Phil. Trans. R. Soc.

A (2010) 368, 1027–1082

doi:10.1098/rsta.2009.0247

REVIEW

Flat-panel electronic displays: a triumph of

physics, chemistry and engineering
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B Y C YRIL H ILSUM*
University College London, London, UK

This paper describes the history and science behind the development of modern flat-
panel displays, and assesses future trends. Electronic displays are an important feature
of modern life. For many years the cathode ray tube, an engineering marvel, was universal,
but its shape was cumbersome and its operating voltage too high. The need for a flat-
panel display, working at a low voltage, became imperative, and much research has been
applied to this need. Any versatile flat-panel display will exploit an electro-optical effect,
a transparent conductor and an addressing system to deliver data locally. The first need
is to convert an electrical signal into a visible change. Two methods are available, the
first giving emission of light, the second modulating ambient illumination. The most
useful light-emitting media are semiconductors, historically exploiting III–V or II–VI
compounds, but more recently organic or polymer semiconductors. Another possible
effect uses gas plasma discharges. The modulating, or subtractive, effects that have been
studied include liquid crystals, electrophoresis, electrowetting and electrochromism.
A transparent conductor makes it possible to apply a voltage to an extended area
while observing the results. The design is a compromise, since the free electrons that carry
current also absorb light. The first materials used were metals, but some semiconductors,
when heavily doped, give a better balance, with high transmission for a low resistance.
Delivering data unambiguously to a million or so picture elements across the display
area is no easy task. The preferred solution is an amorphous silicon thin-film transistor
deposited at each cross-point in an X –Y matrix.
Success in these endeavours has led to many applications for flat-panel displays,
including television, flexible displays, electronic paper, electronic books and advertising
signs.
Keywords: displays; cathode ray tube; liquid crystals

1. Background

Electronic displays are an important feature of modern life. They have a magical
allure, for they make complex operations within electronic circuits visible. The
father of all displays, the cathode ray tube (CRT), was invented at more or less
*[email protected]

One contribution of 17 to a Theme Issue ‘Personal perspectives in the physical sciences for the
Royal Society’s 350th anniversary’.

1027 This journal is © 2010 The Royal Society

 1028 C. Hilsum
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Figure 1. A mini-radar set.

the same time as the vacuum valve, and as the valve improved in performance,
and as circuits grew more complex, so visualizing the outputs became essential,
and here the CRT was supreme. The invention of television (TV) made more
demands on the output device, and the CRT developed into an engineering
marvel, giving a multi-colour representation of any scene, still or moving, that
matched the original in fine detail. Moreover, this device was made in such
numbers and at such a low cost that it could be found in most homes in the
developed world.
However, the design of the CRT gave some serious problems. The first was
the problem of making big screens. It is difficult to bend electrons through wide
angles, so a large-area display had to incorporate a long tube for the electron
source. Further, because thick glass is needed for the face plate, in order to
withstand the air pressure, large tubes are very heavy, a set with a 36 inch
diagonal screen weighing over 100 kg. Other negative features are the need for
high-voltage operation to energize the phosphors, the risk of X-rays, and the life
limit of perhaps 5 years. Scientists were conscious of these limitations and there
were many attempts to invent simpler forms of CRT. Particularly noteworthy
were the tubes proposed by Ross Aiken and by Denes (later Dennis) Gabor, with
the electron gun at the side of the screen. These gave the system a smaller volume,
but could not avoid the other disadvantages.
At this time, the 1950s and 1960s, electronics was experiencing a revolution.
The invention of the transistor had been followed by the integrated circuit, with
several thousand devices packed into a square centimetre, and all driven by a
few volts. The CRT was becoming more and more exposed as a dinosaur. The
major potential return from the invention of a display that matched the virtues
of the new electronics induced many companies to undertake research in the field.
Defence laboratories, already anxious to exact real benefits from the simplicity
and reliability of integrated circuits, were also conscious of the need to find a
solid-state display. A simple Doppler radar set could work off a few volts, and
could be held in the hand (figure 1); while the electronic display to show the
output needed a high voltage and much more space.

Phil. Trans. R. Soc. A (2010)

 Review. Flat-panel electronic displays 1029

2. Display requirements

There are three basic requirements for any flat-panel display capable of showing
a high-resolution colour picture. They are:
— an electro-optical effect;
— a transparent conductor;
— a nonlinear addressing component.

The first need is to convert an electrical signal into a visible change. There are a
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large number of potential candidates for this, and they fall into two classes. The
first gives emission of light; the second modulates ambient illumination, or light
from an artificial source, generally behind the display panel.
The most useful light-emitting media are semiconductors, historically
exploiting III–V or II–VI compounds, but now, more successfully, organic or
polymer semiconductors. There are persistent attempts to breathe new life
into the flat CRT, and much effort into maintaining interest in gas discharge
tubes. Modulating, or subtractive, effects are legion, and the literature abounds
with new candidates, or revisions of old failed ones. Those that have shown
success or potential include liquid crystals, electrophoresis, electrowetting and
electrochromism, in both solids and liquids. Effects that have not survived include
dichroism, whereby elongated crystals with anisotropic absorption are persuaded
to move in an electric field—crossed crystals absorb, parallel crystals transmit.
The favoured medium was herapathite, quinine iodine sulphate, used in the first
sheet polarizers. This was named after a Bristol doctor, William Herapath, who
observed that when one of his students, a Mr Phelps, added iodine to the urine of
a dog that had been fed quinine, green crystals grew in the ‘reaction liquid’ (Land
1951). History does not record the later career of such an imaginative student,
but, alas, it does record the failure of dichroic displays.
The need for a transparent conductor is obvious, since one needs to apply a
voltage to an extended area while observing the results. The current is carried by
the free electrons, but these also absorb incident radiation. There is then a balance
in the design, because, as the thickness of the coating is increased to lower the
resistance, so the transmission decreases. The first materials used were metals,
and the top electrode in early selenium photocells was a very thin gold film. For
all metals, the absorption is so high that the electrode can have a thickness of
only a few hundred ångströms, and it is then difficult to deposit a film of uniform
thickness over a large area. Some semiconductors, when heavily doped, give a
better balance, with high transmission for a low resistance.
Delivering picture or symbol data to the display is no easy task. Each picture
element, or pixel, must be addressed individually, without crosstalk, and a large-
area TV screen can have well over a million pixels. It would be impracticable to
have two connectors to each pixel, and a matrix of orthogonal X and Y lines is
always used, with the cross-points labelled as an address. The technique is called
matrix addressing (figure 2). Applying half the required voltage to, say, column 2
and row B would certainly excite solely pixel 2:B, but the simultaneous excitation
of pixel 5:E would also switch on pixels 2:E and 5:B.
The remedy is sequential activation, or multiplexing, running down the X
rows one by one, applying the half-voltage to the appropriate Y columns at
the correct time. While this does solve the ambiguity problem, it creates a
Phil. Trans. R. Soc. A (2010)
 1030 C. Hilsum

1 2 3 4 5 6 7 8
A

F
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Figure 2. Matrix addressing.

V
(a) –2 (b)
0 0 0 0
A

0 B
brightness or contrast

0
V
+2

0
V/2 V
voltage

Figure 3. Matrix addressing problems. (a) Multiplexing. (b) Electro-optical effects with (curve A)
and without (curve B) a threshold.

crosstalk problem, in that a number of half-voltages will be applied to pixels that

should have been passive. Figure 3a shows that, whenever a pixel is addressed,
there is a possibility of a cross-bar pattern emerging. The situation would be
tolerable for a small display exploiting an electro-optical effect with a voltage
threshold, as in curve A (figure 3b), where a half-voltage impulse has no effect
at all, but most useful effects have an inadequately sharp threshold, showing a
fairly gradual change in transmission with voltage, as in curve B. The solution
is to add to each pixel a circuit element that does have a sharp threshold,
such as a semiconductor diode or a transistor, converting the passive matrix
into an active matrix (figure 4). The element must, of course, be integrated on
the panel, in the form of a thin film. Early panels used CdS or CdSe thin-
film transistors (TFTs), but these proved unstable and short-lived. Progress
on flat-panel displays burgeoned only when amorphous silicon TFTs became
available.

Phil. Trans. R. Soc. A (2010)

 Review. Flat-panel electronic displays 1031

source lines

gate line

display display
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element element

gate line

Figure 4. The active matrix.

3. Transparent conductors

The display medium needs two electrodes, and at least one of these must be
transparent, so that the optical path from the pixel to the eye will suffer little
absorption. For most practical effects, the pixel electrodes are orthogonal to this
path, and run the full width of the display. The conductivity of the electrodes
must then be high enough to give a uniform voltage over the display area.
Let us assume that we will use a semiconductor for the electrode. Drude
theory shows that free carrier absorption will give an absorption coefficient α
at a wavelength λ as
KN
α= , (3.1)
μm ∗2
where N is the electron concentration, μ is the mobility, m ∗ is the electron
effective mass and
e 3 λ2
K=
4π 2 ε0 ηc 3
with η the refractive index. A numerical factor should also be included to allow
for averaging over the electron energies, and this factor will depend on the
relative contributions of scattering by the lattice, impurities, surfaces and grain
boundaries.
For a film of thickness t cm with absorption A less than about 20 per cent,
A = αt. (3.2)
The resistance per square (Rs ) is given by
1
Rs = ohm. (3.3)
etNμ

Phil. Trans. R. Soc. A (2010)

 1032 C. Hilsum

The electrode must be colourless, so the semiconductor energy gap will be greater
than 3 eV. The electron effective mass m ∗ will then be greater than 0.1m0 , so the
mobility μ will certainly be less than 200 cm2 V−1 s−1 . An increase in N will reduce
Rs , though there will be an increase in impurity scattering, so that the mobility
will fall. Typically we require Rs to be between 1 and 100 Ω, depending on the
type and area of the display, and a convenient film thickness will be between 0.1
and 10 μm, so we can aim at N approaching 1021 cm−3 combined with mobilities
around 30 cm2 V−1 s−1 . However, the absorption increases with N , so, since we
need both conductivity and transparency, designing a transparent conductor is a
matter of swings and roundabouts. One factor of merit is the product ARs , which
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is independent of carrier concentration and thickness, since

k
ARs = . (3.4)
(m ∗ μ)2
We wish to minimize this product. Substitution of typical values for the
parameters involved in k shows that, with an effective mass ratio of 0.3
and a mobility of 30 cm2 V−1 s−1 , ARs is approximately 60. So it should be
possible to obtain a resistance per square of 20 Ω with a film absorption of
3 per cent.
Some 30 years ago it was discovered that cadmium oxide had a low ARs
product, and it was widely used. It was in turn replaced by tin oxide, which
then became a standard. In the 1970s indium oxide doped with tin (ITO),
prepared by spraying, was shown to give better results still, but today layers are
prepared by sputtering, a more practicable technique for displays. Such layers
have been reported with N near 1021 cm−3 and a mobility of 43 cm2 V−1 s−1 . Such
a combination is remarkable in a material of such a large energy gap, particularly
when we remember that we are dealing with a polycrystalline layer. ARs products
below 50 have been reported for ITO, but an alternative compound, cadmium
stannate, has shown ARs values a factor of 2 lower. Unfortunately, cadmium is
highly toxic, and is rarely used in production.
This does not mean that ITO has no rivals. Though it has excellent parameters,
there are some disadvantages. The high usage of such coatings has caused the
price of indium to escalate, and there is even the possibility of a world shortage.
A more definite disadvantage is the lack of flexibility in thick coatings, which
makes ITO suspect as the electrode for flexible displays. A possible alternative is
ZnO doped with Al. Sputtered layers have shown values for ARs as low as those
for ITO (Igasaki & Saito 1991a,b).
The transparent conducting electrode represents an important achievement for
material science that is rarely publicized.

4. The visual effect

There is a clear distinction between emissive displays, which work by generating

light, and subtractive displays, which exploit modulation of incident or
transmitted light by controlling absorption, reflection or scattering. Both classes
have their proponents, since each has shortcomings. Subtractive displays are
economic in power, but in the absence of ambient light a subsidiary source is
needed, and much of the power advantage is then lost. In ambient light, some

Phil. Trans. R. Soc. A (2010)

 Review. Flat-panel electronic displays 1033

subtractive effects can have a dull appearance, lacking charm. Emissive displays
are attractive to view in low or moderate light levels, but they fade and are
difficult to read when bright light falls on the panel. We still lack an efficient
emissive technology, though there has been much progress in the past few years.
To obtain sufficient brightness, it is necessary to drive the emitting pixels hard,
and then their life can be curtailed.

(a) Subtractive displays

Progress in semiconductor electronics after 1950 was so rapid that scientists
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assumed that semiconductors could do everything. Certainly our understanding

of the physics of solids became deep and wide, and we could devise strategies
for material design to meet a variety of applications. A number of electro-optical
effects in solids were proposed for displays, but all fell short of the requirements,
usually because they operated at high voltages. It was with some misgivings that
the community realized that the solution could come from liquids, a previously
neglected form of condensed matter, and one where much of our applied physics
and engineering was inappropriate. To augment these concerns was the discovery
that the best effects occurred in organic materials, previously the almost exclusive
province of chemists. Some relief was felt when it was shown that families of
candidate materials could be produced in weeks, in contrast to the years that
were needed to make and purify inorganic semiconductors like silicon and gallium
arsenide. The years when display concepts were being invented and refined were
truly years of equal partnership between physicists and chemists.
The 1960s saw four rival subtractive technologies emerging, with little
indication that any one had crucial advantages.

(i) Liquid crystals

Over 100 years ago an Austrian botanist, Reinitzer (1888), discovered a fourth
state of matter, with properties intermediate between solids and classical liquids.
This was a liquid that showed long-range order, though only over a limited
temperature range. On melting from the frozen state, the long-range order made
the liquid cloudy, but as the temperature was increased, it became clear. The
molecules of the liquid were long and thin, and the long directions followed
an ordered pattern. Further research revealed three types of order. Smectic
crystals are similar in their order to crystalline solids, in that the molecules
form equally spaced layers, all pointing in the same direction, though with little
positional order within a layer. In nematic crystals, there are no layers, the
molecules pointing in the same direction locally, though that direction, called
the director, changes over a distance (figure 5). Cholesteric crystals are layered,
but the molecules lie along the layers, all those in a layer pointing in the same
direction, with that direction changing gradually and regularly with distance, so
that the director follows a helix.
Liquid crystals (LCs) remained an academic curiosity until 1962, when
Williams (1963), at the Radio Corporation of America’s (RCA) Sarnoff Research
Center, discovered changes in the optical transmission of thin films of para-
azoxyanisole held between two glass slides on the application of 12 V. Williams
subsequently left the laboratory, but his lead was followed by George Heilmeier,
who persuaded the RCA management to start an LC project. There was, at

Phil. Trans. R. Soc. A (2010)

 1034 C. Hilsum
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Figure 5. The director in a nematic liquid crystal.

that time, no room-temperature LC, but the RCA chemists devised a mixture of
three Schiff’s bases that had a nematic range from 22 to 105◦ C (Goldmacher &
Castellano 1967). The effect that RCA wished to exploit in displays was called the
dynamic scattering mode (DSM), in which the mixture turns from transparency
to white opalescence over a range of a few volts (Heilmeier et al. 1968). LCs are
anisotropic in almost all their physical characteristics. The values of refractive
index, dielectric constant, conductivity, elasticity and viscosity are very different
when measured along the long molecular axis or the short axes. Because of the
dielectric anisotropy, the molecule will turn in an electric field, and nematics
divide into two classes, positive crystals, which align along the field, and negative
crystals, which try to lie across it. DSM can be generated in negative nematics,
because charges build up along the molecules, giving rise to a field at right
angles to the applied field. At higher fields, turbulence occurs. RCA publicized
their discoveries in 1968, and, amid some excitement, many companies set
about exploiting liquid crystal displays (LCD) in digital watches and calculators.
Curiously, RCA was an exception.
RCA had little interest in small instruments. Their display involvement was in
CRTs, and here their position was almost unique. Harold Law and Al Schroeder
had invented the shadow-mask tube some 10 years earlier, and this was now being
made in quantity at plants in Lancaster, Pennsylvania, and Harrison, New Jersey
(Law 1950, 1976). The company had early adopted the principle of licensing their
inventions, and shadow-mask tubes were now produced worldwide.1 Actually, this
policy was so successful that the royalty income financed the whole of the Sarnoff
Research Center. It was not surprising that the Development Laboratory did not
share the conviction that LCDs were the way forward for TV displays. They were
1 In the UK, English Electric Valve Co., Chelmsford, were licensees.

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 Review. Flat-panel electronic displays 1035

conscious of the problems of addressing, and unconvinced that the RCA invention
of the TFT in 1962 (Weimer 1962a,b) would be the solution. In any case, they
did not see the virtue in trying to replace their own world-leading display, and
did not accept the moral, ‘If you don’t do it, someone else will’.
Looking back, it is obvious that RCA held most of the assets needed to forge
and preserve world leadership in flat-panel displays, but they opted out. The
management set a target of a 1200 pixel integrated display panel to be made
early in 1968, but when no panel was made by the end of the year, the project
was cancelled. In the next year they abandoned all work on LC TV, though some
work on small displays continued until 1972.
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It would not be an overstatement to say that US industry lost its way on

displays in the 1970s. We have seen that the early running on LCs was made by
RCA. That laboratory had not been in the forefront of discovery on transistors
and chips, relying mainly on licensing from Bell Telephone Laboratories (BTL),
but it had a proud record of innovation in vacuum tubes, culminating in the
invention of the shadow-mask CRT. RCA led in the early research on TFTs
and LCDs, but the belief that flat-panel displays were against their long-term
interests led them to withdraw from the field in 1972. The other potential
industrial leader, BTL, had stayed curiously aloof from the frenzied search
for novel display technology, partly because of their increased involvement in
semiconductor lasers for communications, but also because senior figures in
their laboratory were unconvinced that new displays were required. They said
(Gordon & Anderson 1973):

Prospects for new display technologies are clouded by the fact that there exists a device, the
familiar CRT, that has long provided a versatile, elegant, functional, economical, and largely
satisfactory solution.

In circumstances where industry was unwilling to lead in long-term research

programmes, defence funding had previously filled the gap, and we have seen
that this indeed happened in the UK. In the USA, however, the Department
of Defense (DoD) was also unconvinced about flat panels. The opposition
was led, strangely, by the scientist who had contributed much to the earlier
enthusiasm at RCA for LCs, George Heilmeier. He had left RCA in 1970, and
within two years was holding a senior post in the US DoD with responsibility
for electronic device research contracts. He told the main US Displays
Conference (Heilmeier 1973):

How many realistic scenarios are there in which we win because we have a flat-panel, matrix-
addressed display in the cockpit? We must feed on existing technologies.

It was not surprising then that in the 1970s most of the important developments
in this field came from Europe and Japan.
The lack of management interest in LCDs certainly led to a number of the
RCA scientists leaving, and one of their best theorists, Wolfgang Helfrich, joined
Hoffmann-La Roche (H-LR), the Swiss chemical and pharmaceutical company, in
1970. There he suggested to Martin Schadt, the LC group leader, that he should
work on a new display effect that exploited positive nematics. Helfrich’s idea was
to make a thin LC cell that rotated the plane of incident polarized light by 90◦ .
It was known that nematic molecules would lie down on a glass substrate that
had been rubbed with a polishing cloth in one direction. If that direction was

Phil. Trans. R. Soc. A (2010)

 1036 C. Hilsum

polarizer

electrode
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electrode

polarizer
dark
bright

Figure 6. The twisted nematic display.

orthogonal on the two surfaces, a 90◦ twist would be induced, and when the cell
was put between parallel polarizers, no light could pass. However, if a field was
applied across that cell, the molecules would align themselves along the field, the
twist would disappear, and light could pass. Schadt made the cell, it worked, and
the twisted nematic (TN) display was born (figure 6).
There were some curious features to this invention. Helfrich left RCA in
October 1970, made the first TN cells in November, submitted a patent with
Schadt on 4 December (Helfrich & Schadt 1970) and a letter to Applied Physics
Letters 3 days later (Schadt & Helfrich 1971). Such a rapid sequence of conception
and construction is unusual. In fact, as Helfrich admitted 20 years later, he had
thought of the TN effect in 1969, and other ex-RCA staff confirmed this. However,
he made little attempt to attract management interest, since, as he explained, he
was there to help theoretical understanding, not to invent devices. RCA made no
attempt to invalidate the patent or to claim ownership, possibly because there
were further legal complications (Kawamoto 2002).
James Fergason was a scientist who had worked on cholesteric LCs at
Westinghouse in the early 1960s, but left in 1966 to join Kent State University.
Two years later he formed his own company, ILIXCO, to manufacture LC
displays. In 1968 and 1970 he published two papers that effectively contained
descriptions of the TN display (Arora et al. 1968; Fergason et al. 1970). He
made no attempt then to patent the concept, and was surprised, and probably
irritated, when a colleague reported back after a visit to H-LR that Schadt and
Helfrich had invented a new form of LCD. In fact, it was as a result of this
inadvertent disclosure that H-LR had rapidly taken the patenting and publishing
actions. Fergason himself set about composing patents and, after an abortive
attempt in February, submitted in April a patent, which was granted in 1973
(Fergason 1971). No mention was made in this patent of his earlier publications.
Though the validity of Fergason’s patent could have been queried because of
those disclosures, there could be no doubt that he had made and shown a device
in April 1970, because he had recorded the invention in witnessed notebooks. He

Phil. Trans. R. Soc. A (2010)

 Review. Flat-panel electronic displays 1037
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Figure 7. John Stonehouse, UK Minister of State for Technology, 1967–1968.

therefore had good grounds for contesting the H-LR patent, and after protracted
legal proceedings this was withdrawn. However, H-LR regained legal ownership of
TN rights by buying the Fergason patent from ILIXCO, which were in financial
difficulties. A compromise agreement shared royalties amicably between all the
interested parties except RCA.
Though the way was now legally clear for companies to exploit TN displays,
the commercial position was unclear. A number of companies had taken licences
from RCA to exploit dynamic scattering, and they were reluctant to adopt an
untested technology. However, problems soon arose because of the LC material.
DSM effects need negative nematics, and though RCA had now demonstrated
a suitable Schiff’s base that was nematic at room temperature, it did not have
an adequate working range. Sharp developed a eutectic mixture of three Schiff’s
bases that worked over the range 0–40◦ C, but were then frustrated when their
devices failed after only a few weeks of operation. It became apparent that there
was no stable LC available, and LCDs were acquiring a poor reputation for
reliability.
Up to then, the UK had played little part in LC development, though one
or two university chemistry departments were involved in research, and one
company, Marconi, had patented an LCD before the war (Levin & Levin 1934).
Now events took a curious turn, because a politician became involved. Much UK
semiconductor research had been carried out in government defence laboratories,
and early development of LEDs and diode lasers had taken place at the Services
Electronics Research Laboratory (SERL), Baldock, and at the Royal Radar
Establishment (RRE), Malvern. One of the aims of the Labour Government
elected in March 1966 had been to forge a ‘white-hot technological revolution’,
and the next year they established a Ministry of Technology. This assimilated
some of the defence laboratories, including RRE, and in March 1967 the Minister
of State for Technology, John Stonehouse (figure 7), came to Malvern.2
2 Many of the events that follow are not referenced, because they have never been published. They
are based on the recollections of the author, who from 1967 to 1983 led the Displays Group at RRE
and was responsible for the UK Government-supported Civil and Defence Displays programmes.

Phil. Trans. R. Soc. A (2010)

 1038 C. Hilsum

Table 1. Early liquid crystal families.

family central link problem

Schiff’s base –CN=N– hydrolytic cleavage

stilbene CH=C UV instability

C
azo –N=N– oxidation, isomerization
ester –CO.O– nucleophilic attack
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tolane –C≡C– UV instability

azoxy –N=N(O)– yellow colouring

He was surprised to hear that royalties to RCA on the shadow-mask tube cost
the UK more than Concorde, and after overnight deliberation authorized the
Director of RRE, Dr (later Sir) George Macfarlane, to start a programme on flat-
panel electronic displays. Surprised at this rapid decision, and informed by senior
staff that there was no expertise within RRE to mount a meaningful development
programme, he set up a committee to study the field. This recommended in
December 1969 that the UK Government should fund research on flat-panel
electronic displays, with LCs as the first priority (Hilsum 1969).
Though formal approval of this recommendation would normally have taken
some months, and, indeed, was never granted, RRE had anticipated approval, and
justified their action on the urgent need for displays for the portable radar sets
they had invented. They established two consortia, one for materials, involving
RRE, Hull University and BDH, and one for devices, involving RRE, SERL,
Marconi, Rank and STL. The Plessey Research Laboratory at Caswell were also
involved, specializing in electrophoretics. Though most of these organizations
were ‘the usual suspects’ from the semiconductor R&D programmes, Hull
University were unknown. They had come to the attention of RRE during a
meeting held to probe UK expertise on LCs, when it became clear that Hull, led by
Professor George Gray, were clear leaders in the understanding of LC chemistry.
This trust was rewarded manifold. Gray was given the task of finding a stable
LC, because RRE, schooled in defence requirements for reliable components,
appreciated that consumers also would not tolerate short-lived equipment. All
available LCs had serious shortcomings. Schiff’s bases gave erratic results, and
stilbenes, more recently proposed, were degraded when exposed to ultraviolet
radiation.
The solution did not come immediately. Hull worked first on carbonate esters,
then on sulphonate and carboxylic esters. They tried purifying samples of Schiff’s
bases, to see if the short device life was linked with impurities, and, when this
failed, moved to stilbene esters and cyano-Schiff’s bases. All efforts were leading
nowhere, and Gray was now becoming frustrated. He decided to take a step back
and see if the materials had a common fragile feature. Table 1 shows the position
in mid-1972.
Gray realized that one common feature was the central linking group. It
would be possible to have a biphenyl structure, but this was unlikely to give
a practical working temperature range. Nevertheless, an appropriate end group

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 Review. Flat-panel electronic displays 1039

might give a reasonable range, and they knew from their earlier research that –CN
gave a strong positive dielectric anisotropy, crucial for TN devices. The proposed
structure was
R CN

R was chosen to be an alkyl or an alkoxy, essentially the cyano-Schiff’s bases

they had worked on earlier, minus the central linkage. After deciding on the way
forward, and making some of the necessary precursors, in August 1972 Gray and
his colleague John Nash left to attend the International Liquid Crystal Conference
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at Kent State University, in the USA.

They left with some reluctance, for their recently qualified PhD graduate,
Ken Harrison, was ready to attempt the preparation of pentyl-cyano-biphenyl
(5CB) and pentyloxy-cyano-biphenyl (5OCB). They returned to a scene of great
excitement, for both materials had been made and found to be LCs. 5CB showed
a nematic phase from 22 to 35◦ C, and 5OCB worked from 48 to 69◦ C. Even more
exciting were the results of stability tests at Malvern. The resistivity and the
transition temperatures of both materials were unaffected by long exposure to
a damp atmosphere, whereas Schiff’s bases became unusable after a few hours.
However, this was just the start, because now they must find a mixture that
met the temperature requirements, −10 to 60◦ C. Six alkyls and six alkoxys
were then synthesized, and a number of mixtures of these were tried, but the
best combination had a range only from −3 to 52◦ C. They needed to design
complicated eutectic systems, but it would have taken far too long to plot eutectic
diagrams for all promising combinations.
A crucial contribution was then made by Peter Raynes, who had joined the
RRE Displays Group a year earlier, fresh from a PhD on superconductivity.
He realized that the Schroeder–Van Laar equation for binary eutectics might
be extended to predict mixture properties from thermodynamic data for the
individual materials. However, the accuracy was not high enough, and Raynes
then developed a more accurate semi-empirical method, which proved ideal. This
was so useful commercially that it was not put into print for some years (Raynes
1980). Melting points of eutectic mixtures were then predictable to within 5◦ C,
and clearing points, the change from nematic to isotropic behaviour, to within
2◦ C (Hulme et al. 1974). Raynes predicted that no mixture of biphenyls would
operate well below zero. Gray then reasoned that adding a terphenyl component
would give a wider range mixture, and though terphenyls were difficult to make,
they proved to be the solution.
Meanwhile, production processes of pure biphenyls had been perfected at
Poole, where Ben Sturgeon, the Technical Director of BDH, had made inspired
contributions, and before long BDH was selling biphenyl eutectics widely, for
though their temperature range was not ideal, their stability was very attractive.
Late in August 1973, Raynes made a four-component eutectic that had a range
of −9 to 59◦ C. It was called E7, and the composition is shown in figure 8. In
almost all respects it met the specifications put to RRE by manufacturers of
watch displays (table 2).
E7 could be said to be the saviour of the LC industry, for it was invented at a
time when LCDs were suspected of being inherently unreliable, and it remained
the preferred material for many years. The UK Ministry of Defence (MoD) chose

Phil. Trans. R. Soc. A (2010)

 1040 C. Hilsum

individual
temperature amount
range (°C) (%)

C5H11 CN 22 → 35 51
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C7H15 CN 28 → 42 25

C8H17O CN 54 → 80 16

C5H11 CN 130 → 239 8

Figure 8. Composition of eutectic LC material E7.

Table 2. E7 as a display material.

property requirement E7

nematic range −10◦ C to approx. 60◦ C −9◦ C to 59◦ C

threshold voltage less than 1.0 V 1.3 V
resistivity more than 5 × 1010 Ω cm 5 × 1010 Ω cm
response time less than 50 ms 35 ms
colour none none

a restricted licensing strategy, and originally only BDH and H-LR could sell
biphenyls. Rapidly they dominated the market. By 1977 BDH were the largest
manufacturers of LCs in the world (figure 9), and biphenyls had become their
largest-selling product. Less than five years earlier, the company had never made
an LC.3
I should not give the impression that the biphenyls had no rivals. The German
company Merck Chemicals had made LCs for academic users since 1904, had
increased production to meet commercial demand in 1968, and commanded the
market before biphenyls appeared. They did not remain idle. In 1973 they bought
BDH, and, not wishing to disturb the close relationship between BDH, Hull
and the MoD, ran parallel centres in Poole and Darmstadt. Darmstadt was
stimulated by the competition, and they conceived their own stable family, similar
to alkyl-cyano-biphenyls, but with a cyclohexane ring substituted for one phenyl
3A fuller version of some of these events is given in Hilsum (1984).

Phil. Trans. R. Soc. A (2010)

 Review. Flat-panel electronic displays 1041

s
ial
ter
sales (£ millions per annum)

ma
tal
s
cry
3

s
yl
id

en
iqu

ph
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bi
all
2

0
1975 1976 1977 1978 1979
year

Figure 9. The market for liquid crystals, 1975–1979.

Table 3. Parameters for LC material E7.

k11 (×10−12 N) k22 (×10−12 N) k33 (×10−12 N) η (cP)

10.70 10 20.70 38

ring. This family, known as the phenyl-cyclohexanes (PCH), became second in

importance to the biphenyls, having a lower viscosity and some very favourable
optical properties (Eidenschink et al. 1977).
There are many physical parameters of LCs that control the electro-optical
behaviour, but the most important for displays are the elastic constants and the
rotational viscosity. Table 3 gives the room-temperature values for E7 for the
splay (k11 ), twist (k22 ) and bend (k33 ) elastic constants and the viscosity (η).
The threshold voltage for switching, VT , is given by
 1/2
k
VT = π , (4.1)
ε0 ε
where
k33 − 2k22
k = k11 + (4.2)
4
and
ε = ε − ε⊥
is the difference between the dielectric constants along and across the long
molecule. Since ε for E7 is 13.8, the threshold voltage will be just under 1 V.

Phil. Trans. R. Soc. A (2010)

 1042 C. Hilsum

It can be seen that VT is independent of the viscosity and the cell thickness
(d), but the time constants depend on both. We have
η
ton = , (4.3)
ε0 εE 2 − kq 2
where E = V /d and q = π/d, and
η
toff = , (4.4)
kq 2
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so from equation (4.1)

ηd 2
ton = (4.5)
ε0 ε(V 2 − VT2 )
ηd 2 VT2
= . (4.6)
π 2 k (V 2 − VT2 )

For a 10 μm thick cell, toff is about 40 ms, satisfactory for watch and instrument
displays, but marginal for video presentation. Since ton = toff /(V 2 /VT2 − 1), a rapid
switch-on is readily available at higher voltages.
The visual appearance of a TN cell depends strongly on the angle of view,
and both the viewing angle and the contrast ratio came under criticism as the
possibility of major markets became apparent. Major advances were made, both
in the cell configuration and in the LC materials. A big step forward was the idea
of increasing the twist from 90◦ to 270◦ . This supertwist nematic display (STN)
was proposed and patented in 1982 by Waters & Raynes (1982) at RRE, and
independently patented a year later by the Brown Boveri group, led by Terry
Scheffer (Amstutz et al. 1983), afterwards ably assisted by Jurgen Nehring. STN
gave the steep threshold necessary for passive matrix displays, and the response
time and angle of view were similar to the simple TN device (Scheffer 1983;
Waters et al. 1983). It became the preferred display for instruments and lap-
top computers, and lost ground only when the production of TFTs over large
areas was perfected. The STN display was patented and widely licensed by
the MoD, and yielded royalties of over £100 million, the largest return for any
MoD patent.
More radical changes to the TN mode were also introduced. Soref (1972, 1973),
at Beckman Instruments and Sperry Rand, had proposed in 1972 displays using
circular polarizers with interdigitated electrodes on just one of the glass surfaces.
The concept of interdigitated electrodes was improved by the Freiburg Fraunhofer
Institute, which invented the in-plane switching (IPS) display in 1990 (Baur et al.
1990; Kiefer et al. 1992).
The electrodes are on the same cell surface, and, in the absence of a voltage, the
LC molecules lie parallel to the surfaces, which have the same rubbing direction,
so there is no effect on polarized light. Application of a field between the electrodes
induces a rotation on that cell surface, and a twist between the two surfaces.
However, fringe fields and the effect of tilt make the operation more complicated,
and can lead to increased response time. Moreover, each pixel needs two switching
TFTs, and in early versions this reduced the transmittance. IPS was studied by

Phil. Trans. R. Soc. A (2010)

 Review. Flat-panel electronic displays 1043

(a)

LC molecule

ridge vertical alignment film

(b)
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off

on

Figure 10. Operating principle of Fujitsu MVA-LCD (after Koike & Okamoto 1999). (a) Basic
concept. (b) Basic cell structure.

a number of laboratories in the 1990s, notably Hosiden, NEC and, particularly,

Hitachi (Ohe & Kondo 1995; Ohta et al. 1996). There are now a number of
variants in commercial production.
Though TN mode devices showed clear advantages over dynamic scattering,
several laboratories pursued other LC effects in the 1970s. Fred Kahn at
BTL proposed in 1971 a switching effect based on negative nematics aligned
homeotropically, i.e. at 90◦ to the cell walls, so that the electric field was parallel
to the long axis of the molecules, the cell being placed between crossed or parallel
polarizers. Application of the field will then cause the molecules to rotate through
90◦ , and the transmission through the cell will change (Kahn 1971, 1972). Kahn
showed that VT was given by equation (4.1), with k = k33 . For the LCs he used,
VT was 3 V, and the birefringence increased steadily as the voltage was increased
to 20 V. Though this seems a simple mode, the alignment requirements are severe.
The homogeneous alignment used in TN cells is readily obtained by rubbing the
glass surface in one direction. This creates microgrooves, and the long molecules
lie in them. For Kahn’s vertical alignment (VA) mode, it is necessary not only to
persuade the molecules to lie at 90◦ to the surface, but also to impose a slight tilt,
to give a source of defined anisotropy. This proved difficult to achieve over areas
practical for displays, and exploitation of VA awaited the sophisticated control
over LC that developed during the next 20 years. A number of improvements were
then proposed, one of the most effective being the Fujitsu multi-domain vertical
alignment (MVA) mode (figure 10).
In the off state, the molecules adopt a more-or-less homeotropic structure.
When voltage is applied, within each domain the molecules align orthogonally to
the raised structures, which are actually pyramids, so the light is channelled into
a cone, giving a wide angle of view.

Phil. Trans. R. Soc. A (2010)

 1044 C. Hilsum

500

400

£ millions
300

200

100

0
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1988 1990 1992 1994 1996 1998 2000 2002 2004 2006
year

Figure 11. Merck sales of liquid crystals.

The early thirst for LCs shown in figure 9 has not diminished. In 1979 world
sales were £5 million. In 2006 Merck, the dominant supplier, had sales of £500
million (figure 11) and their provisional figures for 2007 exceeded £700 million.
Two other large suppliers, Chisso and Dai Nippon Ink, are anticipated to have
sales of over £300 million, making a sales total of at least £1 billion in 2006. In
1979 sales were measured in grams. Today the measurement unit is tonnes.
Naturally, this growth has had to be served by much R&D on materials to give
better display performance. As I noted earlier, the most important parameters
to consider in designing an LC for displays are the temperature range of the
nematic phase, the magnitude of the elastic constants, the ratio of the bend
constant k33 to the splay constant k11 , and the viscosity η. Also relevant are the
magnitude and sign of the dielectric anisotropy ε, and the magnitude of the
birefringence n.
Though biphenyls and phenyl-cyclohexanes served the LCD industry well
during the first 15 years of development, there were obvious deficiencies in the
display appearance and multiplexing capability. One serious problem was the
resistivity, insufficiently high for large displays. LCs are insulating, but that is
a relative term, and to ensure that the pixel voltage does not drain away in
active matrix applications, the resistivity must be very high, above 1012 Ω cm,
and that rules out some otherwise promising families. Another problem was the
slow switching speed, with a failure to follow fast-changing images. The simple
remedy of reducing viscosity led to both a smaller operating temperature range
and a reduction in the dielectric anisotropy, giving a higher switching voltage.
After much research at Hull University and Merck, the inclusion of fluorine groups
was shown to give much improved performance (Gray et al. 1989; Reiffenrath
et al. 1989a,b; Coates et al. 1993). It should be noted that commercial LCs now
are mixtures of from 10 to 30 individual molecules, but a typical core material is
shown in figure 12. This material has a high ε of over 17, satisfactory for both
IPS and TN modes (Kirsch 2004).
The design of materials for vertically aligned nematic (VAN) mode poses
new problems, since they must have a large negative ε. It was known that
lateral polar substituents would lead to a dipole moment orthogonal to the long
axis, and again fluorine was the preferred substituent. The most useful materials

Phil. Trans. R. Soc. A (2010)

 Review. Flat-panel electronic displays 1045

H7C3 F

F F

Figure 12. A Merck superfluorinated terphenyl.

F F
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H5C2 C3H7

Figure 13. A Merck terphenyl with high negative dielectric anisotropy.

are difluorophenyl derivatives and more recently the difluorindanes have been
invented, giving a ε as large as −8. VAN switching times are longer than for
IPS or TN, and the cell spacing has to be as small as 3 μm. This, in turn, calls
for a larger value of birefringence, and this often results in high viscosity. A
good compromise is found in the terphenyl shown in figure 13, which has ε =
−2.5, n = 0.23 and η = 90 cP (Pauluth & Tarumi 2004). Additional fluorine
substituents give larger negative values of ε, but the viscosity is increased by a
factor of three or more.

(ii) Electrophoresis
The motion of solid particles in a liquid medium under the action of an
electric field has been studied for many years. It is an easy and inexpensive
technique, and is often used for species separation and for particle deposition
on substrates, as in painting large areas uniformly. The system becomes a display
when the particles have a colour that contrasts with that of the liquid. Typically,
white TiO2 particles in blue ink give a most impressive high-contrast image
(figure 14).
Electrophoresis (EP) was one of the early candidates for flat panels,
but research revealed several major disadvantages. The most serious were
gravitational settling, flocculation of the individual particles into clumps and
electrode staining. Staining appeared in time because a field sufficiently high to
move the particles towards an electrode would not always be sufficient to extract
it. Clumping gave a variation in mobility, so that a clump would have a slower
response time than a single particle. In any case, the drive voltage was higher than
for LCDs, and the response time slower. Some of the problems were summarized
by Hopper & Novotny (1979) from Xerox.
The effect was thought unpromising by the display community for several
years until the Nippon Mektron company suggested that microencapsulating the
particles would solve many of these problems (Osamu et al. 1987). There followed
refinements of this technique (Jacobson et al. 1997; Comiskey et al. 1998) until
today it is regarded as a leading candidate for electronic paper, which will be
considered later. The more general application to displays is less obvious, because
transmissive effects are poor.

Phil. Trans. R. Soc. A (2010)

 1046 C. Hilsum

light

+ conducting glass

– back electrode

light
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–
blue dye

particles +

Figure 14. Principle of electrophoresis.

(iii) Electrochromism
Striking colour changes are seen in some solids and liquids on the application of
an electric field. The first attempt to exploit such effects came in 1948 from Sziklai
(1948), a prolific inventor at RCA, who patented an electrically controlled colour
filter for TV cameras. The realization that this gave the foundation for flat-panel
displays came almost 20 years later, but then a number of laboratories produced
simple prototypes. Early in the field of electrochromic solids was American
Cyanamid (Deb & Shaw 1966; Deb & Witzke 1975) and ICI, which studied effects
in organic liquids in-house (Kenworthy 1971) and sponsored research on oxides
at Imperial College (Green & Richman 1974; Green 1976). The Philips Research
Laboratory, Eindhoven, made practical displays based on viologen derivatives
(Van Dam et al. 1972; Schoot et al. 1973).
The basis of the effect is a reduction–oxidation reaction, and for many years
the favoured materials were either simple salts or polymeric forms of bipyridyls
or, for the ‘solid’ displays, transition metal oxides. The oxide displays used
a fast-ion conductor as the electrolyte. The most-studied liquid system used
viologen derivatives, and operated by combining a plating reaction with a dye
reaction, so depositing a violet film on the transparent electrode. One advantage
of electrochromism is that it has memory, so that power is required only when the
data change. Unfortunately, this advantage is temporary, since the effect is not
absolutely reversible, and in time the electrodes become stained. Early viologen
displays had a short lifetime because of recrystallization. The first solid displays
used WO3 , but the response time was over a second. Combinations with Mo, V
and Nb gave different colours, and a move to liquid electrolytes improved the
response time to some tens of milliseconds, but the lifetime was too short for
general adoption. There might have been more sustained interest if the effect had
a threshold, but, as it was, multiplexing was difficult, and there was therefore
little advantage over the alternative effects.

Phil. Trans. R. Soc. A (2010)

 Review. Flat-panel electronic displays 1047

40
16
35
14
30
12

reflectivity (%)
25
10

contrast
20 8
15 6
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10 4
5 2
0
0 –5 –10 –15 –20 –25
voltage (V)

Figure 15. Electrowetting characteristic (after Hayes & Feenstra 2003).

New life has been given recently to the science of electrochromism by

the appearance of two important applications, electronic paper and variable
transmission windows. This interest has stimulated materials research, and
electrochromism in polymers has made much progress. However, the short life,
about 106 cycles, and the long response time of several hundred milliseconds,
remain as problems to be overcome before electrochromism can play a part in
dynamic displays.

(iv) Electrowetting
For a brief period after 1980 it appeared that the tide on the wisdom of
flat-panel development was turning in BTL as the influence of the opposing
senior managers diminished, and a novel approach was published. This was
based on inducing motion in a fluid by the application of an electric field.
Gerardo Beni and Susan Hackwood showed that a porous solid could be filled
with a liquid of the same refractive index, so that it was transparent. If the
liquid was then extracted from the solid, the pixel would be diffusely reflecting.
They found that visible changes occurred at applied voltages of about 1 V
with response times of a millisecond (Beni & Hackwood 1981). This promising
start was not pursued for long at BTL, but the technology was exploited in
microfluidics and tunable liquid microlenses. The circle was completed over
20 years later when Robert Hayes and Johan Feenstra, of Philips Research
in Eindhoven, proposed an electrowetting display of a rather different type.
The pixel was a white surface, which in quiescence was covered by a thin
film of coloured oil. Application of 20 V caused the film to curl into the pixel
corner, causing a marked change in reflectivity (figure 15). For small pixels the
response time was about 10 ms (Hayes & Feenstra 2003). The reflectivity is
much greater than that of LCDs, and approaches that of paper. In transmission
the technique may offer less advantage, but the application to electronic paper
is obvious.

Phil. Trans. R. Soc. A (2010)

 1048 C. Hilsum

emitting
centre
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Figure 16. Frustrated total reflection.

Understanding of electrowetting is incomplete, but some extensive reviews are

now available (e.g. Mugele & Baret 2005). Only certain surfaces demonstrate
the theoretically predicted behaviour, but as the technique acquires commercial
importance, it is likely that more detailed physical models will emerge.

(b) Emissive displays

The exploitation of emissive effects in solids raises an immediate problem. If
the solid surface is planar and the emitted light is incident on the interface at an
angle greater than sin−1 (1/n), n being the refractive index of the solid, the light
cannot emerge (figure 16).
The loss is serious for many semiconductors used in LEDs. For example, n
is 3.66 for GaAs, so the critical angle θc is only 16◦ , and only 4 per cent of
the energy radiated into a hemisphere reaches the outside world. Fortunately
refractive indices decrease as energy gaps increase, but even so only 10 per cent of
the radiation from a semiconductor emitting at visible wavelengths would emerge.
It is possible to reduce the loss in an LED by shaping the surface as a dome or
Weierstrasse sphere (Carr 1966), but that would not be simple for a display, with
perhaps 106 emitting pixels each less than 1 mm2 .

(i) Inorganic solid emitters

The conversion in a solid of electrical energy into light was first observed in 1907
by Henry Round, of Marconi, who saw yellow light emitted from a SiC crystal
when he applied a voltage to it (Round 1907). Round published his discovery
in an admittedly obscure journal, and it attracted little interest. In 1923 Oleg
Lossev at the Radio Laboratory in Nijni-Novgorod, unaware of Round’s work,
repeated the experiment, and published in higher-impact journals (Lossev 1923,
1928). Diode electroluminescence (EL) is therefore known as the Lossev effect.
LEDs are now universal, and it was natural in the early days of flat-panel R&D
to consider their relevance. LEDs are made with high density on single-crystal
substrates, and the size of the substrates is rarely more than a few centimetres
square. Assembling substrates on a large area and handling the interconnections
would be expensive, and there has been no serious attempt to fabricate a TV
display for sale (figure 17). Moreover, at a time when subtractive effects were
making slow progress, no efficient blue LED was available. Today a full range of
colours is available, and huge LED displays are seen in many sports stadia.

Phil. Trans. R. Soc. A (2010)

 Review. Flat-panel electronic displays 1049
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Figure 17. An early tour-de-force in LED assembly: multi-colour LED flat-panel display with
64 × 64 picture elements.

∼
Al top contact

ZnS (Mn) silicon nitride

indium tin oxide

glass substrate

Figure 18. Thin-film AC electroluminescent panel construction.

A more practicable approach to EL had actually come in 1936, when Destriau

(1936) applied an AC field to a capacitor made with ZnS powder immersed in
a dielectric. His device and the subsequent industrial versions were not used
extensively because of their short life at high brightness. Lower-brightness panels,
made by firing a coating containing ZnS particles on to a steel plate, were
marketed by GTE Sylvania, but their application was as night-lights, not displays.
The modern version of the Destriau panel, shown in figure 18, is made entirely
from thin films, avoiding most of the degradation processes of powders.
Above a critical field, typically 106 V cm−1 , insulating layers of ZnS will show
a rapidly increasing current with voltage increase, and they simultaneously emit
light. Generally manganese centres are incorporated in the ZnS to obtain yellow

Phil. Trans. R. Soc. A (2010)

 1050 C. Hilsum

emission, but other centres, such as rare earths, can also be used. The problem is
to operate the layer close to breakdown without risking current runaway. In the
AC device shown, only a limited amount of charge is permitted to pass through
the ZnS, and this amount depends on the capacitance of the dielectric. Clearly
the dielectric must not break down, nor must it demand too high a fraction of the
voltage drive. To ensure that the field in the ZnS is above the threshold required
for light emission ET and the dielectric is kept below its own breakdown field
EDB , the inequality
εD EDB > εZ ET (4.7)
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must be maintained, where the subscripts refer to dielectric (D) and ZnS layer
(Z) respectively. We have, for applied voltage VA ,
VA = EZ dZ + ED dD , (4.8)
with E representing field and d thickness. The EZ dZ product must dominate the
r.h.s. of this equation to give high efficiency at as a low a voltage as possible.
Charge continuity demands constancy of Eε products, giving us three conditions
for the dielectric films.

— The dielectric must be thin.

— The dielectric constant must be high.
— The breakdown field must be high.

Typically, for a dielectric with ε = 10, d = 2000 Å and breakdown field of 3 × 107
V cm−1 , operation at 250 V AC is satisfactory. These values must be achieved
simultaneously, i.e. the high breakdown field is needed in layers as thin as several
thousand ångströms, otherwise the efficiency will be low. I must emphasize the
need to optimize efficiency, which is, at best, only about 0.5 per cent. The external
efficiency is reduced by light trapping within the thin transparent film, which
can easily give a loss of an order of magnitude in such high refractive index
systems.
Such panels were made in 1974 by Sharp, and a few years later by Tektronix.
They each faced the breakdown problems with some success, but the only reliable
efficient phosphor available was ZnS doped with Mn, giving an excellent yellow,
but no good blue or red. A spin-off company from Tektronix, Planar Systems,
did report blue-green emission from SrS:Ce, but, in practice, only small AC
electroluminescent (ACEL) panels were ever produced in number because of the
competition from LCDs.
A major defect of the ACEL panel, which has excellent appearance, and can
be multiplexed to a high level, is the high voltage of operation. Special circuits
must be manufactured, and these add much to the cost of the panel. It should
be simpler, and cheaper, to drive the panels DC, but there are severe problems
in driving a large-area device near to breakdown without risking catastrophic
failure. A film that is non-uniform in thickness, composition or geometry will
obviously break down at weak points, either where the layer is abnormally thin,
or where there is field amplification at edges or points. If we construct a uniform
film, there is still the possibility of an S-shaped negative resistance (figure 19),
which leads to current concentration in filaments, with consequent breakdown
due to local heating.

Phil. Trans. R. Soc. A (2010)

 Review. Flat-panel electronic displays 1051

IF

current, I IB
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voltage, V
V

0
IF

Figure 19. Filamentary breakdown due to S-type negative resistance.

It follows that stable DC thin-film EL over a large area requires a layer that
adds a current-limiting resistance in series, the DC equivalent of the AC dielectric.
This must be done without adding appreciably to the operating voltage, with a
consequent reduction in the already low efficiency. The problem is not simple.
Successful DC electroluminescent (DCEL) panels were made, but these relied
on phosphor powders packed closely enough together to give conduction. In
addition, the ZnS:Mn powder had Cu added, and this was often in the form
of a surface-rich layer. In general, however, panels made in this way had low
brightness, low efficiency and short life. A major step forward was made by Aron
Vecht, who had led research on EL at Associated Electrical Industries, Rugby,
but left in 1968 when the company merged with GEC, and the responsibility for
EL passed to the Hirst Research Centre, Wembley. Vecht and some key members
of his team moved to Thames Polytechnic, later to become the University of
Greenwich, and there he invented an ingenious way of creating stable DCEL
panels (Vecht 1970; Vecht & Werring 1970).
The ZnS particles were coated with Cu, immersed in a polymethylmethacrylate
or nitrocellulose binder, spread over a glass plate previously coated with a
transparent conducting film, and having an Al or Cu electrode applied to the
surface to act as a cathode. The powder concentration is so high that a conducting
path exists between the top cathode and the transparent conductor.
The emitting region is formed by passing a current high enough to heat the
panel, and over a few hours the panel impedance increases. The applied voltage
is steadily increased from a few volts to a maximum value, typically 80–100 V,
to maintain the consumed power approximately constant. The electric current
passing through the panel produces a narrow high-resistivity light-emitting
barrier (typically a micrometre thick) near the positive front electrode film,
and it is the gradual formation of this region that causes the increase in panel
impedance. Presumably this region is formed because Cu diffuses away from the
anode (figure 20).

Phil. Trans. R. Soc. A (2010)

 1052 C. Hilsum

Al top contact

ZnS (Mn)
indium tin oxide formed layer

glass substrate
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Figure 20. A formed DC electroluminescent panel.

By 1980 Vecht had improved the performance of DCEL panels enough for
them to be considered for consumer applications. When driven at 100 V, they
gave an initial brightness of 300 cd m−2 , and had a life to half-brightness of over
15 000 h (Vecht 1982). Two problems prevented wider adoption. Though the Mn
emission spectrum was broad enough for good reds and greens to be obtained
by filtering, no efficient blue emitter was discovered. Rare earths did give a good
narrow blue line, but the solubility was too low for the emission to be useful. The
other problem was the cost of 100 V driver chips, and this made both ACEL and
DCEL uncompetitive. However, that situation changed when the potentialities of
organic materials for EL became apparent.

(ii) Organic solid emitters

There was little interest in EL in organic materials for some years after
Destriau’s work, but in 1953 one French group, led by Bernanose (1955), and
in close collaboration with Destriau, observed ACEL in acridine and carbazole
at voltages up to 2 kV and frequencies of 50 Hz. In 1960 Edward Gurnee and
Reet Fernandez of Dow Chemicals showed that a variety of organic compounds
could be used, and found that most light was emitted when the phosphor was
a host containing a doping agent or activator, and the colour depended on the
combination. A typical phosphor had anthracene as the host, with 0.1 per cent
tetracene as the activator. The EL cell operated off 800 V at a frequency of 2 kHz
(Gurnee & Fernandez 1960). By 1962 Gurnee had added a thin insulating layer
in the cell construction, thereby reducing the operating voltage to 110 V and the
frequency to 60 Hz (Gurnee 1962).
At about the same time we saw the first DCEL organic devices, when Martin
Pope4 used a thin crystal of anthracene with NaCl solutions as electrodes and
applied voltages of 400 V or more. It was apparent that the only way of passing
current through a material that was insulating at low voltages would be to
design injecting contacts, and the experiments had limited success (Pope et al.
1963). Dresner & Goodman (1970a,b) made some progress in 1970 with a tunnel
cathode, but the operating voltage was still nearly 100 V. The next forward step
4 MartinPope’s lifelong contributions to organic electronics are set out in http://chemxserver.
chem.nyu.edu/MPope/scientific%20History.htm.

Phil. Trans. R. Soc. A (2010)

 Review. Flat-panel electronic displays 1053

cathode
Mg::Ag
electron transport
layer
electroluminescent
layer
anode hole transport
indium tin oxide layer

glass substrate
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Figure 21. Organic LED schematic.

remained unacknowledged for several years, being described in a patent by Roger

Partridge, of NPL, in 1975 (Partridge 1975). He set out clearly the device design
for an organic LED (OLED): a low-work-function cathode, to inject electrons,
a high-work-function anode, to inject holes, and, between them, a luminescent
organic film, which he specified as being a polymer, such as polyvinylcarbazole.
Partridge’s patent is specific on the materials and thicknesses of the various films,
but he did not submit his work for publication until 1981, and his results were
not generally available until mid-1983 (Partridge 1983a–d). The delay was not,
of course, Partridge’s responsibility. The Government department to which NPL
reported, the Department for Industry, wanted to preserve publicity until they
could identify exploitation routes. The secrecy was compounded by entitling the
patent ‘radiation sources’, a catch-all phrase (R. H. Partridge 2009, personal
communication). This strategy would have been admirable if the Department
had then used its resources to secure industrial collaborators, but such efforts
as it made were unsuccessful. As a result, Partridge’s claim for priority has
only recently been acknowledged generally. He was the first to design and make
polymer LEDs (PLEDs) with injecting electrodes, though he did not specify the
advantages of using conjugated polymers, one key to later development.
Before Partridge’s paper appeared, others had made important contributions.
Significant was the work of Gareth Roberts’ group at Durham University, which
first obtained EL in 1979 from a Langmuir–Blodgett film of anthracene (Roberts
et al. 1979), and in 1982 used a vacuum-deposited film of anthracene less than
1 μm thick, and saw blue light at a voltage of 12 V (Vincett et al. 1982).
The potential of the field was now apparent, and many groups were working
on EL in small molecules or polymers. Noteworthy was the group at Kyushu
University, which seem to have been the first to obtain results from layered
devices, using cyanine dyes (Era et al. 1985), and then perylene films (Hayashi
et al. 1986). Members of this group, Chihaya Adachi, Shizuo Tokito, Tetsuo
Tsutsui and Shogo Saito, specifically prescribed the structure necessary for
low-voltage efficient OLEDs, shown as a schematic in figure 21. Early in 1988
they reported three-layer devices emitting blue, green and orange-red light from
anthracene, coronene and perylene respectively (Adachi et al. 1988).
The device is made on a glass substrate coated with ITO. ITO has a high
work function, and acts as the anode, injecting holes. The next layer must
transport holes (hole transport layer, HTL), but should also inhibit the passage of

Phil. Trans. R. Soc. A (2010)

 1054 C. Hilsum

electrons. Next to this layer is the electroluminor, where the holes and electrons
will recombine, and there is then an electron transport layer (ETL), inhibiting
hole passage. The final metal cathode has to be a low-work-function metal, such as
Mg:Ag. This structure is now fairly standard, though in some designs one material
can perform two functions. The physics underlying the work of the Kyushu group
cannot be faulted, but their embodiment did not perform well, with a very low
efficiency, a drive voltage of 50 V, and a life of only 5 h.
Adachi had been a PhD student at Kyushu, and he has continued to make
significant contributions to the field at various laboratories since then, returning
to Kyushu 4 years ago. His early collaborator at Kyushu, Tsutsui, remained there
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throughout his career, again making significant contributions until his recent
retirement. Their work has, perhaps, received less acknowledgement than have
the groups linked with industry, but both have certainly been major forces in
OLED development since its inception.
Ching Tang had worked at Eastman Kodak in the early 1980s on organic
EL cells similar to those developed for ACEL in ZnS, described in the previous
section. He had substituted tetraphenylethylene or similar organics for the ZnS,
held them in a polymer binder, and found that conduction was possible when
a layer of a porphyrinic compound was inserted between the anode and the
organic emitter. The cell operated at quite low voltages, around 30 V, but the
efficiency was well below 1 per cent (Tang 1980). He then abandoned the binder,
and in 1987, with Steven VanSlyke, published the classic paper on OLEDs,
with electrons emitted from an Mg:Ag cathode into a layer of Alq3 , tris(8-
hydroxyquinolinato)aluminium, with a layer of diamine acting as the HTL. The
Alq3 layer plays two roles, acting as both the electroluminor and the ETL. Green
light was emitted, with an efficiency approaching 0.5 per cent at 5.5 V. The life of
the device was 100 h, though the voltage had to be increased steadily to maintain
the light output (Tang & VanSlyke 1987). This paper has now been cited over
5000 times, and was followed by a string of publications and patents over the
next 20 years. Much of the progress in the field has been due to the work of them
and their colleagues at Eastman Kodak.
Alq3 has proved a critical component in most advanced OLEDs since its
favourable properties were shown by Tang and VanSlyke. It is a complex molecule
that can adopt a number of crystalline phases, but, since it is usually deposited
by evaporation, resulting in an amorphous film, control of the composition is not
easy. Moreover, though for many years it was believed that there was a single
isomer, it is now clear that there are two, one meridional and one facial, shown in
figure 22 (Cölle & Brütting 2004). The characteristic green emission is due to the
meridional isomer, and the facial, often present as a few per cent in amorphous
films, emits in the blue.
PLEDs had remained unnoticed after Partridge left the field. However, a group
at Cambridge University, led by Richard Friend, had become interested in the
possibility of OLEDs, but believed that the Kodak approach had an inherent
problem of structural instability due to recrystallization. They thought that a
better luminor would be a polymer, and, in particular, a main-chain conjugated
polymer. They noted the ease with which thin films of polymers could be prepared
by spin-coating, and in 1990 made simple diodes, with poly(p-phenylene vinylene)
(PPV), a polymer known to show bright green photoluminescence, spun onto
ITO-coated glass, with a cathode of Mg–Ag. The devices emitted green light at

Phil. Trans. R. Soc. A (2010)

 Review. Flat-panel electronic displays 1055

(a) (b)
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Figure 22. Isomers of Alq3 : (a) meridional; (b) facial (violet, Al; red, O; blue, N; after Cölle &
Brütting 2004).

15 V, albeit at low efficiency, and with a life of a few days (Burroughes et al.
1990; Friend et al. 1990). Their publication attracted much attention, and the
approach was followed by a number of laboratories. Alan Heeger, later to receive
a Nobel Prize for the discovery of conductive polymers, modified both the PPV
polymer and the cathode, and obtained an efficiency approaching 1 per cent
(Braun & Heeger 1991).
There was early realization that the simple sandwich was unlikely to provide
the environment needed for high conversion efficiency, with equal numbers of
electrons and holes available for recombination in the polymer luminor. There
seemed to be some resistance to designing a cell with the full gamut of layers
shown in figure 21, though Friend, with colleagues including Adam Brown, Jeremy
Burroughes and Donal Bradley, did show that an ETL of biphenylylbutylphenyl
oxadiazole (butyl PBD) gave improved efficiency (Brown et al. 1992). Adachi had
previously shown that butyl PBD performed well as an ETL in blue-emitting
OLEDs (Adachi et al. 1990). It was also appreciated that acceptable device
lifetime could be achieved only if the cells were encapsulated to protect them
from the effects of oxygen and moisture. This was particularly necessary if Ca
was used as a cathode, capitalizing on its low work function. There followed a
period of steady progress in both efficiency and lifetime, and the use of a variety
of luminors to give a full range of colours.
By the turn of the century both organic (OLED) and polymer (PLED) devices
had made such progress that commercial exploitation appeared likely. Efficiencies
of both types and of all colours were well above 1 per cent, and some designs
were giving life at constant current of over 10 000 h. There was some concern that
the drive voltage almost doubled during that period, and this would certainly
complicate incorporation in multi-pixel panels. Blue devices were still lagging in
performance and lifetime, but it was thought that this problem would yield to
increased research. Commercial interest of Kodak had always been high, and in
the UK Cambridge University spun out Cambridge Display Technology (CDT)
to exploit PLEDs. Many of the world’s electronic companies were beginning to
become involved.

Phil. Trans. R. Soc. A (2010)

 1056 C. Hilsum

Efficiency lagged behind desired specifications for brightness. The refractive

loss analysed at the beginning of §4b was not easy to overcome, but several
remedies were tried. Almost half the loss came because most of the light emitted
away from the anode was lost. Composite metal–dielectric layers could reduce
this loss. The plane glass surfaces could be etched to give scattering, or low-index
aerogels interposed (Smith & Hilsum 2003). Microlenses could be attached to
the surface, though this would prove problematic for small pixels on large areas.
One remedy that attracted considerable effort was the concept of microcavities.
This entails forming Fabry–Perot etalons at each pixel by interposing a dielectric
mirror stack between the glass and the ITO. This should give directionality, and
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in principle enable most of the radiation that is produced by recombination to

emerge. There are two obvious problems. One is the need for different mirror
stacks for each pixel colour. The second is the need for an appreciable angle of
view (Peng et al. 2003; Shiga et al. 2003).
Though the refractive loss is serious, it does not account for the relatively low
internal efficiency. The excitons formed in the process of recombination take either
a singlet or a triplet spin configuration, and simple theory indicates that the ratio
of these states is 1 : 3. Unfortunately the more numerous triplet states are non-
radiative, so that the maximum internal EL efficiency would be 25 per cent. Since
an isotropic emitter with the refractive index of PPV or Alq3 could emit into the
outside world only 25 per cent of the photons produced, the maximum external
efficiency could not exceed 6 per cent. Measurements confirmed that the singlet
fractions in Alq3 were near 20 per cent (Segal et al. 2003). The situation was not
as serious for polymers, for early measurements showed that the singlet/triplet
ratio could be as high as 50 per cent, and detailed theory indicated that the
actual ratio would depend on the polymer, and in particular on the energy gap
(Wilson et al. 2001). There was, nevertheless, good reason to explore methods for
reducing or eliminating non-radiative recombination for both OLEDs and PLEDs.
Two approaches proved effective.
The first proposal for reducing the effect of the non-radiative triplet states came
from Herbert Börner and his colleagues at the Philips Laboratory in Aachen.
They filed a patent in 1994 suggesting that the OLED should incorporate a
phosphor having emitting triplet states at energy levels available for transfer of
energy from the luminor non-radiative triplet states (Börner et al. 1995). Though
Börner clearly appreciated that this should give an improvement in performance,
he gave no details of any gain he actually achieved, and there was no subsequent
publication. The concept of exploiting phosphorescence was more clearly stated
by the group at Princeton University led by Steve Forrest and including Mark
Thompson and Paul Burrows. The group had previously shown that organic
devices suffered severe degradation if exposed to the atmosphere during life,
and demonstrated the improvements on encapsulation (Burrows et al. 1994).
They now played the major role in establishing the science of phosphorescent
doped OLEDs, or PHOLEDs, and filed a number of patents and published many
papers from 1997 onwards (Thompson et al. 1997; Baldo et al. 1998; Baldo et al.
2000). Thompson had moved to the University of Southern California (USC) in
1995, but he still worked closely with Forrest’s group in the search for efficient
OLEDs, and their results were exploited via a collaboration with United Displays
Corporation (UDC), a company founded in Ewing, near Princeton, in 1994.
UDC has grown to be one of the major suppliers of materials to the display

Phil. Trans. R. Soc. A (2010)

 Review. Flat-panel electronic displays 1057

N
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Figure 23. Schematic of a starburst dendrimer.

industry. The invention of phosphorescent doping played a major role in achieving

commercially viable OLED efficiencies, and world efforts are well summarized in
Holder et al. (2005).
The second initiative was relevant to PLEDs. In the 1980s, Dow Chemical
developed and trademarked Starburst dendrimers, a novel type of three-
dimensional polymer with hollow interiors and surfaces that can be closely packed
with a variety of molecules (figure 23).
The materials are extremely versatile, spanning many structural and functional
applications, and if the right molecules are incorporated, they are efficient
phosphors. The team that decided that dendrimers could make efficient
PHOLEDs was led by Paul Burn and Ifor Samuel. Burn had earlier been a
member of the Cambridge University PLED team, but moved in 1992 to the
University of Oxford, hoping to develop conducting dendrimers. Samuel had set
up his own group at the University of Durham in 1995, with an interest in light-
emitting dendrimers. Together they showed that dendrimers could be designed to
give efficient blue, red and green PLEDs, and founded Opsys in 1997 to exploit
their ideas (Samuel et al. 1998; Ma et al. 2002; Burn et al. 2007). CDT bought
Opsys in 2002, appreciating that dendrimers could be effective in improving the
performance of their PLEDs, and could be deposited by spin-coating or ink-jet
printing, Some of their current commercial PLEDs incorporate dendrimers.
Another pioneer in this application of dendrimers was Jean Fréchet, who had
earlier developed photoresists for integrated circuits, and later used dendrimers
for drug delivery and tissue scaffolds (Gilat et al. 1999; Adronov & Fréchet 2000).
A development that may well affect the future design of OLEDs came from
the Technical University of Dresden, where Karl Leo, Jan Blochwitz and Martin
Pfeiffer had been considering the analogy of OLEDs with inorganic LEDs. They
thought that the operating voltage of OLEDs was unnecessarily high because
of the two blocking layers inherent in all previous designs. Their aim was to
make an organic p-i-n diode, with holes injected from the anode into an intrinsic
region where they would combine with electrons injected from the cathode.

Phil. Trans. R. Soc. A (2010)

 1058 C. Hilsum

Table 4. Performance data for commercial OLEDs and PLEDs.

efficiency efficiency efficiency life (h) CIE

(Cd A−1 ) (%) (l W−1 ) at 1000 cd m−2 coordinates

red
CDT 30 more than 260 000 0.63, 0.37
UDC 28 20 330 000 0.64, 0.36
Kodak 12 8.5 more than 70 000 more than 0.66
Novaled 12 12 10.6 more than 500 000 0.68, 0.31
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blue
CDT 9.4 10 000 0.14, 0.14
UDC 9 4 0.14, 0.13
Kodak 8 6.7 10 000 0.14, 0.15
Novaled 9 5.5 8.4 0.14, 0.23
green
CDT 21 110 000 0.29, 0.64
UDC 67 19 250 000 0.38, 0.59
Kodak 30 8.7 65 000 0.25, 0.66
Novaled 95 23 116 0.31, 0.66
Taiwan group 61 17.6 32 0.29, 0.62

Obviously this entailed controlled p- and n-doping of the appropriate layers.

They accomplished this not by adding donor and acceptor elements, but by
molecular doping, and in a series of publications from 1998 to 2003 reported that
controlled doping was possible (Pfeiffer et al. 1998; Werner et al. 2003). A spin-out
company, Novaled, was founded in 2003, and this has now become a major player
in the field, specializing in PIN-OLEDs. Since the improvement comes from the
contact layers, advances in either dendrimers or phosphorescents can be exploited
in the intrinsic region of the diode, so Novaled works on both polymer and
small-molecule LEDs.
The current state of the art is shown in table 4. Some caution is appropriate
here. The result from Wei-Sheng Huang, Jiann Lin and Hong-Cheu Lin, in
Taiwan, though a striking achievement, may not indicate commercial potential,
because life data are not provided (Huang et al. 2008). On the other hand,
information from companies may not represent the true state of their art, because
commercial confidentiality may restrain them from revealing the full extent of
their capabilities. The commercial competition is very fierce, and as a result it is
difficult to give the composition of the materials favoured for devices, for either
POLEDs or OLEDs. In any case, today’s materials are likely to be supplanted in
the near future by new formulations.
There remain several serious hurdles to overcome in the application of these
devices. Spin-coating was thought to give PLED manufacture an advantage over
OLED sublimation, but colour patterning is not simple, and several companies
have concentrated on ink-jet printing. Similarly, mass production of large areas
by sublimation is not cheap, and UDC has pioneered organic vapour-phase
deposition (OVPD), as used for many years for compound semiconductors

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 Review. Flat-panel electronic displays 1059

(Forrest 2004). They showed that this gave good results for PHOLEDs, and
worked with Aixtron, which now sell OVPD commercial production equipment.
Kodak, for their part, have developed vapour injection source technology, which
they claim is suitable for large-area production, and is more economic than
sublimation (Kyoshi 2006).
One important recent development that could either improve the future
prospects of flat-panel organic displays or act as a considerable diversion of
resources is the realization that organic diodes could be efficient domestic
and commercial sources of illumination. Tungsten filament lamps have a light
production efficiency of less than 20 l W−1 , or 3 per cent, and fluorescent tubes
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give at best 100 l W−1 (15%). Since lighting constitutes a high proportion of a
country’s energy needs, government interest in this field has grown rapidly, and
has been accompanied by generous financial support. It is no surprise, then, to
see the major display players establish lighting divisions. The two applications
have much in common, but there are significant differences. The most obvious
is colour, where the illumination need is for a white, or ‘warm white’ panel,
and here progress has been rapid. Many laboratories have reported white LEDs
with external quantum efficiencies of 15 per cent, and the University of Dresden
obtained an efficiency of 90 l W−1 , with the prospect of 124 l W−1 if measures were
taken to reduce the total internal reflection (Reineke et al. 2009).

(iii) Gas plasma discharge

Light emission from gas discharges is over 200 years old, and the use of inert
gases to give specific colours dates back over 100 years. The first attempt to exploit
the effect in a display was made 40 years ago, when Don Bitzer, Gene Slottow and
their colleagues at the University of Illinois proposed a display panel in which the
discharge was restricted to local areas by a glass sheet containing small holes. This
was interposed between two more sheets on which anode and cathode electrodes
had been deposited as row and column electrodes (Bitzer & Slottow 1966; Bitzer
et al. 1966). The first panels used neon, but soon the standard design used UV
emission from xenon to excite phosphors giving red, blue and green pixels.
In modern panels the column electrodes are deposited as metal stripes on a
glass substrate, and above them are a series of parallel ridges, dividing the display
area into a number of narrow troughs. The sides of the troughs are coated with
the phosphors (figure 24). The row electrodes are ITO stripes on the glass sheet
that forms the top of the panel. The I –V characteristic of a gas discharge is an
S-shaped negative resistance, and the working point is determined by the resistive
load line. It is possible to energize the pixel by a certain voltage, and sustain it by
a lower voltage, so often there are two sets of row electrodes. The driving voltage
is 2–300 V.
Though the ridges reduce optical crosstalk, a fault of the original design,
electrical charges on a pixel can influence neighbouring pixels in the same trough.
This can be reduced by shaping the row electrodes, or, in the limit, by isolating
each pixel cell. Nevertheless, it has proved very difficult to reduce the pixel
dimensions below 0.5 mm, so that a high-resolution display smaller than 30 inch
diameter is impracticable. On the other hand, very large displays are possible,
and in the early period of flat-panel development, the large-panel market was
dominated by plasma panels.

Phil. Trans. R. Soc. A (2010)

 1060 C. Hilsum

ribs

red green blue

phosphor phosphor phosphor

metal data
glass substrate
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electrodes

Figure 24. Schematic of phosphor arrangement in a plasma panel.

A brightness of 1000 cd m−2 was readily available, with excellent colour

rendering, a wide viewing angle and a rapid response time. However, the efficiency
of light production was low, so the power consumption was as high as for a CRT.
Moreover, the need for high voltages made the electronics quite expensive. For
some years plasma panels had a reputation for short life. The phosphors degraded,
and the blue material was particularly bad. A life of 10 000 h was not uncommon,
though manufacturers today would claim a much improved performance. One
other fault has proved more difficult to overcome. This is the tendency for the
display to hold the memory of a persistent bright image.
Commercial interest in plasma display panels (PDPs) was high from 1990
onwards, with first Fujitsu in the lead and then competition entering from many
Far Eastern companies. By 2004 normal economics reduced those interested to
Fujitsu–Hitachi, Pioneer, LG, Samsung and Panasonic, with the last two holding
two-thirds of the market. In 2008 Panasonic claimed to have made the largest flat-
panel display in the world, with a 150 inch diagonal (Ashida et al. 2008). The PDP
market grew from 2000, as the lure of the CRT was fading, and the advantages
of the LCD had yet to become apparent. The superb performance of the panels
convinced many that the device had a promising future, but the manufacturing
problems were not common knowledge. In fact, it was a difficult device to make
in large quantity, and the cost of production was high. The emergence of rival
display effects persuaded Pioneer and Fujitsu to abandon plasma panels early in
2009, and the fact that the total market is reducing may well mean that plasma
panels will become a niche commodity.

(iv) Flat cathode ray tubes

The engineering world had been very conscious in the mid-1900s of the
disadvantages of the CRT display, and it was not sitting idly by waiting for
an alternative to appear. The main problem was the cumbersome shape, which
was a great hindrance in moving to a larger screen size. The designers of a flat
replacement had to face at least two severe problems. The first was to arrange
the gun, itself quite long, within the depth of the tube, and then deflect the beam
through two right angles without losing focus. The activation of the phosphors
available at that time required almost 10 kV, and the beam current needed for a

Phil. Trans. R. Soc. A (2010)

 Review. Flat-panel electronic displays 1061

40 inch screen would approach a milliampere. Such beams are difficult to deflect.
The second problem is the vacuum within the tube. Safe practice demands that
the thickness of the glass face plate must be at least 1/15 of the unsupported
width, so that a 30 inch diagonal flat panel would need two plates over an inch
thick and would weigh nearly 50 kg. One solution is to use supports bridging the
gap, but these may interfere with the picture.
One prolific inventor who attempted to find a solution was Dennis Gabor, a
Hungarian who first worked for Siemens in Germany, but came to the UK in 1934,
and later earned a Nobel Prize for holography. His interest in CRTs was shown by
a number of patents, including some on tubes that had ‘relatively small depth’,
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but had an elliptical cross section to accommodate the electron gun (Gabor 1955,
1956, 1957, 1959). He did not claim a truly flat tube until 1962 (Gabor 1962;
Gabor et al. 1968).
The other early inventor was Ross Aiken, who started his research in 1951,
but waited to file patents until he was sure he had the best design, and could
get financial support for the development. He secured that support from Kaiser
Aircraft in 1953 (Aiken 1984), but when he filed his patent in December (Aiken
1953), he learned that Gabor had anticipated him. There followed a patent battle,
which was resolved with Aiken having the US rights, and Gabor the rights in the
UK. Neither tube was ever produced on a commercial basis.
Ten years later RCA mounted a serious programme aimed at a 40 inch flat-
panel colour CRT. Two approaches emerged. In that led by John Endriz, an
x-array of 500 line cathodes fed electrons into 480 vanes of secondary emission
multipliers (Cosentino et al. 1979; Endriz et al. 1979). The other team, including
Tom Credelle and Tom Stanley, favoured a normal thermionic cathode injecting
electrons into a series of box guides at 90◦ to the line of the gun. These boxes,
which acted as supports between the two display faces, contained a series of plates
to deflect the electrons through a further 90◦ on to the phosphor (Stanley 1975,
1977; Siekanowicz et al. 1976; Credelle 1977).
Other attempts were made by Texas Instruments (Scott 1977) and Siemens
(Graefelfing et al. 1968), but by 2000 it was generally appreciated that the
problems of brightness, resolution and display size could not be met in displays
that would be competitive commercially. Any solution would have to come from
a design that bore little resemblance to the CRT. No matter how clever inventors
were in twisting and bending electron beams, the obvious way forward was to
make a cathode that was itself a plane, and that could be arranged parallel to
the phosphor screen. It would be difficult to do this with a thermionic cathode
array, since the screen would itself get hot, not a desirable attribute.
Ken Shoulders and Louis Heynick, working at the Stanford Research Institute
(SRI), were the first to appreciate that the answer could come from cold cathodes,
with the field required to extract electrons reduced by shaping the cathode into
a point. They made small cathodes as a clump of needles of molybdenum or
tungsten, formed by coating the surface with aluminium, and then heating until
the Al melted (Shoulders & Heynick 1966a,b). They observed that surface tension
then caused material to migrate into the needle shapes, but candidly admitted
that they did not understand the mechanism. A few years later Capp Spindt
collaborated with Heynick to invent a more practicable manufacturing method
(Spindt & Heynick 1970). They evaporated Mo on to a plane surface, and used
an ingenious shadowing technique to form minute cones (figure 25).

Phil. Trans. R. Soc. A (2010)

 1062 C. Hilsum

metal cathode
metal gate
silicon oxide

silicon substrate

Figure 25. Schematic of the Spindt cathode.

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Their success caused many others to join in the search for a flat CRT, and the
Spindt cathode became the standard basis on which flat CRTs were developed
(Spindt et al. 1991). A number of companies were formed to make devices, but
their success was limited, and most saw a period of serious investment before it
was realized that the technical problems militated against commercial success.
Monochrome tubes were made, in sizes up to 12 inch, and colour tubes were
described as producing a picture equal to that of a normal CRT. However, it
was difficult to get sufficient sustained emission for a screen brightness above
500 cd m−2 , and production costs were high. The major player was Candover,
effectively a spin-off from SRI founded in 1990, which attracted funding of over
$300 million. In 2004 they sold their technology to Canon for $10 million, and
abandoned the field. PixTech, a French spin-off from LETI in Grenoble, with a US
subsidiary, was founded in 1992, and they also tried to market displays using their
own version of Spindt cathodes. They had a limited success, and demonstrated
15 inch colour tubes at exhibitions in 1999, but there has been little activity in
the last five years.
Among the companies interested in cold cathodes was the UK General Electric
Company (GEC). Their main potential application was microwave tubes, but
they were conscious of the display possibilities. A group at the Hirst Research
Centre led by Rosemary Lee first concentrated on making microtips from silicon,
since they thought that the production techniques were simpler than those for
Spindt cathodes. They did succeed in making efficient cathodes that were stable
(Lee et al. 1989), but it was clear that this technique could not give cheap large-
area sources. However, in 1987 the group also invented a planar version, which
was potentially suitable for large-area metal cathodes (Lee & Cade 1987, 1988;
figure 26).
There was clear merit in a surface structure that attracted electrons parallel
to the surface and scattered a proportion of those incident on the anode towards
a second anode on the other side of the panel. The surface emitting display
(SED) could be fabricated by the techniques perfected for chips, albeit on a
larger scale. Many variants of the planar cathode were invented subsequently, with
the lead taken by Canon and Futaba. Futaba, with a history of manufacturing
small vacuum fluorescent displays, showed that carbon nanotubes deposited on
the surface gave a larger and more stable current than metal edges (Itoh et al.
2007). Canon also made steady progress. They teamed first with Toshiba, and,
after this collaboration ended because of a legal dispute with Applied Nanotech,
with Hitachi and Matsushita. At regular intervals after 1998 it was announced
that commercial production was imminent, with the press releases after 2006

Phil. Trans. R. Soc. A (2010)

 Review. Flat-panel electronic displays 1063

silicon oxide
metal anode
metal
gates

metal
cathode

silicon
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sapphire

Figure 26. Schematic of the GEC planar cathode.

given weight by the impressive panels shown at exhibitions. In 2006 Canon

demonstrated a panel with a brightness of 450 cd m−2 , a contrast ratio of 50 000 : 1
and a response time less than 1 ms. However, 3 years later there is still no sign of
commercial production of TV panels. Obviously the SED is not easy and cheap
to make.

5. Components for addressing

In §2 I discussed the need for an electrical nonlinear component to be

integrated on the panel. This need came to the fore in the 1970s, when the
potential of LCD panels was becoming apparent, but there was no candidate
component for addressing. It must be admitted that this caught the international
semiconductor expertise off balance, in that almost all effort had been directed
at growing large perfect single crystals, and then depositing thin layers of
controlled purity epitaxially on the crystal slices. Materials experts felt that glass
substrates were incompatible with silicon, germanium and the III–V compounds,
and those semiconducting compounds that could be deposited on glass, like
cadmium selenide and zinc sulphide, would never give stable performance for
the several years that companies expected. Instead they turned to metal–
insulator–metal sandwich diodes, with combinations like Ta/Ta2 O5 /Cr, or glass
switches, made of combinations incorporating chalcogenides, such as GeAsTe
(Ovshinsky & Fritzsche 1973; Adler et al. 1980). Though some of the research
on these components was generously funded, and enjoyed collaboration with
internationally renowned physicists, stability, reproducibility and long life were
never obtained.
The solution came from the semiconductor workhorse, silicon, but in an
unusual form. In the 1960s, a group led by Henry Sterling at the Standard
Telecommunications Laboratory at Harlow had shown that the glassy form of
Si, normally considered an insulator, could be made partially conducting if thin
films were deposited in a hydrogen atmosphere (Chittick et al. 1969). The research
was continued at Dundee University by Walter Spear and Peter LeComber, and in
1975 they showed that the conductivity could be controlled by the addition of the
same impurities as were used for doping crystalline Si (Spear & LeComber 1975).

Phil. Trans. R. Soc. A (2010)

 1064 C. Hilsum

source drain amorphous silicon

insulator
gate
glass
substrate

Figure 27. The first amorphous silicon thin-film transistor.

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10–4

10–6
current (A)

10–8

10–10

10–12
–10 0 10 20 30
voltage (V)

Figure 28. Electrical characteristics of the first a-Si TFT, made at Dundee University.

This discovery inspired worldwide efforts that led to the first practical solar cells.
At that time, the interest in renewal energy was beginning to gain momentum,
and it was not surprising that Spear saw that his priority should be a focused
strategy aimed at keeping his research group at the head of the international a-Si
solar cell effort, leading in the basic physics.
The Displays Group at the Royal Signals and Radar Establishment (RSRE),
Malvern, had a different view. They saw a UK laboratory in possession of the
key to addressing displays. They were sure, following instinct rather than science,
that a-Si TFTs would work with LCDs, but they lacked the facilities for making
the devices, no easy task. Persuading Dundee to collaborate, while their eye was
on a different ball, took many months. In any case, Spear had reservations about
collaboration with non-academic organizations (Adams 2009). It was LeComber,
without Spear’s blessing, and possibly without his knowledge, who eventually
made the original a-Si TFTs, and supplied the first batch to Malvern. RSRE
switched LCD pixels with them on Xmas Eve, 1978. The structure of the TFT and
its characteristic are shown in figures 27 and 28 (P. G. LeComber 1978, personal
communication). Later work at Dundee and Malvern confirmed the potential of
a-Si for displays (LeComber et al. 1979; Snell et al. 1981).

Phil. Trans. R. Soc. A (2010)

 Review. Flat-panel electronic displays 1065

Neither group was able to gain financially from this development, because the
original Weimer patent covered the TFT as a device, and did not specify any
particular semiconductor. The two groups consulted patent experts, but were
advised that an attempt to license the invention would certainly involve legal
action, which they were unlikely to win. So this discovery, which is still widely
used worldwide, brought no direct economic benefit to the UK.
Though the basis for progress was now established, there were many hills to
climb before industry was convinced of the virtues of this new approach. One
major advantage was the use of silicon, for industry knew that this semiconductor
was stable, unlike the sulphides and selenides previously on offer. This conviction
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was not severely undermined by reports of changes in solar cell performance

during prolonged exposure to sunlight. The cause of this effect, first reported by
Staebler & Wronski (1977), is still obscure, and it was not highlighted during the
early days of a-Si addressing. Indeed, the protagonists of more exotic materials
like CdSe for TFTs could well have argued that the playing field was not level,
for they were criticized for changes in device properties during life that were no
worse than those for a-Si (Weimer 1962a; Lee et al. 1992; Brody 1996). However,
fair play was never a feature of displays commercialization, and it is true that
much research and huge funding ensured that stability was eventually obtained,
at least in a-Si arrays for LCDs. Nevertheless, it was many years after the first
pixel was switched at Malvern before large arrays could be produced in industry
with a high yield.
Amorphous silicon has proved essential in the progress of flat-panel displays,
but its semiconductor properties are undistinguished. In particular, the field effect
mobility is rarely as large as 1 cm2 V−1 s−1 , a thousand times lower than that of
crystalline Si. This means that the material can be used only for the addressing
switches. The display requires drivers and data control circuitry as well, and if a-
Si is used for the switching, standard chips have to be fixed to the panel. A dream
of the early workers was that a semiconductor would be found that would have
a high enough mobility to accomplish all the necessary operations. The mobility
needed was at least 10 cm2 V−1 s−1 .
The answer came from standard chip production, where polycrystalline Si
layers were routinely deposited by chemical vapour deposition (CVD) of silane,
though the deposition temperatures were well above the softening point of glass.
However, it was discovered by Doug Meakin and Piero Migliorato at GEC,
Wembley, in collaboration with Nico Economou of the University of Thessaloniki,
that lowering the chamber pressure from the standard 26.6 Pa to below 1.3 Pa
allowed growth at under 600◦ C of polycrystalline Si films with a mobility of
10 cm2 V−1 s−1 (Meakin et al. 1987). This triggered other laboratories to work
on poly-Si, with an emphasis on alternative production methods. The favoured
method was laser annealing of a-Si, and mobilities gradually increased. The
leading companies were, and still are, Seiko–Epson (Jiroku et al. 2004) and Sony
(Sekiya et al. 1994), and both have reported poly-Si TFTs with mobilities of
several hundred cm2 V−1 s−1 . Seiko was using the TFTs for integrated drivers.
The two companies may well combine their display activities soon.
Though the electrical properties of poly-Si are surprisingly good for a film
containing many grain boundaries, the production process is costly, and has not
been used for large displays. Alternatives are being sought. Research has been
reported on several semiconducting oxides, including zinc oxide and indium oxide,

Phil. Trans. R. Soc. A (2010)

 1066 C. Hilsum

each of which can have field mobilities much greater than that of a-Si (Levy et al.
2008; Park et al. 2008; Wang et al. 2008). In addition, progress on semiconducting
organics for LEDs has led to interest in fully organic back planes, and a number of
organic TFTs have been reported. CDT, using 6,13-bis(triisopropylsilylethynyl)
(TIPS) pentacene, has made TFTs with a gate width of 50 μm and mobility up to
1.8 cm2 V−1 s−1 , with little reduction for gates as narrow as 5 μm, demonstrating
the low contact resistance, a key point in organic TFT research. CDT has also
obtained, using a proprietary material from Merck, a TFT with mobility above
3 cm2 V−1 s−1 (J. H. Burroughes 2009, personal communication).
Though early work aimed at replacing a-Si TFTs, and used glass substrates,
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more recently there has been emphasis on solution or ink-jet printing, and
deposition on plastic substrates for flexible displays. An early leader was Plastic
Logic, spun out from the Cavendish Laboratory, which has made TFTs by
ink-jet printing on plastic substrates with mobilities approaching 1 cm2 V−1 s−1 .
Another forward step has been the formulation by CDT, in collaboration with
Silvaco Data Systems, of an equivalent to the SPICE simulator for electronic
device automation. There is little information on the life of organic or polymer
TFTs, though it would be surprising if this were as good as for a-Si or poly-Si,
particularly for devices on plastic substrates.

6. Applications

The spectrum of modern uses of flat-panel displays ranges in size from

microdisplays, requiring optical assistance to view them, to the huge displays
now common in sports stadia, and it encompasses many types of embodiment.
Though there may well be significant differences in the types of visual effect
used for some applications, I will here concentrate on a few applications that
demonstrate the breadth of the technology.
It should not be forgotten that even a simple flat panel may yield a considerable
advantage in cost and complexity over alternative ways of presenting data.
For example, long before active matrix techniques were available, automobile
manufacturers were considering incorporation of LCDs or EL panels into the
driver’s display. Not only was the thickness of the display reduced from 60 to
12 mm, but the number of parts and processes came down from 430 to 35.

(a) TV panels
There were two trends in the consumer market after 2000 that resulted in
the demise of CRT TV sets. The first was the realization by computer users
that a flat panel gave them extra desk top space. They were willing to pay a
considerable premium in price for this privilege. The second was the desire of
households worldwide to view a bigger TV picture. There was absolutely no fault
with the CRT picture—it was bright, sharp, could be viewed at all angles, and
was inexpensive. Certainly the brightness and colour purity faded with time, but
many households were happy to keep the same set for ten years or more. The
change happened very rapidly. It was, of course, made possible by the improved
skills of the manufacturers, which learned how to make a-Si TFTs with high yield
over large areas, illustrated in figure 29.

Phil. Trans. R. Soc. A (2010)

 Review. Flat-panel electronic displays 1067

125

100
diagonal inches

75
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50

25

0
1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006 2007
year

Figure 29. The growth in manufacturing capability of active-matrix LCD panels.

Figure 30. A 150 inch Panasonic plasma panel TV.

The results on sales were surprising. In the UK, Dixons, then the largest
retailers, reported that in 2004 nearly 90 per cent of the TV sets sold were CRTs.
In 2005 the percentage had dropped to 20 per cent, and in 2006 had dropped
to 5 per cent. Dixons stopped selling CRT TVs the next year, and were shortly
followed by other retailers. However, CRTs still retain niche markets, particularly
when high resolution is required.

Phil. Trans. R. Soc. A (2010)

 1068 C. Hilsum

100

80
liquid crystals

60
$ billions

40
cathode ray
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20
plasma panels

0
1986 1988 1990 1992 1994 1996 1998 2000 2002 2004 2006 2008
year

Figure 31. World sales of flat panels, 1986–2008.

The move towards larger TVs had benefited plasma panels (PPs), which were
previously reserved for specialist applications, but after 2000 they dominated the
flat-panel TV market for screens larger than 40 inch. By 2006 the available PP size
was just over 100 inch, though larger panels had been demonstrated (figure 30).
Very large LCs were, however, also becoming available.
The two technologies now compete aggressively in the market for large TVs,
with each having protagonists in their views on the excellence of the picture.
PPs certainly had an early edge here, but LCD manufacturers have made many
improvements in back lighting, power consumption and angle of view, so that
there is now little to choose between them. The current market position is shown
in figure 31.
PPs will face great pressure from LCDs and OLEDs in the future. LCD
manufacturers are investing heavily in increasing capacity and reducing costs by
standardizing on huge glass areas, and the sheet of glass from which displays are
cut is now Generation 10, 2880 × 3130 mm (figure 32). Corning plans to invest
over $400 million in a plant for Sharp at Sakai City. Samsung does not intend
to lag. Their plans are for a plant using Generation 11 glass, 3000 × 3320 mm,
which would give six 72 inch LC panels from one sheet.
The outlook for OLEDs in TV is not certain. Though impressive OLED panels
have been shown in exhibitions for a number of years, the UK consumer had to
be patient until early in 2009 before they could buy one. Sony then announced a
screen 11 inch wide with excellent picture quality. The price, however, illustrated
the manufacturing problems. The first announcement quoted a price near £3500,
though this was quickly followed by offers to import panels from the USA at half
that price.
It is seductive to present any light-emitting technology as simpler than, for
example, an LCD, because no additional source of illumination is necessary.
The counter argument is that LCDs separate the problems, so they can all

Phil. Trans. R. Soc. A (2010)

 Review. Flat-panel electronic displays 1069
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Figure 32. Generation 10 glass for displays.

be attacked individually. The progress in LCD picture quality attests to the

validity of that argument, for much of the recent research has concentrated
on back lights, angle of view, power consumption economies and other factors
that have had lower priority while the technology achieved its leading market
share.
Many of the OLED production problems arise from the interdependence of
many of the display’s functions. The panel must be able to show the three primary
colours, and the red and the green emitters are eminently satisfactory. The blue,
on the other hand, has too short a life. This means that the colour balance of the
picture will change during its use. One method of preserving colour balance is to
use red, green and blue phosphors excited by a deep blue or UV source, but here
it is that source which is short-lived.
Another problem is the addressing. The separation of functions in the LCD
means that the a-Si TFTs are just switches, and they carry a minimum current.
In OLED panels, the current energizing the emitters has to pass through the
TFTs, and they therefore are driven hard throughout their life. Life changes due
to trapping effects in a-Si are of minimal importance in LCDs, but not in OLEDs.
As a result, a number of OLED manufacturers have turned to poly-Si, which is
more stable, but more difficult to make. In addition, the need to pass current
to pixels in the middle of the panel throws an additional load on the quality of
the transparent conductor. It is not then surprising that the heralded arrival of
OLED TV has been delayed, though the penetration into less demanding markets
has continued apace.

Phil. Trans. R. Soc. A (2010)

 1070 C. Hilsum

(b) Flexible displays

In the early days of flat panels, there was some concern about the glass
substrates. The risk of breakage was, perhaps, emphasized, and there were some
experiments with plastic sheets. In time, however, glass became the standard,
and there it has remained. However, at some stage defence users again became
conscious of their dependence on an admittedly fragile component, and began
funding research on plastic substrates. They took this initiative further, asking
for a display that was flexible, with a vision of field maps that were portable,
and could be rolled up. In fact, a form of flexible display had been available
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to the consumer for many years, a temperature indicator containing cholesteric

LC. These were marketed widely, and since they were cheap, the customer
rarely complained when their ability to read the temperature lapsed after some
months. That, however, was symptomatic of the problem of using plastics. Their
ability as a moisture barrier is far less satisfactory than that of glass, whose
main weakness in that regard is the adhesive seal between the two sheets. The
requirement for a display substrate is a water vapour transmittance less than
10−6 g m−2 d−1 and an oxygen transmittance less than 10−5 ml m−2 d−1 , whereas
the best common plastics, PET and PEN, are several orders of magnitude worse
than this.
The demand for moisture and oxygen barrier coatings has attracted much
research activity, for the potential applications are broader than just flexible
displays. Included in these were solar cells, which obviously have to be
exposed continuously to the weather. Many companies have undertaken research,
including 3M, Vitex, Dupont and Batelle, and many government and university
laboratories have also been involved.
The general presumption is that no single material will meet the harsh
specification, so most recipes involve a series of organic–inorganic layers,
sometimes with a thin metal film as the inorganic layer. Diamond, hard carbon,
has been proposed by a number of research workers. The actual measurement
of moisture penetration is not easy. The standard technique has a limit of
0.005 g m−2 d−1 , well above the requirement. As a result it is difficult to assess
whether the films available commercially are good enough, since they usually just
quote performance as better than the standard limit. Early in 2008, the Singapore
Institute of Materials Research and Engineering (IMRE) announced that they
had developed a film that was 1000 times more effective than any technology
on the market. This had some credibility, since IMRE had previously invented
test sensors that claimed to be capable of measuring water vapour permeability
rates of 10−7 g m−2 d−1 . The claim was that incorporating Al2 O3 nanoparticulate
matter into a stack of layers of acrylic polymer, ITO, Al2 O3 and ITO on a
polycarbonate film gave very low permeation, and a series of three stacks met
the device requirements. Titanium nanoparticles could be used together with or
instead of aluminium oxide (Ramadas & Chua 2006). Nevertheless, over a year
later there has been no journal publication, and no independent verification, so
judgement must be deferred.
It seems unlikely that all the production and life problems of making large
flexible video displays will be solved swiftly. Smaller displays, which give more
freedom to the instrument designer because the display can be conformable,
should be available in the near future.

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 Review. Flat-panel electronic displays 1071

top plastic

ITO

microencapsulation
clear fluid
white particle +ve
black particle –ve
metal electrodes
– – + + – + bottom plastic

Figure 33. Schematic of structure of E Ink paper.

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(c) Electronic paper and electronic books

An electronic book, now generally known as an E-book or Reader, is the
digital equivalent of a printed book, in the simplest versions capable of presenting
monochrome text one page at a time, with page changing taking a second or two.
One of the first people to try to capitalize on the advantages of an electronic book
was Robert Maxwell, who approached the author at RSRE, Malvern, in 1981,
with a project to make a portable LCD capable of reproducing a page of text.
Maxwell was then Chairman of the British Printing and Publishing Corporation,
which owned several UK national newspapers, but his interest stemmed from
his ownership of Pergamon Press Ltd, which published many legal and medical
tomes. These were expensive to produce, and new editions were needed every
year. He thought that an electronic memory and display was the way forward,
and was prepared to finance generously an R&D project. He stated that money
was no real object. The concept was clearly ahead of its time, since active matrix
techniques were still in their infancy, and adequate data storage was not then
available within the dimensions of a textbook. The project had to be deferred,
probably fortunately, in view of his subsequent history, but the concept was
certainly valid.
It is simplest to think of an E-book as a Reader in which the visual effect is
provided by a flat or flexible electronic display that rivals the effect of print on
paper, and so is called electronic paper. A number of versions of the E-book are
now on the market. The input data come from inbuilt memory, or via a wireless
connection. The screen size in early versions approximates to a paperback book,
though recent models are as large as A4 paper. Some designs are based on plastic
films, largely to reduce the weight and make the device robust. One important
feature of the E-book is its portability, so that the power must be supplied by a
rechargeable battery. This militates against emissive visual effects, though back
lights can help for viewing in poor light. There is obviously a premium on high
reflectivity and high contrast.
The type of electronic paper that is most widely used exploits electrophoresis
(EP). This effect was discussed previously, in §4a(ii), and there it was explained
that the early technology was found wanting because the pigment particles
clumped, settled under gravity, and left stains on the electrodes. Modern EP
cells reduce these problems by either microencapsulating the pigment particles
in tiny spheres within the carrier fluid, or by dividing the panel volume into
segments by barriers between the surfaces.

Phil. Trans. R. Soc. A (2010)

 1072 C. Hilsum

The pioneering research on microencapsulation was done by E Ink, which

collaborated with research scientists at MIT (Jacobson et al. 1997; Comiskey
et al. 1998). They also worked closely with Philips, at Heerlen and Kobe, and
the structure they devised is shown in figure 33 (Henzen et al. 2004). The main
differences from the classic form shown in figure 14 are the encapsulation and
the use of two sets of pigmented particles, one set black and negatively charged,
the other white and positive. The fluid within the sphere is clear. In principle,
the positive particles could be coloured, or there could be micrometre-sized colour
filters on the front surface. Commercial e-paper has a reflectivity of 40 per cent
and a contrast ratio of 7 : 1. White paper has a reflectivity of 85 per cent.
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Operation of an EP display requires long positive and negative pulses, and

this complicates addressing. The response time is set by the transit time of the
pigment particles, and for E Ink paper this is just less than a second a page if
grey scales are to be shown. The paper is used in the Sony Reader and the Kindle,
which both use glass substrates. There has been some concern about the use of
glass substrates in the larger Readers, which could be A4 size. A flexible Reader
using E Ink, which is planned to reach the market early in 2010, is made by
Plastic Logic in Dresden. This incorporates polymer TFTs (Burns et al. 2006).
Production of a rival EP display was announced by Bridgestone in April 2009.
The medium is a ‘liquid powder’, and this is held between two plastic plates,
with barriers between the plates to prevent pigment motion (Sakurai et al. 2006).
Small colour displays have been used for supermarket labels, and now displays of
A4 size are coming on to the market.
Though constraining the volume available to particle diffusion in EP displays
can certainly reduce clumping and gravitational settling, it does not eliminate
them, and electrode staining, with a higher voltage needed to remove particles
than in first use, is still a problem. There is little published on the life of electronic
paper based on EP, but the patent literature shows that the reflectivity of early
models halved within 2000 h. Modern paper will show some improvement on
that figure.
One requirement of visual effects for electronic paper is bistability, since power
is then required only when the display needs updating. If the bistable states are
separated by a significant energy barrier, so that transition requires a short pulse
with voltage above a threshold, passive matrix addressing is possible, with much
simplification in back plane design, and a considerable reduction in processing
cost. Though standard TN LCDs are not bistable, a change in the design can give
this property. ZBD Displays, following earlier research on LC grating alignment
(Flanders et al. 1978), adds a grating structure to one surface of a TN display, and
there are then two stable states (figure 34). Switching from one state to the other
requires a short pulse, so the updating of a small page requires only 250 ms. The
display has a reflectivity of 39 per cent and a contrast ratio of 10 : 1, surprisingly
good figures considering the need for polarizers (Jones 2007). The main use of
the technology is for shelf-edge labelling (figure 35), but there seems no technical
obstacle to an increase in size.
Nemoptics obtains a similar effect without the grating. They treat one surface
so that the anchoring of the LC molecules is weak, and obtain two stable states
with the nematic molecules parallel to the surfaces, one twisted and one aligned.
Molecules can move from one state to the other only by passing through a third
state, with molecules orthogonal to the surfaces. This transition is made by

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 Review. Flat-panel electronic displays 1073

bistable
V surface

OR

OR
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0 monostable
planar

Figure 34. Bistable LC states in ZBD display.

Figure 35. A ZBD shelf label display.

unipolar pulses of different shapes for writing and erasing (Faget et al. 2006;
Dozov et al. 2007). The display reflectivity is 33 per cent, with a contrast ratio of
over 10 : 1. An A4 page can be refreshed on 0.4 s. Nemoptics displays are available
in colour, under the trade name BiNem, and are being used for shelf labelling. In
November 2007 they announced that Seiko Instruments would be using BiNem
for a Reader.
Though both ZBD and Nemoptics have made experimental displays on plastic
substrates, there is no information on life. The glass versions have the life of
normal LCDs, and, where weight and flexibility are not a prerequisite, could
provide an E-book with a simpler back plane, presumably at a lower cost than
the electrophoretic versions.

Phil. Trans. R. Soc. A (2010)

 1074 C. Hilsum
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Figure 36. Large cholesteric liquid crystal billboard (courtesy Magink).

This is a dynamic field, and while EP has produced commercial devices,

and bistable TN has demonstrated small working prototypes, there are many
reports of visual effects that are claimed to have superior properties and immense
potential for E-books. Proposed effects include electrowetting, electrofluidics and
bistability in cholesteric LCs. Many mechanical effects in microelectromechanical
systems (MEMS) are also under consideration.

(d) Other applications

There are a number of additional applications of flat-panel electronic displays,
but though the uses differ greatly from those covered earlier, the physics and
chemistry are similar. The exception is the very large displays, such as those used
for video presentation in sports stadia. They use several million LEDs, generally
in tiles about a metre square. Smaller displays used for signs and billboards can
exploit cholesteric LCDs. The sign shown in figure 36 is constructed from over
200 tiles to give an area of over 10 m2 , with a reflectivity of 32 per cent. The
picture can change in 1–2 s (Coates 2008).
Any flat-panel display lacks reality unless it can show three dimensions. The
simplest method requires the user to wear polarized spectacles, a disadvantage
for many users. Most other attempts give a good stereoscopic image to one
observer, but others can see a disturbing pseudoscopic presentation. The most
convincing representation comes from computer-generated holography, but this
involves much computation, and is very expensive.

7. Future trends

Market predictions are always suspect, because they assume that consumer
behaviour is like ‘the law of the Medes and Persians, which altereth not’ (King
James Bible, Daniel 6:8). Predictions based on technological progress are even

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 Review. Flat-panel electronic displays 1075

more questionable. Nevertheless, a survey of flat-panel history and achievement

would be incomplete without some words on the future. Some developments seem
clear. The TV market will see competition between LCDs and the various forms
of OLED, with plasma panels decreasing in importance. The conventional CRT
will die away, and it is unlikely that any flat form will become significant.
Competition in smaller devices is more difficult to assess. Flexibility can be an
important feature in design, but its advantages pale if linked with a short display
life. Nevertheless, if a fashionable item is inexpensive, its life is peripheral. That
would indicate an opening for flexible OLEDs in mobile phones, but problems
in Readers. The limited success to date of the research on barrier layers gives
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concern, because much effort and funds have been applied. If the reports of success
from Singapore remain unconfirmed, glass Readers would prevail, with a possible
opening for passive matrix bistable LCDs.
Silicon is truly a workhorse in electronics, and its versatility has been shown
in the Texas Instruments Digital Light Projector. The technology has a natural
home in microdisplays, and it is certainly possible that interesting optical effects
can be obtained by sub-micrometre motion of layers in MEMS. Ingenuity will
be needed, however, before the high definition possible in small chips can be
projected to larger areas within the limited depth of Readers.
A future without three-dimensional TV displays is unimaginable, and a few
companies have made experimental models that come close to a satisfactory
presentation. The interim steps of the Dolby three-dimensional Digital Cinema,
using polarizing goggles, and the Planar Stereo Monitor, involving two screens,
may well kindle consumer interest enough for companies to market displays that
approximate to reality in a form acceptable to consumers.
The past 40 years have seen immense progress in flat-panel technology, and
has led to huge funds being applied in the many areas where panels can provide
excellent images. The future is likely to be as bright for displays as the past has
been rewarding for physicists, chemists and engineers.
The commitment of my many colleagues to progress in display technology cannot be adequately
recognized here. Their achievements played crucial parts in the total picture, but they are not
recorded in publications or patents, so their contributions will remain anonymous. My debt to
them is nevertheless real.
The preparation of this paper was helped by input from Jeremy Burroughes, David Coates,
Anne Dell, John Goodby, Cliff Jones, Roger Partridge, Peter Raynes and Chris Williams, and I
am grateful to them.

References
Adachi, C., Tokito, S., Tsutsui, T. & Saito, S. 1988 Electroluminescence in organic films with
three-layer structure. Jpn. J. Appl. Phys. 27, L269–L271. (doi:10.1143/JJAP.27.L269)
Adachi, C., Tsutsui, T. & Saito, S. 1990 Blue light-emitting organic electroluminescent devices.
Appl. Phys. Lett. 56, 799–781. (doi:10.1063/1.103177)
Adams, A. 2009 Walter Eric Spear. 20 January 1921–21 February 2008. Biogr. Mem. Fell. R. Soc.
55, 267–289. (doi:10.1098/rsbm.2009.2003)
Adler, D., Shur, M. S., Silver, M. & Ovshinsky, S. R. 1980 Threshold switching in chalcogenide-glass
thin films. J. Appl. Phys. 51, 3289. (doi:10.1063/1.328036)
Adronov, A. & Fréchet, J. M. J. 2000 Light-harvesting dendrimers. Chem. Commun. 1701–1710.
(doi:10.1039/b005993p)

Phil. Trans. R. Soc. A (2010)

 1076 C. Hilsum

Aiken, W. R. 1953 Cathode ray tube. Patent US2795731. Filled 4 December. Published 11 June
1957.
Aiken, W. R. 1984 History of the Kaiser–Aiken thin cathode ray tube. IEEE Trans. Electron
Devices 31, 1605–1608. (doi:10.1109/T-ED.1984.21758)
Amstutz, H., Heimgartner, D., Kaufmann, M. & Scheffer, T. J. 1983 Liquid crystal display. Patent
CH664027. Filed 12 July. Published 20 January 1988.
Arora, S. L., Fergason, J. L. & Saupe, A. 1968 Liquid crystal phases with nematic morphology. In
Proc. 2nd Int. liquid crystal conf., Kent State University, OH, 12–16 August, pp. 563–577.
Ashida, H., Murakoso, T., Wada, Y., Okawa, M., Yamamoto, T., Ando, T., Kimura, N. & Ikeda, S.
2008 Development of world’s largest (150 inch diagonal) advanced high definition PDP. Soc. Inf.
Display Symp. Dig. 39, 476–479. (doi:10.1889/1.3069703)
Downloaded from https://royalsocietypublishing.org/ on 28 February 2023

Baldo, M. A., O’Brien, D. F., Shoustikov, A., Sibley, S., Thompson, M. E. & Forrest,
S. R. 1998 Highly efficient phosphorescent emission from OLEDs. Nature 395, 151–154.
(doi:10.1038/25954)
Baldo, M. A., Thompson, M. E. & Forrest, S. R. 2000 High-efficiency fluorescent OLEDs using a
phosphorescent emitter. Nature 403, 750–753. (doi:10.1038/35001541)
Baur, G., Fehrenbach, W., Staudacher, B., Windscheid, F. & Kiefer, R. 1990 Electro-optical liquid
crystal switching element. Patent DE4000451A1. Filed 9 January. Published 11 July 1991.
Beni, G. & Hackwood, S. 1981 Electro-wetting displays. Appl. Phys. Lett. 38, 207–209.
(doi:10.1063/1.92322)
Bernanose, A. 1955 Electroluminescence of organic compounds. Br. J. Appl. Phys. 6, S54–S55.
(doi:10.1088/0508-3443/6/S4/319)
Bitzer, D. L. & Slottow, H. G. 1966 The plasma display panel—a digitally addressable display with
inherent memory. In Proc. AFIPS Fall Joint Computer Conf., San Francisco, 7–10 November,
vol. 29, pp. 541–547.
Bitzer, D. L., Slottow, H. G. & Willson, R. H. 1966 Gaseous display and memory apparatus. Patent
US3559190. Filed 18 January. Published 26 January 1971.
Börner, H. F., Kynast, U., Busselt, W. & Haase, M. 1995 Organic electroluminescent component.
Patent US5756224. Filed 10 August. Published 26 May 1998.
Braun, D. & Heeger, A. J. 1991 Visible light emission from semiconducting polymer diodes. Appl.
Phys. Lett. 58, 1982–1984. (doi:10.1063/1.105039)
Brody, T. P. 1996 The birth and early childhood of active matrix—a personal memoir. J. Soc. Inf.
Display 4, 113–127. (doi:10.1889/1.1985000)
Brown, A. R., Bradley, D. D. C., Burroughes, J. H., Friend, R. H., Greenham, N. C., Burn, P. L.,
Holmes, A. B. & Kraft, A. 1992 PPV light-emitting diodes. Appl. Phys. Lett. 61, 2793–2795.
(doi:10.1063/1.108094)
Burn, P. L., Lo, S.-C. & Samuel, I. D. W. 2007 The development of light-emitting dendrimers for
displays. Adv. Mater. 19, 1675–1688. (doi:10.1002/adma.200601592)
Burns, S. et al. 2006 A flexible plastic SVGA e-paper display. Soc. Inf. Display Symp. Dig. 37,
74–76. (doi:10.1889/1.2433620)
Burroughes, J. H., Bradley, D. D. C., Brown, A. R., Marks, R. N., Mackay, K., Friend, R. H., Burn,
P. L. & Holmes, A. B. 1990 Light-emitting diodes based on conjugated polymers. Nature 347,
539–541. (doi:10.1038/347539a0)
Burrows, P. E., Bulovic, V., Forrest, S. R., Sapochak, L. S., McCarty, D. M. & Thompson,
M. E. 1994 Reliability and degradation of OLEDs. Appl. Phys. Lett. 65, 2922–2924.
(doi:10.1063/1.112532)
Carr, W. 1966 Photometric figures of merit for semiconductor luminescent sources. Infrared Phys.
6, 1–19. (doi:10.1016/0020-0891(66)90019-4)
Chittick, R. C., Alexander, J. H. & Sterling, H. F. 1969 The preparation and properties of
amorphous silicon. J. Electrochem. Soc. 116, 77–81. (doi:10.1149/1.2411779)
Coates, D. 2008 Recent advances in tiled cholesteric billboard displays. Soc. Inf. Display Symp.
Dig. 39, 799–802. (doi:10.1889/1.3069790)
Coates, D. et al 1993 Fluorinated 4 -cyano substituted terphenyls. Patent US5312563. Filed 22
January. Published 17 May 1994.

Phil. Trans. R. Soc. A (2010)

 Review. Flat-panel electronic displays 1077

Cölle, M. & Brütting, W. 2004 Thermal, structural and photophysical properties of the organic
semiconductor Alq3 . Phys. Stat. Sol. (a) 201, 1095–1115. (doi:10.1002/pssa.200404341)
Comiskey, B., Albert, J. D., Yoshizawa, H. & Jacobson, J. 1998 An electrophoretic ink for all-
printed reflective electronic displays. Nature 394, 253–255. (doi:10.1038/28349)
Cosentino, L. S., Christiano, V., Endriz, J. G., Stockdale, G. F., Cooper, J. L., Hewitt, J. N. &
Harrison, J. B. 1979 Feedback multiplier flat-panel television II—technologies. IEEE Trans.
Electron Devices 26, 1335–1345. (doi:10.1109/T-ED.1979.19603)
Credelle, T. L. 1977 Color flat panel television. Patent US4137478. Filed 20 June. Published
30 January 1979.
Deb, S. K. & Shaw, R. F. 1966 Electrooptical device having variable optical density. Patent
US3521941. Filed 25 July. Published 28 July 1970.
Downloaded from https://royalsocietypublishing.org/ on 28 February 2023

Deb, S. K. & Witzke, H. 1975 The solid state electrochromic phenomenon and its applications to
display devices. In Proc. 1975 Int. Electron Devices Meeting, vol. 21, pp. 393–397.
Destriau, G. 1936 AC electroluminesence in ZnS. J. Chim. Phys. 33, 587.
Dozov, I., Joly, S., Faget, L., Stoenescu, D., Lamarque-Forget, S. & Martinot-Lagarde, P. 2007
Bistable nematic display. In Proc. Asia Display 2007, Shanghai, pp. 1–4. Campbell, CA: Society
for Information Display.
Dresner, J. & Goodman, A. M. 1970a Anthracene electroluminescent cells with tunnel-injection
cathodes. Proc. IEEE 58, 1868–1869.
Dresner, J. & Goodman, A. M. 1970b Organic electroluminescent cells having a tunnel injection
cathode. Patent US3710167. Filed 2 July. Published 9 January 1973.
Eidenschink, R., Krause, J. & Pohl, L. 1977 Liquid crystalline cyclohexane derivatives. Patent
US4130502. Filed 10 August. Published 19 December 1978.
Endriz, J. G., Kenema, S. A. & Catanese, C. A. 1979 Feedback multiplier flat-panel television
I-system design. IEEE Trans. Electron Devices 26, 1324–1335. (doi:10.1109/T-ED.1979.19602)
Era, M., Hayashi, S., Tsutsui, T. & Saito, S. 1985 Electroluminescence of a J-aggregated cyanine
dye multilayer. J. Chem. Soc., Chem. Commun. 557–558. (doi:10.1039/C39850000557)
Faget, L., Lamarque-Forget, S., Martinot-Lagarde, P., Auroy, P. & Dozov, I. 2006 Anticonical
anchoring and surface transitions in a nematic liquid crystal. Phys. Rev. E 74, 050701.
(doi:10.1103/PhysRevE.74.050701)
Fergason, J. L. 1971 Display devices utilizing liquid crystal light modulation. Patent US03731986.
Filed 22 April. Published 8 May 1973.
Fergason, J. L., Taylor, T. R. & Harsch, T. B. 1970 Liquid crystals and their application. Electro-
Technology, January, pp. 41–50.
Flanders, D. C., Shaw, D. C. & Smith, H. I. 1978 Alignment of liquid crystals using submicrometer
periodicity gratings. Appl. Phys. Lett. 32, 587–588. (doi:10.1063/1.89864)
Forrest, S. R. 2004 The path to ubiquitous and low-cost organic electronic appliances on plastic.
Nature 428, 911–918. (doi:10.1038/nature02498)
Friend, R. H., Burroughes, J. H. & Bradley, D. D. C. 1990 Electroluminescent devices. Patent
US5247190 PCT. Filed 18 April. Published 21 September 1993.
Gabor, D. 1955 Cathode ray tube. Patent US2795729. Filed 29 November. Published 11 June
1957.
Gabor, D. 1956 Cathode ray tubes. Patent US2885595. Filed 21 November. Published 5 May 1959.
Gabor, D. 1957 Cathode ray tubes. Patent US2878417. Filed 22 March. Published 17 March
1959.
Gabor, D. 1959 Cathode ray tubes. Patent US2982875. Filed 28 December. Published 2 May 1961.
Gabor, D. 1962 Flat display tube utilizing unique collimator. Patent US3171056. Filed 15 May(GB).
Published 23 February 1962.
Gabor, D., Tothill, H. A. W. & Smith-Whittington, J. E. 1968 A fully electrostatic flat thin TV
tube. Proc. IEEE 115, 467–468.
Gilat, S. L., Adronov, A. & Fréchet, J. M. J. 1999 Light-harvesting and energy transfer in novel
convergently constructed dendrimers. Angew. Chem., Int. Edn. 38, 1422–1427. (doi:10.1002/
(SICI)1521-3773(19990517)38:10<1422::AID-ANIE1422>3.0.CO;2-V)
Goldmacher, J. E. & Castellano, J. A. 1967 Electro-optical compositions and devices. Patent
US3540796. Filed 31 March. Published 17 November 1970.

Phil. Trans. R. Soc. A (2010)

 1078 C. Hilsum

Gordon, E. I. & Anderson, L. K. 1973 New display technologies—an editorial viewpoint. Proc.
IEEE 61, 807–813. (doi:10.1109/PROC.1973.9169)
Graefelfing, H. H., Bittorf, H. & Veith, W. 1968 Flat color TV tube. Patent US3621319. Filed 26
June. Published 16 November 1971.
Gray, G. W., Hird, M., Lacey, D. & Toyne, K. 1989 The synthesis and transition temperatures
of some dialkyl and alkyloxyalky terphenyls with difluoro substituents. J. Chem. Soc., Perkin
Trans. II, 2041–2053.
Green, M. 1976 Electrochromic device. Patent US4060311. Filed 8 January. Published 29 November
1977.
Green, M. & Richman, D. 1974 Solid state electrochromic cell. Thin Solid Films 24, S45–S46.
(doi:10.1016/0040-6090(74)90189-8).
Downloaded from https://royalsocietypublishing.org/ on 28 February 2023

Gurnee, E. F. 1962 Electroluminescent cell. Patent US3173050. Filed 19 July. Published 9 March
1965.
Gurnee, E. F. & Fernandez, R. T. 1960 Organic electroluminescent phosphors. Patent US3172862.
Filed 29 September. Published 9 March 1965.
Hayashi, S., Etoh, H. & Saito, S. 1986 Electroluminescence of perylene films with a conducting
polymer as an anode. Jpn. J. Appl. Phys. 25, L773–L775. (doi:10.1143/JJAP.25.L773)
Hayes, R. A. & Feenstra, B. J. 2003 Video-speed electronic paper based on electrowetting. Nature
425, 383–385. (doi:10.1038/nature01988)
Heilmeier, G. H. 1973 Displays—a pentagon perspective. IEEE Trans. Electron Devices 20,
921–925. (doi:10.1109/T-ED.1973.17772)
Heilmeier, G. H., Zanoni, L. A. & Barton, L. A. 1968 Dynamic scattering—a new electro-optic
effect. Proc. IEEE 56, 1162–1171. (doi:10.1109/PROC.1968.6513)
Helfrich, W. & Schadt, M. 1970 Optical device. Patent CH532261. Filed 4 December. Published 15
February 1972.
Henzen, A. et al. 2004 Development of active-matrix electronic-ink displays for handheld devices.
J. Soc. Inf. Display 12, 17–22. (doi:10.1889/1.1824234)
Hilsum, C. 1969 Report of working party on solid state displays and lamps. RRE, Malvern.
12 January 1969.
Hilsum, C. 1984 The anatomy of a discovery—biphenyl liquid crystals. In Technology of chemicals
and materials for electronics (ed. E. H. Howells), ch. 3, pp. 43–68. Chichester, UK: Ellis
Horwood.
Holder, E., Langeveld, B. M. W. & Schubert, U. S. 2005 New trends in the use of transition metal–
ligand complexes for applications in electroluminescent devices. Adv. Mater. 17, 1109–1121.
(doi:10.1002/adma.200400284)
Hopper, M. A. & Novotny, V. 1979 An electrophoretic display, its properties, model, and addressing.
IEEE Trans. Electron Devices 26, 1148–1152. (doi:10.1109/T-ED.1979.19566)
Huang, W.-S., Lin, J. T. & Lin, H.-C. 2008 Green phosphorescent iridium dendrimers
containing dendronized benzoimidazole-based ligands for OLEDs. Org. Electron. 9, 557–568.
(doi:10.1016/j.orgel.2008.03.001)
Hulme, D. S., Raynes, E. P. & Harrison, K. J. 1974 Eutectic mixtures of nematic 4-substituted
4-cyanobiphenyls. Chem. Commun. 98–99. (doi:10.1039/C39740000098)
Igasaki, Y. & Saito, H. 1991a Substrate temperature dependence of electrical properties of ZnO:Al
epitaxial films on sapphire (12̄10). J. Appl. Phys. 69, 2190. (doi:10.1063/1.348748)
Igasaki, Y. & Saito, H. 1991b The effects of deposition rate on the structural and electrical
properties of ZnO:Al films deposited on (112̄0) oriented sapphire substrates. J. Appl. Phys.
70, 3613. (doi:10.1063/1.349258)
Itoh, S. et al. 2007 Development of field-emission displays. J. Soc. Inf. Display 15, 1057–1064.
(doi:10.1889/1.2825090)
Jacobson, J. J., Comiskey, B. & Albert, J. D. 1997 Microencapsulated electrophoretic display. Patent
US5961804. Filed 18 March. Published 5 October 1999.
Jiroku, H., Miyasaka, M., Inoue, S., Tsunekawa, Y. & Shimoda, T. 2004 High-performance
polycrystalline silicon thin-film transistors fabricated by high-temperature process with excimer
laser annealing. Jpn. J. Appl. Phys. 43, 3293–3296. (doi:10.1143/JJAP.43.3293)

Phil. Trans. R. Soc. A (2010)

 Review. Flat-panel electronic displays 1079

Jones, J. C. 2007 The zenithal bistable device: from consumer to customer. Soc. Inf. Display Symp.
Dig. 38, 1347–1350. (doi:10.1889/1.2785562)
Kahn, F. J. 1971 Nematic liquid crystal device. Patent US3694053. Filed 22 June. Published
26 September 1972.
Kahn, F. J. 1972 Electric-field-induced orientational deformation of nematic liquid crystals. Appl.
Phys. Lett. 20, 199–201. (doi:10.1063/1.1654107)
Kawamoto, H. 2002 The history of liquid crysral displays. Proc. IEEE 90, 460–500. (doi:10.1109/
JPROC.2002.1002521)
Kenworthy, J. G. 1971 Variable light transmission device. Patent US3712709. Filed 22 November.
Published 23 January 1973.
Kiefer, R., Weber, B., Windscheid, F. & Baur, G. 1992 In-plane switching of nematic liquid crystals.
Downloaded from https://royalsocietypublishing.org/ on 28 February 2023

In Proc. 12th Int. Display Research Conf., Hiroshima, 12–14 October, pp. 547–550. Campbell,
CA: Society for Information Display.
Kirsch, P. 2004 100 years of liquid crystals at Merck. In Proc. 20th Int. Liquid Crystal Conf.,
Ljubljana, Slovenia, 4–9 July. London, UK: Taylor & Francis.
Koike, Y. & Okamoto, K. 1999 Super high quality MVA-TFT liquid crystal displays. Fujitsu Sci.
Technol. J. 35, 221–228.
Kyoshi, Y. 2006 Constituent material and manufacturing equipment of the organic EL display.
Electron. Parts Mater. 45(12), 18–23.
Land, E. H. 1951 Some aspects on the development of sheet polarizers. J. Opt. Soc. Am. 41,
957–963. (doi:10.1364/JOSA.41.000957)
Law, H. B. 1950 Art of making color-kinescopes. Patent US2625734. Filed 28 April. Published 20
January 1953.
Law, H. B. 1976 The shadow mask color picture tube. IEEE Trans. Electron Devices 23, 752–759.
(doi:10.1109/T-ED.1976.18479)
LeComber, P. G., Spear, W. E. & Ghaith, A. 1979 Amorphous Si field-effect device and possible
application. Electron. Lett. 15, 179–181. (doi:10.1049/el:19790126)
Lee, M. J., Wright, S. W., Judge, C. P., Cheung, P. Y. & Wyman, R. 1992 High-performance CdSe
TFTs as drive circuits in AM liquid crystal cells. Proc. SPIE 1665, 290. (doi:10.1117/12.60397)
Lee, R. A. & Cade, N. A. 1987 Field emission vacuum devices. Patent US4827177. Filed 3
September. Published 2 May 1989.
Lee, R. A. & Cade, N. A. 1988 Patent GB2195046A. Filed 23 May. Published 5 August 1987.
Lee, R. A., Patel, C., Williams, H. A. & Cade, N. A. 1989 Semiconductor fabrication
technology applied to micrometer valves. IEEE Trans. Electron Devices 36, 2703–2708.
(doi:10.1109/16.43776)
Levin, B. & Levin, N. 1934 Improvements in or relating to light valves. Patent GB441274A. Filed
13 July. Published 13 January 1936.
Levy, D. H., Freeman, D., Nelson, S. F., Cowdery-Corvan, P. J. & Irving, L. M. 2008
Stable ZnO TFTs by fast open-air atomic layer deposition. Appl. Phys. Lett. 92, 192101.
(doi:10.1063/1.2924768)
Lossev, O. V. 1923 Behaviour of contact detectors. Telegrafia Telefonia Bez Provodov 18, 45–62.
Lossev, O. V. 1928 Luminous carborundum detector. Phil. Mag. 5, 1024–1044.
Ma, D., Lupton, J. M., Samuel, I. D. W., Lo, S.-C. & Burn, P. L. 2002 Bright electroluminescence
from a conjugated dendrimer. Appl. Phys. Lett. 81, 2285. (doi:10.1063/1.1507826)
Meakin, D. B., Coxon, P. A., Migliorato, P., Stoemenos, J. & Economou, N. A. 1987 High-
performance thin-film transistors from optimized polycrystalline silicon films. Appl. Phys. Lett.
50, 1894. (doi:10.1063/1.97678)
Mugele, F. & Baret, J.-C. 2005 Electrowetting: from basics to applications. J. Phys.: Condens.
Matter 17, R705–R774. (doi:10.1088/0953-8984/17/28/R01)
Ohe, M. & Kondo, K. 1995 Electro-optical characteristics and switching behavior of the in-plane
switching mode. Appl. Phys. Lett. 67, 3895. (doi:10.1063/1.115309)
Ohta, M. et al. 1996 In-plane field type liquid crystal display device. Patent US6266116. Filed 26
September. Published 24 July 2001.
Osamu, I., Akira, T., Takashi, M. & Naoyuki, M. 1987 Electrophoretic display device. Patent
JP1086116. Filed 29 September. Published 30 March 1989.

Phil. Trans. R. Soc. A (2010)

 1080 C. Hilsum

Ovshinsky, S. R. & Fritzsche, H. 1973 Amorphous semiconductors for switching, memory,

and imaging applications. IEEE Trans. Electron Devices 20, 91–105. (doi:10.1109/
T-ED.1973.17616)
Park, J.-W., Han, S.-W., Jeon, N., Jang, J. & Yoo, S. 2008 Improved electrical characteristics of
amorphous oxide TFTs based on TiOx channel layer grown by low-temperature MOCVD. IEEE
Electron Device Lett. 29, 1319–1321. (doi:10.1109/LED.2008.2005737)
Partridge, R. H. 1983a Electroluminescence from polyvinylcarbazole films: 1. Carbazole cations.
Polymer 24, 733–738. (doi:10.1016/0032-3861(83)90012-5)
Partridge, R. H. 1983b Electroluminescence from polyvinylcarbazole films: 2. Polyvinylcarbazole
films containing antimony pentachloride. Polymer 24, 739–747. (doi:10.1016/0032-
3861(83)90013-7)
Downloaded from https://royalsocietypublishing.org/ on 28 February 2023

Partridge, R. H. 1983c Electroluminescence from polyvinylcarbazole films: 3. Electroluminescent

devices. Polymer 24, 748–754. (doi:10.1016/0032-3861(83)90014-9)
Partridge, R. H. 1983d Electroluminescence from polyvinylcarbazole films: 4. Electroluminescence
using higher work function cathodes. Polymer 24, 755–762. (doi:10.1016/0032-3861(83)90015-0)
Partridge, R. H. 1975 Radiation sources. Patent GB3995299. Filed 7 October. Published
30 November 1976.
Pauluth, D. & Tarumi, K. 2004 Advanced liquid crystals for television. J. Mater. Chem. 14,
1219–1227. (doi:10.1039/b400135b)
Peng, H. J., Wong, M. & Kwok, H. S. 2003 Design and characterization of organic light-
emitting diodes with microcavity structure. Soc. Inf. Display Symp. Dig. 34, 516–519.
(doi:10.1889/1.1832326)
Pfeiffer, M., Beyer, A., Fritz, T. & Leo, K. 1998 Controlled doping of phthalocyanine layers by
cosublimation with acceptor molecules. Appl. Phys. Lett. 73, 3202–3204. (doi:10.1063/1.122718)
Pope, M., Kallman, H. P. & Magnante, P. 1963 Electroluminescence in organic crystals. J. Chem.
Phys. 38, 2042. (doi:10.1063/1.1733929)
Ramadas, S. K. & Chua, S. J. 2006 Nanoparticulate encapsulation barrier stack. Patent
WO2008/057045. Filed 6 November. Published 15 May 2008.
Raynes, E. P. 1980 A novel solubility method for the formulation of eutectic mixtures of liquid
crystals. RSRE Memo 3266.
Reiffenrath, V. et al. 1989a 2,3-Difluorobiphenyls. Patent US5204019. Filed 27 February. Published
20 April 1993.
Reiffenrath, V., Krause, J., Plach, H. J. & Weber, G. 1989b New liquid crystal compounds with
negative dielectric anisotropy. Liq. Cryst. 5, 159–170.
Reineke, S., Lindner, F., Schwartz, G., Seidler, N., Walzer, K., Lussem, B. & Leo, K. 2009 White
OLEDs with fluorescent tube efficiency. Nature 459, 234–238. (doi:10.1038/nature08003)
Reinitzer, F. 1888 Beiträge zur Kenntnis des Cholesterins. Monats. Chem. 9, 421–441.
Roberts, G. G., McGinnity, M., Barlow, W. A. & Vincett, P. S. 1979 Electroluminescence,
photoluminescence and electroabsorption of a lightly substituted anthracene Langmuir film.
Solid State Commun. 32, 683–696. (doi:10.1016/0038-1098(79)90728-2)
Round, H. J. 1907 A note on carborundum. Electr. World 49, 309.
Sakurai, R., Ohno, S., Kita, S.-I., Masuda, Y. & Hattori, R. 2006 Color and flexible electronic
paper display using QR-LPD technology. Soc. Inf. Display Symp. Dig. 37, 1922–1925.
(doi:10.1889/1.2433426)
Samuel, I. D. W., Halim, M., Burn, P. L. & Pillow, J. N. 1998 Light-emitting dendrimers and
devices. Patent US6558818. Filed 23 October. Published 6 May 2003.
Schadt, M. & Helfrich, W. 1971 Voltage-dependent optical activity of a twisted-nematic liquid
crystal. Appl. Phys. Lett. 18, 127–128. (doi:10.1063/1.1653593)
Scheffer, T. J. 1983 Liquid crystal display with high multiplex rate. In Proc. 3rd Int. Display
Research Conf., Kobe, Japan, p. 400. Campbell, CA: Society for Information Display.
Schoot, C. J., Ponjee, J. J., van Dam, H. T., van Doorn, R. A. & Bolwijn, P. T. 1973 New
electrochromic memory display. Appl. Phys. Lett. 23, 64. (doi:10.1063/1.1654808)
Scott, W. C. 1977 Internally supported flat tube display. Patent US4118651. Filed 14 April.
Published 3 October 1978.

Phil. Trans. R. Soc. A (2010)

 Review. Flat-panel electronic displays 1081

Segal, M., Baldo, M. A., Holmes, R. J., Forrest, S. R. & Soos, Z. G. 2003 Excitonic singlet–
triplet ratios in molecular and polymeric organic materials. Phys. Rev. B 68, 075211.
(doi:10.1103/PhysRevB.68.075211)
Sekiya, M., Hara, M., Sano, N., Kohno, A. & Sameshima, T. 1994 High-performance polycrystalline
Si thin-film transistors fabricated using remote plasma chemical vapor deposition of SiO2 . IEEE
Electron Device Lett. 15, 69–71. (doi:10.1109/55.285370)
Shiga, T., Fujikawa, H. & Taga, Y. 2003 Design of multiwavelength resonant cavities for white
organic light-emitting diodes. J. Appl. Phys. 93, 19–22. (doi:10.1063/1.1527708)
Shoulders, K. R. & Heynick, L. N. 1966a Needle-type electron source. Patent US3453478. Filed 31
May. Published 1 July 1969.
Shoulders, K. R. & Heynick, L. N. 1966b Method of making a needle-type electron source. Patent
Downloaded from https://royalsocietypublishing.org/ on 28 February 2023

US3497929. Filed 31 May. Published 3 March 1970.

Siekanowicz, W. W., Anderson, C. H. & Credelle, T. L. 1976 Flat display device with beam guide.
Patent US4088920. Filed 29 March. Published 9 May 1978.
Smith, E. & Hilsum, C. 2003 Method for preparing light emitting devices. Patent WO03073526.
Filed 26 February. Published 4 September 2003.
Snell, A. J., Mackenzie, K. D., Spear, W. E., LeComber, P. G. & Hughes, A. J. 1981 Application
of amorphous silicon field effect transistors in addressable liquid crystal display panels. Appl.
Phys. A 24, 357–362. (doi:10.1007/BF00899734)
Soref, R. A. 1972 Liquid crystal display apparatus. Patent US3807831. Filed 20 June. Published 30
April 1974.
Soref, R. A. 1973 Transverse field effects in nematic liquid crystals. Appl. Phys. Lett. 22, 165.
(doi:10.1063/1.1654597)
Spear, W. E. & LeComber, P. G. 1975 Substitutional doping of amorphous Si. Solid State Commun.
17, 1193–1196. (doi:10.1016/0038-1098(75)90284-7)
Spindt, C. A. & Heynick, L. N. 1970 Field ionizer and field emission cathode structures and methods
of production. Patent US3665241. Filed 13 July. Published 23 May 1972.
Spindt, C. A., Holland, C. E., Rosengreen, A. & Brodie, I. 1991 Field-emitter arrays for vacuum
microelectronics. IEEE Trans. Electron Devices 38, 2355–2363. (doi:10.1109/16.88525)
Staebler, D. L. & Wronski, C. R. 1977 Reversible conductivity changes in discharge-produced a-Si.
Appl. Phys. Lett. 31, 292. (doi:10.1063/1.89674)
Stanley, T. O. 1975 Flat CRT. Patent US4031427. Filed 25 August. Published 21 June 1977.
Stanley, T. O. 1977 Flat panel display device. Patent US4143296. Filed 6 June. Published 6 March
1979.
Sziklai, G. C. 1948 Electrochemical colour filter. Patent US2632045. Filed 31 August. Published 17
March 1953.
Tang, C. W. 1980 Organic electroluminescent cell. Patent US356429. Filed 17 July. Published
26 October 1982.
Tang, C. W. & VanSlyke, S. A. 1987 Organic electroluminescent diodes. Appl. Phys. Lett. 51,
912–915. (doi:10.1063/1.98799)
Thompson, M. E., You, Y., Shoustikov, A., Sibley, S., Burrows, P. E. & Forrest, S. R. 1997
OLEDs doped with phosphorescent compounds. Patent US6303238. Filed 1 December. Published
16 October 2001.
Van Dam, H. T., Ponjee, J. J. & Schoot, J. 1972 Image display cell. Patent GB1376799. Filed 20
December. Published 11 December 1974.
Vecht, A. 1970 Improvements in or relating to electroluminescent devices. Patent GB1300548. Filed
27 February. Published 20 December 1972.
Vecht, A. 1982 Developments in electroluminescent panels. J. Cryst. Growth 59, 89–107.
(doi:10.1016/0022-0248(82)90309-8)
Vecht, A. & Werring, N. J. 1970 Direct current electroluminescence in ZnS. Br. J. Appl. Phys. 3,
105–120.
Vincett, P. P., Barlow, W. A., Hann, R. A. & Roberts, G. G. 1982 Electrical conduction and
low voltage blue electroluminescence in vacuum-deposited organic films. Thin Solid Films 94,
171–183. (doi:10.1016/0040-6090(82)90509-0)

Phil. Trans. R. Soc. A (2010)

 1082 C. Hilsum

Wang, K., Vygranenko, Y. & Nathan, A. 2008 High-mobility nanocrystalline indium oxide TFTs
with silicon nitride gate dielectric. MRS Symp. Proc. 1074, I05-35.
Waters, C. & Raynes, E. P. 1982 Liquid crystal devices. Patent GB2123163. Filed 29 June. Published
25 January 1984.
Waters, C., Brimmell, V. & Raynes, E. P. 1983 Highly multiplexable dyed liquid crystal displays.
In Proc. 3rd Int. Display Research Conf., Kobe, Japan, pp. 396–399. Campbell, CA: Society for
Information Display.
Weimer, P. K. 1962a The TFT—a new thin film transistor. Proc. IRE 50, 1462–1469.
Weimer, P. K. 1962b Insulated gate field effect devices. Patent US3191061. Filed 31 May. Published
22 June 1965.
Downloaded from https://royalsocietypublishing.org/ on 28 February 2023

Werner, A. G., Li, F., Harada, K., Pfeiffer, M., Beyer, A., Fritz, T. & Leo, K. 2003
Pyronin B as a donor for n-type doping of organic films. Appl. Phys. Lett. 82, 4495–4497.
(doi:10.1063/1.1583872)
Williams, R. 1963. Domains in liquid crystals. J. Phys. Chem. 39, 382–388.
Wilson, J. S., Dhoot, A. S., Seeley, A. J. A. B., Khan, M. S., Köhler, A. & Friend, R. H.
2001 Spin-dependent exciton formation in π-conjugated compounds. Nature 413, 828–831.
(doi:10.1038/35101565)

Phil. Trans. R. Soc. A (2010)