(Chemical Bonding)

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Marking Scheme:

(i) Each question is allotted 4 (four) marks for each


H CH3 Cl CH3
correct response. (C) C=C (D) C=C
(ii) ¼ (one fourth) marks will be deducted for indicating CH3 H H3C Cl
incorrect response of each question. No deduction
from the total score will be made if no response is Q.14 H – O – H bond angle in H2O is 104.5° and not
indicated for an item in the answer sheet. 109°28' because of –
–––––––––––––––––––––––––––––––––––––––––––––––– (A) lone pair-lone pair repulsion
Q.1 The shape of IF5 is – (B) lone pair-bond pair repulsion
(A) pentagonal bipyramidal (B) square pyramidal (C) bond pair-bond pair repulsion
(C) octahedral (D) trigonal planar (D) high electronegativity of oxygen
Q.2 The hybridisation present in IF3 is – Q.15 Which of the following does not have a coordinate
(A) sp3d (B) sp3 bond –
3
(C) sp d 2 (D) sp3d3 (A) SO2 (B) HNO3
Q.3 The molecule having larges dipole moment among (C) H2SO3 (D) HNO2
the following is – Q.16 In which of the following pairs, both molecules
(A) CHI3 (B) CH4 possess dipole moment ?
(C) CHCl3 (D) CCl4 (A) CO2, SO2 (B) BCl3, PCl3
Q.4 The correct sequence of hybridisation of methane, (C) H2O, SO2 (D) CO2, CS2
ethene and acetylene is – Q.17 Which one of the following molecules will form a
(A) sp, sp2, sp3 (B) sp2, sp3, sp linear polymeric structure due to hydrogen bonding ?
3 2
(C) sp , sp , sp (D) sp3, sp, sp2 (A) NH3 (B) H2O
Q.5 Which of the following elements shows maximum (C) HCl (D) HF
valency Q.18 Among the following the electron deficient
(A) Carbon (B) Barium compound is –
(C) Nitrogen (D) Sulphur (A) BCl3 (B) CCl4
Q.6 Hybridisation present in ClF3 is (C) PCl5 (D) BeCl2
(A) sp2 (B) sp3 Q.19 The relationship between the dissociation energy of
2 (D) sp3d
(C) dsp N2 and N2+ is –
Q.7 Electron deficient molecule is –
(A) Dissociation energy of N2+>dissociation energy
(A) CCl4 (B) PCl5
of N2
(C) BF3 (D) SF6
(B) Dissociation energy of N2= dissociation energy
Q.8 The bond order of O2+ is the same as in –
of N2+
(A) N2+ (B) CN–
(C) Dissociation energy of N2> dissociation energy
(C) CO (D) NO+
Q.9 The compound in which underlined carbon used only of N2+
its sp3 hybrid orbitals for bond formation is – (D) Dissociation energy of N2 can either be lower or
(A) CH3COOH (B) CH3CONH2 higher than the dissociation energy of N2+
(C) CH3CH2COH (D) CH3CH = CH2 Q.20 Cation and anion combines in a crystal to form
Q.10 C – C bond order in benzene is – following type of compound –
(A) 1 (B) 1 (A) ionic (B) metallic
(C) between 1 and 2 (D) None of these (C) covalent (D) dipole-dipole
Q.11 Sequence of bond length of the following is
A. ethane B. ethene C. ethyne For Q.21-Q.25 :
(A) A > B > C (B) B > A > C The answer to each question is a NUMERICAL
(C) C > B > A (D) C > A > B VALUE.
Q.12 Which type of bond is present in Xe molecule?
(A) Covalent (B) Ion-dipole Q.21 The number of  and  bonds present in
(C) Van der Waals’ (D) Dipole-dipole HC C – CH2 – CH = CH2 are (10, X). Find the
Q.13 Which has the highest dipole moment ? value of X.
H CH3 H Q.22 The number of double bonds in gammexane is –
Q.23 Allyl isocyanide contains  and -bonds are
(A) C=O (B) C=C
(9, X). Find the value of X.
H CH3 H

1
Q.24 Value of x in potash alum, K2SO4.Alx (SO4)3.24H2O
is –
Q.25 The number of unpaired electrons in oxygen
molecule is –

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