MSM Lab Manual
MSM Lab Manual
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Theory:
Crystal Lattice: The arrangement of atoms in a crystal can be described w.r.t.
a three dimensional net of straight lines which is known as space or crystal
lattice.
The interaction of these lines are the points of space lattice and atoms are
supposed to occupy these point in the crystal lattice .The special
characteristics of the space lattice is that every point in it will definitely have
identical surroundings.
Lattice Parameters : Let a, b, c be the length of sides of unit cell in x, y, z
coordinates axis and α,β,γ are the inter axial angles .Hence the unit cell
geometry is completely defined in terms of six parameters ,three edge lengths
A,B,C, and three inter axial angles. Sometimes these are termed as lattice
parameters .
On the basis of lattice parameters, there are seven crystal lattice:--
S.NO. Crystal System Axial Relationship Inter axial Angles
1. Cubic a=b=c α=β=γ
2. Hexagonal a=b≠c α = β = 90, γ = 120
3. Tetragonal a=b≠c α = β = γ = 90
4. Rhomobohedral a=b=c α = β = γ ≠ 90
5. Orthorombic a≠b≠c α = β = γ = 90
6. Monoclinic a ≠ b ≠c β = α = 90 ≠ γ
7. Triclinic a≠b≠c α ≠ β ≠ γ ≠ 90
Unit Cell: The smallest portion of the crystal lattice which when used over and
again completely space lattice is obtained is known as unit cell.
The unit cell is the building block of crystal lattice .on the basis of property of
unit cell; we can define property of space lattice. Although total we have seven
unit cells, but here we discuss only three unit cells for examples BCC, FCC,
HCP.
Body Centered Cubic Unit Cell (BCC)
Another common metallic crystal structure also have a cubic unit cell with
atoms located at all eight corners and a single atom at center. if a is unit cell
edge length and R is the atomic radius a=4*R / √3.
For example: Cr ,Fe ,W.
(a) Total No. Atoms: Two atoms are associated with each BCC unit cell, the
equivalent of one atom from the eight corners, each of which is shared among
eight unit cells. A single atom is wholly contained within its cell.
(b) Coordination No.:-- Co-ordination No. for BCC structure is 8.
(c) Atomic Packing Factor (APF):-- As BCC has lower coordination no. So it has
also lower atomic packing fraction that is 0.68.
1D, Dislocations
Edge
Screw
Low angle grain boundary is an array of aligned edge dislocations. This type of
grain boundary is called tilt boundary (consider joint of two wedges).If the
angle of misalignment is less than 15 degrees tilt boundaries are formed. When
the misalignment angle is more than 15 degrees than these are called High
angle grain boundaries.
Twin Boundaries: This is the surface defect separating two regions of a crystal
which are mirror image of each other with respect to the plane of boundary.
Twin boundaries occur in pairs, such that the orientation change introduced
by one boundary is restores by the other boundary. The region between the
pair of boundaries is called twinned region. (Figure 5)
Theory:
Grain boundaries are not visible in an ordinary piece of metal owing to
deformed layer or corroded surface. Their removal is essential for preparation of
the specimen to be viewed under a microscope. Therefore, grinding (rough and
fine), polishing and etching are done on them. Emery papers of grit size 60, 80,
120, 180, 240 are used for rough to medium finish. Fine grinding is done by
abrasive papers of finer grit grades viz. 320, 400, 600, 800 and 1200. Polishing
is done by polishing compound (Alumina powder) of 0.05 micron, placed on a
polishing velvet cloth that is placed on the wheel. Water is used as lubricant.
Etching is done to make the grain boundaries visible.
Procedure:
1. Grind flat surface on the specimen using belt grinder.
2. Support firmly emery paper of grade240on a flat glass plate. Polish the
specimen under light pressure in forward direction only.
3. Observe scratches on specimen. If they are uniform and in same
direction, go to the next finer paper. While changing from one paper to
another, make the specimen free from abrasive of previous paper and
turn it through 90°, so that scratches from the next finer emery paper are
at right angle to the scratches from previous paper.
4. After polishing on emery paper of grade 800/1000, wash your hands &
the specimen & do the fine polishing on polishing wheel. First use SiO2
abrasive before going to polishing wheel again. Also wash off SiO2 from
your hands & fingers. Now use magnesia powder as abrasive on another
polishing wheel. Keep cloth wet with water.
5. Clean off the polished surface of specimen with water; wipe with Alcohol
& Dry the polished surface with the help of electric hot air blower.
6. Observe the polished surface under the microscope for any scratches
present.
7. If the specimen is sketch free, etch the specimen in 2% Nital solution
8. Examine the specimen under the microscope and observe the
constituents present, sketch & identify. Complete micro structural
report.
9. Store the polished and etched specimen in the desiccators.
Observations:
Material: Grey cast Iron
Magnification:
Etchant: 2%Nital
Graphite flakes
Graphite flakes
Figure:
(a) Microstructure of Gray Cast Iron: the dark graphite flakes are embedded in
an α-ferrite matrix @500X
(b) Microstructure of Nodular (ductile) Iron: the dark graphite nodules are
surrounded by an
α-ferrite matrix @200X.
Experiment No. 7:
Aim: To harden and temper a given steel Specimen.
Equipments:
Muffle furnace, Water container for quenching, Tong for handling heated
specimen, Hardness tester, Emery papers etc.
Theory:
Properties of some metals and alloys can be changed by heating followed by
cooling under definite conditions to make them suitable for specific
applications. Accordingly steels can be hardened to resist cutting action and
prevent abrasion. The rate of cooling and the manner of cooling are the
controlling factors in the heat treatment process such as tempering, annealing,
normalizing and hardening. Different heat treatment processes are carried out
in temperature controlled furnaces and ovens.
Muffle furnace:
Chamber size : 100 mm x 100 mm x 250 mm,
Chamber insulation: Ceramic
Maximum temperature: 1200°C
Power: 2 kW
Control panel: Digital controller, ammeter and contactor
Measuring device: LED temperature controller with adjustable set
point
Result: -
1 Hardness of steel specimen before tempering is HRC ………...
Theory:
Properties of some metals and alloys can be changed by heating followed by
cooling under definite conditions to make them suitable for specific
applications. Accordingly .The rate of cooling and the manner of cooling are the
controlling factors in the heat treatment process such as tempering, annealing,
normalizing and hardening. Different heat treatment processes are carried out
in temperature controlled furnaces and ovens.
Muffle furnace:
Chamber size : 100 mm x 100 mm x 250 mm,
Chamber insulation: Ceramic lining
Maximum temperature: 1200°C
Power: 2 kW
Control panel: Digital controller, ammeter and contactor Measuring
device: LED temperature controller with adjustable set point
Result: -
1 Hardness of steel specimen before annealing is HRC ……
2 Hardness of steel specimen after annealing is HRC ……..
Experiment No. 9:
Aim: To analyze microstructure of quench hardened
steel specimen.
Requirement:
1. Heating Furnace
2. Water tub for quenching
3. Tong for handling heated specimen
4. Metallurgical microscope
5. Rough polishing emery paper
6. Fine polishing machine
7. Etchant -2%Nital
8. Hardness tester
Procedure:
1. From Fe-C equilibrium diagram find out the temperature to which
specimen of about 0.4% Carbon steel should be heated so that it's fully
Austenite i.e. 800+40°C =840°C
2. Set the furnace at this temperature for heating the specimen.
3. When the furnace temperature reaches this value. Stabilize the
temperature at this level & when temperature is stabilized, load the
specimen & let it be soaked at this temperature for half an hour. The idea
behind it is to homogenize the Austenite transformation.
4. Take the specimen out of furnace using dry tong & quench the specimen
in water.
5. The sample is rough polished, fine polished on machining so that the
specimen surface is flat, scratch free & has mirror finish.
6. Etch the polished surface.
7. Check the microstructure under metallurgical microscope (It will show
dark patches of pearlite & white areas of cementite)
8. Check the hardness of heat treated specimen on Rockwell hardness tester.
Result:
1 The microstructure of heat treated surface is that of pearlite (10%) &
cementite (90%)
2 Hardness value of heat treated specimen is HRC-
Experiment No. 10:
Aim: To analyze the properties of various types of
plastic
Requirement:
Samples of Polyethylene, PVC, Polypropylene, polystyrene
Theory:
Plastics are organic materials of high molecular weight, which can be moulded
into desired shape or form when subjected to high temperature & pressure in
the presence of catalyst.
Procedure:
We collect samples of different types of plastics like PVC, Polyethylene, Poly
propylene and Polystyrene. These plastics are dipped into acidic and alkaline
media to find out the resistance of plastic.
Observation:
Plastic Acid/Alkalies Resistant/Reactive
PVC Na2CO3&HCl Resistant
Polyethylene HCl & NaOH Resistant
Polypropylene HCl & NaOH Resistant
Polystyrene HNO3 & H2SO4 Reactive
Result:
PVC, Polyethylene and Polypropylene have been found to be more resistant to
acid and alkali and polystyrene has been found more reactive to acid and alkali.