For classes 6th to 12th

EWS Coaching
[ Proud to be associated with Ramkrishna Mission JEE (Mains & advanced) | NEET | NTSE | OLYMPIAD
Vidyapith, Deoghar]

11th RAMP DATE - 09.08.23

CHEMISTRY QUIZ - 16
( JEE-MAINS)

1. Which of the bond length order data is INCORRECT -

(A) P–Cl > P–F in PCl3F2 (B) S–F(axial) > S – F(eq) in SF6
(C) S–F(axial) > S – F(eq) in SF4 (D) NO2– < NO3– (N – O)
2. O2 F2 is an unstable yellow orange solid and H2O2 is a colourless liquid, both have O–O bond.
O–O bond length in H2O2 & O2F2 is respectively.
(A) 1.22Å, 1.48Å (B) 1.48Å, 1.22Å (C) 1.22Å, 1.22Å (D) 1.48Å, 1.48Å
3. Select the correct order of following property.
(A) % s-character : sp3 > sp2 > sp

^ O bond angle 
(B) ON : NO3– > NO 2

(C) All angles in CH2F2 are not identical

(D) C – F bond length : CF4 > CH3F > CH2F2 > CF3H
4. The strongest P–O bond is found in the molecule
(A) F3PO (B) Cl3PO (C) Br3PO (D) (CH3)3PO
5. The order of bond length from the following structure.
F
Cl II
V
As I Cl
III
Br IV
Cl
(A) III > I = V > IV > II (B) IV > II > I = V > III
(C) III > IV > I = V > II (D) I > II > III > IV > V
6. Comment on the C – C bond length for C2H6 and C2F6 compounds :
(A) dC–C(C2H6) > dC–C(C2F6) (B) dC–C(C2F6) > dC–C(C2H6)
(C) dC–C(C2F6) = dC–C(C2H6) (D) Can’t be predicted

Helpline: - 8389971630, 8334000097 Email: [email protected]

Address: - Near HP Gas Agency, East Market Chittaranjan Visit us at: www.enjoywithsubject.in
 For classes 6th to 12th
EWS Coaching
[ Proud to be associated with Ramkrishna Mission JEE (Mains & advanced) | NEET | NTSE | OLYMPIAD
Vidyapith, Deoghar]

7. Which of the following statement is CORRECT for

F3C – CF2 – CF3
(A) All C–F bond lengths are identical
(B) Two C–F bonds attached to middle C-atom are longer compared to other C–F bonds at the terminal
C–atoms
(C) Two C–F bonds attached to middle C-atom are shorter compared to other C–F bonds at the terminal
C-atoms.
(D) None is correct
8. Choose the CORRECT statement regarding bond angle :-
 in F CO < HC
(A) FCF  H in H2CO 
(B) BrP 
Br in PBr3 < FPF in PF3
2


(C) F 
SF(eq)  FSF(ax) in SF4 
(D) All FIF angles in IF5 are identical
9. If the %- s-character in one Sb-H bond in SbH3 is 1.0%. What is % p-character is the orbital occupied
by its lone pair -
(A) 99.0 (B) 97 (C) 90 (D) None
10. Choose CORRECT order of bond length
(A) S – S bond length : S2O42– > S2O62–
(B) O – O bond length : H2O2 > O2F2
(C) N – N bond length : N2O3 > N2O4
(D) All are correct
Assertion & Reason
11. Statement-1 : ClF2 is linear while ClF2 is bent.

Statement-2 : Cl-atom in ClF2 and in ClF2 , is having same state of hybridisation.

(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.
Paragraph for Q.9 to 10
According VSEPR theory, in the electronic geometry of the molecule(s), electron pair tend to minimise repulsion
and follow the repulsion order in presence of lone pair of electrons with bond pair of electrons.
p –p > p – bp > bp – bp
and similarly double bond pair of electrons follow the repulsion order with single bond pair of electrons.
double bond – double bond > double bond – single bond > single bond – single bond

Helpline: - 9835154133, 8389971630, 8334000097 Email: [email protected]

Address: - Near HP Gas Agency, East Market Chittaranjan Visit us at: www.enjoywithsubject.in
 For classes 6th to 12th
EWS Coaching
[ Proud to be associated with Ramkrishna Mission JEE (Mains & advanced) | NEET | NTSE | OLYMPIAD
Vidyapith, Deoghar]

12. Which of the following molecular geometry is distored geometry from their ideal geometry.
(A) PCl3F2 (B) SOF4 (C) XeF5 (D) XeO3F2
13. Which of the following statement is CORRECT about XeO2F2?
(A) XeO2F2 is sp3d hybridized and has lone pair of electron at axial position of its electronic geometry.
(B) XeO2F2 has maximum 10- lone pair of electrons.
(C) XeO2F2 has distorted see-saw shape.
(D) XeO2F2 contains d–d bond.
14. In which molecule all atoms are planar :
(A) CH4 (B) BF3 (C) PF3 (D) NH3
15. Which of the following is V-shaped :
(A) S32– (B) Ι3– (C) N3– (D) none of these
16. Of the following species, the one having a square planar structure is :
(A) NH+4 (B) BF4− (C) XeF4 (D) SCl4
17. Which of the following species is planar ?
(A) CO32− (B) NH3 (C) PCl3 (D) SOCl2
18. Mark out the correct match of shape ?
(A) XeOF2 - Trigonal planar (B) lCl−4 - Square planar
(C) [SbF5]2– - Pentagonal (D) NHΘ2 - Pyramidal
19. The pair of species having identical shapes for molecules of both species is :
(A) CF4 , SF4 (B) XeF2 , CO2 (C) BF3 , PCl3 (D) PF5, IF3
20. In P4 O10 molecule :
(A) There are 4 P–P bond (B) There are 8 P–O bond
^
(C) The P OP bond angle is 180° (D) The phosphorus atom is in excited state
21. The species having bond order different from that in CO is
(A) NO– (B) NO+ (C) CN– (D) N2
22. What is correct sequence of bond order
(A) O2+ > O2− > O2 (B) O2+ > O2 > O2− (C) O2 > O2− > O2+ (D) O2− > O2+ > O2
23. Which of the following is not paramagnetic
(A) S–2 (B) N2− (C) O2− (D) NO

24. The bond order of O2+ is the same as in

−
(A) N2+ (B) CN (C) CO (D) NO+
25. The correct order in which the O – O bond length increases in the following is
(A) H2O2 < O2 < O3 (B) O2 < H2O2 < O3 (C) O2 < O3 < H2O2 (D) O3 < H2O2 < O2
26. N2 accept electron and convert into N2− , where this electron goes
(A) Antibonding π molecular orbital (B) Bonding π molecular orbital
(C) σ bonding molecular orbital (D) σ – anti-bonding molecular orbital
27. Bond order in N2+ ion is :
(A) 1 (B) 2 (C) 2.5 (D) 3

Helpline: - 9835154133, 8389971630, 8334000097 Email: [email protected]

Address: - Near HP Gas Agency, East Market Chittaranjan Visit us at: www.enjoywithsubject.in
 For classes 6th to 12th
EWS Coaching
[ Proud to be associated with Ramkrishna Mission JEE (Mains & advanced) | NEET | NTSE | OLYMPIAD
Vidyapith, Deoghar]

28. Which of the following moleule forms only π-bond using Molecular orbital theory :
(A) Li2 (B) C2 (C) N2 (D) O2
29. How many nodal plane is/are present in σ1s bonding molecular orbital :
(A) zero (B) 1 (C) 2 (D) 3
30. Bond order of C–O in CO3-2 is :
(A) 2 (B) 3 (C) 1.33 (D) 2.5
31. According to Molecular orbital theory, HOMO in O2− is :
(A) π 2px = π 2py (B) π* 2px = π *2py (C) σ 2pz (D) σ* 2pz
32. Order of stability of N2, N2 and N2 is :
+ −

(A) N2 > N2+ > N2− (B) N2+ > N2 > N2− (C) N2− > N2 > N2+ (D) N2− = N2+ > N2
33. The quantum number not obtained from the Schrodinger's wave equation is :
(A) n (B)  (C) m (D) s
34. In 321, the sum of orbital angular momentum, number of spherical nodes and number of angular nodes is :

6h  4 6h  2 8h  4 8h  6
(A) (B) (C) (D)
2 2 2 2
35. For 3s-orbital of hydrogen atom, the normalised wave function is given by
3/2
1  1  4r 4r 2  r / 3a0
3s    6  
18 3  a0   a0 9a02 

The above mentioned orbital (3s) has two nodes at 1.9a0 and xa0. Find the value of x.
(A) 6.4 (B) 7.1 (C) 2.5 (D) 5.6

36. Find :
(A) The number of radial nodes of 5s atomic orbital
(B) The number of angular nodes of 3dyz atomic orbital
(C) The sum of angular nodes and radial nodes of 4d xy atomic orbital
(D) The number of angular nodes of 3p atomic orbital
37. Column-I and Column-II contains four entries each. Entries of Column-I are to be matched with some
entries of Column-II. One or more than one entries of Column-I may have the matching with the same
entries of Column-II.
Column-I Column-II
(A) The orbital which has two angular nodes (p) 3dx2  y2 A- p , B- q , C- s , D- r
(B) The orbital which has one angular node (q) 3px
(C) The orbital without an angular node (r) 4f
(D) The orbital which has three angular nodes (s) 3s
38. Column-I and Column-II contains four entries each. Entries of Column-I are to be matched with some
entries of Column-II. One or more than one entries of Column-I may have the matching with the same
entries of Column-II.

A- q , B- r , C- s , D- p

Helpline: - 9835154133, 8389971630, 8334000097 Email: [email protected]

Address: - Near HP Gas Agency, East Market Chittaranjan Visit us at: www.enjoywithsubject.in
 For classes 6th to 12th
EWS Coaching
[ Proud to be associated with Ramkrishna Mission JEE (Mains & advanced) | NEET | NTSE | OLYMPIAD
Vidyapith, Deoghar]

Column-I Column-II

(A) 3s (p)

(B) 3p (q)

(C) 3d (r)

(D) 2p (s)

More than one may be correct

39. The CORRECT set of their indicated bond length is:-
(A) S–S (S8) > P–P (P4) (B) dN–N ; NH2–NH2 > NF2–NF2
–
(C) dS–Cl ; SOCl2 < SO2Cl2 (D) dB–O ; B(OH)3 < [B(OH)4]
40. The CORRECT statements about the structures of H2O2, O2F2 and OF2 is/are :
(A) H2O2, O2F2, OF2 are polar compounds
(B) dO – O of H2O2 > dO – O of O2F2
(C) dO – F of OF2 > dO – F of O2F2
(D) the strength of O – O bond in O2F2 is greater than that of H2O2

41. In which of the following, the theory of hybridisation does not help to predict the bond angle ?
(A) PH3 (B) SbH3 (C) SiH4 (D) H2S
42. Choose the CORRECT statements :-
(A) dP–F(axial) > dP–F(equatorial) in PF3Cl2
(B) dP–F > dP–Cl in PF2Cl3
(C) dP–Cl(PF2Cl3) > dP–Cl(PF3Cl2)
(D) All dP–Cl (in PF2Cl3) are identical while all dP–F(in PF3Cl2) are not identical
Helpline: - 9835154133, 8389971630, 8334000097 Email: [email protected]
Address: - Near HP Gas Agency, East Market Chittaranjan Visit us at: www.enjoywithsubject.in
 For classes 6th to 12th
EWS Coaching
[ Proud to be associated with Ramkrishna Mission JEE (Mains & advanced) | NEET | NTSE | OLYMPIAD
Vidyapith, Deoghar]

43. Column I Column II (A)- R , S

(A) XeF5+ (P) Two lone pairs on central atom (B)- P,Q,S
(B) ICl4– (Q) Planar
(C)- R
(D)- P,Q
(C) TeCl4 (R) Non-planar
(D) I3+ (S) sp3d2 (Hybridization of central atom)
Subjective :
44. Identify the pair in which the specified bond length of first is greater than second.
PCl3F2 , PF3Cl2 : B LP–Cleq
SO2Cl2 , SO2F2 : B LS=O Ans- 4
BF3 , BCl3 : B LB–X X = F/Cl

NO3 , NO2 : B LN–O

O3 , O2 : B LO–O
CO , CO2 : B LC–O
45. How many of the following species have no d-orbitals involved in their hybridisation
XeF2, SnF2 PbCl2, SF4, CCl4, BF3, SO2Cl2, XeO2F2, XeOF4, POCl3
Ans- 6

ANSWER

Helpline: - 9835154133, 8389971630, 8334000097 Email: [email protected]

Address: - Near HP Gas Agency, East Market Chittaranjan Visit us at: www.enjoywithsubject.in