Topic B The Particulate Nature of Matter
Topic B The Particulate Nature of Matter
Name: ______________________
Class: ______________________
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𝐿 = 𝜎𝐴𝑇 where L is the luminosity, A is the surface area, and T is the absolute
temperature of the body.
o The concept of apparent brightness b.
o Luminosity L of a body as given by 𝑏 = .
o The emission spectrum of a black body and the determination of the
temperature of the body using Wien’s displacement law as given by 𝜆 𝑇 =
2.9 × 10 mK where 𝜆 is the peak wavelength emitted.
Equations
𝜌=
𝐸 = 𝑘 𝑇
𝑄 = 𝑚𝑐∆𝑇
𝑄 = 𝑚𝐿
∆ ∆
= 𝑘𝐴
∆ ∆
𝐿 = 𝜎𝐴𝑇
𝑏=
𝜆 𝑇 = 2.898 × 10 mK
If you are interested in learning more about thermal physics then please read the
book Concepts in Thermal Physics by Stephen J. Blundell and Katherine M.
Blundell.
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2. C: Define fluid.
5. C: Define and give the units for each variable for density 𝜌 = . Is it a scalar
or vector? Do not confuse density ρ with power P or momentum 𝑝⃑ or pressure
p!
7. C: Define diffusion.
8. C: Which state of matter has the most potential energy: a solid, a liquid, or a
gas?
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9. C: Define temperature.
10. C: Define Degrees Celsius. What is the melting point and the boiling point of
water in degrees Celsius?
11. C: Define Kelvin. What is the melting point and the boiling point of water in
Kelvin?
13. C: Which has greater kinetic energy: 0 ℃ ice or 0 ℃ water? Which has greater
potential energy?
14. C: Define and give the units for each variable of the equation for Boltzmann’s
constant 𝑘 = .
15. C: Define and give the units for each variable for the equation for the internal
energy of an ideal gas 𝐸 = 𝑘 𝑇 = 𝑇.
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20. C: What does the equation 𝑄 = 𝑚𝑐∆𝑇 tell us? Define and give the units of
each variable.
21. C: Define melting. Does an object gain potential energy or lose potential
energy when it melts? What about kinetic energy?
22. C: Define freezing. Does an object gain potential energy or lose potential
energy when it freezes? What about kinetic energy?
24. C: Define condensation. Does an object gain potential energy or lose potential
energy when it condenses? What about kinetic energy?
25. C: What does the equation 𝑄 = 𝑚𝐿 tell us? Define and give the units of each
variable.
26. C: What does the equation 𝑄 = 𝑚𝐿 tell us? Define and give the units of each
variable.
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b. How much energy will it take to increase the temperature of solid gold by
50°C?
c. How much energy will be lost by solid gold if its temperature decreases by
50°C?
28. E: How much energy will be needed to increase the temperature of 0.8 kg of
solid ice from minus 30°C to steam at plus 140°C? Draw a temperature vs.
energy graph of this process.
𝑐 𝑐
J
J J 𝑐 = 1,996
= 2,108 = 4,186 kg × K
kg × K kg × K
J J
𝐿 = 3.34 × 10 𝐿 = 2.26 × 10
kg kg
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29. E: Approximately how much energy will be needed to melt 1.25 kg of silver
which is at a room temperature of 22.0 °C? The specific heat capacity of silver
is approximately 236 , the latent heat of vaporization of silver is
×°
approximately 2.51 × 10 J, and the melting point of silver is approximately
962 °C.
30. E: Aaron drops a 6.00 kg gold block with a temperature of 20.0°C into a tub
with 2.00 kg of liquid water at 90.0°C. What will be the final temperature of
the system?
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31. E: A ball of copper, which has a specific heat capacity of 𝑐 = 390. , has a
°
mass of 165 grams and is initially at a temperature of 115°C. This ball is
quickly inserted into an insulated cup containing 125 ml of water at a
temperature of 22.0°C.
a. What will be the final, equilibrium temperature of the ball and the water?
b. How much heat did the copper ball lose to the water?
c. How much heat did the water gain from the ball?
33. C: What is the difference between a thermal conductor and thermal insulator?
Give an example of each.
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∆ ∆
34. C: Describe the equation = 𝑘𝐴 .
∆ ∆
35. E: A silver plate 3.00 cm thick has a cross-sectional area of 4,000. cm . One
face is at 160.°C and the other is at 130.°C. How much heat passes through the
plate each second? For silver, 𝑘 = 406 .
36. E: A metal plate 6.00 mm thick has a temperature difference of 48.0°C between
its faces. It transmits 200. kcal/h through an area of 7.00 cm . Calculate the
thermal conductivity of this metal in .
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37. E: Two metal plates are soldered together. It is known that 𝐴 = 70.0 cm ,
𝐿 = 2.00 mm, 𝐿 = 4.00 mm, 𝑇 = 110. ℃, and 𝑇 = 20.0℃. For the plate
on the left 𝑘 = 45.0 and for the plate on the right 𝑘 = 85.0 .
Determine the temperature of the soldered junction in K and the heat flow rate
in J/s.
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40. C: State the definition, equation, and units for emissivity. What is the emissivity
of a really dark colored object? What is the emissivity of a really light colored
object?
42. C: What does the Stefan-Boltzmann law tell us? State the equation and define
each variable in the Stefan-Boltzmann law.
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44. E: The average surface temperature of the Sun is 5.778 × 10 K and its average
radius is 6.957 × 10 m. Assuming that it radiates as if it were a blackbody, at
what rate (in Watts) is energy radiated from the sphere?
45. E: The radius of star X is four times that of star Y and its temperature is three
times that of Y. Find the ratio of luminosity of Y to that of X.
46. E: A blackbody has a surface area of 4.00 m and temperature of 450. K. The
blackbody is in a closed room with room temperature of 293 K. How much
energy does the blackbody lose per minute?
48. E: The luminosity of the Sun is 3.846 × 10 W and its distance from the Earth
is about 1.50 × 10 m. Determine the apparent brightness b of the Sun.
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49. E: The apparent brightness of star X as observed from Earth is three times
greater than that of star Y as observed from Earth. The luminosity of star X is
two times greater than that of star Y. Determine the ratio of the distance of star
Y to Earth to that of star X to Earth.
50. C: What does Wien’s displacement law tell us? State the equation and define
each variable for Wien’s displacement law. Draw and label a graph describing
Wien’s displacement law.
51. E: The Sun emits electromagnetic waves with a maximum wavelength of 570.
nm. According to this information what is the surface temperature of the Sun?
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Name: ______________________
Class: ______________________
Equations
emissivity =
albedo =
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2. C: State the definition, equation, and units for emissivity. What is the emissivity
of a really dark colored object? What is the emissivity of a really light colored
object?
3. C: State the definition, equation, and units for albedo. What is the albedo of a
really dark colored object? What is the albedo of a really light colored object?
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6. E: By which factor does the power emitted by an object decrease when its
temperature decreases from 800.0 K to 500.0 K?
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8. E: The planet Saturn has an average surface temperature of -178°C and a radius
of approximately 5.82 × 10 m. Suppose Saturn has an emissivity of
approximately 0.650. Determine the rate of thermal energy emitted.
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12. E: The average albedo of Earth is approximately 0.300 and the average
emissivity of the Earth is approximately 0.600. Use the solar constant to
determine the average temperature of the Earth.
13. E: The average albedo of Earth is approximately 0.300. Use the solar constant
to determine the average intensity reaching the Earth during the day or night.
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14. C: Define the greenhouse effect and the enhanced greenhouse effect. What are
the four major greenhouse gases? State their name and chemical formula.
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The world's most viewed site on global warming and climate change
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https://mishtalk.com/economics/lets-review-50-years-of-dire-climate-forecasts-
and-what-actually-happened/
1. 1967 Salt Lake Tribune: Dire Famine Forecast by 1975, Already Too Late
2. 1969 NYT: “Unless we are extremely lucky, everyone will disappear in a cloud
of blue steam in 20 years. The situation will get worse unless we change our
behavior.“
3. 1970 Boston Globe: Scientist Predicts New Ice Age by 21st Century said James
P. Lodge, a scientist at the National Center for Atmospheric Research.
4. 1971 Washington Post: Disastrous New Ice Age Coming says S.I. Rasool at
NASA.
5. 1972 Brown University Letter to President Nixon: Warning on Global Cooling
6. 1974 The Guardian: Space Satellites Show Ice Age Coming Fast
7. 1974 Time Magazine: Another Ice Age “Telling signs everywhere. Since the
1940s mean global temperatures have dropped 2.7 degrees F.”
8. 1974 “Ozone Depletion a Great Peril to Life” University of Michigan Scientist
9. 1976 NYT The Cooling: University of Wisconsin climatologist Stephen
Schneider laments about the “deaf ear his warnings received.”
10. 1988 Agence France Press: Maldives will be Completely Under Water in 30
Years.
11. 1989 Associated Press: UN Official Says Rising Seas to ‘Obliterate Nations’ by
2000.
12. 1989 Salon: New York City’s West Side Highway underwater by 2019 said Jim
Hansen the scientist who lectured Congress in 1988 about the greenhouse
effect.
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13. 2000 The Independent: “Snowfalls are a thing of the past. Our children will not
know what snow is,” says senior climate researcher.
14. 2004 The Guardian: The Pentagon Tells Bush Climate Change Will Destroy
Us. “Britain will be Siberian in less than 20 years,” the Pentagon told Bush.
15. 2008 Associate Press: NASA Scientist says “We’re Toast. In 5-10 years the
Arctic will be Ice Free”
16. 2008 Al Gore: Al Gore warns of ice-free Arctic by 2013.
17. 2009 The Independent: Prince Charles says Just 96 Months to Save the World.
“The price of capitalism is too high.”
18. 2009 The Independent: Gordon Brown says “We have fewer than 50 days to
save our planet from catastrophe.”
19. 2013 The Guardian: The Arctic will be Ice Free in Two Years. “The release of
a 50 gigaton of methane pulse” will destabilize the planet.
20. 2013 The Guardian: US Navy Predicts Ice Free Arctic by 2016. “The US
Navy’s department of Oceanography uses complex modeling to makes its
forecast more accurate than others.
21. 2014 John Kerry: “We have 500 days to Avoid Climate Chaos” discussed Sec of
State John Kerry and French Foreign Minister Laurent Fabious at a joint
meeting.
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Name: ______________________
Class: ______________________
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Equations
𝑃=
𝑁=
= constant
𝑃𝑉 = 𝑛𝑅𝑇 = 𝑁𝑘 𝑇
𝑃 = 𝜌𝑣
𝑈 = 𝑛𝑅𝑇 = 𝑁𝑘 𝑇
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1. C: Define and give the units for each variable for pressure 𝑃 = . Is it a scalar
or vector? Do not confuse pressure P with power P or momentum 𝑝⃑ or density
ρ!
4. C: Define and give the units for each variable for a mole 𝑛 = 𝑁/𝑁 .
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7. E: Consider H O.
a. What is the molar mass of H O?
8. E: Consider CO .
a. What is the molar mass of CO ?
9. E: Consider CH .
a. What is the molar mass of CH ?
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12. C: What are some differences between an ideal gas and a real gas?
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16. C: Take Boyle’s Law, Charles’ Law, and Gay-Lussac’s Law to obtain a general
equation for an ideal gas.
17. C: Define and give the units of each variable for the Ideal Gas Law 𝑃𝑉 = 𝑛𝑅𝑇.
18. C: Define and give the units of each variable for the Ideal Gas Law 𝑃𝑉 =
𝑁𝑘 𝑇.
20. E: What is the volume of 22.0 moles of an ideal gas when it fills a cylinder at a
temperature of 40.0°C and a pressure of 1.01 × 10 Pa?
21. E: What is the temperature of 0.255 moles of an ideal gas when it fills a volume
of 225 cm at a pressure of 1.01 × 10 Pa?
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22. E: Three moles of an ideal gas originally occupies a volume of 120. cm with a
pressure of 1.01 × 10 Pa at a temperature of 23.0℃. What will be its new
volume if its pressure is held constant and its temperature increases to 35.0℃?
23. E: Five moles of an ideal gas originally occupies a volume of 160. cm with a
pressure of 1.01 × 10 Pa at a temperature of 23.0℃. What will be its new
pressure if its volume is held constant and its temperature increases to 75.0℃?
24. E: Two moles of an ideal gas originally occupies a volume of 346. cm with a
pressure of 1.01 × 10 Pa at a temperature of 30.0℃. What will be its new
pressure if its volume increases to 362. cm and its temperature is held
constant?
25. C: Define and give the units for each variable for the equation for the kinetic
theory of an ideal gas 𝑃 = 𝜌𝑣 .
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28. C: Define and give the units for each variable for the equation for the internal
energy of an ideal monatomic gas 𝑈 = 𝑛𝑅𝑇 = 𝑁𝑘 𝑇.
29. E: Determine the internal energy of 7.42 moles of an ideal gas at a temperature
of 32.0°C.
31. E: Use the equation 𝐸 = 𝑘 𝑇 to determine the average kinetic energy and
speed of O at a room temperature of 20.0°C. Assume O is an ideal gas.
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32. E: Use the equation 𝐸 = 𝑘 𝑇 to determine the average kinetic energy and
speed of CO at a temperature of 23.0°C. Assume CO is an ideal gas.
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Name: ______________________
Class: ______________________
B.4 Thermodynamics
Additional HL Understandings
o The first law of thermodynamics, as given by 𝑄 = ∆𝑈 + 𝑊, results from the
application of conservation of energy to a closed system and relates the internal
energy of a system to the transfer of energy as heat and as work.
o The work done by or on a closed system as given by 𝑊 = 𝑃∆𝑉 when its
boundaries are changed can be described in terms of pressure and changes of
volume of the system.
o The change in internal energy, as given by ∆𝑈 = 𝑛𝑅∆𝑇 = 𝑁𝑘 ∆𝑇, of a
system is related to the change of its temperature.
o Entropy S is a thermodynamic quantity that relates to the degree of disorder of
the particles in a system.
o Entropy can be determined in terms of macroscopic quantities such as thermal
∆
energy and temperature as given as ∆𝑆 = and also in terms of the properties
of individual particles of the system as given by 𝑆 = 𝑘 ln Ω where 𝑘 is the
Boltzmann constant and Ω is the number of possible microstates of the system.
o The second law of thermodynamics refers to the change in entropy of an
isolated system and sets constraints on possible physical processes and on the
overall evolution of the system.
o Processes in real isolated systems are almost always irreversible and
consequently the entropy of a real isolated system always increases.
o The entropy of a non-isolated system can decrease locally, but this is
compromised by an equal or greater increase of the entropy of the surroundings.
o Isovolumetric, isobaric, isothermal, and adiabatic processes are obtained by
keeping one variable fixed.
o Adiabatic processes in monatomic ideal gases can be modeled by the equation
as given by 𝑃𝑉 = constant.
o Cyclic gas processes are used to run heat engines.
o A heat engine can respond to different cycles and is characterized by its
efficiency as given by 𝜂 = .
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o The Carnot cycle sets a limit for the efficiency of a heat engine at the
temperatures of its heat reservoirs as given by 𝜂 =1− .
Additional HL Equations
𝑄 = ∆𝑈 + 𝑊
𝑊 = 𝑃∆𝑉
∆𝑈 = 𝑛𝑅∆𝑇 = 𝑁𝑘 ∆𝑇
∆
∆𝑆 =
𝑆 = 𝑘 ln Ω
𝑃𝑉 = constant
𝜂=
𝜂 = 1−
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1. C: Define thermodynamics.
5. C: Consider a system filled with an ideal gas and the equation for the law of
conservation of energy 𝑄 = ∆𝑈 + 𝑊.
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9. E: 246 J of thermal energy is used to compress a gas while its internal energy
increases by 122 J. Determine the amount of energy leaving the system.
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18. C: What does the area under a pressure-volume curve tell us?
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∆
22. C: Describe the equation ∆𝑆 = .
∆
23. C: The change in entropy 𝑆 of a system is defined as ∆𝑆 = .
a. What can we do to make ∆𝑆 positive?
25. E: Two large cubes filled with water are separated by a thin thermally
conducting metal plate. The temperature of the water in cube 1 is 82.0°C and
the temperature of the water in cube 2 is 39.0°C. Determine the change in
entropy of the whole system if heat flows between the plate at 249 Joules per
second.
26. E: 400. g of ice at 0.00°C melts to water at a constant temperature. The latent
heat of fusion of H O is 3.34 × 10 . Determine the change in entropy.
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27. E: 500. g of water at 0.00°C freezes to ice at a constant temperature. The latent
heat of fusion of H O is 3.34 × 10 . Determine the change in entropy.
30. E: A piston is slowly compressed so the temperature of the ideal gas inside it
remains at 40.0°C. 748 J of work is done on the gas. Determine the change in
entropy of the gas.
31. E: A piston is slowly expanded so the temperature of the ideal gas inside it
remains at 68.3°C. 498 J of work is done by the gas. Determine the change in
entropy of the gas.
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37. C: State the arrow of time and entropy in terms of the second law of
thermodynamics.
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47. E: Calculate the efficiency of a Carnot engine operating between the following
temperatures.
48. E: Suppose you have 12 two-sided fair unbiased coins. You throw them all up
and count the number of heads and number of tails. You want to determine the
number of arrangements to land one head, two heads, three heads, etc. and also
its probability. Complete the table below:
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11
12
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Name: ______________________
Class: ______________________
o Electric cells are characterized by their emf 𝜀 and internal resistance 𝑟 as given
by 𝜀 = 𝐼(𝑅 + 𝑟).
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Equations
∆
𝐼=
∆
𝑉=
𝑅=
𝜌=
𝑃 = 𝐼𝑉 = 𝐼 𝑅 =
𝜀 = 𝐼(𝑅 + 𝑟)
If you are interested in learning more about electricity and magnetism then please
read the book Electricity and Magnetism by Edward M. Purcell and David J.
Morin.
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3. C: Use a pencil and ruler! The work done in moving a charge is given by the
equation 𝑊 = 𝑞 × ∆𝑉. Draw and label a diagram to describe this equation.
5. C: Define electric current I and state its equation and units. Do not confuse
current I with impulse 𝐽⃑!
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14. E: A piece of wire, which has a diameter of 0.500 mm, is measured to have a
resistance of 8.40 Ω. What will be the resistance of an otherwise identical wire
which has a diameter of 0.250 mm?
15. C: Define Ohm’s Law. Draw a current vs. voltage graph of a resistor obeying
Ohm’s law.
16. C: What does a thermistor do? Draw a resistance vs. temperature graph of a
thermistor.
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21. E: A current of 0.870 Amperes flows through a certain light bulb when it is
attached to a 115. Volt power supply. How much power does this light bulb
dissipate?
22. E: A 25.0 Ω resistor is connected to a 5.70 Volt battery with negligible internal
resistance.
23. E: A certain light bulb is designed to dissipate 5.00 W of power when attached
to a 12.0 V source. What is the resistance of the light bulb filament?
24. E: A 25.0 Ω resistor and a 75.0 Ω resistor are connected in series across a 12.0
V source. How much power will be consumed by the 25.0 Ω resistor?
25. E: A 55.0 Ω resistor is attached to a 12.0 V power supply. This resistor is then
immersed in a Styrofoam cup containing 25.0 g of water initially at a
temperature of 22.5°C for a period of 150. s.
b. How much energy will be delivered to the water during these 150. s?
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27. C: State Kirchhoff’s loop rule. Which conservation rule does this law obey?
28. State Kirchhoff’s junction rule. Which conservation rule does this law obey?
33. C: What does an ammeter do? Draw its symbol. What is a characteristic of an
ideal ammeter? How/Where do we insert an ammeter in a circuit?
34. C: What does a voltmeter do? Draw its symbol. What is a characteristic of an
ideal voltmeter? How/Where do we insert a voltmeter in a circuit?
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35. E: Six 2.02 Volt cells are connected in series. What will be the total emf
produced?
36. E: What will be the emf produced by four 1.50 Volt cells connected in series?
37. E: What will be the emf produced by three 6.00 Volt batteries connected in
parallel?
38. E: What will be the emf produced by the combination of cells below?
39. E: What will be the emf produced by the combination of cells below?
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40. E: Solve for the unknowns. Give your answers in reduced fractions.
Given:
V = 10 V
R = 2Ω
R = 4Ω
R = 6Ω
𝑉 = 𝐼 =
𝑅 =
𝑉 = 𝐼 =
𝐼 =
𝑉 = 𝐼 =
What will happen to the current leaving the battery if the number of resistors in
series increases? Will the current increase, decrease, or stay the same?
What will happen to the overall resistance of the circuit if the number of resistors
in series increases? Will the overall resistance increase, decrease, or stay the
same?
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41. E: Solve for the unknowns. Give your answers in reduced fractions.
Given:
V = 10 V
R =2Ω
R =4Ω
R =6Ω
𝑉 = 𝐼 =
𝑅 =
𝑉 = 𝐼 =
𝐼 =
𝑉 = 𝐼 =
What will happen to the current leaving the battery if the number of resistors in
parallel increases? Will the current increase, decrease, or stay the same?
What will happen to the overall resistance of the circuit if the number of resistors
in parallel increases? Will the overall resistance increase, decrease, or stay the
same?
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42. E: Solve for the unknowns. Give your answers in reduced fractions.
Given:
V = 10 V
R =2Ω
R =4Ω
R =6Ω
R =8Ω
𝑉 = 𝐼 =
𝑅 = 𝑉 = 𝐼 =
𝐼 = 𝑉 = 𝐼 =
𝑉 = 𝐼 =
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43. E: Solve for the unknowns. Give your answers in reduced fractions.
𝑉 =6V
𝑉 = 11 V
𝑉 = 17 V
𝑅 =3Ω
𝑅 =1Ω
𝑅 =4Ω
𝐼 = 𝑉 =
𝐼 = 𝑉 =
𝐼 = 𝑉 =
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44. E: Solve for the unknowns. Give your answers in reduced fractions.
𝑉 = 10 V
𝑅 =1Ω
𝑅 =2Ω
𝑅 =3Ω
𝑅 =4Ω
𝑅 =5Ω
𝑅 =6Ω
𝑅 = 𝐼 =
𝐼 = 𝐼 = 𝐼 = 𝐼 = 𝐼 = 𝐼 =
𝑉 = 𝑉 = 𝑉 = 𝑉 = 𝑉 = 𝑉 =
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45. E: Solve for the unknowns. Give your answers in reduced fractions.
𝑉 = 30 V
𝑅 =1Ω
𝑅 =2Ω
𝑅 =3Ω
𝑅 =4Ω
𝑅 =5Ω
𝑅 =6Ω
𝑅 = 𝐼 =
𝐼 = 𝐼 = 𝐼 = 𝐼 = 𝐼 = 𝐼 =
𝑉 = 𝑉 = 𝑉 = 𝑉 = 𝑉 = 𝑉 =
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48. C: Define the following variables for the equation 𝜀 = 𝐼(𝑅 + 𝑟). Draw an
image to describe this equation.
49. E: A dry cell has an emf of 3.04 V. Its terminal potential drops to zero when a
current of 50.0 A passes through it. What is its internal resistance?
50. E: A cell has an emf of 145 V. This means that its terminal voltage is 145 V
when no current flows through it. When the terminal potential is 120. V the
current through the circuit is 25.0 A.
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b. What will be the maximum current that can be delivered by the battery?
54. E: A battery is known to have an emf of 4.60 Volts and an internal resistance of
2.20 Ω. What will be the terminal voltage of this battery while connected to a
load of 7.80 Ω?
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d. What will be the voltage drop across each of the 12.0 Ω resistors?
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f. With what efficiency is power being delivered to the load in this circuit?
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