MCAT Equation Sheet
MCAT Equation Sheet
VE - valence electrons
Formal charge
BE - bonding electrons (in pairs)
= VE - ½ BE - LPE LPE - lone pair electrons
Percent yield
percent yield =
actual mass of desired product
theoretical mass of desired product
x 100%
Chemistry Equilibrium (rate forward = rate reverse)
k Keq or Kc - equilibrium constant
Keq = kforward
R - ideal gas constant reverse kforward - rate constant of forward reaction
(8.3145 J · mol-1 · K-1) kreverse - rate constant of reverse reaction
or 0.082 L · atm · K-1 · mol-1) aA + bB cC + dD [A-D] - concentration of reactants and products A-D.
[C] [D]d
c
a-d - stoichiometric coefficients
F - Faraday’s constant Kc = [A]a[B]b
(96,485 C/mol)
Reaction quotient
aA + bB → cC + dD
[C]c [D]d Kc - equilibrium constant
Q = [A]a [B]b
Q - reaction quotient
[A-D] - concentration of reactants and products A-D.
Q > Kc: Reaction nets reactants a-d - stoichiometric coefficients
Q < Kc: Reaction nets products
Q = Kc: Equilibrium
Kelvin Temperature
K - temperature in Kelvin
K = oC + 273.15 o
C - temperature in Celsius
Heat
Q - heat
m - mass
Q = mcΔT c - specific heat
ΔT - change in temperature
Enthalpy of the reaction
ΔH°rxn - enthalpy of reaction
ΔH o
rxn
= ΔHo
products
- ΔHo
reactants
ΔH°products - enthalpy of products
ΔH°reactants - enthalpy of reactants
Chemistry
standard conditions
ΔGorxn = -RTlnKeq R - ideal gas constant
T - temperature
Keq - equilibrium constant
R - ideal gas constant
(8.3145 J · mol-1 · K-1) van der Waals equation
or 0.082 L · atm · K-1 · mol-1)
P - pressure
V - Volume
F - Faraday’s constant
n - moles of gas
(96,485 C/mol)
an2 R - ideal gas constant
(P + V2 )(V - nb) = nRT T - Temperature
a - the attractive forces factor
b - the volume factor
Boyle’s law
P - pressure
PV = constant V - volume
Charles’s law
V - volume
V
T
= constant T - temperature
Gay-Lussac’s law
P - pressure
P
T
= constant T - temperature
Molality
Molarity
Raoult’s law
P - vapor pressure of the solution
P = XAPAO XA - mole fraction of the solvent
PA° - vapor pressure of the pure solvent
Boiling point elevation
ΔTb - magnitude of boiling point elevation
i - van ‘t Hoff factor
ΔTb = iKbm Kb - boiling point elevation constant
m - molality
Osmotic pressure
R - ideal gas constant
(8.3145 J · mol-1 · K-1) Π - osmotic pressure
or 0.082 L · atm · K-1 · mol-1) i - van ‘t Hoff factor
Π = iMRT M - molarity
F - Faraday’s constant R - ideal gas constant
(96,485 C/mol) T - temperature
Arrhenius equation
k - rate constant
A - frequency factor constant
k = Ae-Ea /RT Ea - activation energy
R - ideal gas constant
T - temperature
Reaction rate
rate - reaction rate
k - rate constant
rate = k[A]x[B]y [A] and [B] - concentration of reactants
x and y - order of reaction with respect to each
reactant
Ionization constant of water
Kw - ionization constant of water
KW = [H3O+][OH-] = 1 x 10-14
[H₃O+] and [OH-] - concentrations of hydronium and
at 25oC hydroxide ions in water
pH
pH = -log[H3O+]
pOH
pOH = -log[OH-]
Henderson-Hasselbalch equation
pH - pH of the solution
pKa - pKa of acid
[A ]
-
pH = pKa + log [HA] [HA] - concentration of acid
[A-] - concentration of conjugate base
Equivalence point of a titration
a and b - number of dissociable protons or hydroxide
ions
aMaVa = bMbVb M - molarity of acid or base
V - volume of acid or base
Standard cell potential
Eocell - standard cell potential
E o
cell
=E
o
cathode
-E o
anode
Eocathode - electric potential at cathode
Eoanode - electric potential at anode
Nernst equation
Eocell - standard cell potential
RT E′cell - cell potential
E′cell = Eocell - nF lnQ R - ideal gas constant
T - temperature
Organic
Chemistry
R - ideal gas constant
(8.3145 J · mol-1 · K-1)
or 0.082 L · atm · K-1 · mol-1)
F - Faraday’s constant
(96,485 C/mol)
Pythagorean theorem
Kinematic equation 1
Δx - displacement
t - time
1
d = 2 (vi + vf )t vi - initial velocity
vf - final velocity
Kinetic friction
Fkinetic - kinetic friction force
Fkinetic = μkN N - normal force
ųk - coefficient of kinetic friction
Gravitational formula
Fgrav - gravitational force
m1m2 G - universal gravitational constant
Fgrav = G r2 m - mass of first and second objects
Centripetal acceleration
a - centripetal acceleration
v2 v - velocity
a= r r - distance of an object from the center of orbit
Conservation of energy
Physics
KE - kinetic energy
1
KE = 2 mv2r ms m - mass of a particle
vrms - root mean square of velocity
k - Coulomb’s constant
(8.99 x 109 N · m2/C2) Fahrenheit to Celsius
Specific gravity
ρ ρ - density of substance
specific gravity = ρ ρwater - density of water
water
Physics Pressure
P - pressure
F
P= A F - force
G - universal gravitational A - area
constant (6.67 x 10-11 N · m2 / kg2)
Hydrostatic pressure
g - acceleration due to gravity
(9.8 m/s2) Psub - gauge pressure
ρ - density of fluid
R - ideal gas constant Psub = ρgh g - acceleration due to gravity
(8.3145 J · mol-1 · K-1) h - submerged depth
or 0.082 L · atm · K-1 · mol-1)
Absolute pressure
kB - Boltzmann constant
(1.38 x 10-23 J/K) Pabs - absolute pressure
Patm - atmospheric pressure
pwater - density of water
Pabs = Patm + ρgh ρ - density of fluid
(1 g/cm3 = 1 g/ml = 1000 kg/m3) g - acceleration due to gravity
h - submerged depth
k - Coulomb’s constant
(8.99 x 109 N · m2/C2)
Part of object submerged
ε0 - the permittivity of free space %submerged - how much of an object is submerged
ρobject
(8.85 x 10-12 C2/N · m2) % submerged = ρliquid · 100 ρobject - density of object
ρliquid - density of liquid
μ0 - the permeability of free
space (4π x 10-7 N/A2) Buoyant Force
c - speed of light in a vacuum Fbuoy - buoyant force
(3 x 108 m/s) ρ - density of fluid
Fbuoy = ρVg V - volume of fluid displaced
h - Planck’s constant g - acceleration due to gravity
(6.63 × 10-34 m2 · kg / s)
Pascal’s law
R - the Rydberg constant P - Pressure
(1.097 x 107 m-1) F F
P = A1 = A2 F - force
1 2
A - area
Pascal’s law
W - work
W = F1d1 = F2d2 F - Force
d - displacement
Poiseuille’s law
Q - flow rate
r - radius of the vessel
πr4ΔP ΔP - change in pressure
Q = 8ηL η - viscosity
L - length of the vessel
Bernoulli’s law
P - pressure
1
P1 + 2 ρv12 + ρgh1 = ρ - density of fluid
v - velocity of the fluid
1
P2 + 2 ρv22 + ρgh2 g - acceleration due to gravity
h - height or depth with respect to ground level
Continuity equation
v - velocity
v1A1 = v2A2
Physics A - area of the vessel
Pitot tube
G - universal gravitational Pstag - stagnation pressure
constant (6.67 x 10-11 N · m2 / kg2) 1 Pstatic - static pressure
Pstag - Pstatic = 2
ρv 2
ρ - density of fluid
g - acceleration due to gravity v - velocity of the fluid
(9.8 m/s2)
Resistance
R - ideal gas constant
(8.3145 J · mol-1 · K-1) R - resistance
or 0.082 L · atm · K-1 · mol-1) ρ - resistivity
ℓ
R=ρ A ℓ - length of resistor
kB - Boltzmann constant A - area of resistor
(1.38 x 10-23 J/K)
Conductance
pwater - density of water G - conductance
(1 g/cm3 = 1 g/ml = 1000 kg/m3) σ - conductivity (1/ρ)
A
G=σ ℓ ℓ - length of conductor
k - Coulomb’s constant A - area of conductor
(8.99 x 109 N · m2/C2)
Coulomb’s law
ε0 - the permittivity of free space
(8.85 x 10-12 C2/N · m2) F - electrostatic force
k - Coulomb’s constant
kq1q2
μ0 - the permeability of free F= q - charge of a particle
r2 r - distance between charges
space (4π x 10-7 N/A2)
V - voltage
U - electric potential energy
U kQ k - Coulomb’s constant
V= q = r Q or q - magnitude of charge
r - distance from electric field source
Ohm’s law
V - voltage
V = IR I - current
R - resistance
Power
P - power
V - voltage
V2 I - current
P = IV = I 2R = R
R - resistance
Capacitance
C - capacitance
ε0 - the permittivity of free space
A
C = ε0 d A - cross-sectional area of the plates
d - distance between the plates
Capacitance in parallel
Physics
branch
Speed of sound
v - speed of sound in a medium
B
Vsound = ρ
B - bulk modulus of medium
p - density of medium
Decibel level
dB - decibel level
I
dB = 10log( I ) I - intensity of given sound
0 I0 - reference intensity
Doppler effect
Physics
2L
λ= n L - length of the pipe or string
n - integer of harmonic
Magnification
o - object distance
i
m = -o i - image distance
m - magnification
Power of a lens
Physics P= f
1 P - power of a lens
f - focal distance
G - universal gravitational
constant (6.67 x 10-11 N · m2 / kg2) Mass-energy equivalence
E - binding energy of a nucleus
g - acceleration due to gravity E = mc2 m - mass defect
(9.8 m/s2) c - speed of light in a vacuum
Exponential decay
n - remaining amount
n0 - original amount
n = n0e -λt
t - time
λ - decay constant
Half-life
Physics
G - universal gravitational
constant (6.67 x 10-11 N · m2 / kg2)
kB - Boltzmann constant
(1.38 x 10-23 J/K)
k - Coulomb’s constant
(8.99 x 109 N · m2/C2)
h - Planck’s constant
(6.63 × 10-34 m2 · kg / s)