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Nanoscale Quantum
Materials
Nanoscale Quantum
Materials
Musings on the Ultra-Small World
Tapash Chakraborty
First edition published [2022]
by CRC Press
6000 Broken Sound Parkway NW, Suite 300, Boca Raton, FL 33487-2742
Reasonable efforts have been made to publish reliable data and information, but the author and
publisher cannot assume responsibility for the validity of all materials or the consequences of their use.
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obtained. If any copyright material has not been acknowledged please write and let us know so we may
rectify in any future reprint.
Except as permitted under U.S. Copyright Law, no part of this book may be reprinted, reproduced,
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used only for identification and explanation without intent to infringe.
DOI: 10.1201/9781003090908
Typeset in LM Roman
by KnowledgeWorks Global Ltd.
Contents
Preface ix
Acknowledgments xv
v
vi Contents
Index 229
Preface
Our everyday life today is more and more enmeshed with smart elec-
tronic devices that, in their core, contain nanoscale objects. For re-
searchers, a deeper knowledge of the novel properties of those objects is
absolutely essential to make them perform ever more efficiently. Intense
research on physics of nanoscale systems has uncovered many unexpected
phenomena that has helped push forward the frontiers of our present un-
derstanding of Nature. Sharing that knowledge with the general reader,
who is not well versed about those complicated phenomena, is important
and essential for our collective appreciation of the rapid developments of
this digital age that has been dominating our daily lives. In this book,
I have endeavored to achieve that to some extent, without claiming the
elevated clarity of a popular science book or an authoritative overview
of a textbook. The essential physics at this level is rather complex, but
my goal is to explain the basic principles of the various phenomena as
plainly as I can without resorting to complicated equations. However, for
more technical-minded readers, I have presented some technical-details
in boxes or footnotes that can be skipped for a general reading of the
book.
An alert reader will surely notice that while writing this book I
have taken some poetic license to describe some of the topics in or-
der to make those more palatable to a wider audience. My fervent
hope has been that it will appeal not only to physics researchers, en-
gineers, and advanced students in those disciplines, but perhaps also
to ‘physics enthusiasts’ from other academic disciplines. However, some
familiarities with the fundamentals of quantum mechanics and con-
densed matter physics will be essential to appreciate the book in its
entirety.
The book is by no means a comprehensive treatise of all things nano-
scale. It is also biased toward the theoretical perspectives of nanoscale
ix
x Preface
In this Galileo was not alone. As a matter of fact, over the past
three or four centuries, ‘physicists’10 have begun to rely more on math-
ematics rather than the word to describe the world. This trend has led
to physics, just as mathematics itself, making a retreat from the word.
Steiner warned that, ‘It is arrogant, if not irresponsible, to invoke such
basic notions in our present model of the universe as quanta, the inde-
terminacy principle, ..., if one cannot do so in the language appropriate
to them – that is to say, in mathematical terms. Without it, such words
are phantasms to deck out the pretense of philosophers or journalists’.
In a somewhat less articulate manner, Ernest Rutherford was quoted as
saying if you cannot explain your physics to a barmaid it is probably not
very good physics11 . That must be a daunting job today for any physicist
who would embark upon such undertakings. It will be a genuine shock
for this author if indeed a barmaid or a poet appreciates the contents of
this book!
Interestingly, a few years ago, I interacted with a scientist who con-
siders herself ‘an occasional artist and poet’ and wrote a very interesting
book on the properties of water12 aimed at readers ‘in the arts and hu-
manities as well as scientists’. It has been a motivational factor behind
my present quixotic endeavor. ‘Here is a scientist who can really write,
the letters in which it is composed. It is written in the language of mathematics, and
its characters are triangles, circles, and other geometric figures without which it is
humanly impossible to understand a single word of it; without these, one wanders
about in a dark labyrinth.
10
We should be careful here about the terminology. The word physicist was first
proposed by William Whewell in his book, The Philosophy of the Inductive Sciences,
London, 1840, although those scientists existed for centuries, albeit belonging to a
different category! Incidentally, the term scientist was also proposed in that book by
Whewell as ‘a cultivator of science’ (see Science and Technology in World History,
An Introduction, J.E. McClellan III and H. Dorn (Johns Hopkins University Press,
Baltimore 2015)). However, according to Sydney Ross, in Scientist: The story of
a word, Annals of Science 18, 65 (1964), Whewell introduced the term scientist
much earlier, somewhat ‘jocularly’ in The Quarterly Review 51, 58 (1834), in his
attempt to find a suitable English equivalent of the German term natur-forscher.
The undignified compounds, such as nature-poker or nature-peeper, were ‘indignantly
rejected’ in favor of the word scientist! However, according to Ross, the word was
not an instant hit. In fact, for the natural philosophers, ‘the word scientist implied
making a business of science; it degraded their labors of love to a drudgery for profits
or salary’.
11
Some recollections and reflections on Rutherford, by W. Bennett Lewis, Notes
Rec. R. Soc. Lond. 27, 61 (1972).
12
Living Rainbow H2 O, by Mae-Wan Ho (World Scientific 2012).
Preface xiii
exulted the legendary Nobelist Hans Bethe13 some years ago, while re-
viewing a largely autobiographical book by Freeman Dyson14 . However,
it would be a very rare occasion to witness such a distinction lavished
upon a physics author when the narrative involves advanced quantum
mechanics.
The book is organized as follows: In Chapter 1, we introduce the
subject of scaling from a historical perspective, crediting Galileo for his
original contributions in describing the subject of scaling. We explain
why scaling down to ever greater miniaturization of electronic circuits
and memory devices has enormously improved computer performance
and all related electronic devices that, in turn, has resulted in today’s all-
encompassing digital transformation of our everyday lives. The purpose
of this chapter is to prepare the readers for what comes next in the
nanoscale regime.
Chapter 2 begins with the description of the two-dimensional elec-
tron gas. We explain how the planar electrons can be ideally created, and
then we briefly explain how those were actually made in the laborato-
ries. We then highlight the momentous discoveries in those systems and
how those effects were explained by introducing novel quantum phe-
nomena that have far reaching implications. We discuss the discovery
of the integer quantum Hall effect, the fractional quantum Hall effect,
and Laughlin’s many-electron wave function for a very special quantum
fluid. The fractionally charged quasiparticles and their exotic statistics
and various spin configurations are discussed. Every attempt has been
made to explain those in such a way that it will be of interest to the
non-experts. We have also included several original references and brief
technical steps in boxes that might help in grasping a more detailed
picture if required.
In Chapter 3, we discuss the properties of zero-dimensional electron
systems, the quantum dots. We discuss the fundamental physics of these
systems and their possible applications in quantum cryptography and as
a source for mid-infrared and terahertz radiation. Chapter 4 deals with
the persistent current in small metal rings. The role of interacting elec-
trons in semiconductor quantum rings containing only a few electrons
are discussed. Unusual properties of quantum rings in some novel mate-
rials and the usefulness of the rings are briefly discussed.
13
Physics Today, p. 51, December 1979.
14
Disturbing the Universe, by F. Dyson, Harper & Row, N.Y. 1979.
xiv Preface
I know thou hast created me, and that I have neither being nor
blessing but what is the effect of thy power and goodness.
I know thou art the end for which I was created, and that I can
expect no happiness but in thee.
I know that in love to me, being lost in sin, thou didst send thy
only Son, and that he being the Lord of glory, did humble himself to
the death upon the cross, that I might be raised to glory.
S U N D A Y E V E N I N G.
1. Have I set apart some of this day, to think upon his perfections
and mercies?
Bless my father, &c. my friends and relations, and all that belong
to this family; all that have been instrumental to my good, by their
assistance, advice, example, or writing, and all that do not pray for
themselves.
M O N D A Y M O R N I N G.
O GOD, who art the giver of all good gifts, I thy unworthy servant,
entirely desire to praise thy name for all the expressions of
thy bounty towards me. Blessed be thy love for giving thy Son to die
for our sins, for the means of grace, and for the hope of glory.
Blessed be thy love for all the temporal benefits which thou hast
with a liberal hand poured out upon me; for my health and strength,
food and raiment, and all other necessaries with which thou hast
provided thy sinful servant. I also bless thee that, after all my
refusals of thy grace, thou still hast patience with me, hast
preserved me this night, (――) ¹ and given me yet another day, to
renew and perfect my repentance. Pardon, good Lord, all my former
sins, and make me every day more zealous and diligent to improve
every opportunity of building up my soul in thy faith, and love, and
obedience: make thyself always present to my mind, and let thy love
fill and rule my soul, in all those places, and companies, and
employments, to which thou callest me this day. In all my passage
through this world, suffer not my heart to be set upon it: but always
fix my single eye, and my undivided affections on the prize of my
high calling! This one thing let me do; let me so press toward this,
as to make all things else minister unto it; and be careful so to use
them, as thereby to fit my soul for that pure bliss, which thou hast
prepared for those that love thee!
M O N D A Y E V E N I N G.
5. Have I let him, I thought in the wrong (in a ♦trifle) have the
last word?
Adored be thy goodness for all the benefits thou hast already
from time to time bestowed on me: for the good things of this life,
and the hope of eternal happiness. Particularly, I offer to thee my
humblest thanks for thy preservation of me this day, (――) ¹. If I
have escaped any sin, it is the effect of thy restraining grace: if I
have avoided any danger, it was thy hand directed me. To thy holy
name be ascribed the honour and glory. O let the sense of all thy
blessings have this effect upon me, to make me daily more diligent
in devoting myself, all I am, and all I have to thy glory.
T U E S D A Y M O R N I N G.
O ETERNAL and merciful Father, I give thee humble thanks
(increase my thankfulness, I beseech thee) for all the
blessings, spiritual and temporal, which in the riches of thy mercy
thou hast poured down upon me. Lord, let me not live but to love
thee, and to glorify thy name. Particularly I give thee most unfeigned
thanks for preserving me from my birth to this moment and for
bringing me safe to the beginning of this day (――) ¹ in which, and
in all the days of my life, I beseech thee that all my thoughts, words,
and works may tend to thy glory. Heal O Father of mercies, all my
infirmities (――), strengthen me against all my follies; forgive me all
my sins (――), and let them not cry louder in thine ears for
vengeance, than my prayers for mercy and forgiveness.
O Lord, hear the king in the day of his trouble; let thy name, O
God, defend him. Grant him his heart’s desire, and fulfil all his mind.
Set his heart firm upon thee, and upon other things only as they are
in and for thee. O defend him and his royal relations from thy holy
heaven, even with the saving strength of thy right-hand.
Have mercy upon this kingdom, and forgive the sins of this
people: turn thee unto us, bless us, and cause thy face to shine on
our desolations. Inspire the nobles and magistrates with prudent
zeal, the gentry and commons, with humble loyalty. Pour down thy
blessings on all seminaries of true religion and learning, that they
may remember and answer the end of their institution. Comfort all
the sons and daughters of affliction, especially those who suffer for
righteousness sake. Bless my father and mother, my brethren and
sisters, my friends and relations, and all that belong to this family.
Forgive all who are mine enemies, and so reconcile them to me and
thyself, that we all, together with those that now sleep in thee, may
awake to life everlasting, through thy merits and intercession, O
blessed Jesus; to whom with the Father and the Holy Ghost, be
ascribed by all creatures, all honour, and might, and wisdom, and
glory, and blessing.
T U E S D A Y E V E N I N G.
3. Have I ascribed to myself any part of any good which God did
by my hand?
11. Have I omitted justifying myself where the glory of God was
not concerned? Have I submitted to be thought in the wrong?
¹ Ignatius.
O pour upon our whole church, and especially upon the clergy
thereof, the continual dew of thy blessing. Grant to our universities
peace and piety, and to all that labour under affliction, constant
patience and timely deliverance. Bless all my kindred, (especially my
father and mother, my brothers and sisters) and all my friends and
benefactors (――) ¹. Turn the hearts of my enemies (――); forgive
them and me all our sins, and grant that we and all the members of
thy holy church, may find mercy in the dreadful day of judgment,
through the mediation and satisfaction of thy blessed Son Jesus
Christ, to whom with thee and the Holy Ghost the comforter, be all
honour, praise and thanksgiving, in all the churches of the saints for
ever.
W E D N E S D A Y M O R N I N G.
O THOU who dwellest in the light which no man can approach, in
whose presence there is no night, in the light of whose
countenance there is perpetual day: I thy sinful servant, whom thou
hast preserved this night, who live by thy power this day, bless and
glorify thee, for the defence of thy almighty providence, (――) ¹ and
humbly pray thee, that this, and all my days may be wholly devoted
to thy service. Send thy Holy Spirit to be the guide of all my ways,
and the sanctifier of my soul and body. Save, defend, and build me
up in thy fear and love; give unto me the light of thy countenance,
peace from heaven, and the salvation of my soul in the day of the
Lord Jesus.
O Thou who art the way, the truth, and the life, thou hast said no
man can follow thee, unless he renounce himself. I know, O Saviour,
that thou hast laid nothing upon us but what the design of thy love
made necessary for us. Thou sawest our disease, our idolatrous self-
love, whereby we fell away from God, to be as gods ourselves, to
please ourselves, and to do our own will. Lo, I come! May I ever
renounce my own, and do thy blessed will in all things!
I know, O God, thou didst empty thyself of thy eternal glory, and
tookest upon thee the form of a servant. Thou who madest all men
to serve and please thee, didst not please thyself, but wast the
servant of all. Thou O Lord of the hosts of heaven and earth, didst
yield thy cheeks to be smitten, thy back to be scourged, and thy
hands and feet to be nailed to an accursed tree. Thus didst thou, our
great Master, renounce thyself: And can we think much of
renouncing our vile selves? My Lord and my God, let me not
presume to be above my master! Let it be the one desire of my
heart, to be as my master, to do not my own will, but the will of him
that sent me.
O thou whose whole life did cry aloud, Father, not mine, but thy
will be done, give me grace to walk after thy pattern, to tread in thy
steps. Give me grace to take up my cross daily, to inure myself to
bear hardship. Let me exercise myself unto godliness betimes,
before the rains descend and the floods beat upon me: Let me now
practise what is not pleasing to flesh and blood, what is not
agreeable to my senses, appetites, and passions, that I may not
hereafter renounce thee, for fear of suffering for thee, but may
stand firm in the day of my visitation.
*O thou, who didst not please thyself, altho’ for thy pleasure all
things are and were created, let some portion of thy spirit descend
on me, that I may deny myself and follow thee. Strengthen my soul
that I may be temperate in all things; that I may never use any of
thy creatures but in order to some end thou commandest me to
pursue, and in that measure and manner which most conduces to it.
Let me never gratify any desire, which has not thee for its ultimate
object. Let me ever abstain from all pleasures, which do not prepare
me for taking pleasure in thee, as knowing that all such war against
the soul, and tend to alienate it from thee. O save me from ever
indulging either the desire of the flesh, the desire of the eye, or the
pride of life. Set a watch, O Lord, over my senses and appetites, my
passions and understanding, that I may resolutely deny them every
gratification, which has no tendency to thy glory. O train me up in
this good way, that when I am old I may not depart from it: that I
may be at length of a truly mortified heart, crucified unto the world,
and the world crucified unto me.
Hear also my prayers for all mankind, and guide their feet into
the way of peace: for thy holy Catholic church, let her live by thy
Spirit, and reign in thy glory. Remember that branch of it which thou
hast planted in these kingdoms; especially the stewards of thy holy
mysteries; give them such zeal, and diligence, and wisdom, that
they may save both themselves and those that hear them.
Preserve, O great King of heaven and earth, all Christian princes,
especially our sovereign and his family. Grant that his council, and all
that are in authority under him, may truly and indifferently
administer justice. And to all thy people give thy heavenly grace,
that they may faithfully serve thee all the days of their life. Bless the
universities with prudence, unity, and holiness. However the way of
truth be evil spoken of, may they walk in it even to the end.
Whoever forget or blaspheme their high calling, may they ever
remember, that they are a chosen generation, a royal priesthood, an
holy nation, a peculiar people: and accordingly, shew forth the praise
of him, who hath called them out of darkness into his marvellous
light.
W E D N E S D A Y E V E N I N G.
T H U R S D A Y M O R N I N G.
O ETERNAL God, my Sovereign Lord, I acknowledge all I am, all I
have is thine. O give me such a sense of thy infinite
goodness, that I may return to thee all possible love and obedience.
I humbly and heartily thank thee for all the favours thou hast
bestow’d upon me; for creating me after thine own image, for thy
daily preserving me by thy good providence, for redeeming me by
the death of thy blessed Son, and for the assistance of thy holy
Spirit: for causing me to be born in a Christian country, for blessing
me with plentiful means of salvation, with religious parents and
friends, and frequent returns of thy ever blessed sacrament. I also
thank thee for all thy temporal blessings; for the preservation of me
this night, (――) ¹ for my health, strength, food, raiment, and all the
comforts and necessaries of life. O may I always delight to praise thy
holy name, and, above all thy benefits, love thee my great
benefactor.
*O thou all-sufficient God of angels and men, who art above all,
and through all, and in all; from whom, by whom, and in whom are
all things; in whom we live, move, and have our being; may my will
be as entirely and continually derived from thine, as my being and
happiness are!
I believe, O sovereign goodness, O mighty wisdom, that thou
dost sweetly order and govern all things, even the most minute,
even the most noxious, to thy glory, and the good of those that love
thee! I believe, O Father of the families of heaven and earth, that
thou so disposest all events, as may best magnify thy goodness to
all thy children, especially those whose eyes wait upon thee. I most
humbly beseech thee teach me to adore all thy ways, though I
cannot comprehend them: teach me to be glad that thou art king,
and to give thee thanks for all things that befall me; seeing thou
hast chosen that for me, and hast thereby set to thy seal that they
are good. And for that which is to come, give me thy grace to do in
all things what pleaseth thee, and then, with an absolute submission
to thy wisdom, to leave the issues of them in thy hand.
T H U R S D A Y E V E N I N G.