1. Electromeric effect is a b) temporary effect 2. 2- Pentene contains b). 14 σ -and one π - bond 3. Which of the following statement is NOT correct for a Nucleophile? c). Nucleophile is a Lewis acid. 4. __________ are formed by the homolytic fission of C-C bond in ethane. c). Methyl free radical
6. In a carbocation, the C- atom carrying a positive charge has a/an _____.
C) Sextet of electrons 7.
8. When two ice cubes are pressed over each other, they unite to form one cube. Which of the following forces is responsible to hold them together? (a) Hydrogen bond formation 9. Why does H+ ion always get associated with other atoms or molecules? 1 (d) Loss of an electron from hydrogen atom results in a nucleus of very small size as compared to other atoms 10. The shape of XeF4 molecule according to VSEPR theory is (a) Square planar (b) Square pyramid (c) Tetrahedral (d) d). Pyramidal
11. According to Fajan’s rule, a compound having which of the following properties would exhibit greater covalent character? d) Smaller cation & larger anion 12. Find the molecule in which the central atom is having one lone pair of electrons (a) NH3 (b) PCl5 (c) H2O (d) CH4
13. Take NA as the number of Anti-bonding molecular orbitals and NB as the number of Bonding molecular orbitals. The molecule is stable when NA ____________ NB c) is less than 14. In the modern periodic table, the place of the element with atomic number 56 is in – a) s-block
15. The correct order of increasing energy of atomic orbitals is
(a) 5 p < 4 f < 6 s < 5 d (b) 5 p < 6 s < 4 f < 5 d (c) 5 p < 5 d < 4 f < 6 s (d) None of these 16. The magnetic quantum number of an atom is related to the d). orientation of the orbital in space 17. A 600 W mercury lamp emits monochromatic radiation of wavelength 331.3 nm. How many photons are emitted from the lamp per second? (h = 6.626 × 10 –34 Js; velocity of light = 3 × 108 ms–1)
18. Which of the following is not correct for electronic distribution in the ground state ?
2 (d) All of the above
19. Lines in the hydrogen spectrum which appear in the visible region of the electromagnetic spectrum are called as: (a) Balmer series 20. Arrange the orbital of same shell in the increasing order of shielding strength of the outer shell of electrons. s, f, d, p (d) s > p > d > f 21. Which of the following term is dependent on temperature? (a) Molarity 22. The empirical formula and molecular mass of a compound are CH2O and 180 g respectively. What will be the molecular formula of the compound? Ans c).: C6H12O6 23. Which has the maximum number of molecules among the following? (C=12u,H=1u,O=16u,S=32u)
24. 20.0 kg of N2(g) and 3.0 kg of H2(g) are mixed to produce NH3(g). The amount of NH3(g) formed is [N =14u,H=1u]
25. One litre oxygen gas at S.T.P will weigh :
SECTION B
3 This section consists of 24 multiple choice questions with overall choice to attempt any 20 questions. In case more than desirable number of questions are attempted, ONLY first 20 will be considered for evaluation. 26. Given below are two statements labelled as Assertion (A) and Reason (R ) Assertion: (A): π bond is stronger than σ bond. Reason: (R): The extent of overlapping in σ bond is greater than in π-bond. Ans: (d). Sigma bond is stronger than π bond because the extent of overlapping in sigma bond is greater than in π bond. 27. Given below are two statements labelled as Assertion (A) and Reason (R ) Assertion: (A): BF3 does not contain proton but still acts as an acid. Reason: (R): It is an electron deficient species. Ans: (a). BF3 does not contain proton (H+) but still acts as an acid because it is an electron deficient species. It acts as Lewis acid. 28. Given below are two statements labelled as Assertion (A) and Reason (R) Assertion (A): Geometry of SF4 molecule can be termed as distorted tetrahedron, a folded square or see saw. Reason (R) : Four fluorine atoms surround or form bond with sulphur molecule. (b) Both A and R are true but R is not the correct explanation of A.. 29. Given below are two statements labelled as Assertion (A) and Reason (R) Assertion (A): Generally, ionisation enthalpy increases from left to right in a period. Reason (R): When successive electrons are added to the orbitals in the same principal quantum level, the shielding effect of inner core of electrons does not increase very much to compensate for the increased attraction of the electron to the nucleus. Select the most appropriate answer from the options given below: (a) Both A and R are true and R is the correct explanation of A (b) Both A and R are true but R is not the correct explanation of A. (c) A is true but R is false. (d) A is false but R is true.
30. Given below are two statements labelled as Assertion (A) and Reason (R ) Assertion: (A): Heisenberg's uncertainty principle can be applied to a stationary electron. Reason: (R): Velocity of stationary electron is zero. So, its position cannot be measured accurately. Ans: (d). Heisenberg's uncertainty principle cannot be applied to a stationary electron because its velocity is zero due to which its position cannot be measured accurately.
31. The name of the compound given below is
(a) 4-ethyl-3-methyloctane (b) 3 -methyl-4-ethyloctane (c) 2, 3-diethylheptane (d) 5 – ethyl-6 -methyl octane 4 32. In the formation of π bond, the atomic orbitals overlap in such a way that their axes remain _______ to the other participating orbital and ____ to internuclear axes. (a) Parallel, perpendicular 33. Which of the following orders regarding relative stability of free radicals is correct? (b) 3° > 2° > 1°
35. The IUPAC name of the compound CH3 – C (OH) = CH – CH2 – COOH is ------------- b). 4-hydroxy-pent-3-enoic acid 36. Which of the following hydrides are generally non stochiometric in nature? c). Interstitial Hydrides 37. Metal hydride on treatment with water gives (d) Hydrogen 38. The structure of IF7 is Ans:(a) Pentagonal bipyramid Explanation: IF7 Hybridization is sp³d³ 39. The molecule which has the highest bond order is (b) N2 40. Methanol and ethanol are miscible in water due to (b) hydrogen bonding character 41. The nature of hybridisation in the ammonia molecule is d)sp3 42. What is the IUPAC name of the element with atomic number 114? (c) Ununquadium 43. Alkali metals are powerful reducing agents because (d) their ionisation potential is low. 44.
45. The elements with atomic numbers 9, 17, 35, 53 and 85 belong to
5 c)
46.
47. Number of atoms of He in 100 u of He (Atomic mass of He is 4 u):
a. Ans: 25 No. of atoms in 100 u of He = 100/4 = 25 He atoms 48. What will be the molarity of a solution, which contains 5.85 g of NaCl(s) per 500 mL? Ans:c) 0.2 mol L– 1 SECTION C This section consists of 6 multiple choice questions with an overall choice to attempt any 5. In case more than desirable number of questions are attempted, ONLY first 5 will be considered for evaluation.
Read the given passage and answer the questions that follow:
Redox reactions are reactions in which oxidation and reduction take place simultaneously. Oxidation numbers are assigned in accordance with the set of rules. Oxidation number and ion-electron methods both are used in balancing ionic equations. Redox reactions are classified as a combination, decomposition, displacement, and disproportionation reactions. The concept of redox couple and electrode processes is the basis of electrolysis and electrochemical cells. 50. The oxidation process involves (a) Increase in oxidation number 51. The oxidation number of Cl in Cl2O7 is a). +7 ************************************************************** 6 7
