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    Amines Chemistry class 12

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    Amines Chemistry class 12

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    Amines Chemistry class 12

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    © All Rights Reserved
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    of 3

    Class 12

    Subject Chemistry
    Important questions of Amines

    Topic: introduction, methods of preparation and physical properties ( including basic


    character of amines)
    5 marks questions

    1. Account for the following.

    (a) N-ethylbenzene sulphonyl amide is soluble in alkali.

    (b) reduction of nitro benzene using Fe and HCl is preferred over Sn and HCI

    2. Arrange the following in.


    (a) decreasing order of pkb value
    C6H5NH2, C6H5NHCH3, C6H5CH2NH2, CH3NH2, NH3
    (b) increasing order of solubility in water
    C2H5Cl, C2H5NH2, C2H5OH
    (c) decreasing boiling point
    CH3COOH, C2H5OH, CH3NH2,CH3OCH3

    3 marks questions

    1. Arrange the following in increasing order of property speci ed.

    (i) Aniline, ethanamine, 3-ethylethanamine (solubility in water

    (ii) Ethanoic acid, ethanamine, ethanol (boiling point).

    (iii) Methanamine, N, N- dimethylmethanamine and N-methylmethanamine (basic strength in


    aqueous phase).

    2. State reasons for the following.

    (i) pkb value for aniline is more than that of methylamine.

    (ii) Ethylamine is soluble in water, whereas aniline is not soluble in water.


    (iii) Primary amines have higher boiling points, then tertiary amines

    2 Marks questions

    1. Arrange the following compounds in an increasing order of basic strength.


    C6H5NH2, C6H5N( CH3)2, (C2H5)2NH and CH3NH2
    2. Arrange the following compounds in a decreasing order of PKb values.
    C2H5NH2, C6H5NHCH3, (C2H5)2NH and C6H5NH2
    2. Give reasons.
    1) and line is a weaker base than cyclohexyl amine.
    3. Write equations for.
    1) Gabriel pthalimide reaction
    2) Hofmann bromide reaction

    1 Marks questions

    1. Which of the two is more basic and why?


    4 methyl aniline or aniline

    2. propanamine and N N di methyl methanamine contain the same number of carbon atoms,
    even though N , N dimethylmethanamine. Why ?
    fi
    3. Write IUPAC name of the following compound.
    (CH3)2N.CH2CH3, CH3NH(CH3)2

    Topic 2 : Chemical reactions of amines and diazonium salt

    1 mark questions

    1. Write one reaction that can be used as a test for primary amines.
    2. Give a chemical test to distinguish between ethyl amine and aniline
    3. Why electrophilic substitution take place more readily in aromatic amine than benzene?
    4. How is the following conversion carried out ?
    Aniline to para hydroxyazobenjene

    2 mark questions

    Carried out the following conversion.


    1. Nitrobenzene.To anline.
    2. Aniline to phenol
    3. Nitrobenzene to phenol
    4. Aniline to chlorobenzene
    5. Methyl amine to iodomethane
    6. Chlorobenzene to p cholro aniline

    2. Draw the zwitter iron structure for. Sulphanilic acid


    3. How can the activation e ect of NH2 group in aniline be controlled?

    3 Marks questions
    *Learn all naming reaction*
    1. Complete the following reaction
    ff

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