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Data, Statistics, and
Useful Numbers for
Environmental
Sustainability
Bringing the Numbers to Life
Benoit Cushman-Roisin
Bruna Tanaka Cremonini
Thayer School of Engineering,
Dartmouth College,
Hanover, NH, USA
Elsevier
Radarweg 29, PO Box 211, 1000 AE Amsterdam, Netherlands
The Boulevard, Langford Lane, Kidlington, Oxford OX5 1GB, United Kingdom
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This book and the individual contributions contained in it are protected under copyright by
the Publisher (other than as may be noted herein).
Notices
Knowledge and best practice in this field are constantly changing. As new research and
experience broaden our understanding, changes in research methods, professional prac-
tices, or medical treatment may become necessary.
Practitioners and researchers must always rely on their own experience and knowledge in
evaluating and using any information, methods, compounds, or experiments described
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To the fullest extent of the law, neither the Publisher nor the authors, contributors, or
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of products liability, negligence or otherwise, or from any use or operation of any methods,
products, instructions, or ideas contained in the material herein.
ISBN: 978-0-12-822958-3
xi
xii Preface
Materials
Materials extraction in the world in 2013 was estimated at 84.4 billion (109)
metric tons (45.8% industrial and construction materials, 26.8% biomass,
17.2% fossil fuels, and 10.2% metals, excluding unused portion), or 11.8
metric tons per capita per year [1].
In the United States during 2013, materials consumption including fuels
was estimated at 6.5 billion (109) metric tons per year, corresponding to 23.6
metric tons per capita per year, 51% higher than in Europe [2].
1.1 Metals
1.1.1 Aluminum
Aluminum production from bauxite via alumina is one of the most energy-
intensive processes in the industry. According to a United Nations report
based on 1979 data, the energy profile of aluminum is as tabulated below.
Technologies have evolved ([4] page 125) toward greater energy efficiency.
Compilation of multiple data sets for primary production (excluding the
fabrication stage) yields an embodied energy in aluminum of 210 10 MJ/kg
([4] page 471).
The carbon footprint for primary production is 12 kg of CO2eq/kg whereas
the water usage varies from 495 to 1,490 L/kg ([4] page 471).
Recycling aluminum demands much less energy, only 26 MJ/kg for cast
aluminum and 26.7 MJ/kg for wrought aluminum [5]. Its carbon footprint is
2.1 kg CO2/kg (in average).
Energy
consumption Energy type
1.1.4 Lead
Production of 1 kg of lead (Pb) from ore (galena, PbS) requires 27 MJ,
175e525 L of water and generates 2.0 kg of CO2eq, while production of lead
from recycled sources (mostly discarded automobile batteries) consumes
7.5 MJ/kg and generates 0.45 kg CO2eq/kg. The single largest use of lead (70%
of total production) is as electrodes in lead-acid batteries ([4] page 479).
1.1.5 Magnesium
Production of magnesium causes the following environmental impacts.
4 Data, Statistics, and Useful Numbers for Environmental Sustainability
1.1.6 Nickel
Production of nickel causes the following environmental impacts.
Continued
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Materials Chapter | 1 5
Iridium
Primary 43,000e47,600 2,900 186,000e206,000
Recycled (0.7%) 2,000e2,210 165
Palladium
Primary 149,000e165,000 8,500 186,000e206,000
Recycled (3%) 5,140e5,680 426
Platinum
Primary 257,000e284,000 14,750 186,000e206,000
Recycled (3%) 7,760e8,570 642
Rhodium
Primary 531,000e587,000 30,450 186,000e206,000
Recycled (0.7%) 13,500e14,900 1,120
Silver
Primary 1,400e1,550 100 1,150e3,460
Recycled (66%) 140e170 9.3
Titanium alloys
Primary 650e720 46.5 470e1,410
Recycled (23%) 78e96 5.2
Source: [4]: pages 127, 474, 487, 488 and accompanying CES EduPack software.
1.1.8 Zinc
Production of zinc causes the following environmental impacts.
atoms for every carbon atom in the fuel consumed in production (molar mass
of 15 g per mole), the CO2 emission (with a molar mass of 44 g per mole) is
44/15 ¼ 2.9 kg of CO2 for every kg of plastics produced1. Actual amounts vary
with the type of plastics, as the table below indicates.
Embodied Greenhouse
energy gas emission Water usage
Continued
1. Note: The amount of 6 kg of CO2 emitted per kg of plastic mentioned by Time for Change [8] is
inaccurate.
Materials Chapter | 1 7
1.4 Chemicals
In the United States, the chemical industry consumes an average of 6,935
BTUs per lb of product [15]. This energy intensity, however, depends widely
on the nature of the chemical, as illustrated in the table on the following pages.
Because different production paths consume different amounts of energy,
the energy used in the production of a chemical depends on its feedstock.
Chemicals obtained from the cracking and distillation of petroleum or inor-
ganic sources are called raw materials. Thus, the total energy consumed in the
production of a chemical is the sum of the energy inputs for its production and
that of all its predecessors (each with corresponding mass ratio deduced from
the stoichiometric ratio), starting from the raw material. Example: The energy
consumed in producing 1 lb of ethylene glycol from ethylene oxide (with mass
ratio 0.710:1) from ethylene as raw material (with mass ratio 0.637:1) is:
E ¼ 2,045 þ 0.710 (1,711 þ 0.637 8,107) ¼ 6,923 BTU/lb.
To such number may be added the energy necessary for the intermediate
production of the required hydrogen and chlorine.
Energy consumption
BTUs/lb unless Mass
Chemical otherwise noted Made from ratio
Acetic acid (vinegar) 2,552 [16]
Acetone 7,850
Acrylonitrile 956 Propylene 0.793:1
Ammonia 12,150
Ammonium 323 Ammonia 0.944:1
Ammonium nitrate 341 Nitric acid 0.787:1
Ammonium phosphate 323
Ammonium sulfate 4,000 Ammonia 0.258:1
Benzene 1,255 Petroleum
Bisphenol A (BPA) 6 MJ/kg [17]
1,3-Butadiene 95 by-product of ethylene
Carbon black 3,703 MJ/ton [18]
Chlorine 4,800 Sodium chloride 1.648:1
Cumene 696 Benzene 0.650:1
(Isopropylbenzene)
Cyclohexane 1,743 Benzene 0.928:1
Ethyl benzene 1,404 Benzene 0.736:1
Ethylene 8,107 Petroleum
Ethylene dichloride 3,410 Ethylene 0.283:1
Ethylene glycol 2,045 Ethylene oxide 0.710:1
Ethylene oxide 1,711 Ethylene 0.637:1
Formaldehyde 150 kWh/ton [18]
Hydrochloric acid 1.2 MJ/kg [18]
Hydrogen 1.8 GJ/ton
Isopropyl alcohol 4,693 Propylene 0.700:1
Methanol 38.4 GJ/ton
Methyl tert-butyl ether 1,871 [19]
(MTBE)
Continued
10 Data, Statistics, and Useful Numbers for Environmental Sustainability
Carbon
Energy use emission
Process type Variant (MJ) (kg of CO2eq)
Heavy 0.8e2.5 0.06e0.17
Finishing (light) 6e10 0.4e0.7
Machining (per kg
removed) Grinding 25e35 1.8e2.5
Water jet, EDM, 500e5,000 35e350
laser
Continued
12 Data, Statistics, and Useful Numbers for Environmental Sustainability
Molding Extrusion
CO2 CO2
Energy use footprint Energy use footprint
Polymer (MJ/kg) (kg/kg) (MJ/kg) (kg/kg)
Acrylonitrile 18e20 1.4e1.5 5.8e6.4 0.44e0.48
butadiene styrene
(ABS)
Polyamides 21e23 1.55e1.7 5.9e6.5 0.44e0.49
(Nylons, PA)
Polypropylene (PP) 20.4e22.6 1.5e1.7 5.9e6.5 0.44e0.49
Polyethylene (PE) 22.7e25.1 1.7e1.9 6.0e6.6 0.45e0.49
Polycarbonate (PC) 17e6.19.5 1.3e1.5 5.8e6.4 0.43e0.48
Polyethylene 18.7e20.6 1.4e1.55 5.8e6.4 0.44e0.48
terephthalate (PET)
Polyvinylchloride 13.9e15.4 1.05e1.16 5.6e6.3 0.42e0.47
(PVC)
Polystyrene (PS) 16.5e18.3 1.24e1.37 5.7e6.4 0.43e0.48
Polyhydroxyalka- 16.6e18.4 1.25e1.38 5.8e6.4 0.43e0.48
noates (PHA, PHB)
Polylactide (PLA) 15.4e17 1.15e1.27 5.7e6.3 0.43e0.47
Continued
Materials Chapter | 1 13
Primary production
Embodied Carbon
energy footprint (kg Water usage
Material (MJ/kg) CO2eq/kg) (L/kg)
Anti-freeze 76
Automotive Engine oil 60.2
Other fluids 52
Carbon fiber 450e500 33e36 360e1,367
Alumina 49.5e54.7 2.67e2.95 29.4e88.1
Glass 10e11 0.7e0.8 14e20.5
Glass- 7.4e9.0 0.44e0.54
recycling
Ceramics Glass - 27.7e30.6 1.67e1.84 28.7e31.8
laminated
Pyrex 27e30 1.6e1.8 26e37.5
Pyrex - 20e23 1.2e1.4 26e37.5
recycling
Brick 2.2e3.5 0.20e0.23 2.8e8.4
Cement 0.927
1
Construction Concrete 1.0e1.3 0.09e0.12 1.7e5.1
Sand 1.0
Stone 0.4e0.6 0.03e0.04 1.7e5.1
Continued
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14 Data, Statistics, and Useful Numbers for Environmental Sustainability
Sources
[1] Sustainable Europe Research institute (SERI) in cooperation with Vienna University of
Economics and Business. www.materialflows.net/fileadmin/docs/materialflows.net/WU_
MFA_Technical_report_2015.1_final.pdf. See also Organization for Economic Cooperation
and Development (OECD). www.oecd.org/greengrowth/MATERIAL%20RESOURCES,%
20PRODUCTIVITY%20AND%20THE%20ENVIRONMENT_key%20findings.pdf
[2] University of Michigan e Center for Sustainable Systems e U.S, Material Use Factsheet, Pub.
No. CSS05-18, 2019. For older data, see U.S. Geological Survey, Fact Sheet 2009-3008, css.
umich.edu/sites/default/files/US%20Material%20Use_CSS05-18_e2019.pdf, pubs.usgs.gov/
fs/2009/3008/
Materials Chapter | 1 15
[3] United Nations Center on Transnational Corporations e Climate Change and Transnational
Corporations e Analysis and Trends. U. N. Centre on Transnational Corporations, Environ.
Ser. 2 (1992). ST/CTC/112, ISBN 92-1-104385-9, Chapter 7 “Production of Energy
Intensive Metals”, 110 pages, ieer.org/wp/wp-content/uploads/1992/01/ClimateChange-
TransnationalCorp_1992-FULL.pdf.
[4] M.F. Ashby, Materials and the Environment e Eco-Informed Material Choice, second ed.,
Butterworth-Heinemann, 2013, 616 pages.
[5] M. Schubert, K. Saur, H. Florin, P. Eyerer, H. Beddies, Life Cycle Analysis e Getting the
Total Picture on Vehicle Engineering Alternatives, Automotive Engineering, March 1996,
pp. 49e52.
[6] U.S. Department of Energy, Energy Information Administration (eia) e 2011: Steel
Industry Analysis Brief e Energy Consumption. www.eia.doe.gov/emeu/mecs/iab98/steel/
intensity.html.
[7] Bureau of International Recycling, The Industry. www.bir.org/industry/.
[8] Time for Change, Plastic bags and plastic bottles e CO2 emissions during their lifetime.
timeforchange.org/plastic-bags-and-plastic-bottles-CO2-emissions.
[9] Wood M., Let Your Trees Grow For Profit (undated article). www.woodmagazine.com/
materials-guide/lumber/let-your-trees-grow-for-profit.
[10] How it’s Made, Forest for Paper (About Sappi Company in South Africa). howitsmade.co.
za/growing-forests-for-paper-pulp/.
[11] Sierra Club, How much paper does one tree produce? www.sierraclub.org/sierra/2014-4-
july-august/green-life/how-much-paper-does-one-tree-produce.
[12] Conservatree.org, Trees into Paper e How Much Paper Can Be Made from a Tree?
conservatree.org/learn/EnviroIssues/TreeStats.shtml.
[13] C. Thompson, Recycled Papers e the Essential Guide, MIT Press, Cambridge, MA, 1992,
200 pages. Quoted by, conservatree.org/learn/EnviroIssues/TreeStats.shtml.
[14] Paper Recycles. paperrecycles.org/statistics/paper-paperboard-recovery and. paperrecycles.
org/statistics/where-recovered-paper-goes.
[15] U.S. Department of Energy, Office of Industrial Technologies e Energy and Environmental
Profile of the U.S. Chemical Industry, May 2000. www1.eere.energy.gov/manufacturing/
resources/chemicals/pdfs/profile_full.pdf.
[16] M. Neelis, E. Worrell, E. Masanet, Energy Efficiency Improvement and Cost Saving
Opportunities for the Petrochemical Industry, Lawrence Berkeley National Laboratory, June
2008. www.energystar.gov/ia/business/industry/Petrochemical_Industry.pdf.
[17] R. Agrawal, A. Suman, Production of Bisphenol A, Dept. Chemical Engineering, Jaypee
University of Engineering and Technology, Guna, India, 2012. www.scribd.com/doc/
94377374/Production-of-Bisphenol-A#scribd.
[18] H.-J. Althaus, R. Hischier, M. Osses, A. Primas, S. Hellweg, N. Jungbluth, M. Chudacoff,
Life Cycle Inventories of Chemicals, Swiss Center for Life Cycle Inventories, Zürich,
Ecoinvent Report No. 8, 2007. December 2007, 957 pages, db.ecoinvent.org/reports/08_
Chemicals.pdf.
[19] E. Worrell, D. Phylipsen, D. Einstein, N. Martin, Energy Use and Energy Intensity of the
U.S. Chemical Industry, University of California Berkeley, 2000. LBNL-44314, April 2000,
34 pages, escholarship.org/content/qt2925w8g6/qt2925w8g6.pdf.
[20] European Commission e Integrated Pollution Prevention and Control e Large Volume
Inorganic Chemicals e Solids and Others Industry, August 2007, 711 pages, eippcb.jrc.ec.
europa.eu/sites/default/files/2019-11/lvic-s_bref_0907.pdf.
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