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Checkpoint Exam 2

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Hoang Tuan Anh
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9 views1 page

Checkpoint Exam 2

Uploaded by

Hoang Tuan Anh
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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CHECKPOINT

CHAPTER 5: EDTA TITRATION


1. Fomular of EDTA, pK1-4, the dissociated forms of EDTA in solution; the dominated
form in a certain pH
2. What is Complexon III, Triplex III, and why is they used more than EDTA in preparing
the EDTA solution.
3. The poperties of metal-EDTA complexes: stoichiometric ratio; stability, the influence
factors to the stability.
4. Draw the titration curve (shape, direction) in the titration metal with EDTA and vice
versa.
5. Define the titration jump and the it’s properties, the influence factors (β, pH, auxiliary
ligand)
6. Construc and write the titration error equation at all points and close to the equi. point.
7. What is metal indicators in the EDTA titrations: formular, properties, color of pH-
depended free-metal forms and color of meta-indicator form; requirements.
8. Write the titration reaction and reaction at the end point (with a certain indicator) in the
direct titration, black and replacement titrations.
9. Recorgnize the titration technique (direct, back or preplacement) in the analytical
procedures
10. Write the reactions during the analytical procedure.
Calculation skills
11. Calculate the conditional formation constants of the Metal-EDTA complexes (β’ )
12. Calcualte pM at certain values of Vtitrant using mass conservation law and mass reaction
law or using the error equation.
13. From the ratio of metal-free indicator form:metal-indicator form at the end point,
calculate the pM or pM’.
14. Calculate the error form the pMend point
15. Calculate the practical concentration (without error) and the analytical concentration
(with error).
16. Calculate mass, percentage or concentration of analytes.
CHAPTER 6: ARGENTOMETRY TITRATIONS
1. Why is argentometry popular in the precipitation titration?
2. Which anions can be titrated by argentometry?
3. Draw the titration curves in the titration of:
a. Cl– with AgNO3; compare when Cl– replaced by Br– or I–
b. AgNO3 with CN– or SCN–
4. Define the titration jump and it’s properties.
5. Contructe and write the titration error equations at all point and close to the equi. point.
6. Write the reaction titration, endpoint reaction in Morh’s method to titrate Cl–.
7. The medium, the factor influencing the error in the Morh method
8. Describe the Volhard’s method, how to avoid the error, what is the modified Volhard’s
method. Write the reaction titration and endpoint reaction, color change.
Calculation skills
9. Calculate pAg at the certain values of VAgNO3 from basic laws or from the q-equation
10. Morh’s method: Calucater the titration error in the certain value of CrO42– concentration
and vice versa.
11. Volhard’s method: Calculate the titration error in the certain value of Fe3– concentration
and vice versa.
12. Calculate the practical concentration and the analytical concentration of analytes in
Morh’s and modified Volhard’s methods.

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