[Master Review Package] [JEE MAIN]

Inorganic Chemistry

1. Periodic Properties :

171. Which element form maximum type of oxide (with respect to acidic, basic, amphoteric nature)
(A) Chromium (B) Nitrogen (C) Copper (D) Chlorine

172. Which of the following order is incorrect.

– –
(A) IE of F > Cl (B) IE of F > Cl (C) E.A. of F < Cl (D) E.A. of F+ > Cl+

173. INCORRECT order is :

(A) B > T > In > Ga > Al : First ionisation energy
(B) F > N > C > Si : Non metallic character
(C) O > F > Cl > N : Oxidizing character
(D) Al3+(aq) > Be2+(aq) > Mg2+(aq) > Li+(aq) : Hydration enthalpy

174. Which of the following order is CORRECT for the property mentioned in brackets :
(A) S2– > Cl– > K+ > Ca2+ (Ionisation energy)
(B) C < N < F < O (2nd Ionisation energy)
(C) B > Al > Ga > In > Tl (Electronegativity)
(D) Na+ > Li+ > Mg2+ > Be2+ > Al3+ (Ionic Radius)

175. Which of the following is the INCORRECT match :

(A) [Ar] 3d5 4s1  4th period , 6th group
(B) [Kr] 4d10  5th period, 12th group
(C) [Rn] 6d27s2  7th period, 3rd group
(D) [Xe] 4f14 5d2 6s2  6th period , 5th group

176. Consider the following conversions :

(i) O(g) + e–  O–(g) , H1 (ii) F(g) + e–  F–(g) , H2
(iii) Cl(g) + e–  Cl–(g) , H3 (iv) O–(g) + e–  O2–(g) , H4
Then according to given information the INCORRECT statement is :
(A) H3 is more negative than H1 and H2.
(B) H1 is less negative than H2.
(C) H1 , H2 and H3 are negative whereas H4 is positive.
(D) H1 and H3 are negative whereas H2 andH4 are positive.

177. Which of the following order is CORRECT

(A) K+ < Ca2+ < P3– < S2– : Atomic size
(B) Na+(aq) > K+(aq) > Rb+(aq) > Cs+(aq) : Electrical conductance
(C) Al3+(aq) > Mg2+(aq) > Na+(aq) : Hydrated size
(D) I – (aq)  Br – (aq)  Cl – (aq)  F – (aq) : Ionic mobility

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2. Chemical Bonding :

178. Which pair of molecules has same bond order but different magnetic moment
(A) O2, S2 (B) C2 , O2 (C) H2, F2 (D) F2, Cl2

179. Which anion remains linear on protonation

(A) OH– (B) CN– (C) N3– (D) SCN–

180. Energy between stationary polar molecules and rotating polar molecules is proportional to respectively.

1 1 1 1 1 1 1 1
(A) , (B) , (C) , (D) ,
r3 r6 r6 r6 r3 r3 r6 r3
181. The order of p-d interaction in the compounds containing bond between Si/P/S/Cl and oxygen is in
the order
(A) P > Si > Cl > S (B) Si < P < S < Cl (C) S < Cl < P < Si (D) Si > P > S > Cl

182. Molecule, which does not contain both polar and nonpolar bonds
(A) NOCl (B) H2S2O6 (C) B2Cl4 (D) N2O4

183. INCORRECT statement regarding NH(SiH3)2 molecule is

(A) Hybridization of N : sp2 (B) Si – N – Si bond angle > 120°
(C) Skeleton of the molecule is planar (D) It cannot act as Lewis base

184. The sigma bond having higher bond energy is :

(A) Si – Si (B) S – S (C) C – C (D) N – N

185. The type of molecular forces of attraction present in the following compound is :

OH
NO2

HO
(A) Intermolecular H-bonding (B) Intramolecular H-bonding
(C) Vander waals force (D) All

186. INCORRECT statement regarding BF2NH2 molecule is.

(A) FBF bond angle < 120º (B) HNH bond angle > 109º28
(C) Exhibits intermolecular H-bond (D) Hybridization of N atom is sp3

187. CORRECT match is :

(A) d x2  y2 atomic orbital — One nodal plane

(B) py atomic orbital — Two nodal planes

(C) px molecular orbital — (gerade)

(D) *p y molecular orbital — (ungerade)

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188. Which of the following molecular species is linear and non-polar

(A) C3O2 (B) (SCN)2 (C) OCN– (D) O2F2

189. INCORRECT match is :

Electron Geometry Possible molecular shape from respective electron geometry

(A) Tetrahedron — Bent

(B) Trigonal bipyramidal — Triangular planar

(C) Octahedron — Square pyramidal

(D) Pentagonal bipyramidal — Pentagonal planar

190. Which of the following interaction lies in the range of 8 – 42 kJ/mole

(A) H2 ... H2O (B) HCl ... HCl (C) F–...HF (D) HCN ... NH3

191. The CORRECT order of boiling point is :

(A) T2 < D2 < H2 (B) n-pentane < neo-pentane
(C) Xe < Ar < He (D) m-nitrophenol > o-nitrophenol

192. Statement-1 If d x 2 – y 2 and py orbitals come close together along z-axis, then they can form -

Bond by sideways overlapping.

Statement-2 Both orbitals do not have electron density along z-axis.
(A) Statement-1 is true, Statement-2 is true and Statement-2 is correct explanation for Statement-1
(B) Statement-1 is true, Statement-2 is true and Statement-2 is NOT correct explanation for Statement-
1
(C) Statement-1 is true, Statement-2 is false
(D) Statement-1 is false, Statement-2 is true

193. Statement-1 : The H-bond present in NH3 dissolved in water is best represented by
H
|
H – N – H ······ O – H and not by H – N ····· H – O
| | | |
H H H H
Statement-2 : The O–H bond polarity is more compared to that of N–H bond.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for
statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.

194. Statement-1 : The decrease in bond angle is more between two axial S–F bonds compared to
between two equitorial S–F bonds in SF4 molecule.
Statement-2 : Two axial bonds are more closer to lone pair on S – atom in SF4 molecule.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for
statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.

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195. In which of the following transformations, the bond order has increased and the magnetic behaviour
has changed?
(A) C2  C2 (B) NO+  NO (C) O2  O2 (D) N2  N2

196. In which of the following transformations bond order has been decreased and magnetic behaviour
remains same.

–
(A) C2  C22– (B) N O  NO (C) O2+  O2 (D) N2  N2

197. H.O.M.O. (Highest Occupied Molecular Orbital) of CO molecule is

(A) Non-bonding M.O. with slight antibonding character
(B) Non-bonding M.O. with slight bonding character
(C) Pure non-bonding M.O.
(D) None of these

3. Hydrogen and its Compounds :

198. Which compound is electron rich hydride

(A) B2H6 (B) CH4 (C) NH3 (D) SiH4

199. Select correct statement for structure of ice

(A) Each oxygen atom is surrounded tetrahderally by four other oxygen atom at equidistance
(B) Each oxygen atom is surrounded tetrahderally by four hydrogen atoms at equidistance
(C) Each oxygen atom is surrounded tetrahderally by four hydrogen atoms as well as four oxygen
atoms and both are at equidistance from central oxygen atom
(D) Each oxygen atom is surrounded tetrahderally neither by four hydrogen atoms nor by four oxygen
atom at equidistance

200. Which pair of elements is used for hydrogen storage

(A) Na, K (B) C, Si (C) Pd, Pt (D) F2, Cl2

201. Estimation of Ca2+ and Mg2+ present in hard water is carried out by titration of hard water with.
(A) H4EDTA (B) Na2H2EDTA
(C) Ethylene diamine (D) [Pb(EDTA)]2–

202. Incorrect statement about H2O2 is

(A) It is concentrated by distillation under reduced pressure
(B) It is used in restoration of aerobic conditions to sewage wastes
(C) As an antiseptic, it is sold in market as perhydrol
(D) It does not deposit silver from Ag2O

203. Indicate the INCORRECT statement

(A) Para hydrogen has higher energy than orthohydrogen
(B) At absolute zero temperature, hydrogen gas contains 100% para hydrogen
(C) At high temperature, hydrogen gas contains about 75% orthohydrogen
(D) Ortho and Para hydrogen are nuclear spin isomers

204. Which of the following element does not form hydride by direct heating with dihydrogen ?

(A) Be (B) Mg (C) Sr (D) Ba

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205. Out of following which does not gives H2O2 on hydrolysis ?

(A) H2S2O8 (B) Na2O2 (C) H4P2O8 (D) H2S2O7

4. s-Block Elements :

206. Which property is not similar between lithium & Magnesium metals
(A) Number of H2O in their hydrated chloride
(B) Oxide do not combine with excess oxygen to give any super oxide
(C) Chlorides are deliquescent
(D) Hydroxides are decomposed on heating

207. For which halides formation, enthalpy becomes less negative as atomic number increases down
the alkali metals group
(A) Fluoride (B) Chloride (C) Bromide (D) Iodide

208. Which is not formed when Cl2 reacts with cold and dil.NaOH.
(A) NaCl (B) H2O (C) NaOCl (D) NaClO3

209. Portland cement contains maximum percentage of :

(A) CaO (B) SiO2 (C) Al2O3 (D) Fe2O3

210. Dihydrogen acts as oxidising agent for

(A) Cl2 (B) Na (C) Cu2O (D) PdCl2

211. Which statement is incorrect.

(A) Both LiCl & MgCl2 are soluble in ethanol.
(B) Both LiCl & MgCl2 are deliquescent.
(C) Both LiHCO3 & Mg(HCO3)2 exist in solid state .
(D) Both LiNO3 & Mg(NO3)2 give NO2 & O2 on heating.

212. The reaction that is least feasible is

(A) Li2CO3  Li2O + CO2 (B) 4Li + O2  2Li2O
(C) 6Li + N2  2Li3N (D) 2C6H5C  CH + 2Li  2C6H5CCLi + H2

213. Hydrogen gas is not evolved at 25°C

(A) Na + C2H5OH (B) Al + NaOH solution
(C) Be + H2O (D) NaH + H2O

214. Alkali metal that does not form ethynide on reaction with ethyne :
(A) Li (B) Na (C) K (D) Cs

215. Which of the following metal chloride does not exist in hydrated form :
(A) LiCl (B) SrCl2 (C) MgCl2 (D) RbCl

216. Which combination does not produce Hydrogen gas

(A) CaH2 + H2O (B) NH3 gas + Na
(C) C2H5OH + K (D) Kerosene oil + Na

217. Compound having lowest Melting point.

(A) LiCl (B) CsCl (C) RbCl (D) KCl

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218. INCORRECT statement is

(A) NaHCO3 and KHCO3 have different crystal structure
(B) On heating LiNO3 decomposes into Li2O and NO2
(C) Among alkali metals, Li metal impart no colour to flame
(D) Li2SO4 does not form alum

219. The solubility of metal halides depends on their nature, lattice enthalpy and hydration enthalpy of the
individual ions. Amongst fluorides of alkali metals, the lowest solubility of LiF in water is due to
(A) Ionic nature of lithium fluoride (B) High lattice enthalpy
(C) High hydration enthalpy of lithium ion (D) Low ionisation enthalpy of lithium atom

220. By adding gypsum to cement

(A) Setting time of cement becomes less (B) Setting time of cement increases.
(C) Colour of cement becomes light (D) Shining surface is obtained.

221. The reducing power of a metal depends on various factors. Suggest the factor which makes Li metal
the strongest reducing agent in aqueous solution.
(A) Sublimation enthalpy (B) Ionisation enthalpy
(C) Hydration enthalpy (D) Electron-gain enthalpy

222. A compound (A) is used in preparation of washing soda to recover ammonia in Solvay’s process.
When CO2 is bubbled through an aqueous solution of (A), the solution turns milky. It is used in white
washing due to disinfectant nature. What is the chemical formula of A?
(A) Ca(HCO3)2 (B) CaO (C) Ca(OH)2 (D) CaCO3

5. p-Block Elements :

223. Which compound has different geometry around sulphur atoms

(A) H2S2O4 (B) H2S2O5 (C) H2S2O6 (D) H2S2O7

224. Which pair of species has same structure in solid state

(A) AlF3, AlCl3 (B) AlBr3, AlI3 (C) BeF2, BeCl2 (D) BH3, AlH3

225. Which salt does not liberate oxygen gas on decomposition.

(A) K2Cr2O7 (B) (NH4)2Cr2O7 (C) KClO4 (D) NH4ClO4

226. w + x y + z
y + BCl3 x + z + B2H6
w and x are
(A) LiCl, AlH3 (B) LiH, AlCl3 (C) LiH, LiCl (D) AlH3, AlCl3
227. Which property of inert gases does not affected by vander wall's forces.
(A) Solubility in water (B) Ease of liquification
(C) Boiling point (D) Reactivity

228. Which gas has same composition

(A) Water gas, synthesis gas (B) Synthesis gas, producergas
(C) Producer gas, water gas (D) None of these

229. Which element does not form MO type oxide at room temperature
(A) Carbon (B) Silicon (C) Germanium (D) Tin

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230. Ortho Boric acid is formed by hydrolysis of borax, amount of boric acid can be increased by addition
of
(A) HCl (B) NaOH (C) Cis 1–2 diol (D) H2O2

231. AgCl + H3PO2 + H2O  x + HCl + Ag

x is :
(A) H3PO3 (B) H3PO4 (C) PH3 (D) P2H4

232. O3 + HI  x + O2 + H2O
CO + I2O5  x + CO2
x does not show redox reaction with
(A) Na2S2O3 (B) KI (C) KMnO4/H+ (D) Cl2

233. Which of them contain sp2 hybridize ‘C’ atoms

(i) Graphite (ii) Fullerene (iii) Diamond
(A) All of these (B) Only (i) & (ii) (C) Only (i) (D) Only (ii)

234. Which of the following species is acidic oxide.

(A) CO (B) GeO (C) SnO (D) PbO

235. Which pair form blue coloured bead with borax on heating in Bunsen burner flame
(A) CuO, CoO (B) FeO, CoO (C) CuO, FeO (D) FeO, NiO

236. Which property has lowest value of Ga metal among group 13 elements.
(A) Ionization energy (B) Density
(C) Melting point (D) Electronegativity

237. Which of the following species is not a product of thermal decomposition of (NH4)2BeF4
(A) NH3 (B) HF (C) BeF2 (D) N2

238. Certain combination of cation and anions lead to the formation of colored salts in solid state even
though each of these ions with other counter ions may produce colorless salts. This phenomenon is
due to temporary charge transfer between the two ions. Out of the following, the salt that can exhibit
this behaviour is
(A) SnCl2 (B) SnCl4 (C) SnBr2 (D) SnI4

239. With respect to halogens, four statements are given below

(I) The bond dissociation energies for halogens are in the order : I2 < F2 < Br2 < Cl2
(II) The only oxidation state is – 1
(III) The amount of energy required for the excitation of electrons to first excited state decreases
progesssively as we move from F to I
(IV) They form HX2– species in their aqueous solutions (X = halogen)
The correct statements are
(A) I, II, IV (B) I, III, IV (C) II, III, IV (D) I, III

240. The reaction that does not produce nitrogen is

(A) Heating (NH4)2Cr2O7 (B) Excess NH3 + Cl2
(C) Heating of NaN3 (D) Heating of NH4NO3

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241. The structure of a molecule of N(SiMe3)3 is

(A) Pyramidal with angle close to 110°
(B) T-shaped with angle 90°
(C) Bent T-shaped with angle close to 89°
(D) Trigonal planar with bond angle close to 120°

242. Acidic character of liquid HF increases on passing gas/vapours of which of the following com
pound into it :
(A) BF3 (B) SF6 (C) CF4 (D) All

243. Which of the following oxyacid is formed when phosphorus acid is heated in a sealed tube in the
presence of Br2
(A) H3PO4 (B) H4P2O6 (C) (HPO3)n (D) H3PO2

244. Correct order of reactivity of halogens towards water

(A) Cl2 > F2 > Br2 (B) Cl2 > Br2 > I2 (C) I2 > Br2 > Cl2 (D) F2 > Br2 > Cl2

245. Antichlor property is not exhibited by :

(A) Na2S2O3 solution (B) SO2 gas (C) CO2 gas (D) None

246. Which of the following compound produces white fumes on exposure to moist air.
(A) ZnSO4.7H2O (B) AlCl3.6H2O (C) Na2CO3.10H2O (D) NaCl

247. Correct order of oxidizing character for a fixed concentration is :

(A) H2SO4 > HNO3 > H3PO4 (B) HNO3 > H3PO4 > H2SO4
(C) HNO3 > H2SO4 > H3PO4 (D) H3PO4 > H2SO4 > HNO3

248. Nitric oxide gas is not obtained by

Warm 
(A) [Fe(H2O)5(NO)]2+ (B) Pb + dil. HNO3

(C) NO2(g) + H2O

R.T. (D) Zn + dil. HNO3
R.T.

249. Which of the following compound of xenon is least stable.

(A) XeO3 (B) XeO4 (C) XeO64– (D) XeO2F2

250. INCORRECT order is :

(A) Melting point : TeF4 > SeF4 > SF4
(B) Ease of liquefaction : H2O > H2S > H2Se > H2Te
(C) Reducing character : HI > HBr > HCl > HF
(D) Solubility in water : Xe > Kr > Ar > Ne

251. Oxy acid is not formed on partial hydrolysis of :

(A) P4O10 (B) H2S2O8 (C) PCl5 (D) BF3

252. INCORRECT order is :

(A) HF > H > HBr > HCl : Melting point
(B) H > HBr > HCl > HF : Arrhenius acidic character
(C) 2 > Br2 > Cl2 > F2 : (X – X) Bond length
(D) Cl2 > Br2 > F2 > 2 : (X – X) Bond dissociation energy

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253.

INCORRECT statement regarding above reactions is

(A) Gas ‘Q’ can also be obtained by reaction between NaH and H2O
(B) Both P and Q gases are same and inflammable in nature
(C) ‘Y’ produces precipitate of ZnS with H2S gas
(D) Reaction does not exhibit amphoteric nature of zinc

254. INCORRECT statement regarding XeF6 is :

(A) Its complete hydrolysis produces an explosive substance
(B) Acts as fluoride donor with CsF
(C) XeF6 can undergo partial hydrolysis.
(D) One of hydrolysed product reacts with silica in glass

255. Which of the following parent oxy acid does not have its Hypo acid.
(A) H2SO4 (B) HNO2 (C) H3PO3 (D) HClO3

256. Molecule having polar as well as non polar bonds but the molecule as a whole is non polar :
(A) S2F2 (B) 2Cl6 (C) (CN)2 (D) N2F4

257. In which of the following silicates, only two corners per tetrahedron are shared :
(i) Pyro silicate (ii) Cyclic silicate
(iii) Double chain silicate (iv) Single chain silicate
(v) 3 D silicate (vi) Sheet silicate
(A) (i), (ii) and (v) (B) (iv) and (vi) only
(C) (i) and (vi) only (D) (ii) and (iv) only

258. The CORRECT code for stability, of oxidation states for given cations is :
[I] Pb2+ > Pb4+, T+ < T3+ [II] Bi3+ < Sb3+, Sn2+ < Sn4+
[III] Pb2+ > Pb4+, Bi3+ > Bi5+ [IV] T3+ < In3+ , Sn2+ > Sn4+
[V] Sn2+ < Pb2+, Sn4+ > Pb4+ [VI] Sn2+ < Pb2+, Sn4+ < Pb4+
(A) [V] & [VI] (B) [I], [III], [V] & [VI] (C) [III] & [V] (D) [II] & [IV]

259. In which of the following compounds hydrolysis takes place through SN1 and SN2 mechanism
respectively.
(A) NF3, NCl3 (B) P4O10, SiCl4
(C) SF4, TeF6 (D) SiCl4, SiF4
260. Which of the following is an uncommon hydrolysis product of XeF2 and XeF4?
(A) Xe (B) XeO3 (C) HF (D) O2

261. B(OH)3 + NaOH  NaBO2 + Na[B(OH)4] + H2O

How can this reaction is made to proceed in forward direction?
(A) addition of cis 1, 2 diol (B) addition of borax
(C) addition of trans 1, 2 diol (D) addition of Na2HPO4

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262. Which of the following cation does not give borax bead test
(A) Cr3+ (B) Co2+ (C) Ag+ (D) Mn2+

263. INCORRECT order is

(A) HF < HCl < HBr < HI : Acidic strength
(B) HF > HCl > HBr > HI : Thermal stability
(C) HF > HCl > HBr > HI : Boiling point
(D) HF > HCl > HBr > HI : Bond dissociation enthalpy

264. Statement-1 : In H3PO3, basicity of the oxy acid is two.

Statement-2 : One H-atom is non-ionizable in more stable tautomeric form of H3PO3.
(A) Statement-1 is true, Statement-2 is true and Statement-2 is correct explanation for Statement-1
(B) Statement-1 is true, Statement-2 is true and Statement-2 is NOTcorrect explanation for Statement-
1
(C) Statement-1 is true, Statement-2 is false
(D) Statement-1 is false, Statement-2 is true

HCl(aq)
'X' + Gas 'P'

265. Al
Metal
NaOH(aq)
'Y' + Gas 'Q'
+ H2O
The INCORRECT statement regarding above reactions is
(A) Al shows amphoteric character (B) Gas ‘P’ and ‘Q’ are different
(C) Both X and Y are water soluble. (D) Gas Q is inflammable.

266. INCORRECT statement regarding following reactions is

+Excess H2O
X + HF
XeF6
+2H2O
Y + HF
(A) ‘X’ is explosive. (B) ‘Y’ is an oxyacid of xenon.
(C) Both are example of non-redox reaction (D) XeF6 can undergo partial hydrolysis.

267. The INCORRECT statement regarding ‘X’ in given reaction is

Ether
BF3  LiAlH 4  ( X)  LiF  AlF3
(A) Twelve electrons are involved in bonding (B) Four, two centre-two electron bonds
(C) Two, three centre-two electron bonds (D) X does not react with NH3.

268. INCORRECT statement about PH3 is

(A) It is produced by hydrolysis of Ca3P2
(B) It gives black ppt (Cu3P2) with CuSO4 solution
(C) Spontaneously burns in presence of P2H4.
(D) It does not react with B2H6.

269. Which of the followign noble gas does not form clathrate compound?
(A) Kr (B) Ne (C) Xe (D) Ar

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270. Which of the following compound does not produce oxyacid of central atom on hydrolysis.

(A) BF3 (B) NCl3 (C) SF4 (D) PCl5

271. INCORRECT match regarding following hydrides :

(A) NH3 > PH3 > AsH3 > SbH3 : Thermal stability
(B) NH3 > PH3 > AsH3 > SbH3 : H – X – H (X = N, P, As, Sb) bond angle
(C) NH3 > PH3 > AsH3 > SbH3 : Lewis basic character
(D) NH3 > SbH3 > AsH3 > PH3 : Boiling Point

6. d & f-Block Elements :

272. Pure KMnO4 is not obtained by

(A) K2MnO4 + O3 (B) K2MnO4 + Cl2
(C) K2MnO4 + CO2 (D) Electrolysis of K2MnO4

273. Which property is not simillar among alkali metals and lanthanoids.
(A) Nature of oxide (B) Reaction with dil.HCl
(C) Oxidation state (D) Reaction with H2O

274. MnO2– –
4 is completely converted into MnO4 in presence of :

(A) H2O (B) HCl (C) NaOH (D) Cl2

275. The incorrect statement for lanthanides among the following statements is
(A) 4f and 5d orbitals are so close in energy that it is very difficult to locate the exact position of
electrons in lanthanides
(B) Most common stable oxidation state is +3
(C) Tripositive lanthanide ions have characteristic color depending on nature of group with which
they combines to form compounds
(D) Some lanthanide ions absorb either in infrared or ultraviolet region of electromagnetic spectrum

276. Four statements for Cr and Mn are given below.

(I) Cr2+ and Mn3+ have the same electronic configuration
(I) Cr2+ is a reducing agent while Mn3+ is an oxidizing agent
(III) Cr2+ is an oxidizing agent while Mn3+ is a reducing agent
(IV) Both Cr and Mn are oxidizing agents
The correct statements are
(A) I, III, IV (B) I, II (C) I, II, IV (D) I, IV

277. The nature of Cs[AuCl3] is (This compound contains Au in two oxidation states and there is no Au–Au
bond)
(A) Diamagnetic (B) Paramagnetic
(C) Ferromagnetic (D) Antiferromagnetic

278. Which of the following metal can exhibit negative oxidation state in its compounds?
(A) Ca (B) Mn (C) Zn (D) Pb

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279. Incorrect statement for lanthanoids is

(A) They are good conductors of heat and electricity
(B) All M3+ (aq) Lanthanoids exhibit colour
(C) Ce4+(aq) has good oxidizing character
(D) They liberate hydrogen gas on reacting with water

280. Iron can form alloy with chromium because

(A) They belong to first transition series (B) Their stable oxidation state is +3
(C) Their metallic radius is almost same (D) Both have almost same melting point

281. Which of the following metal does not react directly with oxygen
(A) Cu (B) Zn (C) Ca (D) Hg

282. Incorrect statement for actinoids is

(A) Silvery appearance
(B) They are not attacked by HCl
(D) They donot react with alkalies
(D) Most of the actinoid elements are radioactive

283. Quantitative conversion of K2 MnO4 into KMnO4 does not occur by

(A) O3 (B) Electrolytic oxidation in alkaline medium
(C) Cl2 (D) CO2

H2 S  Excess
284. CuSO 4 ( Aq.)   M    N  O
of KCN

Then final products N and O are respectively

(A) [Cu(CN)4]3–, (CN)2 (B) CuCN, (CN)2 (C) [Cu(CN)4]2–, (CN)2 (D) Cu(CN)2, K2S

285. Consider the following transformation

Room temperature
2CuX 2        2CuX   X 2 
Then X– can be
(A) F– , Br– (B) Cl– , Br– (C) CN– , I– (D) Cl– , F–

286. Statement-1 : Zero and negative oxidation state of d-block metal ion are not possible in their
complex compound.
Statement-2 : Low oxidation state of metal ions are found when a complex compound has ligands
capable of -acceptor character in addition to the -bonding.
(A) Statement-1 is true, Statement-2 is true and Statement-2 is correct explanation for Statement-1
(B) Statement-1 is true, Statement-2 is true and Statement-2 is NOT correct explanation for Statement-
1
(C) Statement-1 is true, Statement-2 is false
(D) Statement-1 is false, Statement-2 is true

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287. Statement-1 Aquated copper (I) cation undergoes disproportionation as :

2Cu+(aq)  Cu2+(aq) + Cu
Statement-2 Hydration energy of Cu++ is higher than that of Cu+ which compensates second
ionization energy of Cu.
(A) Statement-1 is true, Statement-2 is true and Statement-2 is correct explanation for Statement-1
(B) Statement-1 is true, Statement-2 is true and Statement-2 is NOT correct explanation for Statement-
1
(C) Statement-1 is true, Statement-2 is false
(D) Statement-1 is false, Statement-2 is true

288. Acidified KMnO4 does not oxidize

(A) C2O42– (aq) (B) S2O32–(aq) (C) F–(aq) (D) Fe2+(aq)

289. Which of the following solid salt on heating with solid K2Cr2O7 and conc. H2SO4. Orange red vapours
are evolved which turn aquous NaOH solution yellow.
(A) NaBr (B) NaCl (C) NaNO2 (D) NaI

290. In context of the lanthanoids, which of the following statements is not correct ?
(A) Availability of 4f electrons results in the formation of compounds in +4 state for all the members of
the series
(B) There is a gradual decrease in the radii of the members with increasing atomic number in the
series
(C) All the members exhibit +3 oxidaton state
(D) Because of similar properties the separation of lanthanoids is not easy

Paragraph for Question Nos. 291 to 293

Colour of compounds occurs due to phenomenon of polarisation, charge transfer, d-d transition and
H.O.M.O. – L.U.M.O transition. Most of the transition metal complex compound are coloured either
due tod-d electron transition or charge transfer spectrum and ionic compounds are coloured due to
polarisation of anion.
291. Which of the following is correct about KFeII [Fe(CN)6] and KFeIII [Fe(CN)6] complex compounds ?
(I) (II)
(A) Both are blue coloured compound because colour arises due to d-d electron transition in Fe
cation present outside the complex ion.
(B) Both are blue coloured compound because colour arises due to transference of electron between
FeII and FeIII cation.
(C) Both are blue coloured compound because in complexes FeII cation shows same d-d transition
band
(D) Complex (I) has blue colour while complex (II) has brown colour.

292. If MCl2 salt is white, then comment on colour of its iodide salt.
(A) Coloured (B) White
(C) May be white or coloured (D) Black

293. Choose INCORRECT statement.

(A) Halogens are coloured due to HOMO–LUMO transition
(B) During charge transfer, oxidation state of atoms changes
(C) Higher the polarisation, more is colour intensity
(D) Complex compound having no unpaired electron can not undergo d-d transition and therefore it
is colourless

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7. Salt Analysis :

294. Zn + NaOH + NaNO3  Gas 'X'

Gas 'X' can be identified by
(A) FeSO4 + dil.H2SO4 (B) FeSO4 + conc. H2SO4
(C) K2HgI4 + KOH (D) K2HgI4 + HI

295. Which anion gives volatile product on reaction with conc. H2SO4 on redox change.
– –
(A) F (B) Cl (C) Br– (D) B4 O72–

296. Which of the following is precipitate formation reaction

(A) BaCl2 + Na2C2O4 + CH3COOH (B) SrCl2 + Na2CrO4 + CH3COOH
(C) CaCl2 + Na2CO3 + CH3COOH (D) BaCl2 + Na2SO4 + CH3COOH

297. Silver nitrate solution when added to a colorless aqueus solution E forms a white precipitate which
dissolves in excess of E. If the white precipitate is heated with water, it turns black and the supernatant
solution gives a white precipitate with acidified barium nitrate solution. Therefore, E is
(A) Na2S (B) Na2S2O3 (C) Na2SO3 (D) Na2SO4

298. The solubility products (Ksp) of three salts MX, MY2 and MZ3 are 1 × 10–8, 4 × 10–9 and 27 × 10–8,
respectively. The correct order for solubilities of these salts is
(A) MX > MY2 > MZ3 (B) MZ3 > MY2 > MX (C) MZ3 > MX > MY2 (D) MY2 > MX > MZ3

299. Aqueous solution of Na2CO3 does not produce observable change with.
(A) Br2 vapours (B) Fe2(SO4)3 solution
(C) Ba(OH)2 soution (D) CsNO3 solution

300. Mn+(aq) + NH4OH + H2S  P

Which of the following cation does not follow above reaction ?
(A) Cu2+(aq) (B) Al3+(aq) (C) Zn2+(aq) (D) Ba2+(aq)

301. Fe(OH)3 can be separated from Al(OH)3 by addition of

(A) BaCl2 (B) dil. HCl
(C) NaOH solution (D) NH4Cl and NH4OH

302. On passing H2S gas into first group filtrate sometimes yellow turbidity appears even in the absence
of II group radicals, this is because of
(A) sulphur is present in the mixture as impurity.
(B) (IV) group radicals are precipitated as sulphides.
(C) the oxidation of H2S gas by some acid radicals.
(D) III group radicals are precipitated as hydroxides.

303. Cations present in slightly acidic solution are Al3+, Zn2+ and Cu2+. The reagent which when added in
excess to this solution would identify and seperate Cu2+ in one step is
(A) HCl acid (B) NH3 solution
(C) NaOH solution (D) Na2CO3 solution

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304. INCORRECT order of solubility product (Ksp) of given precipitated compound is

(A) AgCl < PbCl2 (B) Al(OH)3 < Zn(OH)2 (C) BaCO3 < MgCO3 (D) MnS < Ag2S

305. Statement-1 : NO3– ion can not be detected by brown ring test in presence of NO2– ion.
Statement-2 : Both NO2– and NO3– ions evolve brown NO2 gas with conc. H2SO4 acid.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for
statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.

306. On adding KI to a metal salt solution, no precipitate was observed but the salt solution gives yellow
precipitate with K2CrO4 in the presence of CH3COOH. Then the salt is
(A) Sr(NO3)2 (B) Pb(CH3COO)2 (C) AgNO3 (D) BaCl2

307. Which of the following precipitate is soluble in excess of NH3solution

(A) Pb(OH)2 (B) Fe(OH)3 (C) Ni(OH)2 (D) Ag2S

308. When a black metal sulphide reacts with dil HCl, a gas liberates, which of the following pair of cation
can be separated by the liberated gas
(A) Zn2+, Cd2+ (B) Hg2+, Ag+ (C) Cu2+, Pb2+ (D) Mn2+, Ni2+

309. Which of the following mixtures can be separated by using excess NH3 solution?
(A) Bi3+(aq) and Al3+(aq) (B) Al3+(aq) and Zn2+(aq)
(C) Hg2+(aq) and Pb2+(aq) (D) Cu2+(aq) and Cd2+(aq)

310. Which of the following salt on heating with concentrated H2SO4, coloured vapours are evolved.
(A) NaBr (B) Na2S (C) CaF2 (D) Na2C2O4

8. Coordination Compound :

311. Select correct set of 'n' and 'x' for given reaction when maximum number of stereoisomers obtained.
(where x = ligands, n = number of ligands)
nx
[Ni(H2O)6]2+ 

(A) 6, NH3 (B) 1, en (C) 2, en (D) 3, en

312. Which anion has maximum donor sites

– – – –
(A) SCN (B) OCN (C) NOS (D) ONO

313. Which set of properties are similar between PtCl2– 2–

4 , Pt(CN)4 complexes

(I) Magnetic moment (II) Geometry

(III) Number of delectrons (IV) Energy order of d orbitals
(A) I, II, III, IV (B) I, II, III (C) II, III (D) Only III

314. [Co(H2O)5 SCN]Br2 cannot show

(A) Ionization isomerism (B) Hydrate isomerism
(C) Linkage isomerism (D) Geometrical isomerism

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315. Which property is not related to [Co(H2O)6]3+ complex cation

(A) Diamagnetic complex (B) Colour complex
(C) Inner orbital complex (D) 0 < Pairing Energy

316. Complex compound Co5NH3NO2Cl2 has two isomers, both give 2 moles of AgCl when one mole of
each complex reacts with excess AgNO3, these complexes are :
(A) Ionization isomers (B) Linkage isomers
(C) Optical isomers (D) Geometrical isomers

317. Which chelating ligand forms complex with Ni2+ containing four stable rings
(A) Oxlate (B) Ethylenediamine (C) dimethylglyoximate (D) Glycinate

318. A person having osteoprosis is suffering from lead poisoning. Ethylene diamine tetra acetic acid
(EDTA) is administered for this condition. The best from of EDTA to be used for such administration
is
(A) EDTA (B) Tetrasodium salt
(C) Disodium salt (D) Calcium dihydrogen salt

319. Four statements for the following reaction are given below
[CoCl2(NH3)4]+ + Cl– [CoCl3(NH3)3] + NH3
(I) Only one isomer is produced if the reactant complex ion is a trans isomer
(II) Three isomers are produced if the reactant complex ion is a cis isomer
(III) Two isomers are produced if the reactant complex ion is a trans isomer
(IV) Two isomers are produced if the reactant complex ion is cis isomer
The correct statements are
(A) I and II (B) III and IV (C) I and IV (D) II and III

excess KCN
Complex 'X'

320. Fe3+

excess of KF
Complex 'Y'
Complex (X) & (Y) both has same
(A) Magnetic moment (B) Hybridization
(C) Geometry (D) Colour

321. Paramagnetic complex ion is formed on adding excess of KCN solution to which of the following
cation
(A) Cu2+(aq) (B) Zn2+(aq) (C) Cr2+(aq) (D) Ni2+(aq)

322. Incorrect statement for complex compound having formula CoCl3.4NH3.

(A) Its geometrical isomers have different colour
(B) It prodces white precipitate with AgNO3 solution
(C) Its optical isomers have different colour
(D) It does not exhibit structural isomerism

323. The complex compound, which exhibits both structural isomerism and stereoisomerism.
(A) [Pt BrCl.(H2O)(NH3)] (B) [Co Br(NO2)(ox)2]3–
(C) [PtCl2(en)2]Cl2 (D) [Zn(NO2)(ox)(NH3)]–

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324. Complex compound [Co(NO3) (H2O) (en)2] [NiCl4] does not exhibit :
(A) Linkage isomerism
(B) Colour
(C) Paramagnetic character
(D) Both geometrical and optical isomerism.

325. Which of the following complex exhibits optical isomerism but does not exhibit geometrical isomerism.
(A) [Ir(ox) (NH3)4]+ (B) [PtBrCl(CN) (NO2)]2–
(C) [Zn(CN) (NO2) (NH3) (H2O)] (D) [Co(NO2)2 (SCN) (H2O)3]

326. INCORRECT match is :

Complex compound Total No. of optical isomers
(A) [Cr(NO2) (SCN) (en)2 ]+ 3
(B) [Ru(H2O)3 (NH3)3] 2
(C) [Fe(ox)3]3– 2
(D) [CoBr2(CN)2 (en)]– 4

327. Which of the following ligand does not act as -acid ligand.
(A) N2 (B) CO (C) C2H4 (D) O22–

328. Select INCORRECT match

(A) [Co(NO2)(H2O)(en)2)]Cl2, [CoCl(NO2)(en)2] Cl . H2O – Hydrate isomerism
(B) [Cu(NH3)4][PtCl4], [CuCl(NH3)3] [PtCl3(NH3)] – Coordination isomerism
(C) [Ni(CN)(H2O)(NH3)4]Cl, [NiCl(H2O)(NH3)4]CN – Ionization isomerism
(D) [Cr(ONO2)(NH3)5] [ZnCl4], [Cr(NO3)(NH3)5] [ZnCl4] – Linkage isomerism

329. If CO ligands are substituted by NO in respective neutral carbonyl compounds then which of
the following will not be correct formula
(A) Cr(CO)3(NO)2 (B) Fe(CO)2(NO)2 (C) Cr(NO)4 (D) Ni(CO)2(NO)2

330. The -acid ligand which uses its d-orbital during synergic bonding in its complex compound.
(A) NO+ (B) PR3 (C) C6H6 (D) CO

331. Select INCORRECT statement about complex [Cr(NO2)(NH3)5][Zn(SCN)4]

(A) It shows co-ordination isomerism
(B) It shows optical activity
(C) It shows linkage isomerism
(D) IUPAC name of the compound is Pentaamminenitrito-N-chromium (III) tetrathiocyanato-S-zincate(II)

332. Find out CORRECT I.U.P.A.C. name of complex compound

(A) Triamminetricyanidochromium(III)hexanitrito-N-irridate(III)
(B) Pentaamminecyanidochromium(III)hexanitrito-N-irridium(III)
(C) Hexanitrito-N-irridium(III)pentaamminecyanidochromate(II)
(D) Pentaamminecyanidochromium(III)hexanitrito-N-irridate(III)

333. CORRECT sequence of CO bond order in given compounds is :

(P) Fe(CO)5 (Q) CO (R) H3B  CO (S) [Mn(CO)5] –
(A) P > R > S > Q (B) S > P > R > Q
(C) Q > S > P > R (D) R > Q > P > S

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334. Which of the following species can act as reducing agent :

(A) [Co(CO)4] – (B) Mn (CO)6 (C) Mn(CO)5 (D) Cr(CO)6

335. In which of the following complex ion the value of magnetic moment (spin only) is 3 BM and outer
d-orbitals is used in hybridization.
(A) [Fe(NH3)6]3+ (B) [Mn(CN)6]4– (C) [CuCl5]2– (D) [Co(NH3)6]2+

336. Which of the following match is INCORRECT

Complex Compounds Type of Hybridization
(A) [V(NH3)6]3+ - d2sp3
(B) [Cr Cl3 (NMe3)3] - d2sp3
(C) [Cu(CN) (NO2) (NH3) (Py)] - dsp 2
(D) K3[Co(ox)3] - sp3d2

337. Which of the following order of CFSE is INCORRECT

(A) [Co(en)3]3+ > [Co(NH3)6]3+ > [Co(H2O)6]3+ (B) [Pt Cl4]2– > [Pd Cl4]2– > [Ni Cl4]2–
(C) [Ni(DMG)2] < [Ni(en)2]2+ (D) [Co(ox)3]3– < [Co(en)3]3+

338. For which of the following dn configuration of octahedral complexes, can not exist in both high spin
and low spin forms.
(I) d3 (II) d 5 (III) d 6 (IV) d8
(A) I, II & III (B) II, III & IV (C) I & IV (D) None

339. Which of the following complex compound exhibits geometrical isomerism

(A) [Fe(DMG)2] (B) [Be (gly)2] (C) [Pd ClBr(gly)] (D) [Cd (NH3)Cl(gly)]

340. In which case racemic mixture is obtained on mixing its mirror images (d &  form) in 1 : 1 molar ratio?
(A) trans-[Co(gly)3] (B) [Ni(DMG)2] (C) cis-[Cu(Gly)2] (D) [Zn (en) (gly)]+

341. Which of the following compound show optical isomerism?

(A) cis–[CrCl3(NH3)3] (B) cis–[Co(NH3)4Cl2]+
(C) [Co(en)3]3+ (D) trans–[Co(en)2Cl2]+

9. Metallurgy :

342. In Bayer's process, impurity SiO2 present after reaction in

(A) Insoluble form (B) Soluble form in cationic part
(C) Soluble form in anionic part (D) Reduced form

343. Which pair of metals is commercially extracted by metal displacement and refined by electrorefining
method
(A) Ag, Au (B) Cu, Mg (C) Ag, Hg (D) Hg, Au

344. In copper metallurgy, bessemer converter is used for

(A) Refining of copper metal (B) Roasting of copper pyrite
(C) Self reduction of Cu2S (D) Froth flotation of CuFeS2

345. Which step is not used in extraction of zinc from calamine.

(A) Roasting (B) Carbon reduction (C) Electrorefining (D) Distillation

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346. Which of the following gas is passed into solution of sodium meta-aluminate to precipitate
hydrated Al2O3 in leaching of alumina from bauxite
(A) SO3 (B) CO2 (C) HCl (D) NH3

347. Which of the following process is not related to the refining of impure metal
(A) Distillation (B) Leaching (C) Bessemerization (D) Poling

348. INCORRECT match is :

(A) Zone refining : Fractional crystallization
(B) Mond’s Process : Vapour phase thermal decomposition
(C) Distillation : Refining of Blister copper
(D) Poling : Hydrocarbons are used as reductant

349. In which of the following refining method impurities are not preferentially oxidised than the metal to
be refined.
(A) cupellation (B) Puddling (C) Beseemerization (D) Liquation.

350. The reduction of an oxide by aluminium is called :

(A) Baeyer’s process (B) Goldschmidt’s aluminothermite process
(C) Hall’s process (D) Van Arkel process

351. Leaching is commercially carried out for in the concentration of :

(A) Galena (B) Argentite (C) Copper pyrites (D) Tin stone

352. NaCN is sometimes added in the forth flotation process as depressant when ZnS and PbS minerals
are expected because :
(A) Pb(CN)2 is precipitated while no effect on ZnS.
(B) ZnS forms soluble complex Na2[Zn(CN)4] while PbS forms froth
(C) PbS forms soluble complex Na2[Pb(CN)4] while ZnS forms froth.
(D) NaCN is never added in froth floatation process.

353. In the purification of impure nickel by Mond’s process, metal is purified by.
(A) Electrolytic reduction (B) Vapour phase thermal decomposition
(C) Thermite reduction (D) Carbon Reduction

354. CORRECT match is

(A) Bayer's method – Na2CO3
(B) Matte – 98% Cu2S + 2% FeS
(C) Van Arkel method – AgI
(D) Thomas slag – Raw material for cement industry

355. INCORRECT statement In electrolysis of Al2O3 by Hall-Heroult process is :

(A) Cryolite Na3 [AlF6] lowers the melting point of Al2O3 and increases its electrical conductivity.
(B) Al is obtained at cathode and CO2 at anode
(C) Li2CO3 can be used in place of cryolite (Na3AlF6)
(D) BeF2 can be used in place of flourspar (CaF2)

356. Which of the following substance acts as collector in froth floatation method
(A) Sodium Xenate (B) Sodium pyrophosphate
(C) Sodium nitroprusside (D) Sodium ethyl xanthate

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10. Environmental Chemistry :

357. Eutrophication is not caused by

(A) Ca(H2PO4)2 (B) NH4NO3 (C) CaCO3 (D) H2NCONH2

358. The basic component of smog is

(A) PAN (B) PBN (C) NO2 (D) All of these

359. BHC and DDT act as

(A) carcinogens (B) allergens (C) asthmatic agents (D) all of these

360. Ozone depletion in the stratosphere is mainly caused by

(A) SO2 (B) NO2
(C) NO (D) chlorofluorocarbons

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