JEE Main, 2023

Solved Paper
Exam Date : 12-04-23 (Shift-I)
Physics 4. Three forces, F1 = 10 N, F2 = 8 N, 10. Body cools from 80°C to 60°C in
F3 = 6 N are acting on a particle of mass 5 minutes. The temperature of the
1. Match List I with List II
5 kg. The forces F2 and F3 are applied surrounding is 20°C. The time it takes to
LIST –I LIST –II perpendicularly so that particle remains cool from 60°C to 40°C is:
A. Spring constant I. [T–1] at rest. If the force F1 is removed, then 25
(A) 3 s (B) 450s
acceleration of the particle is:
B. Angular speed II. [MT–2] (C) 420s (D) 500s
(A) 2 ms–2 (B) 7 ms–2
2 –2
C. Angular
III.
[MT ] (C) 4.8 ms (D) 0.5 ms–2 11. An engine operating between the boiling
momentum 5. To maintain a speed of 80 km/h by a bus and freezing points of water will have
D. Moment of [ML 2T–1] of mass 500 kg on a plane rough road A. ef昀椀ciency more than 27%
IV.
Inertia for 4 km distance, the work done by the B. ef昀椀ciency less than the ef昀椀ciency
Choose the correct answer from the engine of the bus will be...........KJ. [The of a carnot engine operating between
options given below: coef昀椀cient of friction between tyre of bus the same two temperatures.
(A) A-IV, B-I, C-III, D-II and road is 0.04.] C. ef昀椀ciency equal to 27%
(B) A-I, B-III, C-II, D-IV (A) N (B) N D. ef昀椀ciency less than 27%
(C) A-II, B-I, C-IV, D-III (C) D (D) T Choose the correct answer from the
(D) A-II, B-III, C-I, D-IV 6. For a rolling spherical shell, the ratio of options given below.
2. A ball is thrown vertically upward with rotational kinetic energy and total kinetic (A) B and C only (B) B and D only
an initial velocity of 150 m/s The ratio x
energy is 5 The value of x is............
x +1 (C) A and B only (D) C and D only
of velocity after 3's and 5s is x The (A) N (B) N
12. If the r. m. s speed of chlorine molecule
value of x is.............. (C) D (D) T is 490 m/s at 27°C, the r. m. s speed of
{take, g = 10 m/s2} 7. The ratio of escape velocity of a planet to argon molecules at the same temperature
(A) 5 (B) 10 the escape velocity of earth will be-given will be (Atomic mass of argon = 39.9 u,
(C) –5 (D) 6 Mass of the planet is 16 times mass of molecular mass of chlorine = 70.9u)
3. Given below are two statements: earth and radius of the planet is 4 times (A) 751.7 m/s (B) 651.7 m/s
Statement I : A truck and a car moving the radius of earth
(C) 551.7 m/s (D) 451.7 m/s
with same kinetic energy are brought to (A) 1: 2 (B) 2:1 13. A particle is executing simple harmonic
rest by applying breaks which provide (C) 4:1 (D) 1:4 motion (SHM). The ratio of potential
equal retarding forces, Both come to rest 8. Two satellites A and B move round the energy and kinetic energy of the particle
in equal distance. earth in the same orbit. The mass of A is when its displacement is half of its
Statement II : A car moving towards twice the mass of B. The quantity which amplitude will be
east takes a turn and moves towards is same for the two satellites will be (A) 2:1 (B) 1:3
north, the speed remains unchanged, The (A) Kinetic energy (C) 1:1 (D) 1:4
acceleration of the car is zero.
(B) Speed 14. For a certain organ pipe the 昀椀rst three
In the light of given statements, choose
(C) Total energy resonance frequencies are in the ratio of
the most appropriate answer from the
options given below (D) Potential energy 1:3:5 respectively, If the frequency of
(A) Both Statement I and Statement II 9. Glycerin of density 1.25 × 103 kg m–3 昀椀fth harmonic is 405 Hz and the speed
are correct. is 昀氀owing through the conical section of sound in air is 324 ms–1 the length of
(B) Both Statement I and Statement II of pipe. The area of cross-section of the the organ pipe is............ m
are incorrect. pipe at its ends are 10 cm2 and 5 cm2 and 15. Given below are two statements one is
(C) Statement I is correct but Statement pressure drop across its length is 3 Nm–2. labelled as Assertion A and the other is
II is incorrect. The rate of 昀氀ow of glycerin through the labelled as Reason R
(D) Statement I is incorrect but Statement pipe is x × 10–5 m3s–1 The value of x is Asssertion A : If an electic dipole of
II is correct. ........... dipole moment 30 × 10–5 C m is enclosed

Paper | 1
 by a closed surface the net 昀氀ux coming 21. A conducting circular loop is placed in 4 3
(A) 3 (B) 2
out of the surface will be zero. a uniform magnetic 昀椀eld of 0.4 T with
its plane perpendicular to the 昀椀eld. 2 6
Reason R : Electric dipole consists of two (C) 3 (D) 5
equal and opposite charges. Somehow, the Somehow, the radius of the 25. Two convex lenses of focal length 20
In the light of above, statements, choose loop starts expanding at a constant rate of cm each are placed coaxially with a
the correct answer from the options given 1 mm/s. The magnitude of induced emf separation of 60 cm between them. The
below. in the loop at an instant when the radius image of the distant object formed by the
of the loop is 2 cm will be.............µV. combination is ....... cm from the 昀椀rst lens.
(A) A is true but R is false
22. Given below are two statements: 26. A 12.5 eV eletron beam is used to bombard
(B) Both A and R are true and R is the
correct explanation of A Statement I : When the frequency of gaseous hydrogen at room temperature.
an a, c source in a saries LCR circuit The number of spectral lines emitted will
(C) Both A and R are true but R is NOT
increases, the current in the circuit 昀椀rst be :
the correct explanation of A
increses attains a maximum value and (A) 3 (B) 4
(D) A is false but R is true
then decreases.
16. 64 identical drops each charged upto (C) 1 (D) 2
Statement II : In a series LCR circuit,
potential of 10 mV are combined to form 27. A proton and an a-particle are accelerated
the value of power factor at resonance is
a bigger drop. The potential of the bigger from rest by 2V and 4V potentials,
one.
drop will be............mV. respectively. the ratio of their de- Broglie
In the light of given statements, choose
17. A wire of resistance 160 Ω is melted and wavelength is :
the most appropriate answer from the
drawn in a wire of one-fourth of its length. options given below. (A) 8:1 (B) 2:1
The new resistance of the wire will be (A) Statement I is incorrect but Statement (C) 4:1 (D) 16:1
(A) 40Ω (B) 640Ω II is true. 28. A common example of alpha decay is
238
(C) 10Ω (D) 16Ω (B) Statement I is correct but Statement 92 U " 234 2
4
90 Th + He + Q

18. The current 昀氀owing through a conductor II is false. Given:

connected across a source is 2 A and 1.2 (C) Both statement I and Statement II 238
92 U = 238.05060u,
A at 0°C and 100°C respectively. The are true. 234
90 Th = 234.04360u,
current 昀氀owing through the conductor at (D) Both Statement I and Statement II 4
He = 4.00260u and
2
50°C will be............. × 102 mA. are False.
MeV
23. Given below are two statement: one is lu = 931.5
19. A com pass needle qualities 20 times per c2
minute at a place where the dip in 30º labelled as Assertion A and the other is The energy released (Q) during the alpha
times per minute where the dip is 60º The labelled as Reason R decay of 238
92 U is........... MeV

ratio of total manetic 昀椀eld due to the earth Assertion A : EM waves used for optical 29. In an n-p-n common emitter (CE)
at two place receptively is
4
The value communication have longer wavelengths transistor the collector current changes
x than that of microwave, employed in from 5 mA to 16 mA for the change in
of x is.
Radar technology. base current from 100 µA and 200 µA,
(A) N (B) N
Reason R : Infrared EM waves are more respectively. The current gain of transistor
(C) D (D) T
energetic than microwaves (usd in Radar) is..........
20. Given below are two statements:
In the light of given statements, choose (A) 210 (B) 0.9
Statement I: The diamagnetic property
the correct answer from the options given (C) 110 (D) 9
depends on temperature.
below.
Statement II: The diamagnetic magnctic 30. The amplitude of 15 sin (1000 pt) is
(A) Both A and R are true and R is the
dipole moment in a diamagnetic sample is modulated by 10 sin (4 pt) signal. The
correct explanation of A
always opposite to the magnetizing 昀椀eld. amplitude modulated signal contains
In the light of given statements, choose (B) A is false but R is true.
frequencies of
the correct answer from the options given (C) A is true but R is false.
A. 500 Hz
below. (D) Both A and R are true but R is NOT
B. 2 Hz
(A) Statement I is incorrect but Statement the correct explanation of A.
C. 250 Hz
II is ture. 24. An ice cube has a bubble inside. When
D. 498 Hz
(B) Statement I is correct but Statement viewed from one side the apparent distance
II is false. of the bubble is 12 cm, When viewed from E. 502 Hz
(C) Both Statement I and Statement II the opposite side the apparent distance of Choose the correct answer from the
are False. the bubble is observed as 4 cm. If the side options given below:
(D) Both Statement I and Statement II of the ice cube is 24 cm the refractive (A) A and C only (B) A, D and E only
are true. index of the ice cube is (C) A and D only (D) A and B only

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 Chemistry (C) K < Na < Rb < Cs (D) X Y Z
(D) Na < K < Cs < Rb CaO NaCl + CO2 KCI
31. The mass of NH3 produced when 131.8 kg
36. The bond order and magnetic property of 42. Given below are two statements:
of cyclohexanecarbaldehyde undergoes
acetylide ion are same as that of Statement I : SbC15 is more covalent
Tollen's test is ______ kg. (Nearest
Integer) (A) N2+ (B) O2+ than SbC13.
Molar Mass of C = 12g/mol (C) NO+ (D) O2– Statement II : The higher oxides of
N = 14 g/mol 37. 600K, the root mean square (rms) speed halogens also to be more stable than the
O = 16g/mol of gas X (molar mass = 40) is equal to lower ones.
32. A metal chloride contains 55.0% of the most probable speed of gas Y at 90K. In the light of the above statements,
chlorine by weight. 100 mL vapours of the The molar mass of the gas Y is ............g choose the most appropriate answer from
metal chloride at STP weigh 0.57g. The mol–1.(Nearest integer) the options given below.
molecular formula of the metal chloride is 38. One mole of an ideal gas at 350K is in (A) Both statement I and statement II are
(Given: Atomic mass of chlorine is 35.5u) a 2.0L vessel of thermally conducting incorrect
(A) MCl3 (B) MCl2 walls, which are in contact with the (B) Statement I is incorrect but statement
(C) MCl (D) MCl4 surroundings. It undergoes isothermal II is correct
reversible expansion from 2.0L to 3.0L
33. Given below are two statment: one is (C) Both statement I and statement II are
against a constant pressure of 4 atm. The
labelled as Assertion A and the other is correct
change in entropy of the surroundings
labelled as Reason R (D) Statement I is correct but statement
(DS) is ...............J K–1 (Nearest integer)
Assertion A : 5f electrons can participate II is incorrect
Given: R = 8.314 J K–1 mol–1
in bonding to a far greater extent than 4f 43. Given below are two statements :
electrons 39. An analyst wants to convert 1L HCl of
Statement I : Boron is extremely hard
pH = 1 to a solution of HC1 of pH 2. The
Reason R : 5f orbitals are not as buried indicating its high lattice energy.
volume of water needed to do this dilution
as 4f orbitals Statement II : Boron has highest melting
is ...........mL. (Nearest integer)
In the light of the above statements, and boiling point compared to its other
40. Match list I with List II
choose the correct answer from the group members.
options given below List I List II
In the light of the above statements,
(A) Both A and R are true but R is NOT Type of Hydride Examples
choose the most appropriate answer from
the correct explanation of A (a) Electron de昀椀cient I. MgH2
hydride the options given below.
(B) Both A and R are true and R is the (A) Statement I is incorrect but statement
(b) Electron rich II. HF
correct explanation of A hydride II is correct
(C) A is true but R is false (c) Electron precise III. B2H6 (B) Both statement I and statement II are
(D) A is false but R is true hydride
incorrect
34. Values of work function (W0) for a few (d) Saline hydride IV. CH4
(C) Both statement I and statement II are
metals are given below. Choose the correct answer from the correct
Metal W0/eV options given below:
(D) Statement I is correct but statement
Li 2.42 (A) (a)-III, (b)-II, (c)-IV, (d)-I II is incorrect
Na 2.3 (B) (a)-II, (b)-III, (c)-IV, (d)-I 44. Correct statements for the given reaction
K 2.25 (C) (a)-II, (b)-III, (c)-I, (d)-IV are :
Mg 3.7 (D) (a)-III, (b)-II, (c)-I, (d)-IV O OH
Cu 4.8 41. In the given reaction cycle OH 
  'B'
2eq
Ag 4.3 CaCl2 + Na2CO3 X + Y
O OH
The number of metals which will 'A'
show photoelectric effect when light of Z A. Compound ‘B’ is aromatic
wavelength 400 nm falls on it is........... B. The completion of above reaction is
X, Y and Z respectively are
Given: h = 6.6 × 10–34 J s very slow
(A) X Y Z
c = 3 × 108 m s–1 CaCO3 NaCl KCl C. ‘A’ shows tautomerism
e = 1.6 × 10–19 C (B) X Y Z D. The bond length of C-C in compound
35. The density of alkali metals is in the order CaCO3 NaCl HCl B are found to be same
(C) X Y Z Choose the correct answer from the
(A) Na < Rb < K < Cs
CaO NaCl + CO2 NaCl options given below:
(B) K < Cs < Na < Rb

Paper | 3
 (A) B, C and D only (A) a, d only (B) b, c only OH
(B) A, B and C only (C) b, c, d only (D) a, b, d only
(C) A, C and D only (A)
49. The reaction 2NO + Br2 → 2NOBr MgBr
(D) A, B and D only OH
takes places through the mechanism given
45. Three organic compounds A, B and
below:
C were allowed to run in thin layer O
NO + Br2 ⇔ NOBr2 (fast)
chromatography using hexane and gave
the following result (see 昀椀gure). The NOBr2 + NO → 2NOBr (slow) (B)
The overall order of the reaction is ........... OH Br
Rf value of the most polar compound
is ............ × 10–2 50. Four gases A, B, C and D have critical
O
temperatures 5.3, 33.2, 126.0 and 154.3K
A respectively. (C)
MgBr
6 cm B Four their adsorption on a 昀椀xed amount
C 8 cm of charcoal, the correct order is:
4 cm OH
(A) C > D > B > A (B) C > B > D > A
2 cm (D)
(C) D > C > B > A (D) D > C > A > B
51. Given below are two statements: one is
54. 2-hexene →
(i) O3
46. Match List I with List II labelled as Assertion A and the other is (ii) H 2 O Products
labelled as Reason R.
LIST I LIST II The two products formed in above
Assertion A : In the Ellingham diagram, reaction are :
a. Nitrogen oxides I. Eutrophication
in air a sharp change in slope of the line is
(A) Butanoic acid and acetic acid
b. Methane in air II. pH of observed for Mg  MgO at ~ 1120°C
rain water
(B) Butanal and acetaldehyde
Reason R: There is a large change of
becomes 5.6 (C) Butanoic acid and acetaldehyde
entrapy associated with the change of
c. Carbon dioxide III. Global (D) Butanal and acetic acid
state. In the light of the above statements,
warming O
choose the correct answer from the
d. Phosphate IV. Acid rain Me C O Et +
fertilisers in water options given below. 55. C CH3 'A'
∆
major
Choose the correct answer from the (A) Both A and R are true but R is NOT O product
options given below : the correct explanation of A
A in the above reaction is:
(A) a-I, b-II, c-III, d-IV (B) A is true but R is false Me
(B) a-II, b-III, c-I, d-IV (C) A is false but R is true
(C) a-IV, b-II, c-III, d-I (D) Both A and R are true and R is the
(A) O
(D) a-IV, b-III, c-II, d-I correct explanation of A
47. 80 mole percent of MgCl2 is dissociated 52. Match List I with List II O O
in aqueous solution. The vapour pressure List I List II (B) Me C
C = CH C
C CH3

of 1.0 molal aqueous solution of MgCl2 at Complex CFSE (D0) Me O

38°C is ...........mm Hg. (Nearest integer) 2+ Me O

a. [Cu(NH3)6] I. – 0.6
(Given : Vapour pressure of water at 38°C b. [Ti(H2O)6] 3+
II. – 2.0 (C) C — CH3
is 50mm Hg) c. [Fe(CN)6]3– III. – 1.2
48. For lead storage battery pick the correct d. [NiF6]4– IV. – 0.4 O
statements O
C CH 3
Choose the correct answer from the (D) Me C
a. During charging of battery, PbSO4 C=C
C CH 3
options given below:
on anode is converted into PbO2 Me
O
(A) a-I, b-II, c-IV, d-III
b. During charging of battery, PbSO4
(B) a-III, b-IV, c-I, d-II
on cathode is converted into PbO2
56. The incorrect statement regarding the
c. Lead storage battery consists of grid (C) a-II, b-III, c-I, d-IV
reaction given below is
of lead packed with PbO2 as anode (D) a-I, b-IV, c-II, d-III
Me Me
d. Lead storage battery has ~ 38% 53. In the following reaction
solution of sulphuric acid as an O
(i) Mg
electrolyte ‘A’ + NaNO2 + HX 'B'
(ii) H 2 O
Choose the correct answer from the Br (Major Product) 'A'
options given below: ‘A’ is :

4 |
 (A) The reaction occurs at low H (A) 9 (B) 6
temperature N—R
(C) 8 (D) 7
(B) The electrophile involved in the (D) 66. Let the digits a, b, c be in A.P. Nine-digit
O
reaction is NO+ numbers are to be formed using each of
(C) The product ‘B’ formed in the above these three digits thrice such that three
reaction is p-nitroso compound at consecutive digits are in A. P. at least
60. H5C2O CH2CHO
low temperature once. How many such numbers can be
(D) ‘B’ is N-nitroso ammonium (i) NH4Cl/KCN Conc. HNO3 H2SO4 formed ?
compound 'A' 'B'
(ii) H2SO4/H 2eq 67. Let < an > be a sequence such that a1 + a2
57. In an oligopeptide named Alanylglycyl- (i) (CH3CO)2O 10
n 2 + 3n
+... + an = (n + 1) (n + 2) . If 28 / a =
(ii) EtOH,∆
1
phenyl alanyl isoleucine, the number of (iii) H2,NI/C k +1 k

sp2 hybridised carbons is ......... (iv) HNO2 p1 p2 p3... where p1. p2...Pm are
(v) NaI the 昀椀rst m prime numbers, then m is
58. Match List I with List II (CxH19NO4I2)
equal to :
LIST I (Examples) LIST II (Type) (D)
(A) 7 (B) 5
2 - chloro- 1,3- Biodegradable (C) 6 (D) 8
a. I. The value of x in compound ‘D’ is .............
butadiene Polymer
68. If the point c a,
7 3m
Synthetic Mathematics lies on the curve
b. Nylon 2 -nylon 6 II. 3
Rubber traced by the mid-points of the line
61. Let a, b be the roots of the quadratic
c. Polyacrylonitrile III. Polyester equation x 2 + 6 x + 3 = 0. Then segments of the lines x cosθ + y sinθ =
Addition  π
d. Dacron IV. α 23 + β23 + α14 + β14 7, θ ∈  0,  between the co-ordinates
Polymer is equal to  2
α15 + β15 + α10 + β10
Choose the correct answer from the axes, then a is equal to.
options given below: (A) 9 (B) 72
(A) - 7 3 (B) 7
(C) 81 (D) 729
(A) a-II, b-IV, c-I, d-III (C) 7 3 (D) – 7
62. Let C be the circle in the complex plane
(B) a-II, b-I, c-IV, d-III 69. Two circles in the 昀椀rst quadrant of radii r1
1
with center z0 = 2 (1 + 3i) and radius and r2 touch the coordinate axes. Each of
(C) a-IV, b-III, c-I, d-II r = 1, Let z1 = 1 + i and the complex them cuts off an intercept of 2 units with
(D) a-IV, b-I, c-III, d-II number z2 be outside the circle C such that the line x + y = 2, Then r12 + r 22 - r1 r2 is
|z1 – z0| |z2 – z0| = 1. If z0, z1 and z2 are equal to............ .
59. The major product ‘P’ formed in the collinear, then the smaller value of |z2|2
70. Let P e o Q, R and be four
following sequence of reactions is 2 3 6
equal to. ,
7, 7
P(Major Product)

7 5
(A) 2 (B) 2 points on the ellipse 9x2 + 4y2 = 36. Let
OH (i) SoCl2 PQ and RS be mutually perpendicular and
13 3
(C) 2 (D) 2 1 + 1
(ii) R-NH2 pass through the origin. If
63. The number of 昀椀ve digit numbers, greater (PQ) 2 (RS) 2
O (iii) 4AlH4 P
= q , where p and q are co-prime, then
(iv) H3O+ than 40000 and divisible by 5, which can
p + q is equal to :
be formed using the digits 0, 1, 3, 5, 7 and
H (A) 157 (B) 143
N—R 9 without repetition, is equal to.
(C) 137 (D) 147
(A) 96
(A) 71. Among the two statements
OH (B) 120
(S1) : (p ⇒ q) ^ (p ^ (~ q)) ((~p) ^ (~ q))
(C) 72 is a contradiction and (S2) : (p ^ q) V
(D) 132 ((~p) ^ q) V (p ^ (~q)) V (~ q)) is a
H—N—R tautology :
OH 64. The sum, of the coef昀椀cients of the 昀椀rst
(A) only (S2) is true
50 terms in the binomial expansion of (1
(B) (B) both are true
Cl – x)100 is equal to :
101
(C) both are false
(A) C50 (B) – 101C50
(D) only (S1) is true.
99
H (C) C49 (D) –99C49
N—R 72. dice A and B are rolled. Let the numbers
1 n 1 1
65. If C + nC + ... + nCn + nC0 obtained on A and B be a and b
(C) n + 1 n n n–1 2 p
1023 respectively. If the variance of a – b is q ,
= 10 then n is equal to.

Paper | 5
 where p and q are co- prime, then the sum n
C. If the orthocentre of the triangle ABC
/D k
= 96, then n is equal to ......... .
of the positive divisors of p is equal to : k =1  6
is  α, β, 7  , then 98 (a + b)2 is equal
(A) 48 (B) 36 79. If the local maximum value of the
(C) 31 (D) 72
function f(x) = c
3e m  π
2
sin x
to.........
, x ∈  0,  ,
73. Let the positive numbers a1,a2 a3, a4 and 2 sin x  2 x+5 y+4 z-a
is e , then b e l + 5 + k is equal to
k k 8
k 8
8
86. Let the lines l1 : 3 = 1 = - 2
a5 be in a G.P. Let their mean and varaince
e and l2 : 3x + 2y + z – 2 = 0 = x – 3y + 2z
31 m
be 10 and n respectively, where m (A) e5 + e6 + e11 (B) e3 + e6 + e11 – 13 be coplanar. If the point P (a, b, c)
and n are co-prime. If the man of their (C) e3 + e5 + e11 (D) e3 + e6 + e10 on l1 is nearest to the point Q(– 4, – 3, 2),
31 then | a | + | b | + | c | is equal to
reciprocals is 40 and a3 + a4 + a5 = 14, x+7
80. Let I (x) = #
x dx and I (9) = 12
then m + n is equal to..... (A) 10 (B) 12
+ 7 loge 7. If I(1) = a + 7loge (1 + 2 2 )
74. The number of relations, on the Set (C) 8 (D) 14
. then a4 is equal to............
(1, 2, 3) containing (1, 2) and (2, 3), 0.15
87. Let the plane P : 4x – y + z = 10 be
which are re昀氀exive and transitive but not 81. If # k
| 100x - 1 | dx = 3000 , then k
2

rotated by an angle
π
about its line of
symmetric, is.............. -0.15
2
is equal to.............. intersection with the plane x + y – z = 4,
75. Let [x] be the greatest integer ≤ x. Then the
82. The area of the region ecnlosed by the If a is the distance of the point (2, 3, – 4)
number of points in the interval (– 2, 1)
curve y = x3 and its tangent at the point from the new position of the plane P, then
where the function f(x) = |[x]| + x - [x]
(–1, – 1) is 35a is equal to.
is discontinuous, is.............
19 23 (A) 126 (B) 105
(A) 4 (B) 4
76. Let D be the domain of the function f (x)
31 27 (C) 85 (D) 90
= sin–1 d log 3x c mn . If the range
6 + 2 log 3 x (C) 4 (D) 4
- 5x 88. Let a, b, c be three distinct real numbers,
83. Let y = y(x), y > 0 be a solution curve
of the function g : D → R de昀椀ned by none equal to one. If the vectors
of the differential equation (1 – x2) dy =
g(x) = x – [x], [x] is the greatest integer
y (x – y) dx. If y (0) = 1 and y (2 2 ) = aSi +Uj + V
k,S
i + bjU + V
k and S
i +Uj + ckV are
5 1 1 1
function), is (a, b), then
α 2 + , is equal b, then coplanar, then 1 - a + 1 - b + 1 - c is
β
to : (A) e3β
−1
= e (5 + 2 ) equal to.

(A) 135 (B) 46 −1 (A) 1 (B) –1

(B) eβ = e - 2 (5 + 2 )
(C) 136 (D) 45 −1
(C) 2 (D) –2
(C) e3β = e (3 + 2 2 )
89. A fair n (n > 1) faces dice is rolled
77. Let A = >1 51 H If B = =
1
G A
1 2 −1
(D) eβ = e -2 (3 + 2 2 ) repeatedley until a number less than
0 1 - 1 -1
n appears. If the mean of the number
84. Let l ∈ Z, a = λi + j − k and b =
= G , then the sum of all the elements
-1 -2 n
of tosses required is 2 then n is equal
1 1 3i − j + 2 k . Let c be a vector such
50 to.......... .
of matrix /B n
is equal to : that (a + b + c ) × c = 0, a .c = –17. and

n =1 90. In a triangle ABC, if cos A + 2 cos B +
b .c = 20. Then | c × (λi + j + k ) |2 is
(A) 125 (B) 50 cos C = 2 and the lengths of the sides
equal to :
(C) 75 (D) 100 opposite to the angles A and C are 3 and 7
(A) 53 (B) 46
RS V respectively, then cos A – cos C is equal to
SS1 2k 2k - 1 WW (C) 62 (D) 49
WW 10 5
78. Let Dk = SS n n + n + 2
2
n 2
WW . If (A) 7 (B) 7
SS 85. Let the plane x + 3y – 2z + 6 = 0 meet
Sm n + n n + n + 2WW
2 2
9 3
T X the co-ordinate axes at the points A, B, (C) 7 (D) 7

SOLUTIONS
F = [MT2T–1] v5 = u + gt5 = 150 – 10 × 5
1. (B) Spring Constant, K = x
6MLT –2@ Moment of inertia = 1 = mr2 = [ML2]
v5 = 100
6L1@
= [MT–2] v3 x +1 120 x +1
6LT –1@
∴ v5 = x ⇒ 100 = x
v
Angular Speed w = r = 5 ? 2. (A) Given : initial velocity, u = 150 m/s
L 120x = 100x + 100
= [T–1] v3 = u + gt3 = 150 – 10 × 3
⇒ 20x = 100
Angular momentum L = mvr v3 = 120 ⇒ x =5

6 |
3. (D) The value of displacement or mxv 2 x 2 2 v 2 4 2
+ b 3 mR l b R l
k = 50 = 25
distance travelled ‘S’ is same for =
2 2 In second condition,
both truck and car as they are mv 2
1 2 v2
moving with the same K.E. (5 – x) × 2 × 3 mR 2 2 = x Initial temperature = Ti = 60°C
R 2
Also they are brought to rest by the 3 Final temperature = Tf = 40°C
5–x = 2 x
application of brakes which provides
Time taken for cooling is t
equal retarding force therefore both ⇒ x =2
will travel the same distance before Using Newton’s law of cooling
2GM
= 25 : 60 2 40 - 20D
coming to rest so, statement I is 7. (D) As ve = R , 60 - 40 2 +
t
correct. 2G (16M)
= vp = 4R 5 25
vi = v towards positive x – axis t = 12 × 20 = 3 × 60 = 500 s
vf = v towards positive y – axis vp 2G (16M) R
ve = 4R × 2GM
The change in velocity vf – vi 11. (D) Ef昀椀ciency is given by
vp 2 T
= v2 + v2 = v 2 ve = 1 = 2 : 1 h = 1 – T2 , T2 = 273K
1
So, there is same change in velocity, GM T1 = 373 K
8. (D) Orbital Speed = v0 = R
Hence acceleration will not be zero.
273
It is independent of the mass of body. ∴ h = 1 – 373
So, statement II is incorrect.
So, the speed will be same for both
∴ h = 0.268 ≅ 26.8%
" " "
4. (D) F1 = F2 + F3 the satellites.
If F1 is removed, net force is given 9. (D) Given r = 1.25 × 103 kg m–3 The ef昀椀ciency of carnot's engine is
by: Area at the ends, always more than any other engine.

A1 = 10 cm2, A2 = 5 cm2 12. (D) Tar = Tu = T = 27 + 273 = 300K

F1
A 2 v2 vu = 490 m/s
F3 \ A1v1 = A2v2 ⇒ v1 = A1 3RT 3RT
Using Bernoulli's equation vu = Mu , AAr = M Ar
DP = 2 r _ v 22 – v12 i
1 vAr Mu T
F2 70.9
vet = M Ar × T = 39.9
= 2 r =v 22 - c 2 m v 22G = 2 rv 22
" 1 A 2 1 = 1.33
F= F 22 + F33 + 2F2 F3 cos 90° A1
vAr = 490 × 1.33 = 651.7 m/s
=1 - c A 2 m G
= 64 + 36 = 100 = 10 N 2
1
m = 5 kg A 1 13. (D) PE = 2 mw2x2,
1
F 10 ⇒ 3 = 2 × 1.25 × 103 × v22
∴ a = m = 5 = 2 ms–2 1
KE = 2 mw2(A2– x2)
;1 - b 5 l E
2

x = 2 , PE = 2 mw2 b 4 l
10 A 1 A2
5. (D) According to work energy theorem, At,
change in KE is equal to work done. 600 4
⇒ v2 = 125 × 10–3 × 5
2
1
So, to maintain a speed of 80 km/h = 8 mw2A2 ...(i)
v2 = 64 × 10 – 4 = 8 × 10–2 m/s
work done by engine is given by,
KE = 8 wm2 c A 2 - A m
1 2
Discharge rate = A2v2 = 5 × 8 ×
W = F.s. 9
W = – [µ mgx] 10–2 × 10–4 = 4 × 10–5 m3s–1 3 2 2
= 0.04 × 500 × 9.8 × 4 × 103 8 = mw A ...(i)
10. (D) Initial temperature = Ti = 80°C
= 784 KJ Final temperature = Tf = 60°C from eq.(i) and (ii)
1 2 Temperature of Surrounding 1 2 2
KE Iw PE 8 mw A = 1 = 1 : 3
6. (D) KER = 1 2 1 T0 = 20°C KE = 3 3
T 2 2 2 2
2 mv + 2 1w 8 mw A
Time t = 5 min
2 V
I = 3 mR2, w = R According to Newton’s law of 14. (D) Fifth harmonic in closed organ pipe
1b2 2l b v l
2
cooling 5v
f5 = 4l = 405
KE R 2 3 mR R dT
KET = 1 2 1 b2 2l b v l
2 Rate of cooling, dt = k
\
5 × 324
l = 4 × 405
2 mv + 2 3 mR
; Ti Tc - T0E
R +
= 5
x 2 ⇒ l = 1m

=k : 2 - 20D
T f - Ti 80 + 60
∴
5 = b 2 × 3 mR 2 l b R l
1 2 v 2 t 15. (B) Because,
80 - 60 An electric dipole is a system of
5 = k [70 – 20]

Paper | 7
 two equal and opossite charges 2 Thus, As suggested by the graph.
⇒ 100a = 3
separated by a length. Statement I is correct.
1
1 ⇒ 50a = 3
Net 昀氀ux is equal to ε time charge V
0 Z= R 2 + (X L - X C ) 2 , I = Z
I50R50 = I0R0
stored and the net charge is equal to
So, when impedence decrease
zero in case of a dipole. So, 昀氀ux is I0 R0 2R
I50 = R = R (1 +050a) current increase.
also zero. 50 0
2×3 23. (D) Radio waves are used for optical
16. (D) Let the charge on bigger drop be Q = 4 = 1.5A
Let the charge on small drop be q = 15 × 102 mA communication have shorter
wavelength than microwaves.
Here, Q = 64q BH T 2 B cos S T2
19. (D) B 2 = 12 B2 cos S 2 = 12 Hence, assertion is incorrect.
Let R be the radius of bigger drop H1 T2 1 1 T2
Infrared rays have higher frequency
and r be the radius of small drop. B 2 T12
B1 = T22 and energy than microwave. Hence,
4 3 4 3
cos s 2 = b 2 l
reason is correct.
\ 3 pR = 64 × 3 pr ⇒
cos s1 3 2
⇒ R3 = 64r3 24 cm
24. (D)
b3l
2 3
cos 30° 2
⇒ R = 4r cos 60° = 2 2 ×1
Potential on one small drop, 9 3 B
= 4
kq x 24 x cm
V= r 4
Rate given is ;
Potential on big drop x
4 4 From one side.
kQ k (64q) 16kq =
V¢ = R = 4r = r x 9 3 x
x = 243 m = 12 cm ...(i)
= 16 × 10mV = 160 mV
From opposite side
17. (C) Volume of the wire before being 20. (D) The diamagnetic property is (24 –x)/m = 4 cm ...(ii)
melted and after will remains same independent of temperature.
Dividing (i) by (ii) we get
Therefore. Hence, statement I is incorrect.
x
Volume of wire before metling The induced magnetic dipole in m 12 x
= Volume of wire after melting a dimagnetic sample is always (24 - x) = 4 ⇒ 24 - r = 3
opposite to the magnetizing 昀椀eld. m
Al' = Al ⇒ x = 18
Thus, statement II is correct.
pr2l' = pr2l 18 3
m = 12 = 2
l 21. (D) Here, B = 0.4 T
As l = 4 ,
l' dr –3 25. (D)
∴ r2l' = pr2 4 dt = 1 mm/s = 10 m/s f1 = 20 cm f2 = 20 cm
- df BdA Bd
r2 = 4r'2 e = dt ; e = dt = dt (pr2)

⇒ r = 2r' dr
B2pr dt I2
I1
R rl A' l pr'2 22
= 0.4 × 2 × 7 × 2 × 10–2 × 10–3
R' = A × rl ' = l1 × pr 2 60 cm
l r' 2 = 5.024 × 10–5 V = 50.24 × 10–6 V The 昀椀rst image is formed at the
= 1 2
l r
focus of the 昀椀rst lens, 20 cm from
R = R' d 4l ' ×
l' r' 2 n = 50.24 mV = 50mV
(2r ') 2 the 昀椀rst lens. Hence, u = –40cm for
22. (D) The power factor at resonance is
= R' b 4 . 4 l
1 1 second lens
one, hence statement II is true.
v = f + u = 2 + b - 40 l
1 1 1 1 1
160 When frequency increases current
= 16 = 10W
in the circuit 昀椀rst increases, then 1 1 2 -1 1
= 20 + - 40 = 40 = 40
18. (B) Given, I0 = 2A1 I100 = 1.2 A attains a maximum value and then
I0R0 = I100 R100 decreases. v = 40 cm

2R0 = 1.2 R100 The image will form at 40 cm right

from the second lens 60 + 40 = 100
RT = R0 [1 + a (T2 – T1)]
cm right from the 昀椀rst lens.
R100 = R0[1 + 100a] Z
13.6
2R0 = 1.2[R0(1 + 100a)] 26. (D) For n = 3, 9 = 1.5 eV
5 Energy gap = 13.6 – 1.5 = 12.1 eV
3 = 1 + 100a V

8 |
 The maxim excited state is n = 3 131.8 × 1000 nm, they exhibit no photoelectric effect.
WNH3 = × 3 × 17
Number of spectral lines is given by, 112 Mg, Cu and Ag shows photoelectric
= 60 kg effect.
n ( n - 1) 3 (3 - 1)
N= 2 = 2 =3 Caution: When light incident on a metal
32. (B) Number of mole of metal chloride has energy less than the work function
h h
27. (D) la = , lp = 100 of the metal, then no electron is emitted
2 mα qα vα 2m p q p v p =
22400
from the surface of the metal.
qa = 22p , ma = 4mp va = 4v, 100 mL of metal chloride gives
35. (C) Generally, density increases as we
vp = 2v = 0.57g of Cl2 at STP
go down a group. However, there is
lp h So, 22400 mL = 1 mole of metal a notable exception that potassium
la = 2 m p q p (2)
×
0.57 is less denser than sodium.
chloride gives = × 22400g
2 ( 4 m p) ( 2 q p ) 4 100 Reason : Due to an unusual rise in
h
of Cl2 at STP = 127.68 g the atomic radius of potassium, it is
4 considerably lighter than sodium.
= 16 = 1 Mass of chlorine = 55% by Mass of
lp : la = 4 : 1 55 36. (C)
metal chloride = × 127.68
100
Spe- Total Bond Un- Mag-
28. (D) mv = 238.050604, = 70.224 cies Num- order paired netic
mTH = 234.043604 ber of elec- mom-
Number of moles of chlorine in
mHe = 4.002604 70.224 elec- tron entum
metal chloride = tron (n) n× (n + 2)
Energy released = Q = (mV – mTH 35.5
BM
– mHe) 931.5 MeV = 1.978 ≈ 2
Acety- 14 3 0 0
= 238.05060 – 234.043604 Formula of metal chloride : MCl2 lides
– 4.00260) 931.5 ion
33. (B) As number of valence shell
= 0.0044 × 931.5 = 4.0986 MeV (C2–2)
increases, the shielding effect
= 4 MeV on valence electrons decreases. O2– 17 1.5 1 3
Hence, 5f electrons can participate
∆I C in bonding in greater extents than O 2+ 15 2.5 1
29. (B) As, b= 3
∆I B
4f electrons. Both resemble in their
b= (16 - 5) ×10 -3 angular part of wave function, but N2– 15 2.5 1 3
(200 - 100) ×10 –6
5f is not as buried as 4f orbitals,
NO+ 14 3 0 0
11×10 -3 thus electrons present is 5f orbitals
= = 110
100×10 -6
experience less nuclear attraction Caution: Both NO+ and acetylide ion are
30. (D) Frequency of carrier wave than electrons present in 4f orbitals. diamagnetic because both have absence
1000π hc of unpaired electron.
ve = = 500 Hz, 34. The energy photon (E) =
2π λ
37. (Urms) Xgas = (Umps) Ygas
4π λ = 400 nm
v= = 2Hz 3RT 2RT
2π 6.6 × 10 —34 × 3 × 108 =
(E) = MX MY
1000π ± 4π 400 × 10 —9
v + ve =
4π
6.6 × 10 —34 × 3 × 108 3 × R × 600 2 × R × 20
E (in eV) = eV =
= 502Hz, 495 Hz 400 × 10 —9 × 1.6 × 10 —19 400 M

1240 M=4
31.
E(ev) = Related Theory: The most probable
400
CHO COO speed is the maximum value on
= 3.1ev
Maxwell's distribution plot.
+ 2[Ag(NH3)2]OH The metals Li, Na, K have a work function
less than the energy of a photon. So in V 
38. DSSystem = nRln  2 
(131.8 kg) + 2[Ag + 3NH3 + 2H2O] presence of light with wavelength 400  V1 

Paper | 9
 3
covalent character of bond formed 47. MgCl2  Mg+2 + 2Cl–
= 1 × 8.314 ln   between the central atom and the
2 1–a a 2a
atom surrounding it.
DSSystem = 3.37 i = 1 + 2a(a = 0.8)
i = 2.6
DSstar = 3.37 43. (C) Boron is non-metallic in nature.
It is an extremely hard refractory P ° — Ps M
39. At pH = 1, concentration of [H+] = i × molality ×
solid of high melting points Ps 1000
= 10 – 1
and boiling points. Due to very 1 M = 1 mole of solute MgCl2 dissolve
= 0.1 M strong crystalline lattice, boron in 1000 g of solvent water.
At pH = 2 concentration of [H+] has unusually high melting point. 50 — Ps 2.6 × 1
So, =
Rest of the member are soft metals Ps 1000 / 18
= 10 – 2
with low melting point and high
= 0.01 M = 50 – Ps = 0.0468 × Ps
electrical conductivity.
Now for dilution 1.0468 Ps = 50
B Al Ga In Tl 50
M1V1 = M2V2 So, Ps =
Melting 2453 933 303 430 576 1.0468
0.1 × 1 = 0.001 × V2 point/K
= 47.764 ≈ 48mm of Hg
V2 = 10 L Boiling 3923 2740 2676 2353 1730
Final Volume = 10 – 1 point 48. (A) Lead storage battery consists of lead
= 9L 44. (C) Compound (A) is squaric acid anode and a grid of lead packed
= 9000 mL which is a strong acid. So, above with lead oxide (PbO2) as cathode,
reaction proceeds very fast. a 38% solution of H2SO4 is used as
40. (A)
an electrolyte.
HO O O O
Electron Electron Electron
Saline Pb(s) + PbO2 + 4H+ + 2SO42– (aq)
de昀椀cient precise rich
hydride hydride hydride
hydride OH
→ 2PbSO4(s) + 2H2O(l)

HO Squaric O O Ecell = 3.05 V

Hydride Hydride Hydride Hydrides O
which which which of acid Aromatic compound
with same C-C bond Anode :
of not contains contains Alkaline
suf昀椀cient suf昀椀cient excess of and
length Pb(s)→Pb2+ (aq) + 2e–
number of valence valence alkaline
Resonance hybrid of B showing all Pb2+ (aq) + 2SO42– (aq)→PbSO4(s)
electrons electron electron earth
to form to form to form metal. C-C bond length same. Pb(s) + SO42– (aq) → PbSO4 + 2e–
normal covalent covalent Cathode:
covalent bond. bond. O O
2e– + 4H+ + PbO2 (s)→Pb2+ (aq) +
bond.
2H2O(l)
Hydride Hydride Hydride Hydride Pb2+ (aq) + SO42– (aq) + 4H+ + 2e–
of group of group of group of group
13 (BH3 14 (CH4, 15 (NH3, 1&2
O O → PbSO4(s) + 2H2O(l)
or B2H6, SiH4, PH3), & (NaH, On charging the battery the reaction
AlH3 or GeH4, hydride KH, It also shows tautomerism. is reversed and PbSO4(s) on anode
Al2H6) SnH4, of group MgH2, O OH O O
PbH4) 17 (HF, BeH2) and cathode is converted into Pb
HCI, Br) and PbO2 respectively.
Related Theory: While recharging,
OH OH
41. (B) CaCl2 + Na2CO3  CaCO3 + NaCl O Enol form O Keto form
the automobile battery functions
(X) (Y) 45. Compound C is most polar as it travelled like an electroytic cell. The energy
(2HC1) the least distance. required to drive the recharging
(Z) Related Theory : If the compound of comes from an external source,
CaC12 + CO2 + H2O interest is polar, then it will have a strong such as an engine of a car. It is also
af昀椀nity with the polar Silica solid phase important to note that overcharging
42. (C) The halides in higher oxidation
and thus, will not be removed in the of the battery could result in the
state will be more covalent than formation of by-products such
in lower oxidation state. As higher non polar solvent. The compound can
as hydrogen gas and oxygen gas.
the positive oxidation of central be eluted using a more polar solvent such
These gases tend to escape from
atom, more will be the polarising as ethyl acetate or ethanol.
the battery, resulting in the loss of
power which in turns, increase the 46. (D) a-IV, b-III, c-II, d-I reactants.

10 |
49. 2NO + Br2 → 2NOBr the oxide to a high temperature is not possible or metal oxide is
 → NOBr (Fast)
k1 where the boiling point of the unstable. This is the easiest thing
(i) NO + Br2 ←  2
k2 metal is exceeded. However, the for extracting metal from metal
(ii) NOBr2 + NO 
Slow
→ 2NOBr slope increases since the reaction oxide. For extraction of metal from
K2
is now involving a larger entropy its oxide the metal oxide should
r = k3 [NOBr2] [NO] change as the randomness increases be unstable. Every metal oxide is

Keq =
k1
=
[ NOBr2 ] in reatants. For example, likely unstable after the bend. So we
k2 [ NO][ Br2 ] 2 Mg(g) + O2(g) → MgO(s) can easily reduce the metal oxide
after the bend.
k1 × [ NO ][ Br2 ] Here, three moles of gas phases are
⇒ [NOBr2] = Since, the metal oxide is unstable
k2 converted into solid phase in the
after a certain point. This can be
reaction. This takes place above
k1 k3 understood as :
r= [NO]2 [Br2] 1120°C, which is the boiling point
k2 The value of free energy change can
of Mg.
r = k [NO]2 [Br2] be found from DG = DH – TDS
Ag2O
Thus, net order of reaction In this enthalpy change is always
+250
=2+1=3 CuO negative due to combustion. The
value of entropy change is negative
50. (C) Since, extent of adsorption ∝ 0 CO CO2
means - TDS will become positive
ZnO
and DG will become positive. The
sG°/kJ

critical temperature Thus, Gas FeO

CO CO2
which has higher value of critical entropy of the reaction.
500
temperature shows more adsorption Metal + Oxygen → Metal oxide is
SiO2
or get easily liqui昀椀ed. Al 2O 3
negative
gO
TiO2 M C CO This is because the gaseous oxygen
Caution : The higher the critical 1000
CaO
is converted to solid metal oxide. So
temperature, higher is the
entropy change in already negative.
intermolecular force of attraction 500 1000 1500 2000 2500
With the raise in the temperature
and easier is the liquefaction of the Temperature/°C the value of entropy change will be
gas.
Related Theory : In the diagram more and more negative because
51. (D) The diagram predicts that MgO and there is sharp bend in each metal the rate of the reaction increase
ZnO decompose if heated strongly oxide line and the metal oxide line with increases in temperature. So
enough, but it does not hold out started to move upwards (towards the DG will become positive and
much hope for obtaining say pure positive value of DG) indicating metal oxide becomes unstable.
Mg by straight forward heating of that the metal oxide formation

52. (D) For octahedral complex : CFSE = [– 0.4 (n) t2g + 0.6 (n) eg] D0 + *nP.

Complex Ion Con昀椀guration Ligand SFL/WFL t2g, eg con昀椀guration CFSE Value

[Ti(H2O)6]+3 Ti+3 d1 H2O WFL t2g1.0.0 eg0.0 – 0.4 D0

[Cu(NH3)6]+2 Cu+2 d9 NH3 SFL t2g2.2.2 eg2.1 – 0.6 D0

[Fe(Cl)6]–3 Fe+3 d5 Cl WFL t2g1.1.1 eg1.1 0 D0

[NiF6]–4 Ni+2 d8 F WFL t2g2.2.2 eg1.1 – 1.2 D0

Caution : SFL = Strong Field Ligand/WFL = Weak Field Ligand.

53. (B) 54. (A) This reaction is oxidative ozonolysis ozonolysis is the process of
O O O of alkene which give carcoxylic oxidatively cleaving unsaturated
Mg + acid. bonds in the presence of ozone.
Br +MgBr Br
CH3 CH CH CH2 CH2 CH3 This reaction occurs with alkenes
and alkynes causes the oxidative
O3/H2O2
O O cleaving of the double and triple
Br Br
H2O CH3 COOH + CH3 CH2 CH2 COOH bonds, giving the required corbonyl
OH O Related Theory: Oxideative product.

Paper | 11
55. (C) 56. (D) NaNO2 + HX  HNO2 + NaX
+
H – O – N = O  → NO+
H
O — H2 O
(Nitra Osonium ion)
Me C
C CH3 Me Me Me Me
H O N N
OEt
O
Me C + NO NO
2 4 C CH3
1 3 O Caution : Here electrophile NO+
attack onpara position at low
O CH O
3 temperarure.
5
4 1 C CH3
3 2

CH3
O
∆
C CH3
H2O

57. Alanylglycphenyl alanyl isoleucine Oligopeptie :

O O O O
CH3 CH C NH CH2 C NH CH C NH CH C OH
* * * *
NH2 CH2 CH CH3
* CH2
* *
* * CH3
*
* - sp2 hybridised carbons
Caution :
Alanine Phenyl alanine Isoleucine
O O O CH3
H3C Glycine
OH O
H2N OH HO CH3
NH2 OH NH2 NH2

58. (B) A-II, B-I, C-IV, D-III

59. (C) OH Cl NH R
SOCl2 R-NH2
O O O

LiAlH4 CH2 NH R

60.
EtO CH2 CH = O O
I
NHY /H+ (NH4Cl) NH C CH3

CH2 CH = NH EtO CH2 CH

EtO
C O C2H5
KCN NH+ I O
[mf C15H19NO4I2]
EtO CH2 CH
CN
H2SO4/H
+ + (v) NaI O
N2
NH2 NH C CH2
EtO CH2 CH
COOH EtO CH2 CH
(A)
CO2Et
+
HNO3 + H2SO4(2eg) N2
O O (iv) HNO3 O
O2 N O2N NO2 NH2
NH2 NH C CH2 NH C CH2 NH C CH2
AC2O EtOH/H+/∆ H2(Pd)/C
EtO CH2 CH EtO CH2 CH EtO CH2 CH EtO CH2 CH
(i) (ii) (iii)
COOH C OH C OEt C OEt
NO2 (B) NO2 O NO2 O NH2 O
H2(Pd)/C

12 |
61. (C) Given equations – x 2 + 6 x + 3 = 0 10

⇒ 28 / a
63. (B) Digits are 0, 1, 3, 5, 7 and 9 number 1
a, b are roots then. of 昀椀ve digit numbers greater than k =1 k

10
k (k + 1) (k + 2)
a + b = - 6 and a.b = 3 40000 : = 28 / 4
k =1
then a2 + b2 + 2ab = 6 ⇒ a2 = – b2 5    0 10

⇒ 4 / k ( k + 1 ) (k + 2 )
7
and a4 = b4, a8 = b8, a10 = –b10, a20 7    0 k =1

= b20.... [(k + 3) – (k – 1)]

7    5
also a2 + 3 = - 6 a 10

⇒ 4 / k (k + 1) (k + 2) (k + 3)
9    0 7
⇒ a4 + 9 = 0 ⇒ a4 = – 9 k =1

Now, 9    5 – (k – 1) k (k + 1) (k + 2)
α .β +α +β
23 23 14 14
So Required number = 5 × P3 = 1204
7
= ⇒ 4 [10×11×12×13]
α15 + β15 + α10 + β10
64. (D) We know that 7
= 4 ×2×5×11×4×3×13
α 20 . α 3 + β20 .β3 + α14 − α14 (1 – x)100 = C0 – C1x + C2x2 + – C3x3
= 2 × 3 × 5 × 7 × 11 × 13
α12 .α 3 + β12 .β2 + α10 − α10 + ...C99x99 + C100x100
So, m = 6
⇒ C0 – C1 + C2 – C3 + – C99 + C100 =
(Consecutive prime numbers)
0
α (α + β )
20 3 3

⇒ = a8 = (α 4 )2 2 (C0 – C1 + C2 + ........ – C9) + C50  7 3

α12 (α 3 + β3 ) 68. (B) Point =  α,
=0  3 
⇒ –8 = (–9)2 = 81 1
C0 – C1 + C2 + ..........C99 = - 2 Line Segment → x cos θ
62. (B) Given that : 100
C50 + y sin θ = 7
1 1 100! 7
z0 = 2 (1 + 3i) – 2 50!50! x – intercept =
r=1 sin θ
1 100×99!
- = - 2 × 50!50!
|z1 – z0| = 1 2 i =
1
2
⇒ – 99C49 R
2 ; Centre b 2 , 2 l
1 3
⇒ |z2 – z0| = 1 n 1
65. (A) C + nC +........ M (h, k)
n+1 n n n–1
z0 b 2 , 2 l and z, (1, 1)
1 3 1
+ nCn + nC0
2
n
n
Cr n
/ r+1 = n+1 /
1
y – intercept =
7
tan q = – 1 ⇒ Q = 135º r=0 r=0
sin θ
= n +1Cr + 1  7   7 
A:  ,0 B :  0,
1 1023  cos θ   sin θ 
= n + 1 = (2n + 1 = 0) = 10
Z0
Locus of mid point M : (h, k)
Z1
q n + 1 = 10 7 7
h= ,k=
⇒ n=9 2 cosθ 2sin θ

z2 b 2 + 2 cos 135º, l
1 66. digits a, b, c are in A.P. 7 7 3
= 3
Nine digit numbers are to be formed 2sin θ
b 3 + 2 sin 135º l using each of there digits such that
2
Or consecutive numbers are in A.P. 3
⇒ sinq = 2
b 1 - 2 cos 135º,
abc
i.e. c b a π
2 ⇒ q =
2 sin 135º l
3- 7C ×2×6! 3
total Numbers = 21!2!2!
2
7
= 1260x a = =7
⇒ z2 b - 2 , 2 l Or z2 b 3 , 1 l
1 5 2 cosθ
2 2 67. (C) Since an = Sn – Sn – 1
(n - 1) (n + 2) 69. Circle (x – a)2 + (y – a)2 = a2
26 5 n 2 + 3n
⇒ |z2| = 4 , 2
2 = (n + 1) (n + 2) – n (n + 1) x2 + y2 – 2ax – 2ay + a2 = 0
intercept = 2
4
⇒ : z2 = 2D
5 ⇒ an = n (n + 1) (n + 2)
⇒ 2 a2 - d2 = 2
2
min

Paper | 13
 where d = perpendicular distance 2
⇒ tanq = -
of centre from line x + y = 2 3 3

⇒ Re o
-6 3 -6
a2 - d n =2
a+a-2 2
⇒ 2 31
,
31
2

or R e o
(2a - 2) 2 (a, a) 6 3 -6
⇒ a2 – 2 = 1 ⇒ 2a2 – 4a2 ,
31 31
+ 8a – 4 = 2 (0,0) x+y=2 1 + 1
Now =
(RQ) 2 (RS) 2
⇒ 2a2 – 8a + 6 = 0 ⇒ a2 – 4a + 3
70. (A) P e o = 4 c (OP) 2 + (OR) 2 m
2 3 6 1 1 1
=0 ,
7 7

⇒ 4 f 48 p
\ r1 + r2 = 4 and r1 r2 = 3 Equation of ellipse 9x2 – 4y2 = 36 1 1 + 144
1
Let R (2cosq, 3sinq) 7 31
⇒ r12 + r 22 - r1 r2 = (r1 + r2)2 – 3r1r2 as OP ⊥ OR
= 4 b 48 + 144 l
6 1 7 31
⇒ 16 – 9 = 7
3 sin q 7
So, × 2 3 =–1 13
2 cos q ⇒ 144
7
⇒ P + Q = 157

71. (B) Both are true S2 : (p Λ q) ((~p) Λ q) (p Λ (~q)) ((~p) Λ (~q))

S1 = (p ⇒ q) Λ (p Λ (~q) p q pΛq (~p Λ q) (p Λ ~q) (~p) Λ (~q) S2

p q p→q p Λ (~q) S1
T T T F F F T
T T T F F
T F F F T F T
T F F T F
F T F T F F T
F T T F F
F F F F F T T
F F T F F
So, S2 is tautology
So, S1 is Contradiction

72. (A) According to question the condition Sum of divisors B = {(1, 1), (2, 2), (3, 3), (1, 2), (1,
are : = (5º + 5') (7º + 7') 3), (2, 3)}
= 6 × 8 = 48. C = {(1, 1), (2, 2), (3, 3), (6, 2), (1,
a– b Case Probability 3), (2, 3), (3, 1), (2, 1)}
a a
5 (6, 1) 1/36 73. Let , , a, ar, ar 2
r2 r D = {(1, 1), (2, 3), (3, 3), (1, 2), (2,
a a 3), (2, 1), (1, 3)}
4 (6, 2) (5, 1) 2/36 Given 2 + r + a + ar + ar 2
r
3 (6, 3) (5, 2) (4, 2) 3/36 So the number of relation are 3.
31
= 5× 10 ...(i)
2 (6, 4) (5, 3) (4, 3) 4/36 75. f (x) = [x] + x - [x]
2
(3, 1) r r 1 1 1 At x = –2
And a + a + a + ar + 2
ar
1 (6, 5) (5, 4) (4, 3) 5/36 f (–2) = 2
31
(3, 2) (2, 0) = 5× 10 ...(ii) RHL f (–2+) = 2 + 0 = 2
∴ Continuous at x = –2
0 (6, 6) (5, 5)...(1, 1) 6/36 dividing (1) ÷ (ii), a2 = 4 ⇒ a = 2
At x = –1
–1 5/36
1 5 f (–1) = 1 + 0 = 1
–2 4/36 \ r+ = (a ! - 2)
r 2 LHL f (–1–) = 2 + 1 = 3
–3 3/36 \ r =2 ∴ Discontinuous at x = –1
–4 (2, 6) (1, 5) 2/36 At x =0
1
–5 (1, 6) 1/36 \ Now 2 , 1, 2, 4, 8 f (0) = 0
LHL f (0–) = 1 + 1 = 2
s2 = N - b l
Σ(x2) = Σx2 P(x) /x 2 /x 2
∴ Discontinuous at x = 0
= 2 : 36 + 36 + 36 + 36 + 36 D
25 32 27 16 5 N
186 M At x =1
= 25 = N
105 35 f (1) = 1
= 18 = 6
⇒ M + N = 211 LHL f (1–) = 0 + 1 = 1
m = Σ(x) = 0 as data is symmetric ∴ Continuous at x = 1
74. A = {1, 2, 3} Hence, f (x) is discontinuous at x =
s2 = Σ(x2) = Σx2 P(x)
According to the question, 3 sets –1 and x = 0. So, there are 2 points of
35
= 6 P = 35 = 5 × 7 are discontinuity.

14 |
 p
f (x) = sin-1 d log3 x d nn
50

76. (A)
6 + 2 log3 x
Now, /B n Q x ≠ 0 and x ≠
3
- 5x n =1

⇒ log e d n =
3e 1
= C =50I + 25×51 = GG C–1
6 + 2 log3 x 0 1/51 = loge e1/2
Here, ≥0 2 sin x 2
- 5x 0 0
or x ≥0 3e
⇒
= = G= G= G
1 2 50 25 - 1 –2 = e
1 2 sin x
but x ≠ –1 –1 0 50 1 1
3
3 ⇒ sin x =
= 25 = G= G= G
1 2 2 1 - 1 –2
x ∈ c 0, m ....(1)
1 2
This gives -1 -1 0 2 1 1 p
3 ⇒ x =
3
= 25 = G= G = 25 = G
Also, 2 5 –1 –2 3 1 p
at x =
–1 ≤ log3 x d n
6 + 2 log3 x –2 –3 1 1 –1 1 3
≤1 (x )
- 5x
cx = m
Sum of elements = 25 × 4 = 100 f" = positive value
p
6 + 2 log3 x 1 3
RS V p
⇒ 3x < ≤ SS1 2k 2k - 1 WW It is clear that at x = f (x) has
- 5x 3x WW 3
78. DK = SS n n 2 + n + 2 n2 WW minimum value
Two equations are formed : SS
5 Sm n + n n + n + 2WW
2 2
2p
Tm X JK 3e NOO
sin
6 + 2 log3x + ≥0 KK
3
Now / Dk
3 k O
K 2 sin c 3 mOO
⇒ = KK p O
and 15x2 + 6 + 2log3x ≥ 0 k =1 e
n n2 + n n2 L P
x ∈ c 0, m ....(2) = ^ eh
1 k 3/4
Now, = n n +n+2
2
n2 = 96 ⇒
27 e
n n +n n +n+2
2 2

k4
-
23 = e3/2
and x> 3 6 ....(3) Applying R1 → R1 – R2 and R2 → e4
From eq. (1), (2) and (3) R2 – R3 k8
⇒ = e3
RS VW e8
x ∈ <3 6 ; n
-23 1
SS0 –2 0 WW
then, c m + 5 + k8
27 SS0 2 –n –2 WW = 96 k '8 k8
SS W
Q a is a small positive quantity Sn n (n + 1) n 2 + n + 2WW e e
T X = e3 + e3.e3 + e3.e8
1 ⇒ – 2(n2 + 2n) = 96
(a ~ 0) and b = = e3 + e6 + e11
27
⇒ n + 2n – 48 = 0
2
x+7
So, a2 +
5
=0+
5
= 135
80. (D) I(x) = # x .dx
b 1/27 ⇒ (n – 6) (n + 8) = 0
Let x = t2 ⇒ dx = 2t dt
77. (D) A = >1 51 H
1
⇒ n = 6 or – 8
0 1 I(x) = 2 # 7 + t 2 dt
= 2 ; 7 + t2 + 1
t
79. (B) e3 + e6 + e11
B= = GA= G
1 2 -1 -2 2
| x | 6 + 7 + t2E + c
7
f (x) = d n sin 2 x
-1 -1 1 1 3e
2
2 sin x
Let = G = C than C– 1
1 2
⇒ loge f(x) = sin2x loge d n
-1 -1 3e I(x) = [ 7 + x . x +
2 sin x
= = G
–1 –2 ⇒ Differentiating w.r.t. x 7 x x + 7 + x] + C
1 1
1 2 sin x Q I(x) = 12 + 7|n|
So B = C AC–1 .f ' (x) = - sin 2x ×
f (x) 3e 12 + 7|n| = 3 × 4 + 7|n| |3 + 4| + c
3e
The B2 = CA(C–1C) AC–1 = CA2C–1 ×
2
. cot x cosec x C=0

+ log d n
3e
and B3 = CA3C–1 and so on : \ I(x) = x 7 + x + 7|n| x +
2 sin x
.2sin x cos x 7 +x|
50
/B
f '(x) = f (x) 5- sin x cos x
n
= C {A+ A2 +..........A50}.C–1
n =1 Now I(1) = a + 7 |n| (1 + 2 2 )

Q A = = G+= G =I+M n sin x cos xF

1 0 0 1/51
+ 2 log d
3e So I(1) = 2 2 + 7 |n| (1 + 2 2 )
0 1 0 0 2 sin x
(say) For maxima & minima On comparing,
2
Then A = I + 2M
sin x cos x d 2 log e d n - 1n
3e a= 2 2
2 sin x
then a4 = ^2 2 h = 16 × 4 = 64
3
and A = I + 3M =0 4

Paper | 15
 1 dt tx –1 2
81. (D) Let y = x 2 -
10 2
⇒ –
–
dx 1 + x 2
= c (9 + 1 + 1) — [180 + 10]2
1 + x2 =
3 dt x 1 = (36 + 1) (11) – (191)2
Q 0.15 = 20 ⇒ + .t = +
1 1 dx 1 + x 2 1 + x2
x2 x2 = 407 – 361
IR = e y
100 100 x 2
dx = e In 1 + x = 46
1 + x2
1
ï x2 = 1 + x2 85. A (–6, 0, 0) B (0, – 2, 0) C (0, 0, 3)
100
t. 1 + x 2 = + y 1 + x 2 . AB = 6S
i - 2Uj , BC = 2Uj + 3V
1 k
dx + c
1 + x2
AC = 6S
i + 3V
k
3 1 1 1 + x2
y
,0 ,0 3 1
,0 ,0 =+ +C
20 10 10 10 y AH . BC = 0
1 + x2
c a + 6, b, m . (0, 2, 3) = 0
2 2 6
,0
,0 1 + x2 7
20 20
⇒ = – ln x + 1 + x 2 + c
y
<b = F
0.15
-9
at y(0) = 1 then (= 1 = In e
# | 100x - 1 | dx = 2
2 7
–0.15
1 + x2 CH . AB = 0
\ = + ln x + 1 + x 2
y
+ ln e = In e _ x + 1 + x 2 i
−15 
;# (100x 2 - 1) dxE

#
1/10 3/20
(1 - 100x 2) dx +  α, β,  = (6, – 2, 0) = 0
7 
Now, y ^2 2 h = l3
0 1/10

= 2 ;& x - 3 x 3 0 + & 100 0

3 -x E
1/10 3 3/20
100 x
= In e ^2 2 + 3 h
0 1/10 3 6a – 2b = 0
⇒
β
= 2 ;10 - 30 + 3 b 20 l – 20 – 30 + 10 E
100 3 3 3 1 3
1 1 1 a= -7
⇒ e 3b –1
= e ^3 + 2 2 h 98 (a + b)2
= 2 :10 - 30 + 80 – 20 D
2 2 9 3
   
(a + b + c) × c = 0
(144)
84. (B) = (98) 49 = 288
= 2 : 48 –1624027 – 36 D
+    
⇒ (a + b + c) × c = 0 86. (A) 10
23 k 23    x+5 y+4 z-a
= 120 = 3000 = 120
( a + b) × c = 0   l1 :
3
=
1
=
-2
c = k ( a + b)
 l2 : 3x + 2y + z – z = 0
k = 575 Let,

( )
   = x – 3y + 2z – 13
3 Now, a.c = k a 2 + a.b
82. (D) Curve y = x and point (– 1, –1) Since l1 and l2 are coplanar
( )

Equation of tangent : – 17 = k 1912 + a.b (3x + 2y + z – 2)
y + 1 = 3(x + 1)   2
and b.c = k  a.b + b 
+ µ(x – 3y + 2z – 13) = 0
i.e. y = 3x + 2  
x(3 + µ) + y(2 – 3µ) + z(1 + 2µ)
Point of intersection with curve (2, 8)   2
b 
– 20 = k  a.b + 
– 2 – 13µ = 0
#
2
So, Area = (3x + 2 - x 3) dx
-1 Now Now, 3(3 + µ) + 1(2 – 3µ)
27
= 4 –17 ^λ 2 + 2 + 3λ – 1 – 2 h
]3λ – 1 – 2 + 9 + 1 + 14g
= – 2(1 + 2µ) = 0
–20
2 9
83. (C) (1 + x )dy = y(x – y)dx ⇒ 17(3l + 11) = 20(l2 + 3l–1) ⇒
dy y ^ x – y h
µ=
4
⇒ ⇒ 20 l2 + 9l = – 207 = 0
dx
=
1 + x2 So, 4(15 – 8 + a –2) + 9(–5 + 12 +
69
⇒ l = 31 – 2a – 13) = 0
20
dy xy – y 2
⇒ = \ λ = 3 (Q l G ∈ 2) ⇒ –100 + 4a – 54 + 18a = 0
dx 1 + x2
\ – 20 = k(3l – 3 + 14) ⇒ a=7
dy xy –y 2
⇒ – 2 = – 20 = k (3 × 3 + 11) Let, P ≡ (3l – 5, l – 4, –2l + 7)
dx 1– x 1 – x2
DR's of PQ ≡ (3l – 1, l – 1,
1 dy x –1 k = – 10
y 2 dx y ^1 + x 2 h
⇒ – = –2l + 5)
1 + x2
( )

ˆ + 3iˆ — ˆj + 2kˆ
So, c = 3iˆ + ˆj — kc But, PQ ⊥ l1
1 1 dy
Let, =t ⇒ – 2  ⇒ 3(3l – 1) + 1(l – 1)
y y dx ⇒ c = — 6iˆ — kˆ
– 2(–2l + 5) = 0
( )
dt  2
= c × 3iˆ + ˆj + kˆ ⇒ l =1
dx

16 |
 as cos b A 2 C l = sin B
P(–2, –3, 5) c (a – 1) (b – 1) + (1 – b) (1 – c) +
Hence, | a | + | b | + | c | = 2 + 3 + 5 – (1 – c) (a – 1) 2

= 10 c 1 1
1-c +1-a +1-b =0 So cos
A-C B
= 2 sin 2
2
87. (A) Let equation in new positions is c 1 1
1-c +1+1-a +1-b =1 B
2 cos 2 cos
A–C B
= 4 sin 2
(4x – y + z – 10) + l(x + y – z – 4) = 0 2
1 1 1
4(4 + l) – 1 (– 1 +l) + 1 (1 – l) = 0 1-c +1-a +1-b =1 B
cos 2
⇒l=9
n +2nb n l
(n - 1) 1 n-1
So equation in new position is 89. Mean = 1

2 sin b A 2 C l cos b A 2 C l
+ -
+ 3 b 1n l b n n 1 l
–5x – 10y + 10z + 26 = 0 2
-
⇒ a = 54/15
\ 35a = 54/15 × 35 n b n - 1 lb + b 1 l + b 1 l2 l
9= n 1 2 n 3 n .. B B
= 4 sin 2 cos 2
= 126
b n - 1 lb1 - 1 l
-2
n
9 + n n sin A + sin C = 2sin B
88. (A) The vectors aS
i +Uj + V
k,S
i + bjU + V
k
= b n n 1 l.
- n2
a + c = 2b → a = 3, c = 7, b = 5
and S i +Uj + ckV are co-planar (n - 1) 2
cosA – cos C
RS V n n
SSa 1 1WWW 9 = n - 1 ⇒ n = 10 b2 + c2 - a2 - a2 + b2 - c2
SS1 b 1WW = 0 =
SS W 2ab 2ab
S1 1 cWW 90. (A) cosA + cosC = 2 (1 – cosB)
T X 25 - 49 - 9 9 + 25 - 49
C1 → C1 – C2 C2 → C2 – C3 A+C A–C = –
2 cos 2 cos 2 = 4 sin2 70 30
RS V
SSa - 1 0 1WWW
B
2 65 1 20 10
SS1 - b b - 1 1WW = 0 = 70 + 2 = 14 = 7
SS W
S 0 1 - c cWW
T X
qq

Paper | 17