a) There are 33 questions in this question paper. All questions are compulsory. b) Section A: Q. No. 1 to 2 are case-based questions having four MCQs or Reason Assertion type based on given passage each carrying 1 mark. c) Section A: Question 3 to 16 are MCQs and Reason Assertion type questions carrying 1 mark each d) Section B: Q. No. 17 to 25 are short answer questions and carry 2 marks each. e) Section C: Q. No. 26 to 30 are short answer questions and carry 3 marks each. f) Section D: Q. No. 31 to 33 are long answer questions carrying 5 marks each. g) There is no overall choice. However, internal choices have been provided. h) Use of calculators and log tables is not permitted.
1.Read the passage given below and answer the following questions: (1×4=4)
Orbitals are region or space where there is maximum probability of finding electrons. Qualitatively, these orbitals can be distinguished by their size, shape and orientation. An orbital of small size means there is more chance of finding the electron near the nucleus. Shape and orientation means the direction in which probability of finding electron is maximum. Atomic orbitals can be distinguished by quantum numbers. Each orbital is designated by three quantum numbers n, l and ml (magnetic quantum number) which define energy, shape and orientation but these are not sufficient to explain spectra of multi-electrons atoms. Spin quantum number (ms) determines the spin of electron. Spin angular momentum of electron has two orientations relative to chosen axis which are distinguished by spin quantum numbers ms which can take values +1/2 and –1/2. Value of 'l' 1 2 3 4 5 Notation for s p d f g subshell
The following questions are multiple choice questions. Choose the most appropriate answer:
(i) If the value of (n+l) is more than 3 and less than 6, what will be the possible number of orbitals?
a) 6 b) 9 c) 10 d) 13
(ii) Which of the following orbital designations is not correct corresponding to quantum numbers?
a) n=5,l=2 →5d
b) n=2,l=0 →2s
c) n=7,l=2 →7p
d) n=4,l=3 →4f
OR
The maximum number of electrons which can be held by subshell with azimuthal quantum number 'l' in an atom is given by
a) 2(2l+1) b) (2l+1) c) 2l d) 2(2l+2)
(iii) The correct set of quantum numbers (n,l and m l) respectively for unpaired electron of chlorine atom is
a) 2,1,0 b) 3,1,1 c) 3,2,1 d) 3,2,-1
(iv) Identify the CORRECT statement
a) Quantum numbers (n,l,m,s) are obtained arbitrarily
b) All the quantum numbers (n,l,m,s) for any pair of electrons in an atom can be identical under special circumstance.
c) All the quantum numbers (n,l,m,s) may not be required to describe an electron of an atom completely.
d) All the quantum numbers (n,l,m,s) are required to describe an electron of an atom completely.
2. Read the passage given below and answer the following questions: (1x4=4) An ionic compound has 3-D crystal lattice in which positive and negative charges are equal. The crystal lattice is stabilised by enthalpy of lattice formation, bond length, bond angle, bond enthalpy, bond order and bond polarity have significant effect on properties of compounds. All the properties of certain compounds cannot be explained by single structure, more than one structure of a compound to explain its property are called resonating structures. Dipole moment depends upon polarity and shapes of molecules. Shapes of molecules can be determined by VSEPR theory as well as hybridisation sp, sp2, sp3, sp3d, sp3d2 are linear, trigonal planar, tetrahedral, trigonal bipyramidal and octahedral geometery respectively. Hydrogen bond is formed between hydrogen and F, O, N. Intra-molecular H-bonding is within the molecules which is weaker than inter molecular H-bonding, between the molecules.
In these following questions a statement of assertion followed by a statement of
reason is given. Choose the correct answer out of the following choices.
a) Assertion and reason both are correct statements and reason is correct explanation for assertion. b) Assertion and reason both are correct statements but reason is not correct explanation for assertion. c) Assertion is correct statement but reason is wrong statement. d) Assertion is wrong statement but reason is correct statement.
(i) Assertion: C2H2 molecule is linear.
Reason: in C2H2 carbon atoms remain unhybridized. (ii) Assertion: BF3 molecule is planar while NF3 is pyramidal. Reason: N atom is smaller than B atom.
(iii) Assertion: Though the central atom of both NH3 and H2O molecules are sp3 hybridised, yet H-N-H bond angle is greater than that of H-O-H. Reason : This is because nitrogen atom has one lone pair and oxygen has two lone pair electrons. . (iv) Assertion: The bond order between two atoms in a molecule may be taken as an approximate measure of bond length. Reason: The bond length decreases as bond order increases.
OR
Assertion: Resonance destabilizes the molecule.
Reason: The energy of the resonance hybrid is less than the energy of any single canonical structure.
Following questions (No. 3 -11) are multiple choice questions carrying 1 mark each:
3. Inert pair effect is predominant in
a) Si b) Pb c) Ge d) Sn
4. The increasing order of density of alkali metals is
a) Li<K<Na<Rb<Cs b) Li< Na<K<Rb<Cs c) Cs<Rb<Na< K<Li d) Cs<Rb<K<Na<Li
OR
Among the alkaline earth metals, the element forming predominantly covalent compound is a) Barium b) Strontium c) Beryllium d) Calcium
5. Which of the following element has electronic configuration [Ar] 3d54s1?
a) Mn b) Co c) Ni d) Cr
6. A mixture contains 64g of dioxygen and 60 g of neon at a total pressure of 10 bar.
The partial pressures in bar of dioxygen and neon are respectively (atomic masses : O=16,Ne=20) a) 4 and 6 b) 5 and 5 c) 2 and 8 d) 6 and 4 OR Maximum deviation from ideal gas is expected from a) CH4(g) b) NH3(g) c) H2(g) d) N2(g)
7. For reaction, N2(g) + 3H2(g)→2NH3(g), which of the following is valid?
a) ∆H = ∆U b) ∆H > ∆U c) ∆H < ∆U d) None of the above
OR
In which of the following cases, reaction is spontaneous at all temperatures?
a) ∆H>0 ; ∆S>0 b) ∆H<0 ; ∆S>0 c) ∆H<0 ; ∆S<0 d) ∆H<0 ; ∆S=0
8. The formation of oxide ion, O2- (g) requires first an exothermic and then endothermic step as shown below : O(g) + e- → O-(g) ∆H0= -142 kJ mol-1 O-(g) +e- → O2-(g) ∆H0= + 844 kJ mol-1
This is because a) Oxygen is more electronegative b) Oxygen has high electron affinity c) O- will tend to resist the addition of another electron d) O- ion has comparatively larger size than oxygen atom
OR
Identify the wrong statement in the following :
a) Amongst isoelectronic species, smaller the positive charge on the cation, smaller is the ionic radius b) Amongst isoelectronic species, greater the negative charge on the atom, larger is the ionic radius c) Atomic radius of the elements increases as one moves down the first group of the periodic table. d) Atomic radius of the elements decreases as one moves across from left to right in the 2nd period of the periodic table
9. Which of the following hydrides is electron-precise hydride?
a) B2H6 b) NH3 c) H2O d) CH4
10. Oxidation number of P in PO43- ion is
a) +7 b) -3 c) +5 d) +3
11. The ratio of the forward reaction is two times that of the reverse reaction at a given temperature and identical concentration. Kequilibrium is a) 0.5 b) 2 c) 2.5 d) 1.5 In the following questions (Q. No. 12 - 16) a statement of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices.
a) Assertion and reason both are correct statements and reason is correct explanation for assertion. b) Assertion and reason both are correct statements but reason is not correct explanation for assertion. c) Assertion is correct statement but reason is wrong statement. d) Assertion is wrong statement but reason is correct statement
12. Assertion: The pressure of ideal gases is always less than the pressure of real gases. Reason: The intermolecular forces of attraction in ideal gases are less than those of real gases.
13. Assertion: It is impossible to determine the exact position and exact momentum of an electron simultaneously. Reason: The path of an electron in an atom is clearly defined.
14. Assertion: Boron has a smaller first ionisation enthalpy than beryllium. Reason: The penetration of a 2s electron to the nucleus is more than the 2p electron hence 2p electron is more shielded by the inner core of electrons than the 2s electron.
OR Assertion: F atom has less negative electron gain enthalpy than Cl atom. Reason: Additional electrons are repelled more effectively by 3p-electrons in Cl than by 2p-electrons in F atom.
15. Assertion: Some metals like platinum and palladium can be used as storage media for hydrogen. Reason: Platinum and palladium can absorb large volumes of hydrogen.
16. Assertion: K, Rb, and Cs can also form superoxides.
Reason: Their ionic radii increase in the order Cs+<Rb+<K+
SECTION B
The following questions, Q.No 17 – 25 are short answer type and carry 2 marks each.
17. How would you explain the fact that the first ionization enthalpy of sodium is lower than that of magnesium but its second ionization enthalpy is higher than that of magnesium? OR Among the elements B,Al,C and Si, (i) Which element has the highest first ionization enthalpy? (ii) Which element has the most metallic character? Justify your answer in each case.
18. (i) Explain why BeH2 molecule has a zero dipole moment although the Be-H bonds are polar? (ii) Write the Lewis structure of nitrite ion.
19. At 0°C, the density of a certain oxide of a gas at 2 bar is same as that of dinitrogen at 5 bar. What is the molecular mass of the oxide.
OR (i) A gas that follows Boyle's law, Charle's law and Avogadro's law is called an ideal gas. Under what conditions a real gas would behave ideally? (ii) Explain the physical significance of vander waal's parameters.
20. Enthalpy of combustion of carbon to CO2 is -393.5 kJmol-1.Calculate the heat
released upon formation of 35.2 g of CO2 from carbon and dioxygen gas. (Molar mass of CO2 =44 gmol-1)
21. How many sigma and pi bonds are present in each of the following molecules? a) CH2=C=CHCH3 b) CHΞC-CH=CH-CH3
OR
Write the bond line structure of the following organic compounds.
a) 3-methyl octane b) 2- bromo pentane
22. (i) Why is KO2 paramagnetic?
(ii) Why are alkali metals soft and have low melting points?
23. Write reactions to justify amphoteric nature of aluminum.
24. The following concentrations were obtained for the formation of NH3 from N2 and H2 at equilibrium at 500 K. [N2]=1.5×10-2 M, [H2]=3.0×10-2 M and [NH3]=1.2×10-2 M, calculate the equilibrium constant.
25.Justify that the reaction:
2 Cu2O(s) + Cu2S(s)→ 6Cu(s) + SO2(g) is a redox reaction. Identify the species oxidised/reduced, which acts as an oxidant and which act as a reductant. SECTION C
Q.No 26 -30 are Short Answer Type II carrying 3 mark each.
26. What do you understand by (i) electron deficient, (ii) electron-precise, and (iii) electron rich compounds of hydrogen? Provide justification with suitable examples.
27. What will be the pressure exerted by a mixture of 3.2 g of methane and 4.4 g of carbon dioxide contained in a 9 dm3 flask at 27°C?
OR
Pay load is defined as the difference between the mass of displaced air and mass of the balloon. Calculate the pay load when a balloon of radius 10m, mass 100 kg is filled with helium at 1.66 bar at 27°C.( Density of air= 1.2 kg m-3 and R=0.083 bar dm3 K-1 mol-1).
28. When BCl3 is treated with water, it hydrolyses and forms [B(OH)4]- only whereas AlCl3 in acidified aqueous solution forms [Al(H2O)6]3+ ion. Explain what is the hybridisation of boron and aluminium in these species?
29.i) The equilibrium constant for a reaction is 10. what will be the value of ∆G 0? (R=8.314 JK-1mol-1, T=300K).
ii) Define Enthalpy of fusion.
OR
i) Given
N2(g) + 3H2(g) → 2NH3(g) ; ∆rH0 = -92.4 kJmol-1
What is the standard enthalpy of formation of NH3 gas?
ii) Extensive properties depend on the quantity of matter but intensive properties do not. Explain whether the following properties are extensive or intensive.
(ii) The concentration of hydrogen ion in a sample of soft drink is 3.8×10 -3 M. What is its pH? (log 3.8=0.5798)
(iii) What will be the conjugate base for the bronsted acid HF? SECTION-D
31. The combustion of one mole of benzene takes place at 298 K and 1 atm. After combustion, CO2(g) and H2O (l) are produced and 3267.0 kJ of heat is liberated. Calculate the standard enthalpy of formation, ∆fH° of benzene. Standard enthalpies of formation of CO2(g) and H2O(l) are -393.5 kJ mol-1 and -285.83 kJ mol-1 respectively.
OR
(i) Use the following data to calculate ∆latticeH° for NaBr.
a) ∆subH° for sodium metal =108.4 kJmol-1
b) Ionization enthalpy of sodium=496 kJmol-1
c) Electron gain enthalpy of bromine= -325 kJmol-1
d) Bond dissociation enthalpy of bromine= 192 kJmol-1
e) ∆fH° for NaBr(s) =-360.1 kJmol-1
(ii) Calculate the entropy change in the surroundings when 1.00 mole of H 2O(l) is formed under standard conditions. (∆Hf° = -286 kJmol-1)
32. The ionization constant of acetic acid is 1.74×10-5. Calculate the degree of dissociation of acetic acid in its 0.05 M solution. Calculate the concentration of acetate ion in the solution and its pH.
OR
(i) If 0.561 g of KOH is dissolved in water to give 200 mL of solution at 298 , calculate the concentrations of potassium, hydrogen and hydroxyl ions. What is its pH?
(ii) Determine the solubility of barium chromate from its solubility product constant.
Ksp(BaCrO4) =1.2×10-10 33. Write the net ionic equation for the reaction of potassium dichromate(VI), K2Cr2O7 with sodium sulphite, Na2SO3 in an acid solution to give chromium(III) ion and the sulphite ion.
OR
Balance the following redox reaction by ion-electron method.
MnO4-(aq) + I- (aq) → MnO2(s) + I2 (s) (in basic medium)
