of (P + 1) (Q + 1) (R + 1)
N+ 1,
the value of N is (A) 192 (B)
(A) 40 (B) 80 82
(C) 120 (D) 160
Q Q22 Solution set of inequaiton
—
v —x—2
1 3
+ is
lo 59 g log 63 v (A)
Let N = -(
81 3
) xe ）2]
409
. ( (v )7 — 125log256 )）then value
(B) x e

(C) x e
of
）10)
log2 N is equal to xe
(D)
）1)
Q Let a, b and c be such that a + b + c = 0 and

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−
Q23 Let x = √ √ and y = √ + √ . If the
value of the expression
x − y + 2x2 y + 2xy2 − x4 y + xy4 can be
expressed in the form √ + √ q
(where p, q ∈N), then find the value of (p + q)
(A) 320 (B) 430
(C) 570 (D) 610

Q24 If f(x) is a polynomial of degree 4 with leading

coeicient 1 and f(1) =1, f(2) = 2, f(3) = 3, then the
value of equals (where [.] denotes
greatest integer function)
(A) 0 (B) 5
(C) 7 (D) 9

Q25 The sum of all distinct real solutions of the

equation
3 3
(x2 − 3) − (4x + 6) + 216
= 18 (4x + 6) (3 − x2 ), is
(A) –3 (B) 4
(C) 1 (D) –7

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MANZIL JEE(2025)
CHEMISTRY
Some Basic Principles and Techniques : General Organic Chemistry DPP: 3

Q1 Given below are three acids. The order

of
their acidic nature is:

(I) (a)

(b)

(III)
(A) I > III > II
(B) I > II > III
(C) III > I > II (c)
(D) II > III > I
(A) a < b <
Q2 The order of relative basic strengths c (B) a < c
of following compounds is: <b
(C) c < a < b
I. CH3 NHCH3
II. CH2 = CH − NH2 (D) c <b<a

III.
Q4 Correct order of bond length will

(A) I > II > III > IV

IV.I CH
(B) 3 −
> IV > CH −
II >2 III
(C) I > IV > III > II
(D) IV > II > III > I

Q3 Arrange the following cation in increasing order

of stability (A) (iii) > (i) > (ii) >
(iv) (B) (iii) > (ii) >
(i) > (iv)
(C) (i) > (iii) > (ii) >
Q 5 Consider
(iv) the highlighted protons. Which
(D) (iii) < is
compound < (ii) < to have the lowest
(i) predicted pKa
? (A)

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(B)

(C)
Q10
Sum of α-hydrogens of all the given compounds
is:
(A) 19 (B) 16
( (C) 17 (D) 18

Q11 Which of the given compound(s) have high

Dipole moment

Q6 Correct Acidic Strength of

(A) only (i) and (ii)

(B) (ii), (iii) and (iv)
(C) (ii) and (iii)
(D) (ii) only
(A) O = C = O
Q12 The correct order of resonance energy (in
Q ( B ) CHmolecule
Which 2 = C =doesnt
CH2 show kJ/mol ) of the following aromatic compounds
(C) CH2 = C = O
is :
(D) CH2 = C = C =

Q The hyperconjugative stabilities of tert-butyl

cation and 2-butene, respectively, are due to
(A) σ → p (empty) and σ → π ∗ electron
delocalisations
(B) σ → σ ∗ and σ → π electron delocalisations
(C) σ → p (filled) and σ → π electron (A) (i) > (ii) > (iii)
delocalisations (B) (ii) > (i) > (iii)
(D) p (filled) → σ ∗ and σ → π ∗ electron (C) (iii) > (ii) > (i)
delocalisations (D) (ii) > (iii) > (i)

Total number of hyperconjugative hydrogens of Q13 The heat of hydrogenation of 1-hexene is

Q
the given following compound is : 126 kJ mol − 1 . When a second double bond is

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introduced in 1- hexene, the heat of
hydrogenation of the resulting compound is
−1
found to be 230 kJ mol . The resulting
compound (diene) is :
(A) 1,5-hexadiene
pKb of compound would be lowest
when - Me group substituted at
(B) 1, 4-hexadiene (A) Ortho (B) Meta
(C) 1,3-hexadiene (C) Para (D) Both ortho
(D) 2,4-hexadiene
Q18 If 1 mole of H2 is treated with 1 mole of
Q14 Arrange the following in decreasing order of the following compound,
stability.

Which double bond will be hydrogenated?

(A)
(A) i > ii > iii c
(B)
(B) iii > ii > i
b
(C) ii > iii > iii (C)
(D) iii > i > ii a
Q19
⊕
Q The decreasing order of bond length of double CH2 = CH − CH = CH −
bonds is : NH3 ;

⊕ ⊕ ⊕
CH2 − CH = CH − CH − NH3
(II)
⊕
CH2 − CH = CH − CH = NH3
(III)

(A) c >a>b Which of these structures is not a valid canonical

structure?
(B) d > c > a > b
(A) I (B) II
(C) b > c > a > d
(D) a > b > d > c (C) III (D) none of these

Q16 The best site for protonation Q20 Which of the following compound is not
is
resonance stabilized?
(A)

(A) I (B) II
(C) III (D) Both I and (B)

Q
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( Q24 In which of the following pairs of carbanion the

first one is more stable than second?
Θ
Θ
(A)
C F3 C Cl3
(

⊖ ⊖
(B)
HC ≡ C H 2 C = C H

(C)
Q Which of the following structures possesses
a
cross-conjugated system?
(
B ⊖ ⊖
) (D)
CH3 − C H 2 H2 C =C H
Q25 The correct stability order

(
(A)
C

(B)

Q In which pair second ion is more stable than

(C)
(D)
(A) (i) and (B) (ii) and
(ii) (iii)

Q One among the following compounds will not

give efervescence with sodium carbonate:
(A) C 6 H 5 CO2 H
(B)
(C) C6 H5 OH
(D)

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Manzil JEE (2025 )

CHEMISTRY
DPP: 4
IUPAC

Q1 Correct IUPAC name of the following

(A) 3-methyl-4-(3-methylprop-1-enyl)-1-heptyne
compound is
(B) 3, 5-dimethyl-4-propylhept −6 − en-1-yne
(C) 3-methyl-4-(1-methylprop-2-ynyl) -1-heptene
(D) 3, 5-dimethyl-4-propylhept-1 -en-6-yne

Q5 Which of the following is/are incorrect IUPAC

(A) 5,6-diethyl-8-methylde-6-ene
(B) 5,6-diethyl-3-methyldec-4-ene name?
(C) 6-butyl-5-ethyl-3-methyl-dec-4-ene (A) 3-ethyl butane
(D) 2, 4, 5-triethylnon-3-ene (B) 1-methyl heptane
(C) 2, 5-diethyl hexane
The IUPAC name of the given compound (D) 2, 2, 2-trimethyl pentane
Q

Q6 In all compounds of IUPAC name P1 -bromo-

P2 - chloro- P3 -methyl but P4 -yne, which is
always correct (P represent position of side
(A) Ethylacrylate chain and multiple bond according to
IUPAC).
P 1
(B) Ethylmethylbutenoate (A)
P
1
= 4
(C) Ethylacetoethenoate P4 1
(D) Ethyl-3-methylbut-3-enoate
(B)
P
1
= 2
P4 1
(C) 1
= 3
P
P3 1
Q IUPAC name of the following compound (D)
P3
4
= 3

Q7 Which of the following structure represent

Dimethyl butanedioate?
(A)

(B)
(C)
(A) 2-hydroxy-5-iodo toluene
(B) 4-iodo-6-methylphenol
(C) 3-methyl-4-hydroxy-1-iodo benzene
(D)
(D) 4-iodo-2-methylphenol

The IUPAC name for the following compound

Q

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Q8 Write the correct name from the incorrect name Select the position where only methyl is
2, 3-dichloro-2, 4-dibromohept-4-ene substituent in parent chain by dragging (P),
(A) 2, 4-dibromo-2,3-dichloro hept-4-ene ⋅ (Q), (R) to compound M.
(B) 4, 6-dibromo-5,6-dichloro hept-3-ene (P) −COOH, (Q) −CH3 , (R) −CH2 −
(C) 4, 6-dibromo-5,6-dichloro hept-4-ene
(D) 5, 6-dichloro-4,6-dibromo hept-3-ene

Q9

The IUPAC name of (A) P(2) Q(1)

(A) 2,3-dimethyl-ethylcyclohex-4-ene
(B) P(1) Q(2)
(B) 5-ethyl-3, 4-dimethylcyclohex-1-ene
(C) P(1) R(2)
(C) 4-ethyl-5, 6-dimethylcyclohex-1-ene
(D) Q(1) R(2)
(D) 1-ethyl-2, 3-dimethylcyclohex-4-ene
Q13 Find out the correct statement(s) about
Q10 For the following compound given molecule.

CH3 − C ≡ C − CH = CH − CH =
C H 2 (A) All the carbons in given molecule are
in same
plane
(B) IUPAC name is hepta-1,3-dien-5-yne
The correct IUPAC name of the given compound (C) It has 4sp2 hybrid carbons, 2sp
is hybrid carbons and 1sp3 hybrid
(A) 4-Methoxy-3-bromo benzene carbon
(D) All of these
carbonitrile (B) 4-Bromo-3-methoxy
benzene carbonitrile (C) 2-Bromo-4-cyano (i)
anisole
(D) 2-Bromo-4cyano-1-methoxy benzene

Q11 The correct IUPAC name of the given

(ii)

(iii)

(A) 2-methanoyloxy-2-ethoxy carbonyl-3- (iv)

oxo- (A) i and iii both

butanoic acid (B) i only

(C) iv only
(B) 2-ethanoyloxy-2-methoxy carbonyl-3-
oxo- butanoic acid (D) ii and iv only
(C) 2-ethanoyloxy-2-methoxy carbonyl-3-
Q15 Which of the following statement(s) is incorrect?
oxo-
butane carboxylic acid

Q12

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Q19 IUPAC name of compound is

(A) Double bond equivalent (DBE) value of the

compound is 4
(B) Total 3 diferent functional groups are present
(C) Correct IUPAC name is 2-(prop-2-ynyl)
pent- 4-enal
(D) Correct IUPAC name is 2-(propyl) pent-4-ynal
(A) 3-methoxycarbonyl-5-oxo cyclohexanoic
acid (B) 3-ethanoyloxy-5-keto cyclohexane
Q16 Which compound doesn’t contain any one of
carboxylic
these groups-isopropyl; sec-butyl, tert-butyl.
(A) 2-methyl pentane acid
(C) 3-methoxycarbonyl-5-oxo cyclohexane
(B) 2, 2-dimethylpentane
(C) 3-methyl pentane carboxylic acid
(D) 3-keto-5-methoxycarbonyl
(D) 3, 3-dimethyl pentane
Q20 The IUPAC name of the compound is:
Q17 Build 5 - ethyl- 2 , 3 , 4 - trimethyl heptane by
dragging the groups to the question marks

(A) trans-2-chloro-3-iodo-2-pentene
(B) cis-2-chloro-3-iodo-2-pentene
(C) trans-3-iodo-4-chloro-3-pentene
(D) cis-3-iodo-4-chloro-3-pentene

(A) a (1) b (2) (B) a (2) b (1) Q21 The IUPAC name of (CH3 )3 C ⋅ CH2 CH2 Cl is:
(C) a (1) a (2) (D) b (1) b (2) (A) 2, 2-Dimethyl-4-chloro butane
(B) 1-Chloro-3, 3-dimethylbutane
Q18 Which of the following structure is the (C) 4-Chloro-2, 2-dimethyl butane
correct structure of 3-Ethyl-5, 5-diisopropyl- (D) none of these
7-
( Q22 The IUPAC name of

(A) Spiro [2, 2] pentane

(
(B) Bicyclo [2, 2] pentane
(C) Bicyclo [2, 1, 0] pentane
(D) Spiro [2, 1, 0] pentane
(
C Q23
)
The IUPAC name of is

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(A) Bicyclo [0, 1, 2] pentane
(B) Bicyclo [2, 1, 0] pentane
(C) Bicyclo [1, 0, 1] pentane
(D) Bicyclo [1, 0, 2] pentane

Q24 Which of the following compound is bicyclo

[3.3.0] octane?
(A)

(B)
(C)

(D)

Q25 The IUPAC name of is:

(A) 3-Carboxy-3-hydroxypentanedicarboxylic
acid
(B) 2-Hydroxypropane-1, 2, 3-tricarboxylic acid
(C) 2-Hydroxypropane-1, 2, 3-trioic acid
(D) 3-Hydroxypropane-1, 2,3-tricarboxylic acid

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