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HAZARDOUS MATERIALS AND

HAZWOPER AWARENESS TRAINING


OBJECTIVE

Provide an introduction to Hazardous


Materials identification and management in
the workplace, and cover First Responder
Awareness Level requirements, roles, and
responsibilities as prescribed in OSHA’s
Hazardous Waste Operation (HAZWOPER)
standard
MEETING TIPS FOR ONLINE
TRAINING

1). Place yourself on “Mute” to prevent background noise.


2). Use the “Chat with all” feature to ask questions.
Note: All participants will be able to see your comments or
questions.
3). Every participant will receive a certificate of completion.
INSTRUCTOR
INTRODUCTION
BIE BRANCH OF ENVIRONMENTAL
MANAGEMENT (BIE BEM)
WHO WE ARE…
Albuquerque Office
John Clymo, Program Manager, Supervisory Environmental Protection Specialist
Candace DeSantis, Lead Environmental Protection Specialist
Karlisa Benally, Environmental Protection Specialist
Priscilla Avila, Environmental Protection Specialist
Henryetta Price, Environmental Protection Specialist
Rochelle Mariano, Program Support Assistant

Bloomington Office
Russell Brigham, Environmental Protection Specialist
Doug Yocum, Environmental Protection Specialist

Gallup Office
Karmen Billey- Badonie, Environmental Protection Specialist
AGENDA
• Background
• Chemical Management
• HazMat Transportation
• HAZWOPER
BACKGROUND
INFORMATION
WHAT IS A HAZARDOUS
MATERIAL?
Hazardous materials (aka hazmat) are chemical substances that if
released or misused can pose a threat to property, the
environment, or health. Such chemicals are prevalent in many
industries and products, including agriculture, medicine, research,
and consumer product development. Hazardous materials can be:
• Carcinogens
• Toxins
• Irritants
• Damaging to skin, lungs, eyes, mucous
membranes
• Combustible
• Flammable
• Explosive
• Reactive,
• Compressed gases
• Etc.
APPLICABLE REGULATIONS
• OSHA
• Hazard Communication Standard 29 CFR 1910.1200(a)(1)
• Purpose:
• Ensure that hazards of all chemical produced or imported are
classified
• And that information concerning classified hazards is
transmitted to employers and employees
BACKGROUND

Hazardous Materials – Hazardous Chemical Products - Hazardous Waste -


DOT OSHA EPA

Hazardous Substance (Spills) – EPA


CHEMICAL
MANAGEMENT
GLOBALLY HARMONIZED SYSTEM
AND SAFETY DATA SHEETS

The Globally Harmonized System


(GHS) of Classification and Labeling
of Chemicals includes Safety Data
Sheets (SDS). The GHS is a framework
that standardizes chemical hazard
communication elements and hazard
classification criteria around the
world. SDSs are a vital component of
the GHS and global chemical safety.
SDS
• Standardized 16-part
format
• Manufacturer
provides SDS
• Must have SDS for all
chemicals on-site
CHEMICAL MANAGEMENT
BEST PRACTICES
 Label all chemical containers
 Store in appropriate containers and temperatures
 Develop and update chemical inventories
 Good housekeeping – reduce hazardous waste
 Develop emergency response and spill clean-up plan
 Train personnel
 Purchase environmentally preferable products
 Purchase only amounts that can be reasonably expected
to be used up before expiration
WASTE MANAGEMENT THROUGH
CHEMICAL INVENTORY
Inventory Reduced risk and cost due to
Management reduced inventory and waste
generation

Sharing chemicals across


Efficient Use departments reduces purchasing
quantities and costs

Timely Collection Reduced storage and disposal costs


and Disposal due to minimized on-site chemical
quantities

Adequate
Monitoring and Reduced risk and potential errors by
Inspections improving information tracking
CHEMICAL MANAGEMENT
INVENTORY EXAMPLE
HAZMAT
TRANSPORTATION
HAZMAT TRANSPORTATION
• Governed by DOT
• 49 CFR 100-185
• Applicable to schools?
1. If a school has unused and unneeded hazardous materials,
which are still usable, and offers to give it to another user
(different school, other government entity, off-site tribal
entity), the school could be offering for shipment.
2. All hazardous waste shipments are hazmat shipments.

Note: 49 CFR encompasses many requirements, including


“function-specific” training, and it is not the intent of this
training session to cover those requirements.
HAZMAT TRANSPORTATION
• To offer shipment, DOT HazMat
Shipper Certification is required by
49 CFR 172.704 (Subpart H)
HAZARDOUS WASTE OPERATIONS
AND EMERGENCY RESPONSE
WHAT IS HAZWOPER?
HAZWOPER: Hazardous Waste Operations and Emergency Response. Aims to
prevent and minimize the risk of injury and illness from exposure to
hazardous substances.

OSHA 29 CFR 1910.120

Includes requirements for employers to follow specific work policies,


practices, and procedures to protect workers potentially exposed to
hazardous substances during responses to emergencies involving
releases of those substances.
HAZWOPER TRAINING LEVELS

There are 5 levels to HAZWOPER:


1. First Responder Awareness Level
2. First Responder Operations Level
3. Hazardous Materials Technician
4. Technician with Specialties
5. On-Scene Incident Commander
WHAT IS EMERGENCY RESPONSE?
Emergency response or responding to emergencies means a response
effort by employees from outside the immediate release area or by
other designated responders (i.e., mutual-aid groups, local fire
departments, etc.) to an occurrence which results, or is likely to result,
in an uncontrolled release of a hazardous substance.
Responses to incidental releases of hazardous substances where the
substance can be absorbed, neutralized, or otherwise controlled at the
time of release by employees in the immediate release area, or by
maintenance personnel are not considered to be emergency responses
within the scope of this standard.
Responses to releases of hazardous substances where there is no
potential safety or health hazard (i.e., fire, explosion, or chemical
exposure) are not considered to be emergency responses.
WHAT IS EMERGENCY RESPONSE?
For actual emergencies, first responders at the awareness level are
individuals who are likely to witness or discover a hazardous substance
release and who have been trained to initiate an emergency response
sequence by notifying the proper authorities of the release.
They would take no further action beyond notifying the authorities of
the release.
HAZWOPER
AWARENESS LEVEL
WHAT IS A HAZARDOUS SUBSTANCE?
Any substance that can
impact or threaten human
health or the environment
when released or spilled
based on its quantity,
concentration, or location.
UNDERSTANDING AND RECOGNIZING
HAZARDOUS SUBSTANCES
GHS
Identifying hazardous substances
is important for safety
management in the workplace.
It can help prevent accidents,
comply with safety regulations,
and promote a safety culture.

DOT
NFPA
HAZARDS OF HAZARDOUS
MATERIALS/SUBSTANCES

Routes of entry:
• Inhalation*
• Ingestion
• Absorption
• Injection
PHYSICAL HAZARDS
Types of physical hazards associated with hazardous materials:

Flammability Corrosivity
Explosivity Toxicity
Reactivity Asphyxiation
Pressure hazards Physical state changes
HEALTH HAZARDS
Types of Health Hazards associated with hazardous materials:

Acute/chronic toxicity Germ cell mutagenicity


Skin corrosion or irritation Carcinogenicity
Aspiration hazard Reproductive toxicity
Serious eye damage Specific target organ toxicity
or eye irritation
Neurotoxicity
Respiratory or
skin sensitization
AWARENESS LEVEL RESPONDER
COMPETENCIES
Awareness level responders:
• Understanding what hazardous substances are, and risks
associated with them in an incident
• Understand potential outcomes associated with an emergency
with hazardous substances present
• Ability to recognize the presence of hazardous substances in
an emergency
• Ability to identify the hazardous substances, if possible
• Understand their role in the school’s emergency response
plan, including site security and control
• Ability to realize the need for additional resources, and to
make appropriate notifications to proper authorities.
They are not expected to take any further action beyond notifying
the proper authorities.
NOTIFICATIONS

Internal External
• Radios • 911
• Sirens • Site/Program
• Bells Management
• Lights • Regulatory
Agencies
• Flags
• Hand Signals
• Flares
DISCERNING IF ADDITIONAL
RESOURCES ARE NEEDED

Additional resources may be needed for hazardous materials incidents. This


includes: 911, specialist resources, medical support, transportation.

• Identify the materials involved


• Determine the risk or hazard (physical, health, environment) posed by the
spill or leak
• Isolate the area
• Provide/request first aid, as needed
WHAT IS HAZARDOUS WASTE?
• “Waste” means a solid, liquid, or contained gaseous material that is being
discarded or recycled.
• “Hazardous waste” if it has certain characteristics:
o Ignitable (alcohol-based hand sanitizer, waste fuels)
o Corrosive (acid drain cleaner, alkaline floor stripper)
o Reactive (possibly some chemistry lab materials?)
o Toxic (contains metals / chemicals that can leach out)
• Some chemicals are specifically listed by U.S. EPA
o Much less common for schools to generate these
• Expired chemicals are a common type of hazardous waste generated by
schools
CONCLUSION
Hazardous Materials / Hazardous Waste Operations and Emergency Response
(HAZWOPER) Awareness goals are to:

• Prevent and minimize the possibility of worker injury and illness resulting
from potential exposures to hazardous substances
• Provide first responder awareness level information to staff
• Help staff provide effective communication to the workers,
emergency responders, and the general public of the hazards of the materials
present at the Site
RESOURCES
BIE Branch of Safety Management Hazard Communication Safety Program
- Contact your school’s assigned safety officer for more information

OSHA Hazard Communication Standard


1910.1200 - Hazard Communication. | Occupational Safety and Health Administration (osha.gov)

HAZWOPER
Hazardous Waste Operations and Emergency Response (HAZWOPER) - Overview | Occupational Safety and Health
Administration (osha.gov)

DOT Is It Hazmat?
Check the Box: Is it Hazmat? | US Department of Transportation
QUESTIONS?
BIE BEM PROGRAM CONTACTS

Harold John Clymo


Program Manager, Supervisory Environmental Protection Specialist
Albuquerque Office
[email protected]

Candace DeSantis Doug Yocum


Lead Environmental Environmental Protection
Protection Specialist Specialist
Contracting Officer’s Hazardous Materials Lead
Representative
Bloomington Office
Albuquerque Office
[email protected]
[email protected]

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