Material Safety Data Sheet

Dow Chemical (NZ) Ltd

Product Name: D.E.R.* 331 EPOXY RESIN Issue Date: 23.06.2008

Print Date: 05 Oct 2011

Dow Chemical (NZ) Ltd encourages and expects you to read and understand the entire (M)SDS, as
there is important information throughout the document. We expect you to follow the precautions
identified in this document unless your use conditions would necessitate other appropriate methods or
actions.

1. Product and Company Identification

Product Name
D.E.R.* 331 EPOXY RESIN

Use of the substance/preparation

Used in applications such as: Adhesive. Casting. Tooling. Civil engineering. Composites.
Automotive coatings. Can coatings. Coil coatings. Marine and protective coatings. Photocure
industrial coating. Potting and encapsulation.

COMPANY IDENTIFICATION
Dow Chemical (NZ) Ltd
A Subsidiary of The Dow Chemical Company
Level 13
7 City Road
Auckland 1010
New Zealand

Customer Information Number: 0800-504-567

[email protected]

EMERGENCY TELEPHONE NUMBER

24-Hour Emergency Contact: 0800-243-622
Local Emergency Contact: 0800-243-622
For medical advice, contact the New Zealand Poisons Information Centre: 0800 POISON (0800
764766)

2. Hazards Identification
Classification NEW ZEALAND HAZARDOUS SUBSTANCES CLASSIFICATION: Classified as
hazardous according to criteria in the New Zealand Hazardous Substances (Minimum Degrees of
Hazard) Regulations 2001. Refer to Section 15 for HSNO Approval Number.
Hazard Class:
Class 6 - Toxicity, Subclass 6.3 - Skin irritant, Hazard
Classification B
Class 6 - Toxicity, Subclass 6.4 - Eye irritant, Hazard
Classification A
Class 6 - Toxicity, Subclass 6.5 - Sensitisation, Hazard
Classification B
Class 9 - Ecotoxicity, Subclass 9.1 - Aquatic, Hazard

®(TM)*Trademark of The Dow Chemical Company ("Dow") or an affiliated company of Dow

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 Product Name: D.E.R.* 331 EPOXY RESIN Issue Date: 23.06.2008

Classification B

Labeling
Hazard Symbol: Exclamation mark, Environment
Signal Word: Warning
Hazards of product:
Causes eye irritation.
Causes skin irritation.
May cause an allergic skin reaction.
Toxic to aquatic life with long lasting effects.

Precautionary Statements:
Prevention: Wear protective gloves/protective clothing. Wash thoroughly after handling.
Avoid release to the environment.
Response: If skin irritation occurs: Get medical attention. IF ON SKIN (or hair):
Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin
irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before
reuse. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to remove. Continue rinsing. If eye irritation persists: Get medical
attention. Collect spillage.
Disposal: Dispose of contents and container to licensed, permitted incinerator, or other
thermal destruction device.

Transport Information: Hazard Class: 9 ID Number: UN3082 Packing Group: III

3. Composition Information

Component CAS # Amount

Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8 100.0 %

4. First Aid Procedures

Eye Contact: Flush eyes thoroughly with water for several minutes. Remove contact lenses after the
initial 1-2 minutes and continue flushing for several additional minutes. If effects occur, consult a
physician, preferably an ophthalmologist.
Skin Contact: Remove material from skin immediately by washing with soap and plenty of water.
Remove contaminated clothing and shoes while washing. Seek medical attention if irritation persists.
Wash clothing before reuse. Discard items which cannot be decontaminated, including leather articles
such as shoes, belts and watchbands. Safety shower should be located in immediate work area.
Inhalation: Move person to fresh air; if effects occur, consult a physician.
Ingestion: No emergency medical treatment necessary.
Notes to Physician: No specific antidote. Treatment of exposure should be directed at the control of
symptoms and the clinical condition of the patient.

5. Fire Fighting Measures

Extinguishing Media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire
extinguishers. Foam. Do not use direct water stream. May spread fire. Alcohol resistant foams (ATC
type) are preferred. General purpose synthetic foams (including AFFF) or protein foams may function,
but will be less effective. Water fog, applied gently may be used as a blanket for fire extinguishment.
Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Use water
spray to cool fire exposed containers and fire affected zone until fire is out and danger of reignition has
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Product Name: D.E.R.* 331 EPOXY RESIN Issue Date: 23.06.2008

passed. Fight fire from protected location or safe distance. Consider the use of unmanned hose
holders or monitor nozzles. Immediately withdraw all personnel from the area in case of rising sound
from venting safety device or discoloration of the container. Do not use direct water stream. May
spread fire. Move container from fire area if this is possible without hazard. Burning liquids may be
moved by flushing with water to protect personnel and minimize property damage. Water fog, applied
gently may be used as a blanket for fire extinguishment. Contain fire water run-off if possible. Fire
water run-off, if not contained, may cause environmental damage. Review the “Accidental Release
Measures” and the “Ecological Information” sections of this (M)SDS.
Special Protective Equipment for Firefighters: Wear positive-pressure self-contained breathing
apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers,
boots, and gloves). Avoid contact with this material during fire fighting operations. If contact is likely,
change to full chemical resistant fire fighting clothing with self-contained breathing apparatus. If this is
not available, wear full chemical resistant clothing with self-contained breathing apparatus and fight fire
from a remote location. For protective equipment in post-fire or non-fire clean-up situations, refer to
the relevant sections.
Unusual Fire and Explosion Hazards: Container may rupture from gas generation in a fire situation.
Violent steam generation or eruption may occur upon application of direct water stream to hot liquids.
Dense smoke is emitted when burned without sufficient oxygen.
Hazardous Combustion Products: During a fire, smoke may contain the original material in addition
to combustion products of varying composition which may be toxic and/or irritating. Combustion
products may include and are not limited to: Phenolics. Carbon monoxide. Carbon dioxide.
See Section 9 for related Physical Properties

6. Accidental Release Measures

Steps to be Taken if Material is Released or Spilled: Contain spilled material if possible. Absorb
with materials such as: Sand. Polypropylene fiber products. Polyethylene fiber products. Remove
residual with soap and hot water. Collect in suitable and properly labeled containers. Residual can be
removed with solvent. Solvents are not recommended for clean-up unless the recommended
exposure guidelines and safe handling practices for the specific solvent are followed. Consult
appropriate solvent Safety Data Sheet for handling information and exposure guidelines. See Section
13, Disposal Considerations, for additional information.
Personal Precautions: Isolate area. Keep unnecessary and unprotected personnel from entering the
area. Use appropriate safety equipment. For additional information, refer to Section 8, Exposure
Controls and Personal Protection. Refer to Section 7, Handling, for additional precautionary
measures.
Environmental Precautions: Prevent from entering into soil, ditches, sewers, waterways and/or
groundwater. See Section 12, Ecological Information.

7. Handling and Storage

Handling
General Handling: Avoid prolonged or repeated contact with skin. Avoid contact with eyes. Avoid
contact with skin and clothing. Wash thoroughly after handling. Avoid use of electric band heaters.
Failures of electric band heaters have been reported to cause drums of liquid epoxy resin to explode
and catch fire. Application of a direct flame to a container of liquid epoxy resin can also cause
explosion and/or fire.

Storage
Recommended pumping and storage temperature for bulk shipments is 60°C (140°F) Additional
storage and handling information on this product may be obtained by calling your Dow sales or
customer service contact. Ask for a product brochure.
Shelf life: Use within Storage temperature:
24 Months 2 - 43 °C

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Product Name: D.E.R.* 331 EPOXY RESIN Issue Date: 23.06.2008

8. Exposure Controls / Personal Protection

Exposure Limits
None established
Personal Protection
Eye/Face Protection: Use safety glasses.
Skin Protection: Use protective clothing chemically resistant to this material. Selection of specific
items such as face shield, boots, apron, or full body suit will depend on the task. Remove
contaminated clothing immediately, wash skin area with soap and water, and launder clothing before
reuse or dispose of properly. Items which cannot be decontaminated, such as shoes, belts and
watchbands, should be removed and disposed of properly.
Hand protection: Use gloves chemically resistant to this material. Examples of preferred
glove barrier materials include: Butyl rubber. Ethyl vinyl alcohol laminate (“EVAL”). Nitrile.
Neoprene. Polyvinyl chloride (“PVC” or “vinyl”). NOTICE: The selection of a specific glove for
a particular application and duration of use in a workplace should also take into account all
relevant workplace factors such as, but not limited to: Other chemicals which may be handled,
physical requirements (cut/puncture protection, dexterity, thermal protection), potential body
reactions to glove materials, as well as the instructions/specifications provided by the glove
supplier.
Respiratory Protection: No respiratory protection should be needed.
Ingestion: Use good personal hygiene. Do not consume or store food in the work area. Wash hands
before smoking or eating.
Engineering Controls
Ventilation: Good general ventilation should be sufficient for most conditions.

Other Information
Selection and use of personal protective equipment should be in accordance with the
recommendations in one or more of the relevant Australian/New Zealand Standards, including:
AS/NZS 1336: Recommended practices for eye protection in the industrial environment.
AS/NZS 1337: Eye protectors for industrial applications.
AS/NZS 1715: Selection, use and maintenance of respiratory protective devices.
AS/NZS 2161: Occupational protective gloves.
AS/NZS 2210: Occupational protective footwear.
AS 2919: Industrial clothing.

9. Physical and Chemical Properties

Physical State Liquid

Color White to yellow
Odor Mild
Odor Threshold No test data available
Flash Point - Closed Cup 252 °C PMCC, ASTM D93
Flammability (solid, gas) No
Flammable Limits In Air Lower: Not applicable
Upper: Not applicable
Autoignition Temperature Not applicable
Vapor Pressure < 0.01 mmHg @ 25 °C Literature
Boiling Point (760 mmHg) > 100 °C Literature .
Vapor Density (air = 1) No test data available
Specific Gravity (H2O = 1) 1.16 Literature
Freezing Point Not determined
Melting Point Not determined
Solubility in Water (by Insoluble
weight)
pH Not determined

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Product Name: D.E.R.* 331 EPOXY RESIN Issue Date: 23.06.2008

Decomposition No test data available

Temperature
Partition coefficient, n- 3.7 - 3.9 Measured
octanol/water (log Pow)
Evaporation Rate (Butyl No test data available
Acetate = 1)
Dynamic Viscosity 11,000 - 13,500 mPa.s @ 25 °C ASTM D445
Kinematic Viscosity No test data available

10. Stability and Reactivity

Stability/Instability
Stable under recommended storage conditions. See Storage, Section 7.
Conditions to Avoid: Avoid temperatures above 300 °C. Potentially violent decomposition can
occur above 350 °C. Generation of gas during decomposition can cause pressure in closed systems.
Pressure build-up can be rapid.

Incompatible Materials: Avoid contact with oxidizing materials. Avoid contact with: Acids. Bases.
Avoid unintended contact with amines.
Hazardous Polymerization
Will not occur by itself. Masses of more than one pound (0.5 kg) of product plus an aliphatic amine will
cause irreversible polymerization with considerable heat build-up.
Thermal Decomposition
Decomposition products depend upon temperature, air supply and the presence of other materials.
Gases are released during decomposition. Uncontrolled exothermic reaction of epoxy resins release
phenolics, carbon monoxide, and water.

11. Toxicological Information

Acute Toxicity
Ingestion
Very low toxicity if swallowed. Harmful effects not anticipated from swallowing small amounts.
LD50, Rat > 5,000 mg/kg
Eye Contact
May cause eye irritation. Corneal injury is unlikely.
Skin Contact
Prolonged contact may cause skin irritation with local redness. Repeated contact may cause skin
irritation with local redness.
Skin Absorption
Prolonged skin contact is unlikely to result in absorption of harmful amounts.
LD50, Rabbit 20,000 mg/kg
Inhalation
Vapors are unlikely due to physical properties.
Sensitization
Skin
Has caused allergic skin reactions in humans. Did not cause allergic skin reactions when tested in
mice.
Repeated Dose Toxicity
Except for skin sensitization, repeated exposures to low molecular weight epoxy resins of this type are
not anticipated to cause any significant adverse effects.
Chronic Toxicity and Carcinogenicity
Many studies have been conducted to assess the potential carcinogenicity of diglycidyl ether of
bisphenol A (DGEBPA). Indeed, the most recent review of the available data by the International
Agency for Research on Cancer (IARC) has concluded that DGEBPA is not classified as a carcinogen.
Although some weak evidence of carcinogenicity has been reported in animals, when all of the data
are considered, the weight of evidence does not show that DGEBPA is carcinogenic.
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Product Name: D.E.R.* 331 EPOXY RESIN Issue Date: 23.06.2008

Developmental Toxicity
Resins based on the diglycidyl ether of bisphenol A (DGEBPA) did not cause birth defects or other
adverse effects on the fetus when pregnant rabbits were exposed by skin contact, the most likely route
of exposure, or when pregnant rats or rabbits were exposed orally.
Reproductive Toxicity
In animal studies, did not interfere with reproduction.
Genetic Toxicology
In vitro genetic toxicity studies were negative in some cases and positive in other cases. Animal
genetic toxicity studies were negative.

12. Ecological Information

ENVIRONMENTAL FATE

Movement & Partitioning

Bioconcentration potential is moderate (BCF between 100 and 3000 or Log Pow between 3 and 5).
Potential for mobility in soil is low (Koc between 500 and 2000). Given its very low Henry’s constant,
volatilization from natural bodies of water or moist soil is not expected to be an important fate process.
Henry’s Law Constant (H): <= 6.94E-09 atm*m3/mole; 25 °C Estimated
Partition coefficient, n-octanol/water (log Pow): 3.7 - 3.9 Measured
Partition coefficient, soil organic carbon/water (Koc): 1,800 - 4,400 Estimated1,800 - 4,400
Estimated

Persistence and Degradability

Biodegradation under aerobic laboratory conditions is below detectable limits (BOD20 or
BOD28/ThOD < 2.5%).
Based on stringent OECD test guidelines, this material cannot be considered as readily biodegradable;
however, these results do not necessarily mean that the material is not biodegradable under
environmental conditions.
Indirect Photodegradation with OH Radicals
Rate Constant Atmospheric Half-life Method
6.69E-11 cm3/s 1.92 h Estimated
OECD Biodegradation Tests:
Biodegradation Exposure Time Method
12 % 28 d OECD 302B Test
Biological oxygen demand (BOD):
BOD 5 BOD 10 BOD 20 BOD 28
< 2.5 %
Theoretical Oxygen Demand: 2.35 mg/mg
ECOTOXICITY
Material is moderately toxic to aquatic organisms on an acute basis (LC50/EC50/EL50/LL50 between
1 and 10 mg/L in most sensitive species tested). Toxicity to aquatic species occurs at concentrations
above material’s water solubility.

Fish Acute & Prolonged Toxicity

LC50, fathead minnow (Pimephales promelas), 96 h: 3.1 mg/l
Aquatic Invertebrate Acute Toxicity
EC50, water flea Daphnia magna, 48 h, immobilization: 1.4 - 1.7 mg/l
Toxicity to Micro-organisms
IC50; bacteria, Growth inhibition, 18 h: > 42.6 mg/l

13. Disposal Considerations

DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER. All
disposal practices must be in compliance with all Federal, State/Provincial and local laws and
regulations. Regulations may vary in different locations. Waste characterizations and compliance with
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Product Name: D.E.R.* 331 EPOXY RESIN Issue Date: 23.06.2008

applicable laws are the responsibility solely of the waste generator. AS YOUR SUPPLIER, WE HAVE
NO CONTROL OVER THE MANAGEMENT PRACTICES OR MANUFACTURING PROCESSES OF
PARTIES HANDLING OR USING THIS MATERIAL. THE INFORMATION PRESENTED HERE
PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS INTENDED CONDITION AS
DESCRIBED IN MSDS SECTION: Composition Information. FOR UNUSED & UNCONTAMINATED
PRODUCT, the preferred options include sending to a licensed, permitted: Incinerator or other
thermal destruction device.

Waste handling, treatment and disposal practices must be in compliance with the New Zealand
Hazardous Substances (Disposal) Regulations 2001. Additional local requirements may be applicable
in accordance with planning controls under the Resource Management Act. Regulations concerning
waste management may vary in different locations.

This product when disposed of in its unused and uncontaminated state should be treated as a
hazardous waste.

14. Transport Information

ROAD & RAIL
Proper Shipping Name: Environmentally hazardous substance, liquid, n.o.s. (Epoxy resin)
Hazard Class: 9 ID Number: UN3082 Packing Group: PG III

IMDG
Proper Shipping Name: Environmentally hazardous substance, liquid, n.o.s. (Epoxy resin)
Hazard Class: 9 ID Number: UN3082 Packing Group: PG III
EMS Number: F-A,S-F

ICAO/IATA
Proper Shipping Name: Environmentally hazardous substance, liquid, n.o.s. (Epoxy resin)
Hazard Class: 9 ID Number: UN3082 Packing Group: PG III
Cargo Packing Instruction: 914
Passenger Packing Instruction: 914

HAZCHEM CODE: 3Z

This information is not intended to convey all specific regulatory or operational

requirements/information relating to this product. Additional transportation system information can be
obtained through an authorized sales or customer service representative. It is the responsibility of the
transporting organization to follow all applicable laws, regulations and rules relating to the
transportation of the material.

15. Regulatory Information

New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New Zealand

The hazardous components of this product are listed in the New Zealand Inventory of Chemicals
(NZIoC) or the product otherwise complies with the requirements of the Hazardous Substances and
New Organisms (HSNO) Act 1996.

Remarks:
Liquid Epoxy Resins (LERs) are made by reacting bisphenol A and epichlorohydrin. Dow uses both
CAS No. 25085-99-8 and 25068-38-6 for its LERs. Other manufacturers use CAS No. 25068-38-6 for
their LERs. Accordingly, LER manufacturers consider that derivatives of LERs may be described
using either CAS number as a starting material.

HSNO Approval Number

HSR002670

Group Standard Name

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Product Name: D.E.R.* 331 EPOXY RESIN Issue Date: 23.06.2008

Surface Coatings and Colourants (Subsidiary Hazard) Group Standard 2006.

ADVICE TO PRODUCT USERS REGARDING HSNO CONTROLS: Users of this product should make
reference to the New Zealand Hazardous Substances and New Organisms Act and Regulations for
relevant risk management controls. Additional local requirements may be applicable in accordance
with planning controls under the Resource Management Act. Refer Environment Risk Management
Authority publications (1) ER-UG-05-1 11/01 User Guide for HSNO Controls; and (2) ER-QG-31-1
Group Standards Quick Guide available from the web site http://www.ermanz.govt.nz/hs/index.html16.
Other Information

Product Literature
Additional information on this product may be obtained by calling your Dow Chemical Company sales
or customer service contact. Ask for a product brochure.

Revision
Identification Number: 79630 / 4076 / Issue Date 23.06.2008 / Version: 4.0
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this
document.
Legend
N/A Not available
W/W Weight/Weight
OEL Occupational Exposure Limit
STEL Short Term Exposure Limit
TWA Time Weighted Average
ACGIH American Conference of Governmental Industrial Hygienists, Inc.
DOW IHG Dow Industrial Hygiene Guideline
WEEL Workplace Environmental Exposure Level
HAZ_DES Hazard Designation

Dow Chemical (NZ) Ltd urges each customer or recipient of this (M)SDS to study it carefully and
consult appropriate expertise, as necessary or appropriate, to become aware of and understand the
data contained in this (M)SDS and any hazards associated with the product. The information herein is
provided in good faith and believed to be accurate as of the effective date shown above. However, no
warranty, express or implied, is given. Regulatory requirements are subject to change and may differ
between various locations. It is the buyer’s/user’s responsibility to ensure that his activities comply with
all federal, state, provincial or local laws. The information presented here pertains only to the product
as shipped. Since conditions for use of the product are not under the control of the manufacturer, it is
the buyer’s/user’s duty to determine the conditions necessary for the safe use of this product. Due to
the proliferation of sources for information such as manufacturer-specific (M)SDSs, we are not and
cannot be responsible for (M)SDSs obtained from any source other than ourselves. If you have
obtained an (M)SDS from another source or if you are not sure that the (M)SDS you have is current,
please contact us for the most current version.

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